• Title/Summary/Keyword: menthone

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Flavoral Essential Oil Components in the Stems of Agastache rugosa for Aromatherapy (아로마테라피용 배초향(Agastache rugosa) 줄기의 방향성 정유 성분)

  • Kim, Jeong-Mee
    • Journal of the Korean Society of Food Culture
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    • v.36 no.3
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    • pp.317-324
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    • 2021
  • This study was carried out to investigate the flavoral essential oil components in the stems of Agastache rugosa. These components were analyzed using gas chromatography-mass selective detector (GC-MSD). The stems of Agastache rugosa were contained alcohols, aldehydes, ketones, fatty acid esters, and terpenoids. The peak area (%) of estragole was highest among its oil components and the next were pulegone and menthone. The terpenoid alcohols found were 1-octen-3-ol, chavicol, spatulenol, 3-hexen-1-ol, 2-cyclohexen-1-ol, methyl eugenol, and octaethyllene glycol. The stems also contained ketones such as pulegone, menthone, cis-isopulegone, 2-cyclohexene-1-one, 3-octanone, 1-cyclohexanone, isoindole-1-one, t-ionone, inden-2-one, as well as the aldehydes of 4-methoxycinnam and benzaldehyde. The following esters were also detected 1-isopulegone-3-yl acetate, caryophyllene oxide, acetate and benzendicarboxylic acid ester. The terpenoids in the stems were identified as caryophyllene, limonene, cyclohexasiloxane-D, germacrene-D, anethole, cadinene, muurolene, and bourbonene. Overall Agastache rugosa contained several functional oil components including phenylpropanoids and terpenoids as flavoral essential oil components for natural aromatherapy.

Analysis of Phytochemicals in Popular Medicinal Herbs by HPLC and GC-MS (HPLC와 GC/MS를 활용한 약용식물 유래 phytochemicals 분석)

  • Cho, Hyun-Jung;Yoo, Dong-Chan;Cho, Hyun-Nam;Fan, Lu-An;Kim, Hee-Joon;Khang, Kong-Won;Jeong, Ho-Soon;Yang, Seun-Ah;Lee, In-Seon;Jhee, Kwang-Hwan
    • Korean Journal of Food Science and Technology
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    • v.40 no.3
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    • pp.277-282
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    • 2008
  • Oriental herbs are reported as having potent functions for preventing many types of diseases. They also appear to have positive effects and potential capabilities for skin care. Among the many oriental herbs that are available, we chose to analyze four medicinal herbs, Korean red ginseng, Artemisia capillaries Thunb, Schizonepeta tenuifolia Briq, and Foeniculum vulgare Mill, because all are popular and considered as favorite medicinal plants in Korea. Extracts of the herbs were obtained by various methods such as using distilled water, ethyl ether, methanol, ethanol, benzene, 1-butanol, and chloroform. Nine phytochemicals were detected in the extracts: maltol, adenosine, b-pinene, menthone, pulegone, limonene, anethole, estragole, and fenchone, which reportedly have multi-functionalities. All phytochemicals were analyzed quantitatively by various chromatographic techniques such as HPLC and gas chromatography-mass (GC-MS) spectrometry. This article also presents the optimum conditions for extracting these 9 targeted phytochemical compounds that were derived from 4 popular oriental herbs, which could be useful for the efficient preparation of each phytochemical.

A Study on the Identification Odorants using Six Channel Piezoelectric Crystals (6채널 압전소자를 이용한 냄새인식에 관한 연구)

  • 권영수;장상목;박옥순;최용성
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.8
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    • pp.947-950
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    • 1992
  • At-cut quartz crystal has been applied as chemical vapour sensors. The responses of quartz crystal at 9 MHz coated with phosphatidylglycerol(PG), phosphatidylinositol(PI), phosphatidylethanolamine(PE), phosphatidylserine(PS), and lipid A(LA) are determined for amyl acetate, acetoin, menthone and other organic gases which showed different affinities for each lipid. The identification of odorants depending on the species of lipid used for coating is discussed in terms of the normalized resonant frequency shift pattern.

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The Antifungal Activity of Chemical Substances from Artemisia annua (개똥쑥의 천연화학물질에 의한 항균효과와 성분확인)

  • Kim, Hyeon-Cheol;Gil, Bong-Seop
    • The Korean Journal of Ecology
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    • v.24 no.3
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    • pp.137-140
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    • 2001
  • The antifungal activity of chemical substances from Artemisia annua were examined. Antifungal activity of aqueous extracts from A. annua was higher than that of essential oils in Fusarium oxysporum, whereas that of essential oil was higher than that of aqueous extracts in Aspergillus nidulans. The GC/MS methods were employed for the analysis and identification of phytotoxic substances from A. annua. Essential oil of some components were identified including thujone, terpineol, β-pinene, cienole, 2,4-hexndienal, camphor, citronellal, (-)-menthone, (1R)-(-)myrtenol, (S)-(-)-perilla aldehyde, perilla alcohol, 4-tert-buthylaniline, eugenol, isosafrole, isoeugenol and α-humulene. These results suggest that the chemical substances from A. annua such as terphenoids seem to be responsible for the allelopathic effect.

