• Title/Summary/Keyword: membrane processes

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Optimum Chemical Cleaning Conditions for Ceramic Microfiltration Membrane Process (세라믹 정밀여과막 공정을 위한 최적 약품세척 방안)

  • Lim, Jae-Lim;Lee, Kyung-Hyuk;Lee, Young-Joo;Park, Jong-Yul
    • Membrane Journal
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    • v.22 no.6
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    • pp.461-469
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    • 2012
  • This study was carried out to find the optimum chemical cleaning (CIP) conditions for ceramic microfiltration membrane process of Y drinking water treatment plant. B train consists of coagulation as pretreatment process with membrane was chemically cleaned 9 times more than that of A train with ozonation and coagulation. The frequent CIP of B train was due to improper CIP method suggested by membrane manufacture as well as different membrane fouling between A and B train resulting from the different pretreatment processes. That is, recovery rate of CIP was overestimated because the rate was calculated based on normalized trans membrane pressure (TMP) rather than normalized permeability. And also, iron oxide fouling was ineffectively removed by citric acid. By using a mixture of 1% citric acid and 0.1 N sulfuric acid as reagent for acid CIP step, the recovery rate of CIP was the highest while CIP efficiency by 0.1 N sulfuric acid was the lowest. When sulfuric acid concentration increased from 0.1 N to 0.3 N in mixture, total recovery rate of CIP was not increased due to the decreased CIP efficiency in alkali CIP step by 0.3% NaOCl although its rate in acid CIP step was increased. It was proved through the experiment result of CIP sequence changes that an acid followed by alkali CIP was more effective than that of the reverse method.

Hybrid Water Treatment of Carbon Ultrafiltration Membrane and Polypropylene Beads Coated with Photocatalyst: Effect of Organic Materials, Photo-oxidation, and Adsorption in Water Back-flushing (탄소 한외여과막 및 광촉매 코팅 폴리프로필렌 구의 혼성 수처리: 물 역세척 시 유기물 및 광산화, 흡착의 영향)

  • Park, Jin Yong;Jung, Chung Ho
    • Membrane Journal
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    • v.22 no.5
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    • pp.359-368
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    • 2012
  • For hybrid water treatment of high turbidity water, we used the hybrid module that was composed of photocatalyst packing between tubular membrane outside and module inside. Photocatalyst was PP (polypropylene) bead coated with $TiO_2$ powder by CVD (chemical vapor deposition) process. Water back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling for modified solution was prepared with humic acid and kaolin. Resistance of membrane fouling ($R_f$) decreased as humic acid concentration changed from 10 mg/L to 2 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L, which was the same with the previous results. Then, treatment efficiencies of turbidity and humic acid were above 98.9% and 88.7%, respectively. As results of treatment portions of UF, UF + $TiO_2$, and UF + $TiO_2$ + UV processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of humic acid by adsorption and photo-oxidation were 2.5% and 12.3%, respectively. Compared with the previous results, treatment portions of humic acid by adsorption and photo-oxidation were different depending on membrane material and pore size. As simplified the process, the membrane fouling resistance after 180 minutes' operation ($R_{f,180}$) increased and the final permeate flux decreased a little.

Graphene Oxide Incorporated Antifouling Thin Film Composite Membrane for Application in Desalination and Clean Energy Harvesting Processes (해수담수화와 청정 에너지 하베스팅을 위한 산화 그래핀 결합 합성 폴리머 방오 멤브레인)

