• Journal of the Korean Ceramic Society
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• v.51 no.4
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• pp.243-247
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• 2014

Spherical NiO-YSZ particles were synthesized by ultrasonic spray pyrolysis (USP). The morphology of the synthesized particles can be modified by controlling parameters such as precursor pH, carrier-gas flow-rate, and temperature of the heating zone. The synthesized spherical NiO-YSZ particles have rough surface morphology at high carrier-gas flow-rates due to rapid gas exhaustion and insufficient particle ordering. The Ni-YSZ cermet anode synthesized by ultrasonic spray pyrolysis at a flow rate of l L/min, with precursor solution at pH4, showed a higher maximum power density of 256 $mW/cm^2$ compared to a conventionally mixed Ni-YSZ anode (185 $mW/cm^2$) at $800^{\circ}C$. While the area-specific resistance of conventionally mixed Ni-YSZ anodes increases gradually with operation time (indicating performance degradation), the Ni-YSZ anode synthesized by USP does not exhibit any performance degradation, even after 500 h.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2828-2833
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• 2008

Water management is one of many operating parameters, which influences the performance and stability of a proton exchange membrane fuel cell (PEMFC). Local humidity condition including liquid water saturation has profound impacts on the distributions of overpotentials, current density, and membrane water content. Computational fluid dynamics simulations were conducted to investigate the effect of the inlet humidity variation on the performance of a PEMFC of $9\;cm^2$ active cell area with serpentine flow fields. The results showed that the performance of the simulated PEMFC remained at an almost same level when the cathode inlet humidity was changed from 100% to 60%, while reaching its maximum at air humidity of 80%. However, further decrease in the cathode inlet humidity below 40% started to significantly deteriorate the performance of the PEMFC. The variations of overpotentials, membrane water content, etc. due to the change in the cathode inlet humidity were also discussed.

• Journal of Hydrogen and New Energy
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• v.21 no.5
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• pp.419-424
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• 2010

The 125kW external reforming (ER) type molten carbonate fuel cell (MCFC) system for developing a commercial prototype has been operated at Boryeong thermal power plant site since the end of 2009. The system consists of 125kW stack with $10,000 cm^2$ effective area, mechanical balance of plant (MBOP) with anode recycle system, and electrical balance of plant (EBOP). The 125kW MCFC stack installed in December, 2009 has been operated from January, 2010 after 20 days pre-treatment. The stack open circuit voltage (OCV) was 214V at initial load operation, which approaches the thermodynamically theoretical voltage. The stack voltage remained stable range from 160V to 180V at the maximum generating power of 120 kW DC. The stack has been operated for 3,270 hours and operated at rated power for 1,200 hours.

• Journal of IKEEE
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• v.23 no.3
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• pp.826-831
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• 2019

The stand-alone photovoltaic power systems are widely used for lighting equipment and CCTV. In order for these devices to be competitive, the life of power storage devices such as batteries is very important. The characteristic Hybrid supercapacitor is the high power density and long life. We have proposed a stand-alone photovoltaic power system that uses hybrid supercapacitor. The charge and discharge characteristics and the internal resistance of the hybrid capacitor were measured to configure the power converter. A stable maximum output point tracking control algorithm is proposed even with the change in solar radiation. In order to verify the validity of the proposed system, a prototype was fabricated and tested using a 18W hybrid capacitor and a 10W solar cell.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.387-391
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• 2019

A highly porous Ni@MIL-101catalyst for urea oxidation was synthesized by anchoring Ni into a Cr-based metal-organic framework, MIL-101, particles. The morphology, structure, and composition of as synthesized Ni@MIL-101 catalysts were characterized by X-Ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The electro-catalytic activity of the Ni@MIL-101catalysts towards urea oxidation was investigated using cyclic voltammetry. It was found that the structure of Ni@MIL-101 retained that of the parent MIL-101, featuring a high BET surface area of $916m^2g^{-1}$, and thus excellent electro-catalytic activity for urea oxidation. A $urea/H_2O_2$ fuel cell with Ni@MIL-101 as anode material exhibited an excellent performance with maximum power density of $8.7mWcm^{-2}$ with an open circuit voltage of 0.7 V. Thus, this work shows that the highly porous three-dimensional Ni@MIL-101 catalysts can be used for urea oxidation and as an efficient anode material for urea fuel cells.

