• 한국지하수토양환경학회지:지하수토양환경
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• 제20권2호
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• pp.22-31
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• 2015

In the present study, surface of laccase producing Ceriporia lacerata was modified using 4-bromobutyryl chloride and polyethylenimine. The modified biomass was freeze dried and utilized as a biosorbent for the removal of Ni(II) from aqueous solution. The physicochemical properties of the biosorbent were analyzed using scanning electron microscopy and Fourier transform infrared spectroscopy. Batch experiments were carried out as a function of contact time (0-60 min), pH (2 to 8), adsorbent dosage (25-150 mg), and initial Ni(II) concentration (25-125 mg/L). The results indicate that surface modified biosorbent effectively adsorbed (9.5 mg/0.1 g biomass) Ni(II) present in the solution. The equilibrium adsorption data were modeled with different kinetic and isotherm models. The Ni(II) adsorption followed pseudo-first-order kinetics (R² = 0.998) and Langmuir isotherm (R² = 0.994) model. Hydroxyl and carbonyl functional groups present in biomass play a major role in the adsorption of Ni(II). The adsorbed Ni(II) from the biosorbent was successfully desorbed (85%) by 1M HCl. The results of the study indicate that the surface modified C. lacerate biomass could be used for the treatment of Ni(II) contaminated ground waters.

• 폴리머
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• 제29권1호
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• pp.96-101
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• 2005

PTFE 및 PFA 등의 불소수지는 최대 연속 사용 온도가 260$^{\circ}C$에 달하는 고온 내열성 고분자 소재로서, 본 연구에서 수행된 280 $^{\circ}C$, 7주 간의 열노화에 의해서도 충분한 열적 안정성이 유지됨을 관측하였다. 그러나 기계적 강도, 융점 및 열분해 개시 온도 등의 소재적 물성이 유지됨을 의미하는 상기한 열적 안정성은 본 연구에서 수행된 코팅막으로서의 표면접촉각, 미세 모폴로지, 내스크래치성 분석에 의한 방법을 기준하면 충분하지 못하다는 것이 확인 되었다. 공기 치환율이 제어되는 기어식 노화시험기로 진행된 불소수지 코팅막의 280 $^{\circ}C$ 열노화에 대한 분석의 결과는 심각한 표면 모폴로지의 손상과 금속기재에 대한 접착력의 손실을 지적하고 있다.

• 폴리머
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• 제24권3호
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• pp.382-388
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• 2000

이온전도도가 높으며 균일하고 또 기계적 강도와 전기화학적 안정성이 우수한 전해질막을 얻기 위하여 poly(vinylidenefluoride-hexafluoropropylene) (PVdF-HFP) 공중합체를 전해질의 지지체로 선택하고, LiClO$_4$ 염이 포함된 ethylene carbonate (EC)와 ${\gamma}$-butyrolactone (GBL)의 흔합용매를 사용하여 겔-전해질을 제조하였다. 다양한 조성의 겔-전해질에 대하여 이온전도도, 열분석 및 선형주사전위 실험을 수행하였다. 이온전도도는 30PVdF-HFP+7.8LiClO$_4$+62.2EC/GBL 전해질막에서 3.8$\times$$10^{-3}$ S$cm^{-1}$ /로 가장 높았다. 열분석 결과에서 대부분의 시료는 대략 10$0^{\circ}C$ 정도까지는 안정하였으며, 특히 염은 고분자 사슬과 민감하게 반응하여 PVdF 결정질의 고온용융점을 낮추는 건을 확인하였다. 리튬 금속과 전해질 사이의 부식에 의해 생성된 부동태막에 의해 계면저항이 시간에 따라 계속적으로 증가하는 것을 확인하였으며, anodic stability는 대략 4.5 V vs. Li까지 안정한 것으로 측정되었다.

