• 제목/요약/키워드: metal corrosion

검색결과 1,069건 처리시간 0.024초

용사코팅층의 분극특성 (Polarization Characteristics of Thermal Sprayed Coating Layer)

  • 안석환;김선진;김영식
    • 동력기계공학회지
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    • 제8권4호
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    • pp.38-43
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    • 2004
  • Thermal spraying onto the metal substrate has been widely used as a technique of the surface treatment in the various industrial field. A wide range of thermal spray technologies exist and all rely on the fundamental process of fusing a metal feedstock, atomizing it and transporting it to the surface of a substrate. Specially, these methods have been taken into account as the protection method against the corrosion. In this study, the polarization characteristics were carried out on the thermal sprayed coating layer immersed in various pH of diluted aqueous solutions at $25^{\circ}C$. Aluminum, Zinc, Ni-base alloy, alumina and polyethylene powder were used with sprayed coating materials. From the polarization curves, the electrochemical corrosion potential($E_{corr}$) and the corrosion current density($I_{corr}$) were investigated.

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Corrosion Behavior of Arc Weld and Friction Stir Weld in Al 6061-T6 Alloys

  • Yoon, Byoung-Hyun;Kim, Heung-Ju;Chang, Woong-Seong;Kweon, Young-Gak
    • Corrosion Science and Technology
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    • 제5권6호
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    • pp.196-200
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    • 2006
  • For the evaluation of corrosion resistance of Al 6061-T6 alloy, Tafel method and immersion test was performed with Friction Stir Weld(FSW) and Gas Metal Arc Weld(GMAW). The Tafel and immersion test results indicated that GMA weld was severely attacked compared with those of friction stir weld. It may be mainly due to the galvanic corrosion mechanism act on the GMA weld.

Effect of Hydrodynamic Condition on the Electrochemical Behavior of Various Metals in 3.5 wt% NaCl Solution

  • Pan, Szu-Jung;Hadinata, Samuel-Sudibyo;Kao, Ruey-Chy;Tsai, Wen-Ta
    • Corrosion Science and Technology
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    • 제14권5호
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    • pp.218-225
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    • 2015
  • The electrochemical behaviors of various metals with and without diamond-like-carbon (DLC) coating in 3.5 wt% NaCl solution were investigated. The effect of hydrodynamic conditions was focused by employing a rotating disc electrode (RDE). The experimental results showed that each bare metal had a more positive corrosion potential and a higher corrosion rate due to enhanced oxygen transport at the higher rotating speed of the RDE. DLC coating caused a substantial increase in the corrosion resistance of all metals studied. However, localized corrosion was still found in the DLC-coated metal at sites where deposition defects existed. Surface morphology examination was performed after the electrochemical test to confirm the roles of hydrodynamic conditions and DLC coating.

Al 합금막의 식각후 $CHF_3$ 처리에 의한 부식억제 효과 (The Effect of the Anti-corrosion by$CHF_3$ Treatment after Plasma Etching of Al Alloy Films)

  • 김창일;권광호;윤용선;백규하;남기수;장의구
    • 한국전기전자재료학회논문지
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    • 제11권7호
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    • pp.517-521
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    • 1998
  • After etching Al-Cu alloy films using $SiCl_4/Cl_2/He/CHF_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS(X-ray pheotoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, $CHF_3$ plasma treatment subsequent to the etch has been carried put. A passivation layer is formed by fluorine-related compounds on the etched Al-Cu surface after $CHF_3$ treatment, and the layer suppresses effectively the corrosion on the surface as the $CHF_3$treatment in the pressure of 300m Torr.

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탄소강관에서의 인산염 부식억제제농도 감소의 반응속도상수 평가 (Adsorption rate of Phosphate Corrosion Inhibitor in Carbon Steel pipe)

  • 우달식;황병기
    • 환경영향평가
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    • 제14권1호
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    • pp.17-24
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    • 2005
  • This study was performed to evaluate the adsorption rate of phosphate corrosion inhibitor and reaction rate constant in drinking water distribution systems. The optimum concentration of corrosion inhibitor would vary depending on the quality of water, pipe materials, and condition of metal surfaces. The current adsorption study indicated that the residual phosphate concentration of the corrosion inhibitor decreased with the time as it adsorbed on the surface of pipe material. As time went by, the residual phosphate concentration became constant. It means that the formation of the corrosion protection film on metal surfaces is completed.

