• Title/Summary/Keyword: matrix application

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Preparation of Azidated Polybutadiene(Az-PBD)/Ethylene-Vinyl Acetate Copolymer(EVA) Blends for the Application of Energetic Thermoplastic Elastomer (에너지함유 열가소성탄성체 적용을 위한 아지드화 폴리부타디엔/에틸렌-비닐아세테이트 공중합체 블렌드 제조)

  • Yoon, Sang Won;Choi, Myung Chan;Chang, Young-Wook;Noh, Si-Tae;Kwon, Soon Kil
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.282-288
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    • 2015
  • A new energetic thermoplastic elastomer based on the azidated polybutadiene(Az-PBD)/ethylene vinyl acetate copolymer (EVA) blends was prepared, and structure and properties of the blends were invetigated by SEM, DSC, DMA, tensile testing and combustion test. The Az-PBD was synthesized via a two-step process involving the addition reaction of commercially available 1,2-PBD with $Br_2$ and subsequent nucleophilic substitution reaction of the brominated PBD with $NaN_3$. EVA/Az-PBD with 90/10, 80/20, 70/30 (wt/wt) was prepared by a solution blending. SEM, DSC, and DMA results revealed that the blends are partially compatible and Az-PBD is dispersed in continuous EVA matrix. Tensile test showed that modulus and tension set increased while elongation-at-break of the blends decreased with increasing Az-PBD content in the blends, but all the blends showed a elongation at break as high as 700% and a tension set of less than 5%, indicating that the blends are typically elastomeric. Combustion test showed that, with increasing Az-PBD content in the blend, higher energy can be released.

A Study on the Effective Method to Producing Data for The ROKA Live Fire Training Range Safety (한국군 실 사격 훈련간 효율적인 안전지대 데이터 구축 방안 연구)

  • Lee, June-Sik;Choi, Bong-Wan;Oh, Hyun-Seung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.3
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    • pp.64-77
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    • 2015
  • An effective method for produce munitions effectiveness data is to calculate weapon effectiveness indices in the US military's Joint Munitions Effectiveness Manuals (JMEM) and take advantage of the damage evaluation model (GFSM) and weapon Effectiveness Evaluation Model (Matrix Evaluator). However, a study about the Range Safety that can be applied in the live firing exercises is very insufficient in the case of ROK military. The Range Safety program is an element of the US Army Safety Program, and is the program responsible for developing policies and guidance to ensure the safe operation of live-fire ranges. The methodology of Weapon Danger Zone (WDZ) program is based on a combination of weapon modeling/simulation data and actual impact data. Also, each WDZ incorporates a probability distribution function which provides the information necessary to perform a quantitative risk assessment to evaluate the relative risk of an identified profile. A study of method to establish for K-Range Safety data is to develop manuals (pamphlet) will be a standard to ensure the effective and safe fire training at the ROK military education and training and environmental conditions. For example, WDZs are generated with the WDZ tool as part of the RMTK (Range Managers Tool Kit) package. The WDZ tool is a Geographic Information System-based application that is available to operational planners and range safety manager of Army and Marine Corps in both desktop and web-based versions. K-Range Safety Program based on US data is reflected in the Korean terrain by operating environments and training doctrine etc, and the range safety data are made. Thus, verification process on modified variables data is required. K-Range Safety rather than being produced by a single program, is an package safety activities and measures through weapon danger zone tool, SRP (The Sustainable Range Program), manuals, doctrine, terrain, climate, military defence M&S, weapon system development/operational test evaluation and analysis to continuously improving range safety zone. Distribution of this K-range safety pamphlet is available to Army users in electronic media only and is intended for the standing army and army reserve. Also publication and distribution to authorized users for marine corps commands are indicated in the table of allowances for publications. Therefore, this study proposes an efficient K-Range Safety Manual producing to calculate the danger zones that can be applied to the ROK military's live fire training by introducing of US Army weapons danger zone program and Range Safety Manual

