• Macromolecular Research
• /
• v.14 no.3
• /
• pp.261-266
• /
• 2006

Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared using a melt blending technique in the presence and absence of glass fiber and coupling agents. The effect of glass fiber and coupling agents on the thermal, dynamic mechanical, morphological pro-perties and cure characteristics of VMQ/LCP blends were studied. The vinyl silane coupling agent showed a significant effect on the above mentioned properties of VMQ/LCP blends by reacting at the interface between VMQ and LCP. The viscosity of the VMQ/LCP blends decreased with the addition of a coupling agent. A substantial improvement in storage modulus of VMQ/LCP blends was observed in the presence of glass fiber and coupling agents. However, as a coupling agent vinyl silane proved to be better than amine for the VMQ/LCP-glass-containing blends. The thermal stability of the pure silicone rubber was higher than those of the blends. This high thermal stability of silicone rubber was attributed to the Si-O-Si bonds. However, the thermal stability of the blends decreased further in the presence of a coupling agent, possibly due to a decrease in blend crystallinity.

• Journal of the Korean Society for Precision Engineering
• /
• v.18 no.12
• /
• pp.60-65
• /
• 2001

To simulate the real molding conditions, the effects of phase change and compressibility of the resin were considered in the present investigation. A modified Cross model with either an Arrhenius-type or WLF-type functional form was used for modeling viscosity of the resin. A double-domain Tait equation of state was employed to describe the compressibility of the resin during molding. The energy balance equation including latent-heat dissipation fur semi-crystalline materials was solved in order to predict the solidified layer and temperature profile. Injection molding experiments were carried out using polypropylene(PP) in the present study. Based on the comparison between experiments and simulations, it was found out the predicted pressure distributions and melt front propagations were accurate. Thus it was concluded that the program developed in this study was proved to be useful in simulations of injection molding process.

• Composites Research
• /
• v.19 no.3
• /
• pp.15-22
• /
• 2006

In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

• Polymer(Korea)
• /
• v.38 no.5
• /
• pp.566-572
• /
• 2014

Maleic anhydride (MAH) grafted polypropylenes (PP) (MAH-g-PP) were prepared by changing MAH content and styrene monomer (SM)/MAH mole ratio with different type PP, using a twin screw extruder. The types of PP were isotatic PP (iPP), block PP (bPP), and random PP (rPP) and dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C=O) stretching peak at $3100cm^{-1}$ of FTIR spectrum. Thermal properties of MAH-g-PP and PP/MAH-g-PP/pulp composites were investigated by DSC and TGA. There was no district change in thermal properties of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for fractured surface of PP/MAH-g-PP/pulp composites, MAH-g-rPP was the best as the compatibilizer and optimum formulation was MAH content of 1.0 wt%, SM/MAH mole ratio of 1.0, and melt index (MI) of 25 g/10 min. The rheological properties of the composites were investigated by a dynamic rheometer. The complex viscosity, shear thinning effect, and water uptake incresed with pulp content.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.4
• /
• pp.86-92
• /
• 2019

Polymers with various compositions of azobenzene and hexamethylene groups in the main chain were synthesized by a Schotten-Baumann reaction and their properties were investigated. The chemical structures and physical properties of the synthesized polymers were investigated by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, polarized optical microscopy, and x-ray diffraction. The polymers showed an inherent viscosity of 1.28-1.36 dl/g and were relatively insoluble in most organic solvents. The melt transition temperature increased rapidly with increasing number of azobenzene groups in the polymer. When the azobenzene monomer content was more than 50 mol%, no melting transition occurred below the decomposition temperature. Among the polymers with a melt transition temperature, the MP-A3C7 and MP-A5C5 polymers were liquid crystalline materials and exhibited a nematic phase with weak liquid crystallinity over a wide liquid crystal temperature range. This difference in the properties of the synthesized polymers is likely due to the changes in intermolecular forces resulting from the linearity and polarity of the trans-form of azobenzene.

• Applied Chemistry for Engineering
• /
• v.22 no.6
• /
• pp.679-684
• /
• 2011

Branched polypropylenes (LCB-PP) with a long chain branch were prepared by the solid-state and molt-state reaction. Divinylbenzene (DVB), 1,4-benzenediol (RES), and furfuryl sulphide (FS) were used as branching agents of fabricate LCB-PP/silicate composites. Chemical structures, thermal properties, and rheological properties of the LCB-PP were determined by FT-IR, DSC, TGA, and dynamic rheometer (ARES). The chemical structure of the LCB-PP was confirmed by the existence of =C-H stretching peak of the branching agent at $3100cm^{-1}$. From DSC and TGA results, the melting reaction was more effective than the solid state reaction in the manufacture of LCB-PP, which was additionally certified by rheological properties. Based on rheological properties, FS was the best for branching efficiency of PP. Compared to PP, LCB-PPs indicated an increase of complex viscosity in the low frequency and shear thinning tendency, and G'-G" plot represented an increase in elasticity and the heterogeneousness in a melt state. Rheological properties of LCB-PP/silicate composites were observed with the silicate content. When 5 wt% silicate was added in LCB-PP, distinct changes in the shear thinning and the slope of G'-G" plots were observed.

