• Title/Summary/Keyword: membrane process

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Thermopile sensor with SOI-based floating membrane and its output circuit

  • Lee, Sung-Jun;Lee, Yun-Hi;Suh, Sang-Hi;Kim, Tae-Yoon;Kim, Chul-Ju;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.11 no.5
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    • pp.294-300
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    • 2002
  • In this study, we fabricated thermopile infrared sensor with floating membrane structure. Floating membrane was formed by SOI(Silicon On Insulator) structure. In SOI structure, silicon dioxide layer between top silicon layer and bottom silicon substrate was etched by HF solution, then membrane was floated over substrate. After membrane was floated, thermopile pattern was formed on membrane. By insertion of SOI technology, we could obtain thermal isolation structure easily and passivation process for sensor pattern protection was not required during fabrication process. Then, the amplifier circuit for thermopile sensor was fabricated by using $1.5{\mu}m$ CMOS process. The voltage gain of fabricated amplifier was about two hundred.

Fabrication of Hydrocarbon Membrane based DMFC MEAs with Low Temperature Decal Method (탄화수소계 전해질막과 저온 전사법을 이용한 DMFC용 MEA 제조)

  • Krishnan, N. Nambi;Prabhuram, Joghee;Ha, Heung-Yong;Kim, Soo-Kil
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.415-417
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    • 2009
  • A low temperature decal (LTD) transfer method is tried to fabricated hydrocarbon (HC) membrane based MEA. Sandwiched structures of outer ionomer/catalyst/carbon coating/substrate, which had been developed for Nafion membrane, are used for transfer of catalyst to the HC membrane. Performances of the HC MEA before and after 500hr continuous operation are compared and it is found that a severe delamination occurs at the interface between the HC membrane and the catalyst layer, which is the main reason of the low performance and its degradation. The delamination is due probably to the different nature of HC membrane to the Nafion ionomer. A substitutional method, therefore, is suggested to overcome this. In such a way, the outer ionomer process is removed and the low transfer rate of catalyst by skipping the ionomer process is compensated with optimization of other process variables such as transfer time or temperature. The resulting performance is superior to the original LTD method, which can be explained in terms of low resistive components both in ohmic and kinetic.

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Surface hydrophilicity modification of PVDF membranes with an external electric field in the phase inversion process

  • Shi, Bao-Li;Su, Xing;He, Jing;Wang, Li-Li
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.351-363
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    • 2015
  • To increase the surface hydrophilicity of PVDF membranes, in this paper, an electric enhancing method was adopted to treat PVDF nascent membranes during the phase inversion process. It was found that when PEG 600 was taken as the additive, the surface water contact angle of the PVDF membrane treated under 2 kV electric field was decreased from $84.0^{\circ}$ to $65.7^{\circ}$. The reason for the surface elements change of the PVDF membranes prepared under the electric field was analyzed in detail with the dielectric parameters of the polymer dope solutions. Results from BSA adsorption experiment showed that the antifouling ability of the external electric field-treated membranes was distinctly enhanced when compared with that of the untreated membranes. The amount of BSA adsorbed by the treated membranes was lower by 38-43%. Compared with the common chemical reaction methods to synthesize hydrophilic additives or membrane materials, the electric field-assisted processing method did not involve any additional chemical synthesis process and it was capable of realizing better hydrophilicity.

Improvement of the Thermochemical water-splitting IS Process Using the Membrane Technology (분리막 기술을 이용한 열화학적 수소제조 IS[요오드-황] 프로세스의 개선)

  • Hwang, Gab-Jin;Kim, Jong-Won;Sim, Kyu-Sung
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.3
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    • pp.249-258
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    • 2002
  • Thermochemical water-splitting IS(Iodine-Sulfur) process has been investigating for large-scale hydrogen production. For the construction of an efficient process scheme, two kinds of membrane technologies are under investigating to improve the hydrogen producing HI decomposition step. One is a concentration of HI in quasi-azeotropic HIx ($HI-H_2O-I_2$) solution by elecro-electrodialysis. It was confirmed that HI concentrated from the $HI-H_2O-I_2$ solution with a molar ratio of 1:5:1 at $80^{\circ}C$. The other is a membrane reactor to enhance the one-pass conversion of thermal decomposition reaction of gaseous hydrogen iodide (HI). It was found from the simulation study that the conversion of over 0.9 would be attainable using the membrane reactor using the gas permeation properties of the prepared silica hydrogen permselective membrane by chemical vapor deposition (CVD). Design criterion of the membrane reactor was also discussed.

Preparation of Silicone Rubber Membrane and its Porosity (Silicone Rubber Membrane의 제조 및 기공특성)

  • Lee, Seung-Bum;Kim, Hyung-Jin;Hong, In-Kwon
    • Elastomers and Composites
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    • v.30 no.3
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    • pp.185-194
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    • 1995
  • Membrane process has been employed to separate a specific substance from gas or liquid mixture, and treat wastewater. This is due to the fact that the substance of mixture can be permeated and separated selectively by membrane. Since Initial equipment and operation costs are not expensive, membrane process has been adopted in various fields such as petroleum Industry, chemistry, polymer, electronics, foods, biochemical industry and wastewater treatment. In this study, $CaCO_3$ particles impregnated in silicone rubber network were extracted by using supercritical carbon dioxide and pore distribution of silicone $rubber-CaCO_3$ was investigated with varying amount of extract. Silicone rubber has excellent mechanical properties such as heat-resistance, cold-resistance etc. and $CaCO_3$ has microporous structure. It is possible to make silicone $rubber-CaCO_3$ composite sheets via work-intensive kneading processes. In so doing $CaCO_3$ particles become distributed and impregnated in silicone rubber network. Supercritical carbon dioxide diffuse through composite sample, then sample is swollen. $CaCO_3$ in silicone rubber network Is dissolved in supercritical carbon dioxide, and its sites become pores. Pore distribution, pore shape and surface area are observed by SEM(scanning electron microscope) micrograph and BET surface area analyzer examination respectively. Pore characteristics of membrane suggest the possibilities that the membrane can be used for process of mixture separation and wastewater treatment.

