• Title/Summary/Keyword: mechanical resistance

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UV-cured Polymer Solid Electrolyte Reinforced using a Ceramic-Polymer Composite Layer for Stable Solid-State Li Metal Batteries

  • Hye Min Choi;Su Jin Jun;Jinhong Lee;Myung-Hyun Ryu;Hyeyoung Shin;Kyu-Nam Jung
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.85-95
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    • 2023
  • In recent years, solid-state Li metal batteries (SSLBs) have attracted significant attention as the next-generation batteries with high energy and power densities. However, uncontrolled dendrite growth and the resulting pulverization of Li during repeated plating/stripping processes must be addressed for practical applications. Herein, we report a plastic-crystal-based polymer/ceramic composite solid electrolyte (PCCE) to resolve these issues. To fabricate the one-side ceramic-incorporated PCCE (CI-PCCE) film, a mixed precursor solution comprising plastic-crystal-based polymer (succinonitrile, SN) with garnet-structured ceramic (Li7La3Zr2O12, LLZO) particles was infused into a thin cellulose membrane, which was used as a mechanical framework, and subsequently solidified by using UV-irradiation. The CI-PCCE exhibited good flexibility and a high room-temperature ionic conductivity of over 10-3 S cm-1. The Li symmetric cell assembled with CI-PCCE provided enhanced durability against Li dendrite penetration through the solid electrolyte (SE) layer than those with LLZO-free PCCEs and exhibited long-term cycling stability (over 200 h) for Li plating/stripping. The enhanced Li+ transference number and lower interfacial resistance of CI-PCCE indicate that the ceramic-polymer composite layer in contact with the Li anode enabled the uniform distribution of Li+ flux at the interface between the Li metal and CI-PCCE, thereby promoting uniform Li plating/stripping. Consequently, the Li//LiFePO4 (LFP) full cell constructed with CI-PCCE demonstrated superior rate capability (~120 mAh g-1 at 2 C) and stable cycle performance (80% after 100 cycles) than those with ceramic-free PCCE.

Quality Characteristics of Pork with Addition of Jubak(Sulchigegie) (주박 첨가가 돈육의 품질특성에 미치는 영향)

  • Won, Ji-Hee;Son, Ju-Ah;Youn, Aye-Ree;Kim, Ho-Jong;Kim, Gye-Won;Noh, Bong-Soo
    • Journal of the Korean Society of Food Culture
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    • v.21 no.5
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    • pp.565-570
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    • 2006
  • This study was to investigate the effect of Jubak(Sulchigegie) on the physicochemical properties of pork. A pork was cooked in a pot opening the lid with the Jubak for 20 min and then covering the lid without Jubak for 20 min at $100^{\circ}C$. Effect of the added amounts of Jubak on the pork was examined by principal component analysis and electronic nose consisting of six metal oxide sensors. As a pork was cooked with 30g Jubak, ratio of resistance was increased. This condition removed unpleasant smell of pork. Effect of the pork with Jubak is better the end location than middle of pork. Also, first principal component score increased as the pork cooking time was increased. In the texture properties, hardness, chewiness, gumminess, and springness of the pork with 30g Jubak were significantly lower than others processed in this study. With sensory evaluation, the pork with 30g Jubak obtained the best score in taste, texture and overall acceptability. It could be concluded that the pork(400g) with 30g Jubak reduces the pork odor, increase the tenderness and improve the flavor and taste of pork.

A Study on Methodology for Improvement of Bond of FRP reinforcement to Concrete (초단유리섬유(milled glass fibers)와 에폭시 혼합물을 이용한 FRP 보강근 표면성형기법 연구)

  • Moon, Do-Young;Sim, Jongsung;Oh, Hongseob
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.775-785
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    • 2006
  • This study focused on the development of surface deformations of GFRP rebars with a better bond characteristic for reinforcing concrete, and simultaneously, of GFRP rebars with more simple and economic production process. This research paper describes a development and bond performance of GFRP rebar with molded deformations, which is composed of polymer resin and milled glass fiber. To determine proper mix ration of milled fibers, material test of hardened epoxy and pullout tests of GFRP rebar with various mix ratio were conducted. The test results indicate that the new strategy of using a mixture of epoxy resin and milled fiber could be successfully applied to a surface structure of GFRP rebar to enhance bond with concrete. The bearing resistance of the ribs was further enhanced by the milled fibers at mechanical and environmental loading state.

Mechanical Characteristics of High Tension Bolted Joint Connections using Shear Ring (전단링을 사용한 고장력볼트 이음부의 역학적 특성에 관한 연구)

  • Lee, Seung Yong;Park, Young Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.2A
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    • pp.327-338
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    • 2006
  • Friction type high tension bolted joints is one of the most common steel structure connections and requires significant concerns on axial force of the bolts. However, its high shear capacity is not appropriately considered in design and hence the number of bolts is over-designed than actually required. It is primarily due to a slip-load-based design method. This study, therefore, suggests a new technology of connection using a shear ring, which may reduce the shortcomings from the friction-typed high tension bolted joints and maximize the advantages from the bearing-typed joints. Experimental and numerical studies were performed to compare the capacity of the suggested method with traditional high tension bolted joints. From the results, it is known that the suggested connections has higher bearing capacity than friction-typed high tension bolted joints due to the higher shear resistance from the ring. For further study, it may be necessary to investigate on design parameters including the depth of shear ring, for increased connection capacity.

