• Title/Summary/Keyword: mechanical and thermal behavior

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An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell (직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구)

  • Ahn, Seong Yool;Rhie, Young Hoon;Eom, Seong Yong;Sung, Yeon Mo;Moon, Cheor Eon;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

Design and Analysis of Composite Reflector of High Stable Deployable Antenna for Satellite (위성용 전개형 고안정 반사판 안테나 복합재 주반사판 설계 및 해석)

  • Dong-Geon Kim;Kyung-Rae Koo;Hyun-Guk Kim;Sung-Chan Song;Seong-Cheol Kwon;Jae-Hyuk Lim;Young-Bae Kim
    • Composites Research
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    • v.36 no.3
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    • pp.230-240
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    • 2023
  • The deployable reflector antenna consists of 24 unit main reflectors, and is mounted on a launch vehicle in a folded state. This satellite reaches the operating orbit and the antenna of satellite is deployed, and performs a mission. The deployable reflector antenna has the advantage of reduce the storage volume of payload of launch vehicle, allowing large space structures to be mounted in the limited storage space of the launch vehicle. In this paper, structural analysis was performed on the main reflector constituting the deployable reflector antenna, and through this, the initial conceptual design was performed. Lightweight composite main reflector was designed by applying a carbon fiber composite and honeycomb core. The laminate pattern and shape were selected as design variables and a design that satisfies the operation conditions was derived. Then, the performance of the lightweight composite reflector antenna was analyzed by performing detailed structural analysis on modal analysis, quasi-static, thermal gradient, and dynamic behavior.

Microstructure and Strengthening Behavior in Squeeze Cast Mg-Zn by Addition of Zr (용탕단조 Mg-Zn-Zr 합금의 미세조직 및 강화기구)

  • Oh, Sang-Sub;Hwang, Young-Ha;Kim, Do-Hyang;Hong, Chun-Pyo;Park, Ik-Min
    • Journal of Korea Foundry Society
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    • v.19 no.1
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    • pp.38-46
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    • 1999
  • Microstructural characteristics and strengthening behavior in Mg-5wt%Zn-0.6wtZr alloys have been investigated by a combination of optical, secondary electron and transmission electron microscopy, differential thermal analysis, and hardness and tensile, creep property measurements. The result have been compared with those of Mg-5wt%Zn alloys. The as-squeeze cast microstructure consisted of dendrite ${\alpha}-Mg$, interdendrite or intergranular $Mg_7Zn_3$ and fine dispersoids of $ZnZr_2$. The size of secondary solidification phases in Mg-5wt%Zn-0.6wtZr alloys was significantly smaller than that of the Mg-5wt%Zn alloys due to the existence of fine dispersoid of $ZnZr_2$ which also effected the refinement of grain size. TEM study showed that the main cause of age hardening is formation of fine rodlike ${\beta}_1\;'$ precipitates as well as fine $ZnZr_2$ dispersoids. Due to the observed microstructural characteristics mechanical propeties of Mg-5wt%Zn-0.6wtZr alloys was found to be superior to those of Mg-5wt%Zn alloys.

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Evaluation of Mechanical Performance Considering Prolonged Length of Glass Fiber-Reinforced Composite on Structure Weakness by Thermal Stress at Secondary Barrier in Cryogenic Liquified Gas Storage (극저온 액화가스 화물창 2차방벽 구조 열 응력 취약 부 Prolonged 길이 고려 유리섬유 강화 복합재 기계적 물성 평가)

  • Yeon-Jae Jeong;Hee-Tae Kim;Jeong-Dae Kim;Jeong-Hyun Kim;Seul-Kee Kim;Jae-Myung Lee
    • Composites Research
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    • v.36 no.4
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    • pp.246-252
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    • 2023
  • A secondary barrier made of glass fiber reinforced composites has been installed infinitely using automatic bonding machine(ABM) in membrane type LNG cargo containment system (CCS). At the same time, significant thermal stress due to cryogenic heat shrinkage has occurred in the composite on the non-bonding area between the adhesive fixation at both ends. There have been studies from the perspective of structural safety evaluation taking this into account, but none that have analyzed mechanical property taking an prolonged length into account. In this study, 2-parameter Weibull distribution statistical analysis was used to standardize reliable mechanical property for actual length, taking into account the composite's brittle fracture of ceramic material with wide fracture strength dispersion. Related experimental data were obtained by performing uniaxial tensile tests at specific temperatures below cryogenic condition considering LNG environment. As a result, the mechanical strength increased about 1.5 times compared to -20℃ at -70℃ and initial non-linear behavior of fiber stretched was suppressed. As the temperature decreased until the cryogenic, the mechanical strength continued to increase due to cold brittleness. The suggested mechanical property in this study would be employed to secure reliable analysis support material property when assessing the safety of secondary barrier's structures.

