• 제목/요약/키워드: metal cathode

검색결과 353건 처리시간 0.028초

Li:Al cathode layer and its influence on interfacial energy level and efficiency in polymer-based photovoltaics

  • 박순미;전지혜;박오옥;김정원
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.72-72
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    • 2010
  • Recent development of organic solar cell approaches the level of 8% power conversion efficiency by the introduction of new materials, improved material engineering, and more sophisticated device structures. As for interface engineering, various interlayer materials such as LiF, CaO, NaF, and KF have been utilized between Al electrode and active layer. Those materials lower the work function of cathode and interface barrier, protect the active layer, enhance charge collection efficiency, and induce active layer doping. However, the addition of another step of thin layer deposition could be a little complicated. Thus, on a typical solar cell structure of Al/P3HT:PCBM/PEDOT:PSS/ITO glass, we used Li:Al alloy electrode instead of Al to render a simple process. J-V measurement under dark and light illumination on the polymer solar cell using Li:Al cathode shows the improvement in electric properties such as decrease in leakage current and series resistance, and increase in circuit current density. This effective charge collection and electron transport correspond to lowered energy barrier for electron transport at the interface, which is measured by ultraviolet photoelectron spectroscopy. Indeed, through the measurement of secondary ion mass spectroscopy, the Li atoms turn out to be located mainly at the interface between polymer and Al metal. In addition, the chemical reaction between polymer and metal electrodes are measured by X-ray photoelectron spectroscopy.

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Al:Au 음극층을 이용한 양면발광(dual emission) 유기 EL 소자의 Al 두께별 특성 평가 (Characterization of Organic Light-Emitting Diode (OLED) with Dual Emission using Al:Au Cathode)

  • 이수환;김달호;양희두;김지헌;이곤섭;박재근
    • 반도체디스플레이기술학회지
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    • 제7권1호
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    • pp.47-51
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    • 2008
  • The Al:Au double-layer metal electrode for use in transparent, dual emission of organic light-emitting diode (OLED) was fabricated. The electrode of Al:Au metals with various thicknesses was deposited by the vacuum thermal evaporation technique. For Al thickness of 1 nm, a bottom luminance of $4880\;cd/m^2$ was observed at 8 V. Otherwise, top luminance of $2020\;cd/m^2$ were observed at 8 V. In addition, the threshold voltages of the electrodes were 2.2 V. It was forward that the inserting 1 nm Al between LiF and Au enhanced electron injection with tunneling effect.

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원자 방출 분광 분석을 위한 개선된 관통형 속빈 음극관 글로우 방전 셀 개발 및 기초 연구 (The Fundamental Studies and Development of the Modified See - Through Hollow Cathode Glow Discharge Cell for Atomic Emission Spectrochemical Analysis)

  • 이성훈;조원보;정종필;최우창;스튜어드 보든;김규환;이장수;이상천
    • 분석과학
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    • 제15권6호
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    • pp.502-508
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    • 2002
  • 관통형 속빈 음극관 글로우 방전 (See-through hollow cathode glow discharge)셀을 이용한 미량 및 극미량 분석을 가능한 분광 분석 장치를 개발하였다. 이 장치는 기존의 관통형 속빈 음극관 글로우 방전 셀을 개선하기 위하여 수냉식 냉각 장치를 부착한 새로운 방전 셀의 형태로 개발하였다. 기존의 방전 셀로 미량 및 극미량 분석은 가능하였지만, 공랭식 냉각장치로도 플라즈마의 온도를 높이는 데 한계가 있으며, 단 시간에 플라즈마가 불안정해지는 문제점이 발생하였다. 이러한 문제점을 개선하기 위해서 본 장치에서는 수냉식 냉각 방식을 채택하여 플라즈마의 안정성을 높였으며, 플라즈마 온도를 증가시킬 수 있다. 개선된 방전 셀의 기초 연구를 위해 속빈 음극관의 재질 및 구경변화에 따른 방전 전력 및 압력에 관련한 연구를 하였으며, 속빈 음극관의 구경의 변화에 따른 플라즈마 온도 변화에 대해 측정하였다.

양극 활물질의 표면 코팅처리가 Ni-MH 2차 전지의 전기화학적 특성에 미치는 영향 (Effects of the Surface Coating Treatment of Cathode Materials on the Electrochemical Characteristics of Ni-MH Secondary Batteries)

  • 김병섭;양동철;박봉기;박충년;박찬진
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.495-503
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    • 2011
  • The sealed nickel-metal hydride (Ni-MH) secondary battery are primarily used as energy storage for the HEV. But, the research on Ni-MH battery has focused on anode materials. In the present study, we investigate to improve the electrochemical characteristics of Ni-MH batteries using the surface treatment of $Ni(OH)_2$ cathode by CoOOH. Surface treated $Ni(OH)_2$ cathode showed significant improvement in the activation behavior, rate capability, charge retention, and cycle life of the batteries were significantly improved. In addition, the surface treated electrode exhibited the higher overvoltage for oxygen evolution than the untreated electrode. This phenomenon indicates that the charge efficiency can be improved by suppressing the oxygen evolution on cathode.