Effect on Graphene Addition on Characteristics of Polypropylene Biocomposites Reinforced with Sulfuric Acid Treated Green Algae (황산처리된 녹조류 보강 폴리프로필렌 바이오복합재료에 대한 그래핀 첨가영향)

  • Jang, Young Hun;Han, Seong Ok;Kim, Hyung-Il;Sim, I Na
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.518-525
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    • 2013
  • To improve the mechanical properties of polypropylene (PP) biocomposites reinforced with sulfuric acidtreated green algae (SGA), SGA/graphite nanoplatelets (GNP)/PP biocomposites were prepared and their properties were evaluated depending on the particle size and content of GNP. The flexural and impact strength of SGA/GNP/PP biocomposites decreased with the addition of GNP, whereas the flexrual and storage moduli were greatly improved with increasing GNP loading. SGA/GNP/PP biocomposites reinforced with GNP5 showed generally better mechanical properties compared to that reinforced with GNP15 mainly due to the improved dispersion of the smaller GNP. SGA/GNP/PP biocomposites reinforced with GNP5 showed a lower resistance to the thermal expansion because the relatively uniform dispersion of smaller GNP was responsible for the effective heat transfer to the polymer matrix. As a result, SGA/GNP/PP biocomposite was acceptable for the general purpose application due to the improved flexural resistance, storage moduli, and damping characteristics.

Application of the Pesticide Multiresidue Analysis Method for Potatoes and Carrots (감자 및 당근의 개선된 농약 동시다성분 분석법 적용 연구)

  • Kim, Min-Jung;Jung, See-Sub;Park, Jong-Sel;Kim, Jang-Eok;Lee, Young-Deuk;Kim, Jeong-Han;Oh, Chang-Hwan
    • Korean Journal of Food Science and Technology
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    • v.37 no.2
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    • pp.304-307
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    • 2005
  • Multiresidue method was set up for the simultaneous determination of various residual pesticides in potatoes and carrots, which was analyzed by gas chromatography-electron capture detector/nitrogen phosphorus detector. Method consisted with acetone/acetonitrile (9 : 1) extraction and dichloromethane partition, followed by florisil cartridge purification with hexane/dichloromethane/acetonitrile (50 : 45 ; 5) elution. Among 197 pesticides (194 kinds) spiked to food materials, 143 and 155 pesticides were recovered over 70% on potatoes and carrots, respectively. Nineteen pesticides including bromacil, cyproconazole, were not detected in water and sample matrices. Matrix components may affect the low detections of 25 pesticides such as benfuracarb, bitertanol from potatoes and 16 pesticides such as bitertanol, carbosulfan from Carrots. Some pesticides including dichlobenil, fluoroimide and iprodione were highly detected from one or both matrices even though they were not detected from water.

Synthesis and Characterization of PPC/Organo-Clay Nanohybrid: Influence of Organically Modified Layered Silicates on Thermal and Water Absorption Properties (PPC와 Organo-Clay 나노 조성물의 합성과 실리카층의 수분흡수와 열적특성에 대한 영향)

  • Han, Hak-Soo;Khan, Sher Bahadar;Seo, Jong-Chul;Jang, Eui-Sung;Choi, Joon-Suk;Choi, Seung-Hyuk
    • Membrane Journal
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    • v.19 no.4
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    • pp.341-347
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    • 2009
  • Nanohybrid based on environmentally friendly and biodegradable polymer, poly propylene carbonate (PPC) and cloisite 20B (PPC/C-20B) have been synthesized by solution blending method and their morphology, thermal and water absorption properties have been evaluated. The structure of PPC/C-20B nanohybrid was confirmed by X-ray diffraction (XRD). The thermal property of PPC and PPC/C-20B nanohybrid were investigated by thermal gravimetric analysis (TGA) and differential scanning calorimetric (DSC). The experimental results demonstrated that nanohybrid showed the highest thermal stability in TGA and DSC. TGA tests revealed that the thermal decomposition temperature ($T_{d50%}$) of the nanohybrid increased significantly, being $23^{\circ}C$ higher than that of pure PPC while DSC measurements indicated that the introduction of 5 mass% of clay increased the glass transition temperature from 21 to $30^{\circ}C$. Further the water absorption capacity of the PPC was significantly decreased by the incorporation of clay. Water absorption cause degradation of the coating by the moistures and affect the physical and mechanical performance. This result indicates that organic modifiers have effect on thermal and water absorption capacity of PPC and are of importance for the practical process and application of PPC.

