• Title/Summary/Keyword: membrane performances

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Influence of Operating Conditions on the Performances of a Continuous Electrodeionizatioin with Cation Exchange Textile (CEDI-CET)

  • Song, Jung-Hoon;Lee, Jin-Woo;Lee, Hong-Joo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.18-26
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    • 2007
  • The transport and removal characteristics of cobalt ions were investigated in a continuous electrodeionization with cation exchange textile (CEDI-CET). It was shown that the removal properties of cobalt ions are strongly dependent on the operating parameters such as temperature, flow velocity, and the solution pH. The transport and removal of cobalt ions was mainly related to the sorption on the surface and the convection and electro-migration through the ion exchange medium. In this study, the CEDI-CET showed good process performance for the removal of metal ions compared with the conventional CEDI with resins.

Development of Geno-chromatographic Assay System for Salmonella species

  • Kim, Seok-Ha;O, Hong-Il;Jo, Jeong-Hwan;Baek, Se-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.827-828
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    • 2001
  • We developed a geno-chromatographic assay system based on hybridization between target DNA (e.g., amplified product from PCR) and a capture probe immobillized on a predetermined site of membrane. This system can offer a rapid detection of a gene sequence specific to a certain type of cells as well as simplicity of the analytical procedure. Such performances were demonstrated by utilizing Salmonella typhimurium as model analyte.

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Auto Tuning of PID for RO System Using Immune Algorithm (면역 알고리즘을 이용한 RO 공정 PID 제어기의 자동 튜닝)

  • Kim, Go-Eun;Park, Ji-Mo;Kim, Jin-Sung;Kwon, O-Shin;Heo, Hoon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.11
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    • pp.1103-1109
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    • 2009
  • In this paper, the control of a membrane used in reverse osmosis desalination plant by using immune algorithm(IA) is addressed. The proposed algorithm IA of auto tuning method can find optimal gains and compared with conventional Ziegler-Nichols tuning method. The results of computer simulation represent that the proposed IA shows a good control performances better than Ziegler-Nichols tuning method.

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고체 알칼리 연료전지용 음이온 교환 세공충진막의 제조 및 특성)

  • Choi, Young-Woo;Park, Gu-Gon;Yim, Sung-Dae;Lee, Mi-Soon;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.150-153
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    • 2009
  • Anion exchange polymer electrolyte pore-filling membranes consisting of the whole hydrocarbon materials were prepared by photo polymerization with various quaternary ammonium cationic monomers and characterized on the properties for applying to solid alkali fuel cell (SAFC). Hydrocarbon porous substrates such as polyethylene were used for the preparation of the pore-filling membranes. The hydroxyl ion conductivity of the polymer electrolyte membranes prepared in this research was dependent on the composition ratio of an electrolyte monomer and crosslinking agents used for polymerization. Furthermore, these pore-filling membranes have commonly excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lower fuel crossover through the membranes, and easier preparation process than those of traditional cast membranes.

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Studies on the Separation Performances of Chlorophenol Compounds from Water by Thin Film Composite Membranes

  • Yogesh, K.M. Popat;Ganguly, B.;Brahmbhatt, H.;Bhattacharya, A.
    • Macromolecular Research
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    • v.16 no.7
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    • pp.590-595
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    • 2008
  • The pressure driven membrane process has been a breakthrough in the removal of pollutants from drinking water. These experiments examined the removal of chlorophenol compounds from water using low pressure membranes. The removal performance of the membranes was based primarily on size exclusion. Apart from size exclusion, the polarity and pKa of the compounds also influences the membrane performance. The molecular size and dipole moments of the respective molecules were calculated using a quantum chemical method. The rejection of pollutants also followed the same trend as salt rejection by the membranes.

Stack Performances of Proton Exchange Membrane Fuel Cell

  • Kho, Young-Tai;Cho, Won-Ihl;Park, Yong-Woo-
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1994.11a
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    • pp.14-16
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    • 1994
  • The development of proton exchange membrane fuel cells(PEMFCs) with high energy efficiencies and high power densities is gaining momentum because their performance characteristics are attractive for terrestrial(power sources for electrical vehicles, stand-by power), space and underwater application[1]. Fuel cells are capable of running on non-petroleum fuels such as methanol, natural gas or hydrogen and also have major impact on improving air quality. They virtually eliminate particulates, NO$_{x}$, SO$_{x}$, and significant reduce hydrocarbons and carbon monoxide. Especially, fuel cell-battery hybrid power sources appear to be well suited to overcome both the so-called battery problem(low energy density) and the fuel cell problem(low power density)[2].[2].

