• Title/Summary/Keyword: maximum rate phenomenon

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The Analysis on the Effects of Hygrothermal Aging to THPP Using DSC and XPS (DSC와 XPS를 통한 수분노화가 THPP 점화제에 미치는 영향 분석)

  • Oh, Juyoung;Kim, Yoocheon;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.79-92
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    • 2019
  • Titanium hydride potassium perchlorate (THPP) is one of the commonly utilized pyrotechnic materials in aerospace industries. The current study elucidates the effects of hygrothermal aging on the combustion of THPP experimentally. First, applying the Differential Scanning Calorimetry (DSC) and isocoversional method, both the delay of reaction start and decrease in maximum reaction rate were observed. The kinetics parameters tended to fluctuate depending the thermal reaction or intermediate product formation of THPP. Also, the oxidants decomposition and fuel oxidation phenomenon were discovered by X-ray photoelectron spectroscopy (XPS). The experimental heat from DSC data were verified as reasonable by comparing with the theoretical heat obtained utilizing both THPP formulation from XPS and NASA Chemical Equilibrium with Applications (CEA). Both data had identical variation trend, which expecially had the highest heat value at 10 weeks aged sample.

A feasibility study on photo-production of 99mTc with the nuclear resonance fluorescence

  • Ju, Kwangho;Lee, Jiyoung;ur Rehman, Haseeb;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.176-189
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    • 2019
  • This paper presents a feasibility study for producing the medical isotope $^{99m}Tc$ using the hazardous and currently wasted radioisotope $^{99}Tc$. This can be achieved with the nuclear resonance fluorescence (NRF) phenomenon, which has recently been made applicable due to high-intensity laser Compton scattering (LCS) photons. In this work, 21 NRF energy states of $^{99}Tc$ have been identified as potential contributors to the photo-production of $^{99m}Tc$ and their NRF cross-sections are evaluated by using the single particle estimate model and the ENSDF data library. The evaluated cross sections are scaled using known measurement data for improved accuracy. The maximum LCS photon energy is adjusted in a way to cover all the significant excited states that may contribute to $^{99m}Tc$ generation. An energy recovery LINAC system is considered as the LCS photon source and the LCS gamma spectrum is optimized by adjusting the electron energy to maximize $^{99m}Tc$ photo-production. The NRF reaction rate for $^{99m}Tc$ is first optimized without considering the photon attenuations such as photo-atomic interactions and self-shielding due to the NRF resonance itself. The change in energy spectrum and intensity due to the photo-atomic reactions has been quantified using the MCNP6 code and then the NRF self-shielding effect was considered to obtain the spectrums that include all the attenuation factors. Simulations show that when a $^{99}Tc$ target is irradiated at an intensity of the order $10^{17}{\gamma}/s$ for 30 h, 2.01 Ci of $^{99m}Tc$ can be produced.

Decision based uncertainty model to predict rockburst in underground engineering structures using gradient boosting algorithms

  • Kidega, Richard;Ondiaka, Mary Nelima;Maina, Duncan;Jonah, Kiptanui Arap Too;Kamran, Muhammad
    • Geomechanics and Engineering
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    • v.30 no.3
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    • pp.259-272
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    • 2022
  • Rockburst is a dynamic, multivariate, and non-linear phenomenon that occurs in underground mining and civil engineering structures. Predicting rockburst is challenging since conventional models are not standardized. Hence, machine learning techniques would improve the prediction accuracies. This study describes decision based uncertainty models to predict rockburst in underground engineering structures using gradient boosting algorithms (GBM). The model input variables were uniaxial compressive strength (UCS), uniaxial tensile strength (UTS), maximum tangential stress (MTS), excavation depth (D), stress ratio (SR), and brittleness coefficient (BC). Several models were trained using different combinations of the input variables and a 3-fold cross-validation resampling procedure. The hyperparameters comprising learning rate, number of boosting iterations, tree depth, and number of minimum observations were tuned to attain the optimum models. The performance of the models was tested using classification accuracy, Cohen's kappa coefficient (k), sensitivity and specificity. The best-performing model showed a classification accuracy, k, sensitivity and specificity values of 98%, 93%, 1.00 and 0.957 respectively by optimizing model ROC metrics. The most and least influential input variables were MTS and BC, respectively. The partial dependence plots revealed the relationship between the changes in the input variables and model predictions. The findings reveal that GBM can be used to anticipate rockburst and guide decisions about support requirements before mining development.