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Hydrogen Isotopes Recovery Using Pd Membrane and Process Simulation (Pd 분리막을 이용한 수소동위원소 회수 실험과 공정 시뮬레이션)

  • JUNG, WOO-CHAN;PARK, JONG-HWAN;HAN, SANG-WOO;JANG, MIN-HO;LEE, HYEON-GON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.219-227
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    • 2021
  • Hydrogen isotopes, which are used as raw materials in fusion reaction, participate in the reaction only in small amount, and most of them are released together with impurities. In order to recover and reuse only hydrogen isotopes from this exhaust gas, a recovery process is required, and most of the hydrogen isotopes can be recovered using a Pd Membrane. In this study, the recovery rate of hydrogen isotopes was measured through the first and second stage Pd membrane experiments. In the case of the experiment using a single stage Pd membrane, about 99.2%, and in the case of the first stage and second stage Pd membrane connection experiments, a recovery rate of 99.9% or more was obtained. Therefore, the recovery rate of Pd membrane process applied to hydrogen can be applied to hydrogen isotopes. In addition, the simulation model was established using aspen custom modeler, a commercial software, and the validity of the simulation was checked by applying the references and experimental data. The simulation results based on the experimental data showed a difference of 2% or less.

History of Membrane Development and Mass Tranfer Modelling

  • Matsuura, Takeshi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.33-89
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    • 1996
  • History of Membrane Process Development 1920 : microfiltration : Zsigmondy 1930 : ultrafiltration 1950 : hemodialysis : Kolff 1955 : electrodialysis 1960 : reverse osmosis : Loeb, sourirajan 1960 : ultrafiltration 1979 : gas separation : Henis, Tripodi 1982 : pervaporation : Tusel

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Study of membrane fouling in the crossflow MBR system (교차흐름 막결합형 생물반응기에서의 막오염 연구)

  • 최중구;김인철;최남석;홍서표;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.150-152
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    • 1998
  • Now the lack of water is serious problem all over the world because of the growth of population and expansion of industrial activities. So wastewater recycle and reuse is essential in many countries. One of the most popular wastewater treatment processes is conventional activated sludge system. In spite of significant degree of treatment rate the biological process has some operational difficulties and capital disadvantages. In conventional activated sludge process, sludge settling condition is getting worse in case of sludge bulking, it is common that overall process fails due to wash-out of biomass causing low concentration of MLSS in the aeration tank. Because of the absence of claifier the membrane bioreactor(MBR) process is less affected by such problems.

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A study on boron removal for seawater desalination using the combination process of mineral cluster and RO membrane system

  • Cho, Bong-Yeon;Kim, Hye-Won;Shin, Yee-Sook
    • Environmental Engineering Research
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    • v.20 no.3
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    • pp.285-289
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    • 2015
  • Complicated and expensive seawater desalination technology is a big challenge in boron removal process. Conventional seawater desalination process of coagulation utilized for pre-treatment is difficult to remove boron. Boron can be removed more effectively in Reverse Osmosis (RO) process than any other processes. In this study, a coagulant with the name Mineral Cluster was examined its boron removal ability. Boron removal efficiency of Mineral Cluster depended on pH value and Mineral Cluster dosage. Desalination process combines the pre-treatment process with Mineral cluster diluted at the ratio of 1:2500 and the RO membrane process. The original sea water could be desalinated to drinking water quality, 1 mg/L, without any pH adjustments. Therefore, if the Mineral cluster is added without any other chemicals for adjusting pH, the desalination process would be much safer, efficient and economical.

Advanced Wastewater Treatment using Bioreactor Combined with Alternative Membrane (하수의 고도처리를 위한 저비용 저에너지의 대체 막을 조합한 생물반응기의 개발)

  • Kim, Dong-Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.25-30
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    • 2005
  • In order to decrease the high costs of membrane process, we have tried to develop two alternatives to membrane; a cartridge type filter and a metal membrane were tested for the high permeation flux with low cost and low energy. This research mainly focused on three points; 1) operation with high permeation flux by using of a cartridge type filter and a metal membrane, 2) removals of the filterable organic materials (FOC) by pretreatments for the membrane fouling control, and 3) advanced wastewater treatment by SMBR process with intermittent aeration and high MLSS. An Intermittently aerated membrane bioreactor using a submerged micro filter (cartridge type) was applied in laboratory scale for the advanced wastewater treatment. To minimize membrane fouling, intermittent aeration was applied inside of the filter with $3.0kg_f/cm^2$. The experiments was conducted for 6 months with three different HRTs (8, 10, 12 hr) and high MLSS of 6,000 and 10,000mg/L. The filtration process could be operated up to 50 days with permeation flux of 500LMH. Regardless of the operating conditions, more than 95% of COD, BOD and SS were removed. Fast and complete nitrification was accomplished, and denitrification was appeared to be the rate-limiting step. More than 75% T-N could be removed due to the endogenous denitrification. T-P removal efficiency was increased to 80% under the condition of MLSS 10,000mg/L.