• Korean Journal of Remote Sensing
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• v.15 no.1
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• pp.9-20
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• 1999

The use of climatic information is essential in the industial society. More specialized weather servies are required to perform better industrial acivities including agriculture. Especially, crop models require daily weather data of crop growing area or cropping zones, where routine weather observations are rare. Estimates of the spatial distribution of daily climates might complement the low density of standard weather observation stations. This study was conducted to estimate the spatial distribution of daily minimum and maximum temperatures in Korean Peninsula. A topoclimatological technique was first applied to produce reasonable estimates of monthly climatic normals based on 1km $\times$ 1km grid cell over study area. Harmonic analysis method was then adopted to convert the monthly climatic normals into daily climatic normals. The daily temperatures for each grid cell were derived from a spatial interpolation procedure based on inverse-distance weighting of the observed deviation from the climatic normals at the nearest 4 standard weather stations. Data collected from more than 300 automatic weather systems were then used to validate the final estimates on several dates in 1997. Final step to confirm accuracy of the estimated temperature fields was comparing the distribution pattern with the brightness temperature fields derived from NOAA/AVHRR. Results show that differences between the estimated and the observed temperatures at 20 randomly selected automatic weather systems(AWS) range from -3.$0^{\circ}C$ to + 2.5$^{\circ}C$ in daily maximum, and from -1.8$^{\circ}C$ to + 2.2$^{\circ}C$ in daily minimum temperature. The estimation errors, RMSE, calculated from the data collected at about 300 AWS range from $1.5^{\circ}C$ to 2.5$^{\circ}C$ for daily maximum/minimum temperatures.

• Journal of Ocean Engineering and Technology
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• v.17 no.6
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• pp.7-15
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• 2003

A Digital Wave Tank simulation technique, based on a finite-difference method and a modified marker-and-cell (MAC) algorithm, is applied in order to investigate the characteristics of nonlinear Tsunami propagations and their interactions with a 2D sloping beach, Ohkushiri Island, and to predict maximum wove run-up around the island. The Navier-Stokes (NS) and continuity equation are governed in the computational domain, and the boundary values are updated at each time step, by a finite-difference time-marching scheme in the frame of the rectangular coordinate system. The fully nonlinear, kinematic, free-surface condition is satisfied by the modified marker-density function technique. The near shore Tsunami is assumed to be a solitary wave, and is generated from the numerical wave-maker in the developed Digital Wave Tank. The simulation results are compared with the experiments and other numerical methods, based on the shallow-water wave theory.

• Journal of Biomedical Engineering Research
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• v.14 no.3
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• pp.209-220
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• 1993

Microspheres are expected to be applied to biomedical areas such as solid-phase immunoassays, drug delivery systems, Immunomagnetic cell separation. To synthesize micro-spheres for biomedical application, "two stage shot growth method" was developed. The uniformity ratio or synthesized microspheres was always smatter than 1.05. And the surface charge density (or the number of ionizable functional groups) of the microspheres synthesized by "two stage shot growth method" was 6-13 times higher than thats of the ml crospheres synthesized by conventional seeded batch copolymerization. As a previous step for biomedical application, adsorption experiments of bovine albumin on microspheres were carried out under various conditions. The maximum adsorbed amount was obtained in the neighborhood of pH 4.5. Isoelectric point of bovine albumin Is pH 5.0, so experimental result shows that it shifted to acid area. The adsorption Isotherm was obtained, the plateau region was always reached at 2.Og/L (bulk concentration of bovine albumin ) . The effect of the kind and the amount of surface functional group was also examined.p was also examined.

• Journal of Biomedical Engineering Research
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• v.7 no.2
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• pp.183-190
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• 1986

Microspheres are expected to be applied to biomedical areas such as solid-phase immunoassays, drug delivery systems, immunomagnetic cell separation. To synthesize microspheres for biomedical application, "two stage shot growth method" was developed. The uniformity ratio of synthesized microspheres was always smaller than 1.05. And the surface charge density (or the number of ionizable functional groups) of the microspheres synthesized by "two stage shot growth method" was 6~13 times higher than that of the microspheres synthesized by conventional seeded batch copolymerization. As a previous step for biomedical application, adsorption experiments of bovine albumin on microspheres were carried out under various conditions. The maximum adsorbed amount was obtained in the neighborhood of pH 4.5. Isoelectric point of bovine albumin is pH 5.0, so experimental result shows that it shifted to acid area. The adsorption isotherm was obtained, the plateau region was always reached at 2.Og/L (bulk concentration of bovine albumin).The effect of the kind and the amount of surface functional group was also examined.p was also examined.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.11a
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• pp.5-6
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• 2006

There are typically applied on both rear and front sides of electrical contacts to the solar cell. The front contact formation is particularly sensitive to many parameters. Accordingly patterning of front grid line is an important factor of solar cells. This paper describe the electrical conversion efficiency, inclusive of shading loss that gives various spacing between front metal grid lines. In experiments with variation of spacing. It was verified that the wide spacing of grid fingers could increase the series resistance, also the narrow spacing of grid fingers also implies a grid with a higher density of grid fingers. The sunlight of incidence was more of reflection by grid fingers. In result, the short circuit current, which contribute to conversion efficiency was decreased, because maximum power input was reduced and increase the series resistance.