• Title/Summary/Keyword: metal ion effect

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Antioxidant Effects and Application as Natural Ingredients of Korean Sanguisorbae officinalis L. (한국산 지유(地楡)(Sanguisorbae officinalis L.)의 항산화 효과 및 천연소재로서의 활용방안)

  • Lee, Jin-Tae;Lee, Soon-Ae;Kwak, Jae-Hoon;Park, Jung-Mi;Lee, Jin-Young;Son, Jun-Ho;An, Bong-Jeun
    • Applied Biological Chemistry
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    • v.47 no.2
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    • pp.244-250
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    • 2004
  • Biological activities and application of Sanguisorbae officinalis L. were investigated. In the enzymological physiological activities, the electron donating ability (EDA) was 54.9% in 10 ppm and it was over 90% over 50 ppm and SOD-like activity was high as 65.4% in 1000 ppm, it was gradual increased. As inhibitory effect of xanthine oxidase, it was 17.9% in 200 ppm and little low as 36.9% in 500 ppm and inhibitory effect of tyrosinase. As the result of measuring the lipid oxidation, all the concentrations of medical ion treatments had the ability to keep it from acidification and metal ion blocking effects about the lipid oxidation promoting factors ($Fe^{2+}$ and $Cu^{2+}$), $Fe^{2+}$ was better than $Cu^{2+}$ and all concentrations of medical ion treatments was 40% in 50 ppm. When it was applied into normal skin-softener it showed safe effect so that we can expect that as the natural material of cosmetics.

The Gettering Effect of Boron Doped n-type Monocrystalline Silicon Wafer by In-situ Wet and Dry Oxidation

  • Jo, Yeong-Jun;Yun, Ji-Su;Jang, Hyo-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.429-429
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    • 2012
  • To investigate the gettering effect of B-doped n-type monocrystalline silicon wafer, we made the p-n junction by diffusing boron into n-type monocrystalline Si substrate and then oxidized the boron doped n-type monocrystalline silicon wafer by in-situ wet and dry oxidation. After oxidation, the minority carrier lifetime was measured by using microwave photoconductance and the sheet resistance by 4-point probe, respectively. The junction depth was analyzed by Secondary Ion Mass Spectrometry (SIMS). Boron diffusion reduced the metal impurities in the bulk of silicon wafer and increased the minority carrier lifetime. In the case of wet oxidation, the sheet resistance value of ${\sim}46{\Omega}/{\Box}$ was obtained at $900^{\circ}C$, depostion time 50 min, and drive-in time 10 min. Uniformity was ~7% at $925^{\circ}C$, deposition time 30 min, and drive-in time 10 min. Finally, the minority carrier lifetime was shown to be increased from $3.3{\mu}s$ for bare wafer to $21.6{\mu}s$ for $900^{\circ}C$, deposition 40 min, and drive-in 10 min condition. In the case of dry oxidation, for the condition of 50 min deposition, 10 min drive-in, and O2 flow of 2000 SCCM, the minority carrier lifetime of 16.3us, the sheet resistance of ${\sim}48{\Omega}/{\Box}$, and uniformity of 2% were measured.

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Colour Change of Black-dyed PET Fabrics by Sputter Coloration and Their Physical Properties (Sputter 착색에 의한 Black-dyed PET 직물의 색상 및 물성변화)

  • Koo, Kang;Won, Eun-Hee;Park, Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.4
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    • pp.11-19
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    • 2006
  • Black-dyed PET fabrics were sputtered with stainless steel through DC-magnetron type device to investigate the possibility of coloration effect, and then considered the morphological structure and physical characteristics such as water permeation ability and washing fastness. Change in color was estimated on the basis of CIELAB color system. The color coordination of metal plated PET was shifted to yellow-red from red-blue. Colour difference$({\Delta}E^*)$ was increased by sputtering conditions with increasing ion current and treatment time. Especially, $Lightness(L^*)$ value of PET was remarkably increased by sputtering, whereas $Chroma(C^*)$ increased gradually. From SEM analysis, rough and uneven craters were found and thickened on the fiber surfaces with longer sputtering time. And washing fastness was a little poor and absorption ability slightly decreased. There were little changes of breaking load and breaking extension. It was evident that observed uneven craters in the plated thin layer resulted in the colour change of PET fabrics by sputtering treatments.