Evaluation of Hardening Properties and Dry Shrinkage of Non-Sintered Binder Based Floor Mortar Utilizing Alpha-Hemihydrate Gypsum (알파반수석고를 활용한 비소성결합재 기반 바닥 모르타르의 경화특성 및 건조수축 평가)

  • Lee, Kye-Hyouk;Kim, Gyu-Yong;Lee, Bo-Kyeong;Kim, Rae-Hwan;Shin, Kyoung-Su
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.359-365
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    • 2015
  • Floor mortar experiences dry shrinkage by temperature and humidity difference of internal matrix with material type. Also, since floor mortar is influenced by environmental conditions during placing and curing period, cracks are likely to be occurred. In this study, it was evaluated the hardening and dry shrinkage properties of non-sintered binder based floor mortar utilizing alpha-hemihydrate gypsum which has expansibility in order to prevent crack of the floor mortar. It was applied to the construction site, and examined the effects of external environmental conditions on shrinkage deformation and cracking. Different types of slag accelerated initial and final setting in comparison with cement mortar and its compressive strength was satisfied standard compressive strength for floor mortar. Also shrinkage deformation behavior after the initial expansion exhibited a similar tendency with the cement mortar. From the field application result, no crack was found from slag mortar, and it is determined that the slag mortar has better dimensional stability than cement mortar caused by external environment conditions.

Metal Matrix Composite(MMC) Layered Armour System (금속복합판재 적용 다층 구조 방호성능 평가)

  • Lee, Minhyung;Park, Sang-Won;Jo, Ilguk
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.6
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    • pp.752-757
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    • 2017
  • Analysis has been performed for the penetration of a long-rod into MMC/Ceramic layered armour system with several shot test and a series of simulations. Two types of MMC plate have been fabricated by a liquid pressing method; A356/45%vol.%SiCp with a uniform distribution of SiC particle and Al7075/45%vol.B4Cp with B4C particle. The mechanical properties were measured with the high-speed split Hopkins bar test, hardness test and compression test. The popular Simplified Johnson-Cook model was adopted to represent the material characteristics for FEM simulations. The performance of the MMC applied armour system has been made by comparing with the semi-infinite mild steel target using the depth of penetration(DOP). The results show that placing ceramic front layer provides a certain gain in protection, and that placing another ductile front layer provides a further gain. The application of MMC is found to be attractive.

WebPR : A Dynamic Web Page Recommendation Algorithm Based on Mining Frequent Traversal Patterns (WebPR :빈발 순회패턴 탐사에 기반한 동적 웹페이지 추천 알고리즘)

  • Yoon, Sun-Hee;Kim, Sam-Keun;Lee, Chang-Hoon
    • The KIPS Transactions:PartB
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    • v.11B no.2
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    • pp.187-198
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    • 2004
  • The World-Wide Web is the largest distributed Information space and has grown to encompass diverse information resources. However, although Web is growing exponentially, the individual's capacity to read and digest contents is essentially fixed. From the view point of Web users, they can be confused by explosion of Web information, by constantly changing Web environments, and by lack of understanding needs of Web users. In these Web environments, mining traversal patterns is an important problem in Web mining with a host of application domains including system design and Information services. Conventional traversal pattern mining systems use the inter-pages association in sessions with only a very restricted mechanism (based on vector or matrix) for generating frequent k-Pagesets. We develop a family of novel algorithms (termed WebPR - Web Page Recommend) for mining frequent traversal patterns and then pageset to recommend. Our algorithms provide Web users with new page views, which Include pagesets to recommend, so that users can effectively traverse its Web site. The main distinguishing factors are both a point consistently spanning schemes applying inter-pages association for mining frequent traversal patterns and a point proposing the most efficient tree model. Our experimentation with two real data sets, including Lady Asiana and KBS media server site, clearly validates that our method outperforms conventional methods.