Investigation of the Cryogenic Performance of the High Density Polyurethane Foam (고밀도 폴리우레탄 폼의 극저온 성능 분석)

  • Jeong-Hyeon Kim;Jeong-Dae Kim;Tae-Wook Kim;Seul-Kee Kim;Jae-Myung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_3
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    • pp.1289-1295
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    • 2023
  • Polyurethane foam insulation required for storing and transporting cryogenic liquefied gas is already widely used as a thermal insulation material for commercial LNG carriers and onshore due to its stable price and high insulation performance. These polyurethane foams are reported to have different mechanical performance depending on the density, and the density parameter is determined depending on the amount of the blowing agent. In this study, density-dependent polyurethane foam was fabricated by adjusting the amount of blowing agent. The mechanical properties of polyurethane foam were analyzed in the room temperature and cryogenic temperature range of -163℃ at 1.5 mm/min, which is a quasi-static load range, and the cells were observed through microstructure analysis. The characteristics of linear elasticity, plateau, and densification, which are quasi-static mechanical behaviors of polyurethane foam, were shown, and the correlation between density and mechanical properties in a cryogenic environment was confirmed. The correlation between mechanical behavior and cell size was also analyzed through SEM morphology analysis. Polyurethane foam with a density of 180 kg/m3 had a density about twice as high as that of a polyurethane foam with a density of 96 kg/m3, but yield strength was about 51% higher and cell size was about 9.5% smaller.

Solder Alloy Types and Solder Joint Reliability Evaluation Techniques (솔더 합금 종류 및 솔더 조인트의 신뢰성 평가 기법)

  • You-Gwon Kim;Heon-Su Kim;Tae-Wan Kim;Hak-Sung Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.1
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    • pp.17-29
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    • 2023
  • In this paper, a method for evaluating the reliability of solder joints is introduced, as they play a crucial role in packaging technology due to the miniaturization and high-performance requirements of electronic device. Firstly, properties of solder based on various alloy compositions and solder types are described, followed by an analysis of solder joint structures in different packages. Next, the influence of solder alloy composition and microstructure on the thermal and mechanical properties of solder is analyzed, and solder creep behavior is briefly introduced. Subsequently, analytical techniques considering creep models and fatigue models for reliability evaluation are presented, and various ways to improve the reliability of solder joints are discussed. This study is expected to provide valuable information for evaluating and enhancing the reliability of solder joints in the semiconductor packaging technology field.

Analysis of Mechanical Behavior and Fracture Toughness $K_{IC}$ on EGW Welded Joints for High Strength EH36-TMCP Ultra Thick Plate (고강도 극후판 EH36-TMCP강 EGW용접부의 역학적 거동 및 파괴인성 $K_{IC}$에 관한 해석)

  • Bang, Hee-Seon;Bang, Han-Sur;Joo, Sung-Min
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.565-572
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    • 2009
  • This work intends to establish the reliability and fracture toughness $K_{IC}$ criterion of welded joints by EGW for high strength EH36-TMCP ultra thick plate. For this, firstly thermo elasto-plastic analysis has been carried out on two pass X-groove butt joint model to clarify the thermal and mechanical behaviour(residual stress, plastic strain, magnitude of stress and their distribution and production mechanism). Moreover, to establish fracture criterion, analysis of fracture toughness $K_{IC}$ has been performed under the notch machined and residual stress with the load condition on EGW welded joints. A quantitative fracture criterion for EGW welded joints is suggested by using $K_{IC}$.