  • Lee, Daewon;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.1
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    • pp.16-34
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    • 2021
  • Water supplies are decreasing in comparison to increasing clean water demands. Using nanofiltration is one of the most effective and economical methods to meet the need for clean water. Common methods for desalination are reverse osmosis and nanofiltration. However, pristine membranes lack the essential features which are, stability, economic efficiency, antibacterial and antifouling performances. To enhance the properties of the pristine membranes, graphene oxide (GO) is a promising and widely researched material for thin film composites (TFC) membrane due to their characteristics that help improve the hydrophilicity and anti-fouling properties. Modification of the membrane can be done on different layers. The thin film composite membranes are composed of three different layers, the top filtering active thin polyamide (PA) layer, supporting porous layer, and supporting fabric. Forward osmosis (FO) process is yet another energy efficient desalination process, but its efficiency is affected due to biofouling. Incorporation of GO enhance antibacterial properties leading to reduction of biofilm formation on the membrane surface. Pressure retarded osmosis (PRO) is an excellent process to generate clean energy from sea water and the biofouling of membrane is reduced by introduction of GO into the active layer of the TFC membrane. Different modifications on the membranes are being researched, each modification with its own advantages and disadvantages. In this review, modifications of nanofiltration membranes and their composites, characterization, and performances are discussed.

Thin-Film Composite (TFC) Membranes with Hydrophilic Ethyl Cellulose-g-poly(ethylene glycol) (EP) Substrates for Forward Osmosis (FO) Application (친수성을 가지는 에틸셀룰로스-폴리에틸렌글리콜 가지형 고분자의 정삼투 복합막 지지층으로의 응용)

  • Yu, Yun Ah;Kim, Jin-joo;Kang, Hyo;Lee, Jong-Chan
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.510-518
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    • 2016
  • Ethyl cellulose-g-poly(ethylene glycol) (EP) was synthesized by esterification of carboxylic acid functionalized methoxy polyethylene glycol (MPEG-COOH) with ethyl cellulose (EC) in order to develop a hydrophilic substrate for thin-film composite (TFC) membrane in a forward osmosis (FO) system. A porous EP substrate, fabricated by a non-solvent induced phase separation method, was found to be more hydrophilic than the EC substrate due to the presence of polyethylene glycol (PEG) side chains in the EP. Since the EP substrate exhibits smaller water contact angles and higher porosity, the structural parameter (S) of TFC-EP is smaller than that of TFC-EC, indicating that internal concentration polarization (ICP) within porous substrates can occur less when TFC-EP is used as a membrane. For example, the water flux value of the TFC-EP is 15.7 LMH, whereas the water flux value of the TFC-EC is only 6.6 LMH. Therefore, we strongly believe that the TFC-EP could be a promising candidate with good FO performances.

Protective Effects of a Ginseng Component, M altol(2- M ethyl-3- Hydroxy-4- Pyrone) against Tissue Damages Induced By Oxygen Radicals

  • Jae-Gook Shin;Jon
    • Proceedings of the Ginseng society Conference
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    • 1990.06a
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    • pp.45-48
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    • 1990
  • Maltol(2-methyl-3-hydroxy-r-pyrone), a component known to be present in Korean Ginseng root showed an antioxidant action but its potency as an antioxidant was low; about 1150th that of other antioxidants such as p-phenylenediamine , BHA and BHT. However, maltol was able to protect the oxidation adamants in biological systems such as adriamycin-induced membrane damage in isolated cardiomyocytes, parquet-induced toxicities in isolated hepatocytes and repercussion injury in isolated hearts. The antioxidant action of maltol was also shown to be effective in vivo. The antioxidant action of this compound was probably due to the removal of hydroxyl radicals. In view of the roles of oxygen radical in various pathological processes, Korean Ginseng root, which contains several antioxidants including maltol, is expected to have beneficial efforts on the oxygen radical-involved processes. Keywords Maltol, Oxygen free radicals, Lipid preoccupation, Repercussion injury and Korean ginseng

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Analysis of Superplastic Forming Processes U sing Finite Element Method (유한요소법을 이용한 초소성 성형공정 해석)

  • 홍성석;김민호;김용환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.6
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    • pp.1411-1421
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    • 1995
  • A rigid visco-plastic finite element method has been developed for modeling superplastic forming processes. The optimum pressure-time relationship for a target strain rate and thickness distributions was predicted using two-node line element based on membrane approximation for plane strain and axisymmetric condition. Analysis of superplastic forming was carried out using the developed program and the numerical results were compared to the values available in the literature for plane strain problems. For description of the contact between the dies and sheet, the direct projection method was applied to the complicated problem and the validity of the scheme was tested. Experiments for the various geometries such as hemisphere and cone were performed with the developed forming machine using the calculated optimum pressure-time curves. Comparison between analysis and experiments showed good agreement.