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Potentiometric performances of polymer membrane electrode based on cyclosporin (싸이크로스포린을 이용한 고분자막 전위차 전극)

  • Rhee Paeng, Insook
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.491-494
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    • 2005
  • The main component governing selectivity in ion-selective electrodes and optodes is the ionophore. For this reason, a member of natural products that possess selective ion-binding properties have long been sought after. By applying this principle, the performance of cyclosporin used as neutral carriers for calcium selective polymeric membrane electrode was investigated. The calcium ion-selective electrode based on cyclosporin gave a good Nernstian response of 26.6 mV per decade for calcium ion in the activity range $1{\times}10^{-6}M$ to $1{\times}10^{-2}M$. The optimized calcium ion-selective electrode displayed very comparable selectivity for $Ca^{2+}$ ion against alkali and alkaline earth metal ions, $Na^{2+}$, and $Mg^{2+}$ in particular.

Performance Analysis of Plate-and-Frame Forward Osmosis Membrane Module for Concentrating High Salinity Wastewater (고염도 폐수 농축을 위한 평판형 정삼투막 모듈의 성능 분석)

  • Kim, Yu Chang;Lee, Sungyun;Park, Sang-Jin;Kim, Han Seok
    • The KSFM Journal of Fluid Machinery
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    • v.19 no.6
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    • pp.68-74
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    • 2016
  • Hydraulic fracturing of wells during oil and gas (O&G) exploration consumes large volumes of fresh water and generates larger volumes of contaminated wastewater with high salinity. It is critical to treat and reuse the O&G wastewater in a cost-effective and environmentally sound manner for sustainable industrial development and for meeting stringent regulations. Recently, forward osmosis (FO) has been examined if it is a promising solution for treatment and desalination of complex industrial streams and especially fracturing flowback and produced waters. In the present study, the performances of a plate-and-frame FO membrane element and a module (6 elements combined in series) were investigated for concentrating high TDS wastewater. An FO module has achieved up to 64 % water recovery (i.e., concentration factor of 2.76) from 10,000 ppm wastewaters and can concentrate feed streams salinities to greater than 30,500 ppm.

Fabrication of an Optical Hydrogen Sensor Based on 3C-SiC Photovoltaic Effect and Its Characteristics (3C-SiC 광기전 특성 기반 광학식 수소센서의 제작과 그 특성)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.21 no.4
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    • pp.283-286
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    • 2012
  • This paper presents the optical hydrogen sensor based on transparent 3C-SiC membrane and photovoltaic effect. Gasochromic materials of Pd and Pd/$WO_3$ were deposited by sputter on 3C-SiC membrane for gas sensing area. Gasochromic materials change to transparency by exposure to hydrogen. The variations of light intensity by hydrogen generate the photovoltaic of P-N junction between N-type 3C-SiC and P-type Si. Single layer of Pd shows higher photovoltaic compared with Pd/$WO_3$. However, phase transition from ${\alpha}$ to ${\beta}$ is shown at 6 %. Pd/$WO_3$ structure show the more linear response to hydrogen range of 2 % ~10 %. Also, almost 2 times fast response and recovery characteristics are shown at Pd/$WO_3$. These fast performances are come from the fact that Pd promoted the chemical reaction between hydrogen and $WO_3$.

The effects of Nafion$^{(R)}$ ionomer content in dual catalyst layer on the performances of PEMFC MEAs

  • Kim, Kun-Ho;Jeon, Yoo-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.95.2-95.2
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    • 2011
  • In order to achieve high performance and low cost for commercial applications, the development of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, must be optimized. Expensive platinum is currently used as an electrochemical catalyst due to its high activity. Although various platinum alloys and non-platinum catalysts are under development, their stabilities and catalytic activities, especially in terms of the oxygen reduction (ORR), render them currently unsuitable for practical use. Therefore, it is important to decrease platinum loading by optimizing the catalysts and electrode microstructure. In this study, we prepared several different MEAs (non-uniform Nafion$^{(R)}$ ionomer loading electrode) which have dual catalyst layers to find the optimal Nafion$^{(R)}$ ionomer distribution in the electrodes. We changed Nafion$^{(R)}$ ionomer content in the layers to find the ideal composition of the binder and Pt/C in the electrode. For MEAs with various ionomer contents in the anodes and cathodes, the electrochemical activity (activation overpotential) and the mass transport properties (concentration overpotential) were analyzed and correlated with the single cell performance. The dual catalyst layers MEA showed higher cell performance than uniformly fabricated MEA, especially at the high current density region.

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