Effect of perlite powder on properties of structural lightweight concrete with perlite aggregate

  • Yan, Gongxing;Al-Mulali, Mohammed Zuhear;Madadi, Amirhossein;Albaijan, Ibrahim;Ali, H. Elhosiny;Algarni, H.;Le, Binh Nguyen;Assilzadeh, Hamid
    • Structural Engineering and Mechanics
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    • v.84 no.3
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    • pp.393-411
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    • 2022
  • A high-performance reactive powder concrete (RPC) has been readied alongside river sand, with 1.25 mm particle size when under the condition of 80C steam curing. As a heat and sound insulation, expanded perlite aggregate (EPA) provides economic advantages in building. Concrete containing EPA is examined in terms of cement types (CEM II 32.5R and CEM I 42.5R), doses (0, 2%, 4% and 6%) as well as replacement rates in this research study. The compressive and density of concrete were used in the testing. At the end of the 28-day period, destructive and nondestructive tests were performed on cube specimens of 150 mm150 mm150 mm. The concrete density is not decreased with the addition of more perlite (from 45 to 60 percent), since the enlarged perlite has a very low barrier to crushing. To get a homogenous and fluid concrete mix, longer mixing times for all the mix components are necessary due to the higher amount of perlite. As a result, it is not suggested to use greater volumes of this aggregate in RPC. In the presence of de-icing salt, the lightweight RPC exhibits excellent freeze-thaw resistance (mass is less than 0.2 kg/m2). The addition of perlite strengthens the aggregate-matrix contact, but there is no apparent ITZ. An increased compressive strength was seen in concretes containing expanded perlite powder and steel fibers with good performance.

Rock cutting behavior of worn specially-shaped PDC cutter in crystalline rock

  • Liu, Weiji;Yang, Feilong;Zhu, Xiaohua;Zhang, Yipeng;Gong, Shuchun
    • Geomechanics and Engineering
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    • v.31 no.3
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    • pp.249-263
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    • 2022
  • The specially-shaped Polycrystalline Diamond Compact (PDC) cutter is widely used in drill bit design due to its advantages of high rock cutting efficiency, strong impact resistance and long service life in hard and abrasive formation drilling. A detailed understanding of rock cutting behavior of worn specially-shaped PDC cutter is essential to improve the drilling efficiency and decrease the drilling costs. In this paper, the theoretical models of two new principles (loading performance (LP) and cutting performance (CP)) are derived for evaluating the cutting process of worn specially-shaped cutter, the theoretical models consider the factors, such as cutter geometry, aggressiveness, stress state, working life, and rock cutting efficiency. Besides, the numerical model of heterogeneous granite is developed using finite element method combined with Voronoi tessellation, the LP and CP of 12 kinds of worn specially-shaped PDC (SPDC) cutters are analyzed. The results found that the mechanical specific energy (MSE) of worn cutters first increase and then decrease with increasing the cutting depth, and the MSE increase with the increase of back rake angle except for Conical cutter and Wedge-shaped cutter. From the perspective of CP, the worn PDC cutters are more suitable for the smaller cutting depths, and the back rake angle has little effect on the CP of the specially-shaped worn PDC cutters. Conical cutter, Saddle-shaped cutter and Ellipse-shaped cutter have the highest CP value, while Rhombus-shaped cutter, Convex cutter and Wedge-shaped cutter have the lowest value in selecting cutters. This research leads to an enhanced understanding of rock-breaking mechanisms of worn SPDC cutters, and provides the basis to select of specially-shaped PDC cutters for the specific target formation.

Analysis of the mechano-bactericidal effects of nanopatterned surfaces on implant-derived bacteria using the FEM

  • Ecren Uzun Yaylaci;Mehmet Emin Ozdemir;Yilmaz Guvercin;Sevval Ozturk;Murat Yaylaci
    • Advances in nano research
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    • v.15 no.6
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    • pp.567-577
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    • 2023
  • The killing of bacteria by mechanical forces on nanopatterned surfaces has been defined as a mechano-bactericidal effect. Inspired by nature, this method is a new-generation technology that does not cause toxic effects and antibiotic resistance. This study aimed to simulate the mechano-bactericidal effect of nanopatterned surfaces' geometric parameters and material properties against three implant-derived bacterial species. Here, in silico models were developed to explain the interactions between the bacterial cell and the nanopatterned surface. Numerical solutions were performed based on the finite element method. Elastic and creep deformation models of bacterial cells were created. Maximum deformation, maximum stress, maximum strain, as well as mortality of the cells were calculated. The results showed that increasing the peak sharpness and decreasing the width of the nanopatterns increased the maximum deformation, stress, and strain in the walls of the three bacterial cells. The increase in spacing between nanopatterns increased the maximum deformation, stress, and strain in E. coli and P. aeruginosa cell walls it decreased in S. aureus. The decrease in width with the increase in sharpness and spacing increased the mortality of E. coli and P. aeruginosa cells, the same values did not cause mortality in S. aureus cells. In addition, it was determined that using different materials for nanopatterns did not cause a significant change in stress, strain, and deformation. This study will accelerate and promote the production of more efficient mechano-bactericidal implant surfaces by modeling the geometric structures and material properties of nanopatterned surfaces together.

