• Journal of the Computational Structural Engineering Institute of Korea
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• 제16권1호
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• pp.9-18
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• 2003

In static analysis of a variety of structures, the matrix method of structural analysis is the most widely used and powerful analysis method. However, this method has drawback requiring high-performance computers with many memory units and fast processing units in the case of analyzing accurately structures with a large number of degrees-of- freedom. Therefore, it's very difficult to analyze these structures accurately in personal computers. For overcoming the drawback of the matrix method of structural analysis, authors suggest the transfer stiffness coefficient method(TSCM). The TSCM is very suitable to a personal computer because the concept of the TSCM is based on the transfer of the stiffness coefficient for an analytical structure. In this paper, the static analysis algorithm for frame structures is formulated by the TSCM. We confirm the validity of the TSCM through the comparison of computation results by the TSCM, the NASTRAN, the matrix method of structural analysis and the analytical solution.

• Analytical Science and Technology
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• 제32권3호
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• pp.88-95
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• 2019

This study was conducted to establish the analytical method for the determination of cyanide in blood, urine, lung and skin tissues in rats. In order to detect or quantify the sodium cyanide in above biological matrixes, it was derivatized to Pentafluorobenzyl cyanide (PFB-CN) using pentafluorobenzyl bromide (PFB-Br) and then reaction substance was analyzed using gas chromatography mass spectrometer (GC/MS)-SIM (selected ion monitoring) mode. The analytical method for cyanide determination was validated with respect to parameters such as selectivity, system suitability, linearity, accuracy and precision. No interference peak was observed for the determination of cyanide in blank samples, zero samples and lower limit of quantification (LLOQ) samples. The lowest limit detection (LOD) for cyanide was $10{\mu}M$. The linear dynamic range was from 10 to $200{\mu}M$ for cyanide with correlation coefficients higher than 0.99. For quality control samples at four different concentrations including LLOQ that were analyzed in quintuplicate, on six separate occasions, the accuracy and precision range from -14.1 % to 14.5% and 2.7 % to 18.3 %, respectively. The GC/MS-based method of analysis established in this study could be applied to the toxicokinetic study of cyanide on biological matrix substrates such as blood, urine, lung and skin tissues.

• Analytical Science and Technology
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• 제7권4호
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• pp.555-561
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• 1994

A method was described for the graphite furnace atomic absorption spectrophotometric determination of trace cadmium, copper, chromium and lead in urine samples. The elements were directly determined without any other treatments. The ash temperature was intensively optimized to improve the large background by the removal of organic materials and alkali and alkali earth metals in urine samples. Two kinds of standard solutions were used to plot calibration curves. From the recovery data, it could be confirmed that the analytical results with the synthetic urine matrix similar to real urine were more accurate than with a deionized water matrix.

• Steel and Composite Structures
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• 제52권3호
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• pp.343-356
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• 2024

This paper presents an analytical solution for correctly predicting the Lateral-Torsional Buckling critical moment of simply supported castellated beams, the solution covers uniformly distributed loads combined with compressive loads. For this purpose, the castellated beam section with hexagonal-type perforation is treated as an arrangement of double "T" sections, composed of an upper T section and a lower T section. The castellated beam with regular openings is considered as a periodic repeating structure of unit cells. According to the kinematic model, the energy principle is applied in the context of geometric nonlinearity and the linear elastic behavior of materials. The differential equilibrium equations are established using Galerkin's method and the tangential stiffness matrix is calculated to determine the critical lateral torsional buckling loads. A Finite Element simulation using ABAQUS software is performed to verify the accuracy of the suggested analytical solution, each castellated beam is modelled with appropriate sizes meshes by thin shell elements S8R, the chosen element has 8 nodes and six degrees of freedom per node, including five integration points through the thickness, the Lanczos eigen-solver of ABAQUS was used to conduct elastic buckling analysis. It has been demonstrated that the proposed analytical solution results are in good agreement with those of the finite element method. A parametric study involving geometric and mechanical parameters is carried out, the intensity of the compressive load is also included. In comparison with the linear solution, it has been found that the linear stability underestimates the lateral buckling resistance. It has been confirmed that when high axial loads are applied, an impressive reduction in critical loads has been observed. It can be concluded that the obtained analytical solution is efficient and simple, and offers a rapid and direct method for estimating the lateral torsional buckling critical moment of simply supported castellated beams.

• Steel and Composite Structures
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• 제22권2호
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• pp.301-321
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• 2016

The objective of this paper is to investigate buckling behavior of composite laminated cylinders by using semi-analytical finite strip method. The shell is subjected to deformation-dependent loads which remain normal to the shell middle surface throughout the deformation process. The load stiffness matrix, which is responsible for variation of load direction, is also throughout the deformation process. The shell is divided into several closed strips with alignment of their nodal lines in the circumferential direction. The governing equations are derived based on the first-order shear deformation theory with Sanders-type of kinematic nonlinearity. Displacements and rotations of the shell middle surface are approximated by combining polynomial functions in the meridional direction and truncated Fourier series along with an appropriate number of harmonic terms in the circumferential direction. The load stiffness matrix, which is responsible for variation of load direction, is also derived for each strip and after assembling, global load stiffness matrix of the shell is formed. The numerical illustrations concern the pressure stiffness effect on buckling pressure under various conditions. The results indicate that considering pressure stiffness causes buckling pressure reduction which in turn depends on various parameters such as geometry and lay-ups of the shell.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 한국전산구조공학회 2006년도 정기 학술대회 논문집
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• pp.778-785
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• 2006