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Fumigant Activity of Essential Oils and Components of Illicium verum and Schizonepeta tenuifolia Against Botrytis cinerea and Colletotrichum gloeosporioides

  • Lee, Sun-Og;Park, Il-Kwon;Choi, Gyung-Ja;Lim, He-Kyoung;Jang, Kyong-Soo;Cho, Kwang-Yun;Shin, Sang-Cheol;Kim, Jin-Cheol
    • Journal of Microbiology and Biotechnology
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    • v.17 no.9
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    • pp.1568-1572
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    • 2007
  • To develop a natural fungicide against Botrytis cinerea and Colletotrichum gloeosporioides, a total of 25 essential oils were tested for their fumigant activity against post-harvest pathogens. The vaporous phases of oils were treated to each fungus on potato dextrose agar medium in half-plate separated Petri plates at $10\;{\mu}g$ per plate. The essential oil of Illicium verum strongly inhibited the mycelial growth of both B. cinerea and C. gloeosporioides by over 90%. On the other hand, the essential oil of Schizonepeta tenuifolia showed inhibitory activity against mycelial growth of only B. cinerea by over 90%. Gas chromatography-mass spectrometry and bioassay indicated trans-anethole in I. verum and menthone in S. tenuifolia as a major antifungal constituent. The essential oils of I. verum and S. tenuifolia and their major constituents could be used to manage post-harvest diseases caused by B. cinerea and C. gloeosporioides.

Development of Odorant Sensor System using Six Channel Lipid-Coated SAW Resonator Devices imitating the Olfactory Mechanizm (후각 메카니즘을 모방한 냄새 센서의 개발 연구)

  • Chang, Sang-Mok;Isao, Karube
    • Proceedings of the KOSOMBE Conference
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    • v.1991 no.05
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    • pp.98-100
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    • 1991
  • A sensitive surface acoustic wave (SAW) sensor for the detection of odorants has been constructed by depositing different phospholipids and fatty acids on the surface of the SAW device wi th the Langmuir-Blodgett technique. The characteristics of SAW device operating at 310 MHz deposited with phosphatidylcholine were analyzed. Amyl acetate, acetoin, menthone and other organic gases showed different affinities. The identification of odorants depending on the species of lipid used for coating is discussed in terms of the similarity of the normalized resonant frequency shift pattern. Using a number of different lipid-coated SAW devices, odorants could be identified by a neural-network pattern recognition with back-propagation algorithm.

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A Multivariate Statistical Approach to Comparison of Essential Oil Composition from Three Mentha Species

  • Park, Kuen-Woo;Kim, Dong-Yi;Lee, Sang-Yong;Kim, Jun-Hong;Yang, Dong-Sik
    • Horticultural Science & Technology
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    • v.29 no.4
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    • pp.382-387
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    • 2011
  • The chemical composition of essential oils obtained from aerial parts in spearmint, apple mint and chocolate mint, was investigated by gas chromatography/mass spectrometry analyses. (-)-Carvone (33.0%) was quantitatively major compound in spearmint, followed by R-(+)-limonene (11.7%) and ${\beta}$-phellandrene (9.7%); (-)-carvone (37.4%) and germacrene D (11.9%) in apple mint; and (-)-menthol (34.3%), p-menthone (18.4%) and menthofuran (9.8%) in chocolate mint. Hierarchical cluster analysis and principle components analysis showed the clear difference in chemical composition of the three mint oils.

Detection of odorants and study on the odorant sensor system by using SAW device (SAW 디바이스를 이용한 냄새물질 측정 및 냄새센서 시스템의 연구)

  • 장상목;김기영;김종민;최용성;권영수
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.48-55
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    • 1995
  • A surface acoustic wave (SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. The characteristics of a SAW device operating at 310 MHz deposited with silicon monoxide were analyzed. Menthone, amylacetate, acetoin, and other organic gases show different affinities to the coated lipids. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids. The identification of odorants depending on the tkpe of lipid used for coating is discussed in terms of the similarity of their normalized resonant frequency shift patterns. Using a number of different lipid-coated SAW devices, odorants can be identified by a computerized pattern recognition algorithm.

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Bifuntional Derivatives of the Monoterpene Odorants and Olfaction - The Structure-Activity-Relationships between Odorants and Olfaction - (Monoterpene 향료의 화학구조와 Olfaction과의 구조활성 상관작용)

  • 유충규
    • Journal of Food Hygiene and Safety
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    • v.2 no.2
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    • pp.75-81
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    • 1987
  • Bifunctional monoterpene 유도체의 향의 유무는 분자내에 존재하는 두 개의 관능기인, proton donor(AH)와 proton acceptor(B)가 olfaction과 구조활성 상호작용(SAR)과 밀접한 관계가 있다. 일반적으로 Ohloff가설에 의하면, p-menthane monoterpene 분자내의 AH와 B의 입체배위적 최소거리가 3${\AA}$ 이하인 경우 향을 갖고, 3${\AA}$ 이상인 경우는 향을 갖지 않는다. Bifunctional pinanone, thujane, carane, carvomenthone 및 기타 menthone 유도체 등을 이용하여 이 가설을 확대 연구하였다. Bifunctional monoterpene인 (원문이미지참조) 등은 분자내에 각각 AH (OH 혹은 COOH)와 B (C=O)의 입체배위적 최소 거리가 항상 3${\AA}$ 이하여서 향을 가지며, 이들은 olfactory three point attachment에 의한 구조활성 상관관계를 가지는 것으로 사료된다. 상기 화합물의 proton donor인 OH, 혹은 COOH가 각각 acetylation이나 methylation되는 경우에는 proton donor로서의 기능 상실로 향이 사라지게 되었다.

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Characteristics of odorant sensor using SAW Device (SAW 디바이스를 이용한 냄새센서의 특성)

  • Kim, Ki-Young;Kim, Jong-Min;Shin, Hoon-Kyu;Choi, Yong-Sung;Kwon, Young-Soo;Chang, Sang-Mok
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1457-1459
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    • 1994
  • A surface acoustic wave(SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. Applying the Langmuir-Blodgett technique, it was possible to deposit the optimal number of layers which was found to be between 10 and 20. Menthone, amylacetate, acetoin, and other organic gases showed different affinities to the coated lipids. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids.

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