• Polymer(Korea)
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• v.24 no.1
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• pp.38-47
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• 2000

A study of linear and branched polycarbonates blend system is presented. Flow and mechanical properties, and miscibility were studied for the blends of various compositions. No phase separations were observed in the blend systems. The mechanical properties of blends were examined through tensile strength, tensile modulus, flexural strength, flexural modulus and impact strength. Melt viscosity, storage and loss moduli of the blends with various compositions were examined at various temperatures. The dependence of viscosity on molecular weight was also presented. Flow properties of the blends showed significant variations however, mechanical properties were relatively independent of the compositions. As the content of branched polycarbonate increased, the dependence of viscosity on molecular weight and shear thinning behavior became more marked. Therefore the blend systems which have same mechanical properties but different flow properties can be obtained.

• Polymer(Korea)
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• v.24 no.3
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• pp.374-381
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• 2000

Composites of polypropylene (PP) and organically modified montmorillonite (org-MMT) were prepared by melt mixing in an intensive mixer. Three grades of PP's having different melt viscosities were employed to investigate the dispersion characteristics of the composites with various org-MMT's. Depending on the matrix viscosity and nature of the interlayer in org-MMT significant variations of the phase structure were found. Under the constant mixing condition and matrix viscosity, intercalation of PP chains into the interlayer of org-MMT was possible when initial interlayer distance and packing density were maintained in the optimum range; by which the loss in entropy associated with the confinement of polymer chains was compensated. The state of org-MMT particle dispersion was improved by increasing the matrix viscosity only in the case that dispersed phase is suitable for intercalation process thermodynamically, otherwise little variation was occurred regardless of the matrix viscosity. Due to the lack of specific interaction between PP and erg-MMT considered here, although the intercalation was possible for an appropriate org-MMT, the composites revealed unstable phase structure upon increasing the mixing time, which was characterized by agglomeration of the org-MMT domains.

• Proceedings of the Korean Society of Rheology Conference
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• 2002.11a
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• pp.23-26
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• 2002

No Abstract, See Full Text

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.194-202
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• 1996

Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.10a
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• pp.80-83
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• 2003

Transcribability of pit or land groove structures in replicating an optical disk substrate greatly affects the performance of a high-density optical disk. However, a solidified layer, generated during the polymer filling, deteriorates transcribability because the solidified layer prevents the polymer melt in filling the sub-micro patterns. Therefore, the development of the solidified layer during filling stage of injection molding must be delayed. For this delay, passive heating by insulation layer has been used. In the present study, to examine the development of the solidified layer delayed by passive heating, the flow of polymer melt with passive heating was analyzed. Passive heating markedly delayed the development of the solidified layer, reduced the viscosity of the polymer melt, and increased the fluidity of the polymer melt in the vicinity of the stamper surface with the sub-micro patterns. As a result, we predict that passive heating can improve transcribability of an optical disk substrate. To verify our prediction, we fabricated an optical disk substrate by using passive heating of a mold and measured the transcribability.

• Transactions of Materials Processing
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• v.13 no.1
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• pp.39-44
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• 2004

Transcribability of pit or land groove structures in replicating an optical disk substrate greatly affects the performance of a high-density optical disk. However, a solidified layer, generated during the polymer filling, deteriorates transcribability because the solidified layer prevents the polymer melt from filling the sub-micro patterns. Therefore, the development of the solidified layer during filling stage of injection molding must be delayed. For this delay, passive heating by insulation layer has been used. In the present study, to examine the development of the solidified layer delayed by passive heating, the flow of polymer melt with passive heating was analyzed. Passive heating markedly delayed the development of the solidified layer, reduced the viscosity of the polymer melt, and increased the fluidity of the polymer melt in the vicinity of the stamper surface with the sub-micro patterns. As a result, we predict that passive heating can improve transcribability of an optical disk substrate. To verify our prediction, we fabricated an optical disk substrate by using passive heating of a mold and measured the transcribability of an optical disk substrate.

• Design & Manufacturing
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• v.9 no.2
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• pp.20-24
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• 2015

Recently, the light guide plate (LGP), a component of the BLU, becomes thinner and larger than ever. In industrial field, specialized injection molding technique is applied to mold the ultra-thin LGP such as a ultra-high speed injection molding. Usually very high melt temperature is used for low viscosity. High injection speed and melt temperature lead to yellowing of LGP. In the present paper a series of injection molding experiment was performed under various injection molding conditions. Yellow index, CIE xy, spectral transmittance of sample were measured using the UV-Visible spectrophotometer. Systematic decrease of spectral transmittance in UV-B range was found as the melt temperature was higher. Yellow index and CIE xy were became higher near the gate location in LGP. From the result of analysis of variance, the main factor to affect for yellow index was mold temperature and that for spectral transmittance(at 315 nm) was melt temperature.

• Food Science and Biotechnology
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• v.15 no.5
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• pp.721-727
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• 2006

This study was carried out to investigate the effect of hydrocolloids on the changes in physical properties of a model ice cream. The model ice cream contained water, sugar, skin milk powder, com oil, and 4 different hydrocolloid stabilizers (gelatin, pectin, hydroxyethylstarch, locust bean gum), was manufactured in a batch type freezer. The following physical characteristics of ice cream were examined: flow behavior, overrun, air cell size, ice crystal size, and melt resistance. With regard to flow behavior, all of aged mixes had a lower apparent viscosity relative to the mix before aging, and ice cream mix containing locust bean gum had the highest viscosity. Air cell size was observed to range from 20 to $38\;{\mu}m$, and ice cream with locust bean gum showed the largest size. There was an inverse correlation between overrun and air cell size. The ice crystal sizes of all samples ranged from 25 to $35\;{\mu}m$. Ice cream with added pectin contained the smallest ice crystal size, which was significantly difference from other stabilizers (p<0.05), and resulted in superior melt resistance with increased melting time compared to other samples.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.2
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• pp.147-154
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• 2003

A three-dimensional numerical analysis of the flow and heat transfer characteristic of wood-flour-filled polypropylene melt in an extrusion die was carried out. Used for this analysis were Finite Concept Method based on FVM, unstructured grid and non-Newtonian fluid viscosity model. Temperature and flow fields are closely coupled through temperature dependent viscosity and viscous dissipation. With large Peclet, Nahme, Brinkman numbers, viscous heating caused high temperature belt near die housing. Changing taper plate thickness and examining some predefined parameters at die exit investigated the effect of taper plate on velocity and temperature uniformities. In the presence of taper plate, uniformity at die exit could be improved and there existed an optimum thickness to maximize it.

• Polymer(Korea)
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• v.26 no.3
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• pp.353-359
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• 2002

High intensity ultrasound has been applied to a series of poly(ethylene oxide) (PEO)/water systems having different molecular weights of PEO. Major interest was focused on the effect of ultrasonic wane on the melt viscosity chemical structure and thermal properties of PEO. The expected role of ultrasound used in this study was to generate macroradicals of PEO chains by the formation and subsequent collapse of bubbles. It was found that the melt viscosity and chemical structure of PEO change significantly depending on the sonication time. For the prolonged sonication, PEO chains were significantly degraded and new end groups were formed by the interplay of various radical species. When the molecular weight of PEO was relatively higher, the crystallization rate was decreased and the intensity of the melting peak was reduced.