In this paper, two possible ways for mode shape expansion are proposed and opened for discussion for future use. The first method minimizes the modal flexibility error between the experimental and analytical mode shapes corresponding to the measured DOFs to find the multiplication matrix which can be treated as the least-squares minimization problem. In the second method, Normalized Modal Difference (NMD) is used to calculate multiplication matrix using the analytical DOFs corresponding to measured DOfs. This matrix is then used to expand the measured mode shape to unmeasured DOFs. A simulated simply supported beam is used to demonstrate the performance of the methods. These methods are then compared with two most promising existing methods namely Kidder dynamic expansion and Modal expansion methods. It is observed that the performance of the modal flexibility method is comparable with existing methods. NMD also have the potential to expand the mode shapes though it is seen more sensitive to the distribution of error between FEM and actual test data.

• Analytical Science and Technology
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• 제8권4호
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• pp.865-868
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• 1995

The method of matrix-assisted laser desorption ionization mass spectrometry has been used to solve some bioanalytical problems, which is difficult to analyse by general methods. For the selection of proper laser wavelength and matrices, eight matriees was used with laser wavelength of 226 and 355nm. The result shows that with wavelength of 355nm better results could be obtained with most of the matrices. The molecular weight of eytochrome C, which was seperated by gel electrophoresis and electro-blotted onto NC membrane is determined by MALDI. The accuracy is better than 0.1%, which is much higher than that of SDS-PAGE. Protein mixture extracted from crude peanut oil is directly determined by MALDI. The molecuiar weight of its three components are determined, and the result also demonstrated that these proteins are in free manner. As proteins arc in 2S bond, with the traditional method, SDS-PAGE, it is not able to decide whether protein exists in combination mode or in free manner. In the technique of two phase aquesous solution, which is used for separating biomaterials, water soluble polymers stained with dyes are used in this technique. By the use of MALDI the number or the dye molecules react with the polymer PEG molecule are determined, and that is difficult to determined by other methods.

• Journal of Korean Society of Coastal and Ocean Engineers
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• 제22권3호
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• pp.163-170
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• 2010

Both scatterer method and transfer matrix method are compared to analyze their characteristics, which are wave propagation models due to topographic change based on plane wave approximation. Results from the scatterer method are closer to the results obtained by the more accurate existing models and it is appraised that the scatterer method gives the clearer explanation about physical process involved in the wave transformation. Since both methods have analytical solutions, in the computational point of view they are very fast and easy to be implemented. Both methods give a good prediction for wave scattering by relatively simple bedform.

• Analytical Science and Technology
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• 제11권6호
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• pp.499-504
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• 1998

An analytical method for the simultaneous measurement of trace Cu, Sn, and Bi in sea water has been investigated by Inductively Coupled Plasma-Mass Spectrometry. Amberlite IRC-718 resin was used as a solid phase in solid-liquid extraction technique for the removal of matrix interferences such as Na, S, P, and other polyatomic ion species. Recoveries of 99.8% for Cu, 99.6% for Sn, and 97.9% for Bi were obtained for the standard spiked sample. The developed method was applied to analysis of trace metals in sea water.

• Journal of environmental and Sanitary engineering
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• 제16권1호
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• pp.91-101
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• 2001

In order to propose a optimum method increasing accuracy and reproducibility in analysis of urine lead levels, we compared matrix modifier addition method and microwave digestion method. The results were as follows ; 1. Where the concentration of $Pd(NO_3)_2$(matrix modifier) was $50mg/{\ell}$, and ashing temperature was $900^{\circ}C$, the results were optimum. In case of matrix modifier addition method, the average coefficient of variation (CV) of normal man was 24.1%, and lead worker was 7.9%. The average urine lead levels of standard were $10.42\mu{g}/{\ell}$ and $19.89\mu{g}/{\ell}$ , the accuracies compared to reference values were 97.0% and 92.6%, respectively. 2. Microwave digestion temperature($160~180^{\circ}C$), time(15~25min) and the ratio of urine/ashing acid(1:1~4:1) did not significantly affect lead absorbance and background absorbance. Therefore we set up a optimum analytical conditions as follows: temperature, $160^{\circ}C$; time, 15min; the ratio of urine/ashing acid, 4:1. after samples were digested by the above analytical conditions, lead absorbance and background absorbance was measured at $450^{\circ}C$ as ashing temperature. The average coefficient of variation (CV) of normal man was 12.4%, and lead worker was 6.2%. The average urine lead levels of standard urine were $10.66\mu{g}/{\ell}$ and $23.31\mu{g}/{\ell}$, the accuracies compared to reference values were 99.3% and 103.9%, respectively. From the results, we suggest that microwave digestion method is a more favorable method than matrix modifier addition method because of easiness to reduce organic matter, possibility to analysis at low temperature and accuracy.