Machine learning techniques for reinforced concrete's tensile strength assessment under different wetting and drying cycles

  • Ibrahim Albaijan;Danial Fakhri;Adil Hussein Mohammed;Arsalan Mahmoodzadeh;Hawkar Hashim Ibrahim;Khaled Mohamed Elhadi;Shima Rashidi
    • Steel and Composite Structures
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    • v.49 no.3
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    • pp.337-348
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    • 2023
  • Successive wetting and drying cycles of concrete due to weather changes can endanger the safety of engineering structures over time. Considering wetting and drying cycles in concrete tests can lead to a more correct and reliable design of engineering structures. This study aims to provide a model that can be used to estimate the resistance properties of concrete under different wetting and drying cycles. Complex sample preparation methods, the necessity for highly accurate and sensitive instruments, early sample failure, and brittle samples all contribute to the difficulty of measuring the strength of concrete in the laboratory. To address these problems, in this study, the potential ability of six machine learning techniques, including ANN, SVM, RF, KNN, XGBoost, and NB, to predict the concrete's tensile strength was investigated by applying 240 datasets obtained using the Brazilian test (80% for training and 20% for test). In conducting the test, the effect of additives such as glass and polypropylene, as well as the effect of wetting and drying cycles on the tensile strength of concrete, was investigated. Finally, the statistical analysis results revealed that the XGBoost model was the most robust one with R2 = 0.9155, mean absolute error (MAE) = 0.1080 Mpa, and variance accounted for (VAF) = 91.54% to predict the concrete tensile strength. This work's significance is that it allows civil engineers to accurately estimate the tensile strength of different types of concrete. In this way, the high time and cost required for the laboratory tests can be eliminated.

Testing and evaluation of the corrosion behavior of Aluminum/Alumina bulk composites fabricated via combined stir casting and APB process

  • Abdalkareem Jasim;Ghassan Fadhil Smaisim;Abduladheem Turki Jalil;Surendar Aravindhan;Abdullah Hasan Jabbar;Shaymaa Abed Hussein;Muneam Hussein Ali;Muataz S. Alhassan;Yasser Fakri Mustafa
    • Advances in materials Research
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    • v.12 no.4
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    • pp.263-271
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    • 2023
  • In this study, AA1060/Alumina composites were fabricated by combined stir casting and accumulative press bonding (APB). The APB process was repeated up to six press bonding steps at 300Ċ. As the novelty, potential dynamic polarization in 3.5Wt% NaCl solution was used to study the corrosion properties of these composites. The corrosion behavior of these samples was compared and studied with that of the annealed aluminum alloy 1060 and versus the number of APB steps. So, as a result of enhancing influence on the number of APB process, this experimental investigation showed a significant enhancement in the main electrochemical parameters and the inert character of the Alumina particles. Together with Reducing the active zones of the material surfaces could delay the corrosion process. Also, at higher number of steps, the corrosion resistance of composites improved. The sample produced after six number of steps had a low corrosion density in comparison with high corrosion density of annealed specimens. Also, the scanning electron microscopy (SEM), was used to study the corrosion surface of samples.

Performance Evaluation of Impermeable Asphalt Mixture using Cationized Silicate Fiber Modifier (양이온화 실리케이트 섬유 개질재(CSM)를 활용한 비배수성 아스팔트 혼합물의 성능 평가)

  • Young-Wook Kim;Sun-Gyu Tae;Young-Soo Kim;Diana Kim;Young-Il Jang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.3
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    • pp.59-65
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    • 2024
  • In this study, in order to improve the mechanical properties and durability of asphalt mixtures, a modifier (CSM, Cationized Silicate Modifier) was applied to asphalt to derive optimal mixing ratio conditions. Design of asphalt mixture using modified asphalt binder was conducted, and moisture resistance and dynamic stability were evaluated for optimal mixing conditions. The evaluation results showed that it exceeded the standards stipulated in the relevant guidelines, and as a result of conducting a water permeability test on the optimal mixing condition, it was confirmed that impermeable performance was secured. As a result of examining the noise reduction performance through field test, a noise reduction performance of about 10 dB was secured compared to before paving. It will be necessary to secure reliability through continuous noise generation evaluation in the future.