• 소성∙가공
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• 제29권6호
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• pp.331-337
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• 2020

Blind rivet nuts (BRNs) are increasingly used in automotive industry because unlike conventional bolt fastening, BRN fastening requires access from one side only. Generally, fastening is conducted using automated units, but manual fastening may be resorted to in case of small quantities. Since the fastening direction is not exactly perpendicular to the sheet metal, the BRN axis is tilted with respect to the plate and may result in damage or incomplete fastening. As the tilt angle (clamping angle α) increases, undesired plate deformation occurs and the contact area of the plate with the BRN fastening area decreases, reducing the clamping effect. In this study, the reduction of the clamping effect with the α was investigated to ensure stable fastening force. M6 BRNs were used in the tests. The fastening force was measured as follows: the plate was cut in half through the center of the hole; the BRN was inserted into the hole and fastened; and the clamping angle a was measured (values, 0° ≤ α ≤ 9°). The force leading to the separation of the halves was measured using a universal testing machine (UTM). The maximum α range, in which the fastening force remains stable, was determined. Finite element (FE) analysis confirmed that the fastening force decreases approximately linearly with increasing α. Based on the experiment and FE analysis using various α, the fastening force was found to decrease with α. Further, the maximum tolerance for α that provides secure fastening without damage is suggested.

• 한국재료학회지
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• 제22권10호
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• pp.552-561
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• 2012

Diamond-like carbon (DLC) films have been widely used in many industrial applications because of their outstanding mechanical and chemical properties like hardness, wear resistance, lubricous property, chemical stability, and uniformity of deposition. Also, DLC films coated on paper, polymer, and metal substrates have been extensively used. In this work, in order to improve the printing quality and plate wear of polymer printing plates, different deposition conditions were used for depositing DLC on the polymer printing plates using the Pulsed DC PECVD method. The deposition temperature of the DLC films was under $100^{\circ}C$, in order to prevent the deformation of the polymer plates. The properties of each DLC coating on the polymer concave printing plate were analyzed by measuring properties such as the roughness, surface morphology, chemical bonding, hardness, plate wear resistance, contact angle, and printing quality of DLC films. From the results of the analysis of the properties of each of the different DLC deposition conditions, the deposition conditions of DLC + F and DLC + Si + F were found to have been successful at improving the printing quality and plate wear of polymer printing plates because the properties were improved compared to those of polymer concave printing plates.

• 비파괴검사학회지
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• 제21권1호
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• pp.46-53
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• 2001

음향방출 신호를 이용하여 분류기를 설계하는 과정에서의 특징값 선택법에 관해 연구하였다. 분류기는 역전파법을 이용한 신경망 분류기를 사용하였다. Fisher's criterion, class mean scatter criterion, eigenvector analysis와 함께 본 논문에서 새로 제안하는 특징값 공간에서의 특징값 좌표사이의 차이를 이용하는 2-D criterion, 3-D criterion을 이용해서 특징값을 선택하고 각각에 대해 분류기를 설계하여, 인식률과 수렴속도를 비교하였다. 분류를 위한 자료를 얻기 위하여 용접부 결함시편과 로터리 압축기 금속 접촉부 결함시편을 사용하였다. 인식률 면에서 2-D criterion과 3-D criterion이 우수한 결과를 나타내었다.

• 미술이론과 현장
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• 제3호
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• pp.9-34
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• 2005

Contemporary Korean art in the 1960s and the 1970s reflects the social and political contexts in Korea from the 5 16 revolution through the Yoo Shin period. This paper investigates whether art has been free from power or not. It examines the power embedded in contemporary Korean art in the 1960s and the 1970s. This paper examines the historical moments of the Korean Art Exhibition, focusing on the complications between the abstract and figurative artworks of the 1960s. One of the significant art exhibitions since the 8 15 liberation of Korea, the Korean Art Exhibition witnessed conflict among Korean artists who wanted to have power in the art world of Korea. Institutional contradiction based on factionalism and conservatism prevailed in the Korean Art Exhibition was attacked by the avant-garde young artists in the 1960s. With the contact of Abstract Expressionism, young artists' generation participated in the The Wall Exhibition. This exhibition challenged and established moral principles and visualized individual expression and creation similar to the Informal movement in the West. In the world of the traditional painting of Korea, the Mook Lim Exhibition of 1960, organized by young artists of traditional painting, advocated the modernization of Soo Mook paintings. Additionally, abstract sculptures in metal engraving were the new trends in the Korean Art Exhibition. In the 1970s, the economic development and establishment of a dictatorial government made the society stiffen. Abstract expression died out and monochrome painting was the most influential in the 1970s. After the exhibition of Five Korean Artists, Five White Colors in the Tokyo Central Art Museum in 1976, monochrome paintings were formally discussed in Korea. 'Flatness' 'physicality of material' 'action' 'post-image' 'post-subjectivity' and 'oriental spirituality' were the critical terms in mentioning the monochrome paintings of the 1970s. 'Korean beauty' was discussed, focusing on the beauty of white which was addressed by not only Yanagi Muneyoshi but also the policy of national rehabilitation under the Yoo Shin government. At this time, the monochrome paintings of the 1970s in Korea, addressing art for art's sake, cutting of communication with the masses, and elitism, came to be authorized.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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• pp.1158-1161
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• 2004