• Polymer(Korea)
• /
• v.30 no.1
• /
• pp.85-89
• /
• 2006

The effect of vapor grown carbon fiber (VGCF) contents on electrical and rheological properties of VGCF filled polyphenylene sulfide (PPS) composites prepared through melt mixing using a twin screw exruder was studied. This method was proved to be quite effective to produce good dispersion of VGCF in the matrix even for highly filled PPS. From the dependence of the electrical conductivity on VGCF content, the percolation phenomena began to occur above $10\;wt\%$. While there is only a marginal increase of viscosity for 1 and $5\;wt\%$ VGCF filled PPS, the composites containing $10\;wt\%$. While VGCF showed abrupt increase in viscosity as well as flattening of frequency vs modulus curve, indicating a transition from a liquid-like to a solid-like behavior due to the creation of VGCF network. This result agrees well to the fact that the network formation in the composite can be composite by rheological property dependence on filler content as well as by electrical conductivity measurement.

• Korean journal of food and cookery science
• /
• v.28 no.6
• /
• pp.865-870
• /
• 2012

This study was performed to investigate the effect of steamed garlic powder (SGP) on the quality characteristics of Jochung, saccharide by barley melt. Physicochemical properties and sensory quality were determined in Jochungs were prepared that 5% (SGP 5), 10% (SGP 10), 20% (SGP 20) and 30% (SGP 30) of SGP to sikhe for making jochung and hard boiled (W/W). Turbidity and viscosity of SGP added groups increased than control, significantly. The viscosity was $133{\pm}10^3$ cps in control group, it higher than SGP added groups ($140{\pm}11^3{\sim}272{\pm}2^3$ cps). The pH decreased with increasing SGP concentration. Reducing sugar was significantly higher in SGP added groups than control group, especially 30% SGP addition group in $44.66{\pm}0.26$ mg/100 g. HMF (Hydroxymethyl-furfural) content increased with increasing of SGP concentration, and 30% SGP addition group was higher in 48% than control group. In HPLC determination, free sugars content increased with amounts of SGP addition level. Fructose and glucose contents increased while maltose and raffinose contents decreased. Fructose content was $0.84{\pm}0.02$ mg/100g in control group but $1.36{\pm}0.03{\sim}1.62{\pm}0.01$ mg/100 g in SGP added groups. In the sensory evaluation, the color of Jochung decreased dose dependently with the SGP. Garlic flavor was significantly greater in SGP added groups compared to that of control group. The overall acceptability had not significantly difference among control, SGP 5 and 10 group. Preference was decreased in contain more than 20% of SGP added groups. The optimal concentration of SGP was found in the range of less than 10%.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.34 no.7
• /
• pp.1109-1113
• /
• 2005

The objective of this study was to determine the effect of extrusion temperature on puffing of white and red ginseng powder. The extrusion variables were feed material (red and white ginseng powder) and die temperature $(100\;and\;115^{\circ}C)$. The analyzed characteristics of ginseng extrudates were sectional expansion index, microstructure and rheological properties. Most of biopolymer was highly puffed at higher extrusion temperature, but the cross-sectional expansion of white and red ginseng powder was higher at 1000e and longitudinal expansion seems to higher at $115^{\circ}C$. White and red ginseng powder were puffed inconsistently and discontinuously at $115^{\circ}C$. The scanning electron microphotograph of extruded white ginseng was uniform air cell distribution at 100oe, but pore size increased at $115^{\circ}C$ and had fine uniformity due to pore explosion. White ginseng and its extrudate were pseudoplastic. Intrinsic viscosity was lower as a result of increased die temperature. The cross-sectional expansion seems to be inconsistent and decreased due to decrease in melt viscosity at $115^{\circ}C$.

• Elastomers and Composites
• /
• v.41 no.2
• /
• pp.97-107
• /
• 2006

The recycled polyethylene composites with various ratio of ground waste tire powder were manufactured by using a fully intermeshing co-rotating twin screw extruder for the reuse of waste tire scrap. In this investigation, the ground waste tire powders (GWTP) were blended with virgin HDPE and recycled polyethylene in the weight ratio of 0 to 50 wt.%. Mechanical properties such as tensile strength, elongation at break and impact strength were measured by using ASTM standard. The experimental results for the various composite showed that the tensile strength of composites decreased with increasing GWTP ratio, while elongation at break increased with the amounts of GWTP. On the other hand, the impact strength for the three kinds of composites showed maximum at the 30 wt.% of GWTP and then decreased. Morphology of the fracture surface tends to be rough with increasing waste tire powder content. Rheological properties were investigated by measuring the shear viscosity against shear rates and softening temperatures. They showed that melt viscosity of rubber composites in this study subsequently increased with increasing GWTP content as a result of increase of flow resistance against external stress and followed a Power-law behavior.