Antioxidant Activity of Extract from Scutellaria baicalensis Georgi (황금 열수추출물의 항산화 작용에 대한 연구)

  • 이문조;오정석;박진우;김준기;최달영;김철호
    • Journal of Life Science
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    • v.10 no.3
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    • pp.236-240
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    • 2000
  • The purpose of this study was to investigate the antioxidant activity of the water extract from Scutellaria baicalensis Georgi. using linoleic acid as lipids. The extract exhibited antioxidative effect at all concentrations tested. With metal ion(Fe3+) present, the extract showed strong antioxidative effect. These result indicated that the extract can be used for antioxidative agents in oriental medicine.

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Purification and Characterization of an Extracellular Protease from Bacillus pumilus CN8

  • Jin, Yong-Guo;Li, Hao-Li;Mal, Mei-Hu;Wang, Jun;Kim, Ha-Na;Oh, Deog-Hwan
    • Journal of Food Hygiene and Safety
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    • v.26 no.1
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    • pp.76-81
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    • 2011
  • The protease produced by a Bacillus pumilus CN8 strain was purified by DEAE-Cellulose-52 ion exchange. It has a molecular weight of approximately 96,920 Dalton. In the present study, this protease showed strong activity over a broad range of pH (6.5-9.5) and temperature from $40^{\circ}C$ to $60^{\circ}C$, and the protease performed the maximal activity at pH 7.3 at $42^{\circ}C$. The effect of metal ions on protease activity showed that $K^+$ could slightly increase the protease activity, and other ions such as $Zn^{2+}$, $Fe^{2+}$, $Na^+$, $Ca^{2+}$, $Mg^{2+}$ had no significant activation or inhibition to the protease (P> 0.05), and the more important is that $Cu^{2+}$, $Mn^{2+}$, $Sn^{2+}$, $Cd^{2+}$ had a strong inhibitory effect on the protease activity.

Combustion Synthesis of $LiMn_2$$O_4$with Citric Acid and the Effect of Post-heat Treatment

  • Han, Yi-Sup;Son, Jong-Tea;Kim, Ho-Gi;Jung, Hun-Teak
    • Journal of the Korean Ceramic Society
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    • v.38 no.4
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    • pp.307-307
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    • 2001
  • Combustion process with citrate was used to produce the LiMn$_2$O$_4$powder. Precursors are pre-ignited in open air followed by post-heating in the range from $600^{\circ}C$ to 80$0^{\circ}C$ for 4h. With varying the molar ratio (R) of ethylene glycol (EG) to citric acid (CA) from 0 to 4, the effect of EG content on powder characteristics is evaluated. Vacuum drying promote the auto-ignition at room temperature. With small addition of EG metal ion was selectively segregated with organic substances and undesired lithium evaporation occurred during post-heating. LiMn$_2$O$_4$phase which is produced by combustion reaction was decomposed back to Mn$_3$O$_4$because the reaction temperature was higher than 95$0^{\circ}C$. With increasing EG content, the homogeneity of LiMn$_2$O$_4$powder increased and specific surface area increased. And lithium evaporation during vacuum drying and/or ignition also increased.

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Recent Trend of Ultra-Pure Water Producing Equipment

  • Motomura, Yoshito
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.121-147
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    • 1996
  • Since 1980, the water quality of ultra-pure water has been rapidly improved, and presently ultra-pore water producing equipment for 64Mbit is in operation. Table 1 shows the degree of integration of DRM and required water quality exlmple. The requirements of the ultra-pure water for 64Mbit are resistivity: 18.2 MQ/cm or higher, number of particulates: 1 pc/ml or less (0.05 $\mu$m or larger). bacteria count: 0.1 pc/l or less. TOC (Total Organic Carbon, index of organic snbstance) : 1ppb or less, dissolved oxygen: 5ppb or less, silica: 0.5ppb or less, heavy metal ions: 5ppb or less. The effect of metals on the silicon wafer has been well known, and recently it has been reported that the existence of organic substance in ultra-pure water is closely related to the device defect, drawing attention. It is reported that if organic substance sticks to the natural oxidation film, the oxide film remaims on the organic substance attachment in the hydrofluoric acid treatment (removal of natural oxidation film). The organic substance forms film on the silicon wafer, and harmful elements such as metals and N.P.S., components contained in the organic substance and the bad effect due to the generatinn of silicon carbide cannot be forgotten. In order to remove various impurities in raw water, many technological develoments (membrane, ion exchange, TOC removal, piping material, microanalysis, etc.) have been made with ultra-pure water producing equipment and put to practical use. In this paper, technologies put to practical use in recent ultra-pure vater producing equimeut are introduced.