Contribution of Non-Point Pollution to Water Quality and Runoff Characteristics from Agricultural Area of the Upstream Watersheds of Lake Chinyang

  • Lee, Chun-Sik;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.22 no.3
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    • pp.259-267
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    • 2013
  • In this study, non-point source(NPS) contribution was investigated based on flow rates and water qualities of streams into the lake during rainfall events. Event mean concentration(EMC) and the pollution loads were calculated to establish a database for NPS control measurement in the survey area, and so on. The runoff characteristics of NPS were investigated and estimated on the basis of the ratio of an agricultural to forest area in the stream of sub-catch basin during rainfall events. Non-point source pollution loads were also calculated to establish a database for NPS control measure in the upstream lake Chinyang. At a rainfall event, BOD concentrations rise sharply at the early peak time of runoff, however, peaks of TSS concentration were observed at the similar time of peak flow. This was a phenomenon shown at the watersheds caused by forest and geological types. The discharged EMC range was 2.9-4.8 mg/L in terms of BOD. The discharged EMC range was 6.2-8.2 mg/L in terms of SS. The discharged EMCs of T-N and T-P were 1.4-2.5 mg/L and 0.059-0.233 mg/L, respectively. Total BOD loading rate through the 3 tributaries to the lake Chinyang was 1,136 kg/d during dry weather. The upper watershed area of the Nam-river dam in this study was divided into 14 catchment basins based on the Korean guideline for total maximum daily load(TMDL) of water quality pollutants. The higher the agricultural land-use ratio, the more NPS loading rate discharged, but the more occupied a forest area, the lower more NPS loading rate discharged. In an agricultural land-use area more than 20%, the increase of NPS loadings might be dramatically diffused by increasing the integrated complex-use like vinyl-house facilities and fertilizer use etc. according to the effective land-use utilization. The NPS loading rates were BOD 0.3 $kg/ha{\cdot}day$, SS 0.21 $kg/ha{\cdot}day$, TN 0.02 $kg/ha{\cdot}day$, TP 0.005 $kg/ha{\cdot}day$ under less than 10% agricultural land-use. In agricultural land-use of 20%-50%, these values were investigated in the range of 0.32 $kg/ha{\cdot}day$-0.73 $kg/ha{\cdot}day$ for BOD, 0.92 $kg/ha{\cdot}day$-3.32 $kg/ha{\cdot}day$ for SS, 0.70 $kg/ha{\cdot}day$-0.90 $kg/ha{\cdot}day$ TN, 0.03 $kg/ha{\cdot}day$-0.044 $kg/ha{\cdot}day$ for TP.

A Study on the Application Scheme of Fire Identification Considering the Heat Release Rate Characteristics of Inflammable Material (가연물의 발열량 특성을 고려한 화재감식 적용방안에 관한 연구)

  • Kang, Jung-Ki;Oh, Jin-Hee;You, Woo-Jun;Ryou, Hong-Sun;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.52-57
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    • 2014
  • The present study suggests the fundamental method for the prediction time of the fire origin by analyzing the combustion phenomenon of inflammable material in the building structure. The heat release rate (HRR) with time variant is evaluated for the interphone as a inflammable material, which is opted from the fire incidents in the stairwell. the fire dynamics simulator (FDS ver. 6.1) is applied in order to analyze the difference of the smoke inflow time to the downstair from the fire event area with various fire pattern. The results show that the maximum inflow time difference for the case of the interphone made from ABS materials is about 4.93 times with the input conditions of heat flux values and the environment in the FDS for the fixed stairwell which composed of total volume $291.3m^3$, floorage $23.3m^2$ and the height of each floor 2.5 m. This research can be practical information for the application method of simulation scheme with experimental data to the fire Identification.

Effects of Low Air Temperature and Light Intensity on Yield and Quality of Tomato at the Early Growth Stage (정식 초기의 저온·저일조가 토마토 수량·품질에 미치는 영향)

  • Wi, Seung Hwan;Yeo, Kyung-Hwan;Choi, Hak Soon;Yu, Inho;Lee, Jin Hyong;Lee, Hee Ju
    • Journal of Bio-Environment Control
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    • v.30 no.4
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    • pp.448-454
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    • 2021
  • This study was conducted to the effect of low air temperature and light intensity conditions on yield and quality of tomato at the early stage of growth in Korea. Inplastic greenhouses, low temperature and low temperature with shade treatments were performed from 17 to 42 days after plant. Tomato growing degree days were decreased 5.5% due to cold treatment during the treatment period. Light intensity decreased 74.7% of growing degree days due to shade. After commencing treatments, the plant growth decreased by low temperature and low radiation except for height. Analysis of the yield showed that the first harvest date was the same, but the yield of the control was 3.3 times higher than low temperature with shade treatment. The cumulative yields at 87 days after transplanting were 1734, 1131, and 854 g per plant for control, low temperature, and low temperature with shade, respectively. The sugar and acidity of tomatoes did not differ between treatment and harvesting season. To investigate the photosynthetic characteristics according to the treatment, the carbon dioxide reaction curve was analyzed using the biochemical model of the photosynthetic rate. The results showed that the maximum photosynthetic rate, J (electric transportation rate), TPU (triose phosphate utilization), and Rd (dark respiration rate) did not show any difference with temperature, but were reduced by shading. Vcmax (maximum carboxylation rate) was decreased depending on the low temperature and the shade. Results indicated that low temperature and light intensity at the early growth stage can be inhibited the growth in the early stage but this phenomenon might be recovered afterward. The yield was reduced by low temperature and low intensity and there was no difference in quality.