Application of Multiresidue Analysis Method of Unregistered Pesticides in Korea for Imported Food (수입식품 중 국내 미등록 농약의 다성분 잔류분석법 적용)

  • Jeon, Young-Hwan;Kim, Hyo-Young;Hwang, Jeong-In;Kim, Ji-Hwan;Do, Jung-Ah;Im, Moo-Hyeog;Oh, Jae-Ho;Kwon, Ki-Sung;Lee, Joong-Keun;Lee, Young-Deuk;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.30 no.3
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    • pp.339-345
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    • 2011
  • BACKGROUND: Recently in Korea, the import of agricultural products is rising due to the increasing amount of trade. Unregistered pesticides, allidochlor, propachlor, propham, cycloate, diallate and pebulate are widely used as pesticides for rice cultivation in foreign countries, while they are not registered in Korea. Therefore, the residue amount of imported agri-foods should be verified using the proper official analytical method for each of them that has not registered in Korea. METHODS AND RESULTS: This work was conducted to apply the official method of Korea Food & Drug Administration (KFDA) for determining multi class pesticide multiresidues in agricultural commodities. Brown rice and orange which have different characteristics as a matrix were selected as representative samples for residue analysis. The recoveries of cycloate, diallate and pebulate by GC/MS in fortified brown rice and orange with levels of 0.04~0.4 mg/kg were ranged from 82.8% to 110.3%. The quantification limits of three pesticides in brown rice and orange were 0.04 mg/kg. CONCLUSION: As a result, this method can surely be used as an official method for routine analysis of unregistered pesticides in Korea for imported agri-food.

Case of Service Design Process for Medical Space Focused on Users (사용자중심 의료공간을 위한 서비스디자인 프로세스의 적용사례)

  • Noh, Meekyung
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.21 no.4
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    • pp.27-36
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    • 2015
  • Purpose: Of late, the focus of service design is moving toward emphasizing customer satisfaction and taking users' experience more seriously. In addition to the change in perspective in service design, scholars in this area are paying more attention to service design methodology and process, as well as its theory and real-world case studies. In the case of medical space, there have been few studies in attempting to apply service design methods useful for deriving user-focused results. The author of this paper believes, however, case study-oriented approaches are more needed in this area rather than ones focusing on theoretical aspects. The author hopes thereby to expand the horizon to practical application of spatial design beyond service design methodology. Methods: In order to incorporate the strengths of service design methodology that can reflect a variety of user opinions, this study will introduce diverse tools in the framework of double diamond process. In addition, it will present field cases that successfully brought about best results in medical space design. It will end with summarizing the ideal process of medical space design which is reasonable and comprehensive. Results: Medical service encompasses preventive medicine as well as treatment of existing medical conditions. A study in establishing the platform of medical service design consists of a wide range of trend research, followed by the summary of two-matrix design classification based on results of the trend research. The draft of design process is divided into five stages composed of basic tools for establishing spatial flow lines created by matching service design tools with each stage of space design processes. In all this, most important elements to consider are communication and empathy. When service design is actually applied to space design, one can see that output has reflected the users' needs very well. The service design process for user-oriented medical space can thus be established by interactions on the final outcome and feedback on the results. Implications: One can see that the service design with the hospital at its center produces the result that encompasses the user's needs best. If the user-focused service design process for medical space can be extended to other space designs, the author believes that it would enhance the level of satisfaction for users and minimize trials and errors.