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The Characterization of Anthocyanin Pigments Prepared from Cherry (Prunus serrulata L. var. spontanea Max. Wils.) for the Potential Sources of Red Colorant (적색 색소자원으로서의 버찌(Prunus serrulata L. var. spontanea Max. Wils.) anthocyanin 색소의 특성)

  • Kim, Yong-Hwan
    • Applied Biological Chemistry
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    • v.42 no.2
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    • pp.134-139
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    • 1999
  • The characteristics of anthocyanin pigments extracted from cherry(Prunus serrulata L. var. spontanea Max. Wils.) were investigated at the various conditions, such as light, temperature, organic acid, metal ion and pH. The pigments were fairly stable under the sunlight during the 20 days storage period at room temperature. The pigments covered with the Al-foil, as well as red, blue, green and yellow films, were very stable at pH 2.5. The high thermal stability (over the 64% at $115^{\circ}C$, 30 min) of the pigments in the dark at pH 2.5 was also found. In the presence of organic acid, the hyperchromic effect of red color was greatly increased in the dark at $25^{\circ}C$. Addition of metal ion, such as $Na^+,\;K^+,\;Mg^{2+},\;Ca^{2+}\;and\;Mn^{2+}$, was contributed on the stability in color at pH 2.5 throughout 20 days storage period in the dark at $25^{\circ}C$. However, $Cu^{2+}\;and\;Fe^{3+}$ caused the rapidly degradation of pigments, and $Al^{3+}$ converted red color to blueish violet. The hyperchromic effect of the red color increased, as pH decreased. Therefore, these results indicated that cherry anthocyanin pigments might be used as the potential sources of natural red colorant for foods.

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Effect of the Water Quality on the Variation of Ascorbic Acid Content during Yulmoo Mul-kimchi Fermentation (담금수의 수질이 열무 물김치의 비타민 C 함량에 미치는 영향)

  • Kim, Yoo-Jin;Oh, Ji-Young;Lee, Tae-Young;Hahn, Young-Sook
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.175-183
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    • 1998
  • Yulmoo Mul-kimchi was prepared by fermentation of the mixture of 1 part of leafy radish and 2.75 parts of water. It is thought that during the kimchi fermentation both the biosynthesis and destruction of ascorbic acid occurred at the same time. So the ascorbic acid content in Kimchi broth was strongly influenced by the environment of the processing period. In the present studies, an attempt had been made to elucidate the effect of water quality on the content of ascorbic acid and the population change of microorganism during Mul-kimchi fermentation. Five kinds of water such as tap water, an underground water, one commercially available processed water, distilled water and triply distilled water were examined. Nevertheless there were no differences in the population of microorganism and the pattern of acid formation among the five different kind of waters, a large variation of ascorbic acid content was observed. The ascorbic acid content of Kimchi prepared with triply distilled water showed the highest of 7.2 mg% in contrast to 3.37 mg% in tap water kimchi, and 5.72 mg% in the kimchi using underground water which has relatively high concentration of Ca. These results suggested that pure water free of metal ions might prevent the destruction of ascorbic acid during the fermentation. The considerable amount of ascorbic acid in the Kimchi with underground water might be due to Ca ion in the water.

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The Effect of Pd Coating on Electron Emission from Silicon Field Emitter Arrays (Pd 코팅이 실리콘 전계 방출 어레이의 전자 방출에 미치는 영향)

  • Lee, Jong-Ram;O, Sang-Pyo;Han, Sang-Yun;Gang, Seung-Ryeol;Lee, Jin-Ho;Jo, Gyeong-Ik
    • Korean Journal of Materials Research
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    • v.10 no.4
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    • pp.295-300
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    • 2000
  • Uniform silicon tip arrays were fabricated using the reactive ion etching followed by the reoxidation sharpening, and the effect of Pd-coated layer on electron emission characteristics was studied. The electron emission from Si field emitter arrays(FEAs) was a little, but improved by removing surface oxide on the FEA, but pronounced drastically by coating a $100-{\AA}-thick$ Pd metal layer. The turn-on voltage in the Pd-coated Si FEAs was reduced by 30 V in comparison with that in uncoated ones. This results from the increase of surface roughness at the tip apex by the Pd coating on Si FEA, via the decrease of the apex radius at which electrons are emitting. The Pd-coated emitters showed superior operating stability over a wide current range to that of the uncoated ones. This suggests that Pd coating enhances the high temperature stability and the surface inertness Si FEA.

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