Changes in Major Components of Japanese Apricot during Ripening (매실의 성숙중 주요성분의 변화)

  • Shim, Ki-Hwan;Sung, Nack-Kie;Choi, Jine-Shang;Kang, Kap-Suk
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.1
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    • pp.101-108
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    • 1989
  • In order to determine optimal conditions for the preparation of Japanese apricot wine, the changes in major components were experimented during ripening. A weight was $18.3{\pm}2.57\;g$ at June 22 or so. Moisture was reached $92.1{\pm}0.17\;%$ at that time. Respiration amounts were decreased by degrees during the ripening of Japanese apricot but came near climacteric maximum state about June 22. pH was decreased from $2.76{\pm}0.025$ to $2.51{\pm}0.081$, titratible acidity was increased from $1.15%{\pm}0.083%$ to $1.39{\pm}0.061%$. Fe was detected most of all and Zn, Mg, Cu and Ca were checked by the next order in mineral contents. And the rate of mineral contents was decreasing phenomenon slightly with ripening. Total sugar, about June 8, was higher than any other time with $1.74{\pm}0.090%$ and reducing sugar was increased with similarly a tendency of total sugar. Malic and citric acid were much of organic acids. The content of malic acid was decreased greatly but ctric acid was increased during ripening.

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A Study of Cardiothoracic Ratio in Insurance Medicine (심흉비(心胸比)의 보험의학적(保險醫學的) 고찰(考察))

  • Im, Young-Hoon
    • The Journal of the Korean life insurance medical association
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    • v.2 no.1
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    • pp.152-181
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    • 1985
  • A statistical analysis on the cardiothoracic ratio in insurance medicine was carried out for 5,200 insured persons who were medically examined including photofluorography of the chest at the Honam medical department, Dong Bang life insurance Company, Ltd from November, 1979 to August, 1984. The results were as follows: 1. The mean value of the cardiothoracic ratio in all of the insured was $44.2{\pm}4.3%$. The mean value of the cardiothoracic ratio was $43.1{\pm}4.1%$ in all males and $45.2{\pm}4.2%$ in all females, and the difference of the values between males and females showed statistical significance(P<0.001). In each age group, the mean value of the cardiothoracic ratios of female was higher than that of male without exception and the difference of the values between males and females showed statistical significance(P<0.001). The mean value of the cardiothoracic ratio showed gradual increase with age from the second to sixth decade in male(P<0.05 or 0.001 after fourth decade) and from the second to seventh decade in female(P<0.05 or 0.001 from the second to sixth decade). 2. Correlation between both sexes and among age groups relating to the cardiothoracic ratios of the insureds seen to be a physiological phenomenon of the cardiac size and should be considered on the rating of the cardiothoracic ratio. Based on the correlation above mentioned and an author's assumption that the incidence of normal and abnormal cardiothoracic ratios in each age group would show the same rate in male and female, author prepared a modified rating table from the existing table; in male group the existing rating table is used and in female group the ratings of 0, 30-50, 50-100 and 100-D are to calculate by the cardiothoracic ratio of 51%or under, 52-56%, 57-61% and 62% or over respectively in the age group below 39, by the cardiothoracic ratio of 52% or under, 53-57%, 58%-62% and 63% or over respectively in the age group of 40-49, by the cardiothoracic ratio of 53% or under, 54-58%, 59-63% and 64% or over respectively in the age group over 60. 3. The relative frequency distribution polygons of the cardiothoracic ratio of both sexes drawn in a pair on one coordinate plane revealed lying in juxtaposition each other horizontally and showed the shifting of females polygon to male's one toward the direction of greater value of the cardiothoracic ratio at a short distance which increased gradually with age. 4. The minimum cardiothoracic ratio was 31.2% and the maximum cardiothoracic ratio was 63.6% in all of the insured. 5. In each age group, no significant sex difference was found in the relative frequency distribution of ratings by the cardiothoracic ratios of 5,200 insureds by using the rating table modified by author, while significant sex difference was found by using the existing rating table.