Technologies for Volatile Organic Compounds(VOCs) Treatment (휘발성 유기 화합물(VOCs) 처리 기술)

  • 서봉국;나영수;송승구
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.825-833
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    • 2003
  • The emission of volatile organic compounds (VOCs) generated from painting and coating processes is a worldwide problem as contributing factors to the development of photochemical smog and other environmental problems. Common methods of reducing VOC emissions are adsorption on activated carbon, membrane separation, absorption, incineration, or catalytic oxidation. In this article, the environmental issues caused by VOC emissions and the trend of legislation against such emissions will be surveyed first. Several conventional control technologies will then be summarized and the characteristics of each process will be introduced. Lastly, some examples will be described to show the hybrid processes which have been industrially applied for the recovery of VOC.

Concentration/Purification Technologies: Multi-Functionalities of Nanostructures in Biosensing Fields

  • Son, Sang Jun;Min, Junhong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.87-87
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    • 2013
  • Sample concentration and purification processes are essential in the bio-analytical and pharmaceutical fields because most bio samples or media are extremely sophisticated. To concentrate and purify specific substances, passive membrane type filters have been utilized, which is driven by size or charge differences between target and others. The traditional and representative method to identify nucleic acid sequences in the complex biosample is gel electrophoresis, which has been worked by size and net charge of molecules. The adsorption phenomena have been also utilized to concentrate and purify biomolecules. This adsorption of biomolecule can be controlled under specific salts and surfaces as well as surface area. To utilize the differences of physical properties of molecules or bio-targets such as virus, bacteria, and cells, the nanotechnologies can be introduced in target concentration, purification, and isolation processes. In here, I'd like to briefly survey typical examples of nanobiotechnologies which are introduced in sample treatment. Also I specifically demonstrate two different simple techniques to concentrate and detect bacteria from the samples using multifunctional silica nanotube (SNT).

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Ion Exchange Processes: A Potential Approach for the Removal of Natural Organic Matter from Water

  • Khan, Mohd Danish;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.2
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    • pp.70-80
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    • 2018
  • Natural organic matter (NOM) is among the most common pollutant in underground and surface waters. It comprises of humic substances which contains anionic macromolecules such as aliphatic and aromatic compounds of a wide range of molecular weights along with carboxylic, phenolic functional groups. Although the concentration of NOM in potable water usually lies in the range of 1-10 ppm. Conventional treatment technologies are facing challenge in removing NOM effectively. The main issues are concentrated to low efficiency, membrane fouling, and harmful by-product formation. Ion-exchangers can be considered as an efficient and economic pretreatment technology for the removal of NOM. It not only consumes less time for pretreatment but also resist formation of trihalomethanes (THMs), an unwanted harmful by-product. This article provides a comprehensive review of ion exchange processes for the removal of NOM.

3-D Finite Element Analysis of Superplastic Forming/Diffusion Bonding Processes with Consideration of Contact between Deformable Bodies (변형체간의 접촉을 고려한 3차원 초소성 성형/확산접합의 유한요소해석)

  • Kang, Yung-Kil;Song, Jae-Sun;Hong, Sung-Suk;Kim, Yong-Hwan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.1
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    • pp.57-65
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    • 2008
  • Superplastic forming/diffusion bonding(SPF/DB) processes with inner contact were analyzed using a 3-D rigid visco-plastic finite element method. A constant-triangular element based on membrane approximation and an incremental theory of plasticity are employed for the formulation. The hierarchical search algorithm for the contact searching has been applied. The algorithms for contact force processing were designed to handle equally well contact between deformable bodies, as well as rigid bodies. The plate of three and four sheets for 3-D SPF/DB model are analyzed using the developed program. The validity for the analysis is verified by comparison between analysis, experiment and results in the literature.