Bonding of nano-modified concrete with steel under freezing temperatures using different protection methods

  • Yasien, A.M.;Bassuoni, M.T.
    • Computers and Concrete
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    • v.26 no.3
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    • pp.257-273
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    • 2020
  • Concrete bond strength with steel re-bars depends on multiple factors including concrete-steel interface and mechanical properties of concrete. However, the hydration development of cementitious paste, and in turn the mechanical properties of concrete, are negatively affected by cold weather. This study aimed at exploring the concrete-steel bonding behavior in concrete cast and cured under freezing temperatures. Three concrete mixtures were cast and cured at -10 and -20℃. The mixtures were protected using conventional insulation blankets and a hybrid system consisting of insulation blankets and phase change materials. The mixtures comprised General Use cement, fly ash (20%), nano-silica (6%) and calcium nitrate-nitrite as a cold weather admixture system. The mixtures were tested in terms of internal temperature, compressive, tensile strengths, and modulus of elasticity. In addition, the bond strength between concrete and steel re-bars were evaluated by a pull-out test, while the quality of the interface between concrete and steel was assessed by thermal and microscopy studies. In addition, the internal heat evolution and force-slip relationship were modeled based on energy conservation and stress-strain relationships, respectively using three-dimensional (3D) finite-element software. The results showed the reliability of the proposed models to accurately predict concrete heat evolution as well as bond strength relative to experimental data. The hybrid protection system and nano-modified concrete mixtures produced good quality concrete-steel interface with adequate bond strength, without need for heating operations before casting and during curing under freezing temperatures down to -20℃.

A Study on Contact Characteristics of Mechanical Face Seals for a Hydro-power Turbine Depending on the Rubbing Surface Geometry (소수력 터빈용 기계평면시일의 표면마찰형상에 따른 접촉특성 해석에관한 연구)

  • Kim Chung-Kyun
    • Tribology and Lubricants
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    • v.22 no.3
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    • pp.119-126
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    • 2006
  • In this paper, the contact behavior characteristics of a primary sealing components such as a seal ring and a seal seat has been presented for a small hydro-power turbine. Using the non-linear FEM analysis, the maximum temperature, the axial displacement, radial differences between a seal ring and a seal seat, and maximum contact normal stress have been analyzed for three optimized sealing profiles in which are designed based on the FEM analysis and Taguchi's experimental method. The three primary sealing profiles between a seal ring and a seal seat are strongly related to a leakage of a water for a hydro-power turbine and wear of a primary sealing component. The computed results show that the contact rubbing area between a seal ring and a seal seat is very important for reducing a friction heating and wear in a sealing gap, and increasing a contact normal stress in primary sealing components. Based on the FEM computation, models II and III in which have a small rubbing surface of seal rings show low dilatation of primary sealing components, and high normal contact stress between a seal ring and a seal seat. Thus, the FEM computed results recommend a short contacting width of a primary sealing component for reducing a leakage and thermal distortions, and expanding a seal life. This means that a conventional primary sealing component may be switched to a reduced sealing face of seal rings.

Characterization of Dicyclopentadiene and 5-Ethylidene-2-norbornene as Self-healing Agents for Polymer Composite and Its Microcapsules

  • Lee, Jong-Keun;Hong, Sun-Ji;Xing Liu;Yoon, Sung-Ho
    • Macromolecular Research
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    • v.12 no.5
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    • pp.478-483
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    • 2004
  • Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbornene (ENB)] as self-healing agents for polymeric composites were microencapsuled by in situ polymerization of urea and formaldehyde. We obtained plots of the storage modulus (G') and tan $\delta$ as a function of cure time by using dynamic mechanical analysis to investigate the cure behavior of the unreacted self-healing agent mixture in the presence of a catalyst. Glass transition temperatures (T$\_$g/) and exothermic reactions of samples cured for 5 and 120 min in the presence of different amounts of the catalyst were analyzed by differential scanning calorimetry. Of the two dienes, ENB may have advantages as a self-healing agent because, when cured under same conditions as DCPD, it reacts much faster in the presence of a much lower amount of catalyst, has no melting point, and produces a resin that has a higher value of T$\_$g/. Microcapsules containing the healing agent were successfully formed from both of the diene monomers and were characterized by thermogravimetric analysis. Optical microscopy and a particle size analyzer were employed to observe the morphology and size distribution, respectively, of the microcapsules. The microcapsules exhibited similar thermal properties as well as particle shapes and sizes.