3.5 wt.% NaCl로 오염된 콘크리트 기공 용액에서 아크 용사 Al 및 Al/에폭시 이중 금속 고분자 코팅의 내식성 성능 (Corrosion resistance performance of arc thermal sprayed Al and Al/epoxy dual metal polymeric coating in 3.5 wt.% NaCl-contaminated concrete pore solution)

  • 지텐드라 쿠마 싱;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.119-120
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    • 2023
  • Corrosion of the steel rebar in coastal environment caused huge economical loss of the globe. Therefore, coating on the steel rebar being used to mitigate the corrosion. In the present study, we have applied epoxy coating on arc thermal sprayed Al coating (a dual metal/polymeric coating) vis-à-vis compared with as coated one (Al coating). The corrosion studies were performed in simulated concrete pore solution with 3.5 wt. % NaCl solution. The morphology of the dual epoxy/Al coating is smooth while Al coating shows rankle and defects. Due to defects, Al coating is susceptible to corrosion while dual epoxy/Al coating has performed excellent compared to as coated one at extended period of immersion.

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Effect of Induction Heat Bending Process on the Properties of ASME SA106 Gr. C Carbon Steel Pipes

  • Kim, Ki Tae;Kim, Young Sik;Chang, Hyun Young;Oh, Young Jin;Sung, Gi Ho
    • Corrosion Science and Technology
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    • 제14권2호
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    • pp.47-53
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    • 2015
  • Recently, the bending process is greatly applied to fabricate the pipe line. Bending process can reduce welding joints and then decrease the number of inspection. Thus, the maintenance cost will be reduced. Induction heat bending process is composed of bending deformation by repeated local heat and cooling. By this thermal process, corrosion properties and microstructure can be affected. This work focused on the effect of induction heating bending process on the properties of ASME SA106 Gr. C low carbon steel pipes. Microstructure analysis, hardness measurements, and immersion corrosion test were performed for base metal and bended area including extrados, intrados, crown up, and down parts. Microstructure was analyzed using an optical microscope and SEM. Hardness was measured using a Rockwell B scale. Induction heat bending process has influenced upon the size and distribution of ferrite and pearlite phases which were transformed into finer structure than those of base metal. Even though the fine microstructure, every bent area showed a little lower hardness than that of base metal. It is considered that softening by the bending process may be arisen. Except of I2, intrados area, the others showed a similar corrosion rate to that of base metal. But even relatively high rate of intrados area was very low and acceptable. Therefore, it is judged that induction heat bending process didn't affect boric acid corrosion behaviour of carbon steel.

저온 PEMFC용 금속분리판 코팅의 내구 특성 연구 (Coating Durability of Metal Bipolar plate for Low Temperature PEMFC)

  • 강성진;전유택
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.82.2-82.2
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    • 2010
  • The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

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침부식에 의한 CANDU형 원전 2차측 배관의 감육 예측에 관한 연구 (A Study on Prediction of Metal Loss by Flow-Accelerated Corrosion in the CANDU NPP Secondary Piping Systems)

  • 심상훈;송정수;윤기봉;황경모;진태은;이성호;김위수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.616-621
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    • 2001
  • Flow-accelerated corrosion(FAC) is a phenomenon that results in metal loss from piping, vessels, and equipment made of carbon steel. FAC occurs only under certain conditions of flow, chemistry, geometry, and material. Unfortunately, those conditions are in much of the high-energy piping in nuclear and fossil-fueled power plants. Also, for domestic NPP secondary pipings whose operating time become longer, more evidences of FAC have been reported. The authors are studying on FAC management using CHECWORKS, computer code developed by EPRI. This paper is on the prediction results of metal loss by FAC in the one of CANDU type NPP secondary piping systems.

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OPTIMIZATION OF VARIABLES AFFECTING CORROSION RESISTANCE OF VACUUM SINTERED STAINLESS STEELS

  • Klar, Erhard;Samal, Prasan
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 1995년도 추계학술강연 및 발표대회 강연 및 발표논문 초록집
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    • pp.9-9
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    • 1995
  • MATERIAL AND PROCESS VARIABLES THAT STRONGLY AFFECT THE CORROSION RESISTANCE OF PA4 STAINLESS STEELS, INCLUDE : ALLOY COMPOSITION, POWDER CLEANLINESS, NITROGEN, OXYGEN AND GARBON CONTENTS, CHROMIUM DEPLETION DUE TO SURFACE EVAPORATION AND SINTERED DENSITY. THE OPTIMUM PROCESS PARAMETERS FOR DELUBRICATION AND SINTERING THAT RESULT IN LOWEST LEVELS OF NITROGEN, OXYGEN AND CARBON AND MINIMUM LEVELS OF CHROMIUM DEPLETION WILL BE PRESENTED, FOR A NUMBER OF AUSTENTIC AND FERRITIC STAINLESS STEELS. THE EFFECT OF SINTERED DENSITY ON THE CORROSION RESISTANCE OF BOTH AUSTENITIC AND FERRITIC GRADES OF STAINLESS STEEL WILL ALSO BE COVERED.

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