This paper presents structural characteristics of station class lightning arresters and electrical characteristics of manufactured ZnO varistor blocks which are usable in those arresters. Three types of station class lightning arresters were investigated and those are a ceramic arrester, a FRP tube type polymer arrester, and a FRP rod type polymer arrester. Each arrester has merits and demerits with structural characteristics. In general, polymer arresters were made of silicon rubber for housing materials, FRP tube or rod for mechanical strength, ZnO blocks for electrical characteristics, and metal parts for electrical contact and the silicon rubber, the housing materials, was directly injected to the arrester module which was assembly composed of electrodes, ZnO blocks and FRP tube or rod, and to prevent the nonlinear electric fields distribution on upper parts of arresters, the grade ring was adopted to the upper electrodes. The reference voltage, nonlinear coefficient, residual voltage, and voltage ratio of manufactured ZnO varistors are 4.90kV, 50, 9.54kV, 1.94, respectively. Compared to designed electrical characteristics, the reference voltage was low for 600v and the voltage ratio was slightly high. However, the characteristics of discharge withstand was so excellent that the mechanical destruction does not occur at the impulse current of $8/20{\mu}s$ 10kA for 100 times.

• 대한금속재료학회지
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• 제48권12호
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• pp.1056-1063
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• 2010

We present a new joining method for Pd-Cu membrane foils used as permeation tubes to collect $CO_2$. Since foils have poor mechanical strength, joining should be done at low temperatures to reduce residual stresses and without joining pressure. This contradicts the well known conditions for good contact between base materials that determines joint qualities. We selected Sn-Ag-Cu alloys that are highly reactive with Pd and Cu as a filler metal. As the filler melts at joining temperatures as low as $220{\sim}280^{\circ}C$, Pd and Cu are dissolved into the melt and react with the filler elements, which raises the melting temperature of the filler based on eutectic structures among the elements. Then, isothermal solidification progresses for the rest of the joining time. Intermetallic compounds (IMC) in the joints, one of the main factors for brittle joints, are inevitably formed. However, by optimizing both joining time and temperature, we balanced the wettability with IMC. Sealing test results confirmed that the joints are mechanically reliable during operation.

• 한국기계가공학회지
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• 제17권6호
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• pp.68-74
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• 2018

Study on the Ti-6Al-4V have been carried out using cutting simulation, and researches for cutting force and chip shape prediction have been actively conducted under various conditions. However, a 3D printer application method using Ti-6Al-4V metal powder material as a high-power method has been studied for the purpose of prototyping, mold modification and product modification while lowering material removal rate. However, in the case of products / parts made of 3D printers using powder materials, problems may occur in the contact surface during tolerance management and assembly due to the degradation of the surface quality. As a result, even if a 3D printer is applied, post-processing through cutting is essential for surface quality improvement and tolerance management. In the cutting simulation, the cutting force and the chip shape were predicted based on the Johnson-Cook composition equation, but the shape of the shear type chip was not predictable. To solve this problem, we added a damaging term or strain softening term to the Johnson-Cook constitutive equation to predict chip shape. In this thesis, we applied the constant value of the S-K equations to the cutting simulation to predict the cutting force and compare with the experimental data to verify the validity of the cutting simulation and analyzed the machining characterization by considering conditions.