암모니아 농도에 따른 Rich-Ni 양극 소재의 전구체 형태와 특성 변화 (Changes in the Shape and Properties of the Precursor of the Rich-Ni Cathode Materials by Ammonia Concentration)

  • 박선혜;홍순현;전형권;김천중
    • 한국재료학회지
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    • 제30권11호
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    • pp.636-640
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    • 2020
  • Due to the serious air pollution problem, interest in eco-friendly vehicles is increasing. Solving the problem of pollution will necessitate the securing of high energy storage technology for batteries, the driving force of eco-friendly vehicles. The reason for the continuing interest in the transition metal oxide LiMO2 as a cathode material with a layered structure is that lithium ions reveal high mobility in two-dimensional space. Therefore, it is important to investigate the effective intercalation and deintercalation pathways of Li+, which affect battery capacity, to understand the internal structure of the cathode particle and its effect on the electrochemical performance. In this study, for the cathode material, high nickel Ni0.8Co0.1Mn0.1(OH)2 precursor is synthesized by controlling the ammonia concentration. Thereafter, the shape of the primary particles of the precursor is investigated through SEM analysis; X-ray diffraction analysis is also performed. The electrochemical properties of LiNi0.8Co0.1Mn0.1O2 are evaluated after heat treatment.

The effect of process parameters on copper powder particle size and shape produced by electrolysis method

  • Boz, Mustafa;Hasheminiasari, Masood
    • Steel and Composite Structures
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    • 제15권2호
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    • pp.151-162
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    • 2013
  • In this study, an electrolyzing device for the production of metal powders was designed and fabricated. The production of copper powders was performed using a variety of current densities, anode-cathode distances and power removal times. The effect of these parameters on powder particle size and shape was determined. Particle size was measured using a laser diffraction unit while the powder shape was determined by SEM. Experimental results show that an increase in current density leads to a decrease in powder particle size. In addition particle shape changed from globular dendritic to acicular dendritic with increasing the current density. Distance between the cathode and anode also showed a similar influence on powder particle size and shape. An increase in time of powder removal led to an increase in powder particle size, as the shape changed from acicular dendritic to globular dendritic.

Optical Simulation for Transparent and Top Emission PLEDs to Optimize the Metal/ITO Cathode

  • Tsai, Yao-Chou;Chen, Chen-Chun;Liu, Kou-Chen;Chang, Yung-Ting;Lee, Jiun-Haw
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1422-1424
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    • 2007
  • A simulation method has been purposed in this paper to optimize the stack structure of metal/ITO cathode for full transparent or top emission devices. The result demonstrates that the complexity of the two proper layers thicknesses design is reduced. Finally, the experiment data also strain the simulation result.

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PMOS 집적회로 제작기법을 사용한 Seven Segment Decoder/Driver의 설계와 제작 (Design and Fabrication of a Seven Segment Decoder/Driver with PMOS Technology)

  • 김충기;박형규
    • 대한전자공학회논문지
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    • 제15권3호
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    • pp.11-17
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    • 1978
  • Medium scale 집적회로인 BCD to seven segment decoder/driver를 P-channel Metal-Oxide-Semiconductor집적회로 제작 기법으로 설계, 제작하였다. 본 소자는 특별히 common cathode seven segment light emitting diode에 적합하도록 설계되었다. decoder logic은 직렬로 연결된 두 개의 Read-Only-Memory로 구성되어 있으며 driver로는 channel이 넓은 FET를 사용하였다. 제작된 집적회로는 전원 전압이 -7 volt에서 -26 volt까지 변화할 때 정상적으로 동작하였으며 LED각 segment 전류의 non-uniformity는 약 ±10%이었다.

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Use of Speckle Pattern for Monitoring Thermal Energy Behavior of Battery Cathode

  • Kim, Byungwhan;Jang, Junyoung
    • Journal of the Optical Society of Korea
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    • 제20권3호
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    • pp.396-400
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    • 2016
  • Laser speckle patterns were used to monitor variations of thermal voltages of a cathode during a battery discharge. Discharge voltages measured with an oscilloscope were utilized as a figure of merit of thermal voltages in Zn metal. Using an optical imaging system, speckle patterns were taken for zinc metal surface over a time period of 3 minutes. Pixel sum distribution functions (PSDFs) were extracted from speckle patterns. Accumulated pixel sums quantified from PSDFs over an optimized grayscale range strongly correlated with discharge voltages. This suggested that dark matter or particles may have the capability of both absorbing and radiating thermal energies simultaneously. The black body-like properties were able to be validated by identifying coincidences with distinct features of a black body spectrum. The pixels belonging to the grayscale range were confirmed to represent dark matter of a speckle pattern. It was clear that dark matter was part of surface plasmon carriers. The proposed sensing system can be applied to monitor thermal energy variations in any material.

Recovery of RE-less U From U/RE Ingot by Electrochemical Oxidation Process

  • Kim, Si Hyung;Yoon, Dalsung;Jang, Junhyuk;Kim, Taek-Jin;Paek, Seunwoo;Lee, Sung-Jai
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2018년도 춘계학술논문요약집
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    • pp.51-52
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    • 2018
  • Selective oxidation of RE elements from the U/RE metal ingot was studied in this paper using electrochemical process. Constant potential of -1.7V was applied between anode and cathode, where the potential value corresponds to standard potentials between actinide and rare earth materials. When the current values approached to nearly 0 mA, the reaction was finished. It is confirmed from the EPMA analysis that only U part of the U/RE ingot was remained. The metal recovered to the zinc cathode was obtained through the distillation process and it is being chemically analyzed in the KAERI analytical laboratory.

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