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Micropropagation through Stem, Node-bud Shoot Tip and Bulblet Scale Culture in Fritillaria thunbergii Miq. (패모의 줄기, 마디, 정단 및 자구인편 배양에 의한 기내 증식)

  • Peak, Kee-Yoeup;Yu, Kwang-Jin;Seong, Nak-Sul;Choi, In-Sick;Cho, Jin-Tae
    • Korean Journal of Medicinal Crop Science
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    • v.2 no.2
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    • pp.154-161
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    • 1994
  • This experiment was carried out to establish micropropagation system in Fritillaria thunbergii Miq. Through the culture of bulblet scales, stems, node-buds and shoot tips with special reference to the effect of physiological age of explant and plant growth regulators on bulblet formation. Number of formed bulblets was significantly increased in node-bud or stem tissue compared to scals segments and on the medium supplemented with kinetin than BA containing medium. Optimum levels of kinetin for bulblet formation from node-bud taken from above 3 cm shoot length and stem segments excised from below 3 cm shoot length were 5.0 mg /L and $1.0{\sim}3.0\;mg$ /L kinetin, respectively. Interesting phenomenon was observed, the direct formation of bulblets from the axilliary bud of cultured explants. Bulblet forming capacity in stem tissue was depended on stem age, young stem had high regeneration ability compared to old stem taken from above 10 cm shoot length. 1.0 mg /L kinetin was optimum concentration for the formation of bulblets from old stem segments. Stem tissue taken from underground growing plant was promoted coampare to shoot tips or bulb scale segments. Optimum concentration of sucrose was $5{\sim}7%$. Summariged above results revealed that effective explant for micropropagation was stem and /or node-bud tissue excised from less than 3 cm plant height compared to those of bulb scale segments which showed high contamination after culture. Maximum multiplication rate of young stem and /or node-bud segment was about 20 times. Kinetin requirement for stimulation of bulblet formation from cultured explant depended on source of explants but favorable levels of kinetin for organogenesis ranged from 1.0 mg /L to 5.0 mg /L.

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THREE DIMENSIONAL FINITE ELEMENT STRESS ANALYSIS OF IMPLANT PROSTHESIS ACCORDING TO THE DIFFERENT FIXTURE LOCATIONS AND ANGULATIONS (임플랜트 지지 보철물에서 고정체의 식립위치와 각도에 따른 삼차원 유한요소법적 응력분석에 관한 연구)

  • Park Won-Hee;Lee Young-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.43 no.1
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    • pp.61-77
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    • 2005
  • Statement of problem. The implant prosthesis has been utilized in various clinical cases thanks to its increase in scientific effective application. The relevant implant therapy should have the high success rate in osseointegration, and the implant prosthesis should last for a long period of time without failure. Resorption of the peri-implant alveolar bone is the most frequent and serious problem in implant prosthesis. Excessive concentration of stress from the occlusal force and biopressure around the implant has been known to be the main cause of the bone destruction. Therefore, to decide the location and angulation of the implant is one of the major considering factors for the stress around the implant fixture to be dispersed in the limit of bio-capacity of load support for the successful and long-lasting clinical result. Yet, the detailed mechanism of this phenomenon is not well understood. To some extent, this is related to the paucity of basic science research. Purpose. The purpose of this study is to perform the stress analysis of the implant prosthesis in the partially edentulous mandible according to the different nature locations and angulations using three dimensional finite element method. Material and methods, Three 3.75mm standard implants were placed in the area of first and second bicuspids, and first molar in the mandible Thereafter, implant prostheses were fabricated using UCLA abutments. Five experimental groups were designed as follows : 1) straight placement of three implants, 2) 5$^{\circ}$ buccal and lingual angulation of straightly aligned three implants, 3) 10$^{\circ}$ buccal and lingual angulation of straightly aligned three implants. 4) lingual offset placement of three implants, and 5) buccal offset placement of three implants. Average occlusal force with a variation of perpendicular and 30$^{\circ}$ angulation was applied on the buccal cusp of each implant prosthesis, followed by the measurement of alteration and amount of stress on each configurational implant part and peri-implant bio-structures. The results of this study are extracted from the comparison between the distribution of Von mises stress and the maximum Von mises stress using three dimensional finite element stress analysis for each experimental group. Conclusion. The conclusions were as follows : 1. Providing angulations of the fixture did not help in stress dispersion in the restoration of partially edentulous mandible. 2. It is beneficial to place the fixture in a straight vertical direction, since bio-pressure in the peri-implant bone increases when the fixture is implanted in an angle. 3. It is important to select an appropriate prosthodontic material that prevents fractures, since the bio-pressure is concentrated on the prosthodontic structures when the fixture is implanted in an angle. 4. Offset placement of the fixtures is effective in stress dispersion in the restoration of partially edentulous mandible.