• 한국환경과학회지
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• 제22권7호
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• pp.837-845
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• 2013

This study was designed to synthesize mesoporous carbon, porous carbonic material and to characterize its surface in an attempt to adsorption methane gas($CH_4$). Synthesis of mesoporous carbon was carried out under two steps ; 1. forming a RF-silica complex with a mold using CTMABr, a surfactant, and TEOS, raw material of silica, and 2. eliminating silica through carbonization and HF treatment. The mesoporous carbon was synthesized under various conditions of synthesis time and calcination. Eight different types of mesoporous carbon, which were designated as MC1, MC2, MC3, MC4, MCT1, MCT2, MCT3, and MCT4, were prepared depending upon preparation conditions. The analysis of mesoporous carbon characteristics showed that the calcination of silica stabilized the mixed structure of silica and carbonic complex, and made the particle uniform. The results also showed that hydrothermal synthesis time did not have a strong influence on the size of pore. The bigger specific surface area was obtained as the hydrothermal synthesis time was extended. However, the specific surface area was getting smaller again after a certain period of time. In adsorption experiments, $CH_4$ was used as adsorbate. For the case of $CH_4$, MCT3 showed the highest adsorption efficiency.

• 센서학회지
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• 제21권1호
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• pp.13-20
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• 2012

Due to its high conductivity, pyrylium has been frequently used in electron transfer reactions or in the synthesis of various organic materials. It has also been used as a sensor material. Traditionally, the compounds have been synthesized using various methods; mostly in a multiple steps. In this study, two pyrylium salts, 2, 6-di-(4'-methylphenyl) pyrylium fluoroborate and perchlorate were synthesized. The synthesis of these products was confirmed by 1H-NMR, LC/TOF-MS and FT-IR analyses while their photo-properties were analyzed using UV/VIS spectrophotometry. In addition, the electron transfer capacities of the salts were analyzed with a conductivity meter, it was found that their electron conductivities were high. When the synthesized compounds were dissolved in acetone, a green fluorescent material was observed to form. The fluorescent material can be used as a sensitizer in the electrical industry.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.123-128
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• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2765-2768
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• 2012

• 한국전기전자재료학회논문지
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• 제36권6호
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• pp.633-637
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• 2023

Recently, with the development of the smart device market, the integration of high-functional devices has increased the heat density, causing overload of the device, and resulting in various problems such as shortened lifespan, performance degradation, and failure. Therefore, research on heat dissipation materials is being actively conducted to realize next-generation electronic products. The heat dissipation material is characterized in that it is easy to dissipate heat due to its high thermal conductivity and minimizes leakage current flowing through the heat dissipation material due to its low electrical conductivity. In this study, flower-shaped Al₂O₃ and BN composites were engineered with a simple hydrothermal synthesis approach, and their thermal conductivity characteristics were compared and evaluated for each synthesis condition for the application to a heat dissipation material. Spherical BN and flower-shaped Al₂O₃ were easily obtained, and SEM/EDS analyses confirmed the uniform presence of BN between the Al₂O₃, and it can be expected that these shapes can affect the thermal conductivity.

• 공업화학
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• 제5권1호
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• pp.30-36
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• 1994

가솔린 옥탄가 향상제인 ETBE(ethyl tert-butyl ether) 합성반응의 촉매활성과 촉매의 산특성에 상관성 및 반응특성에 관하여 연구하였다. pyridine의 흡착량과 TBA전화율은 좋은 상관성을 보였지만, $NH_3$의 흡착량과 TBA전화율은 전이금속과 complex를 형성하는 $NH_3$의 흡착특성 때문에, 전이금속의 경우는 선형적인 상관성을 나타내지 않았다. 담지촉매의 경우, 담지량에 따른 촉매활성과 생성물 분포는 반응물인 TBA 또는 iso-butene의 흡착특성이 중요한 역할을 하였다.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.634-640
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• 2011

The effect of cycling on the absorption and desorption characteristics of the 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm system was investigated. The material was made by Hydrogen Combustion Synthesis. The cycling experiment was performed at 298 K, 30 atm for 15 min. During the reaction time, the amount of absorption was fully desorbed. After the full activation, the hydrogen storage capacity was 1.57 wt% and the capacity was maintained until 50 cycles. And the reaction rate does not change with an increase in the number of cycles. This material has good durability and reversible feature.

• 한국전기전자재료학회논문지
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• 제36권3호
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• pp.203-213
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• 2023

Owing to carbon materials' diverse functionalization and versatility, the design and synthesis of carbon-based three-dimensional porous structures have become important foundational research topics across various fields. Among the various methods for producing porous carbon structures, laser-induced graphene (LIG) has garnered attention because of its large surface area, controllable structure, excellent electrical conductivity, scalability, and eco-friendly synthesis process. In addition, recent research results have reported more novel functionalities by advancing further from the unique characteristics of LIG through functionalization or compounding of LIG, making it an attractive material for various applications in electronic devices, sensing, catalysis, and energy storage. This review aims to update the research trends in LIG and its functionalization, providing insights to inspire more interesting studies on functional LIG to expand its potential applications ultimately. Starting with the synthesis method and material characteristics of LIG, we introduce the functionalization of LIG, which is classified into surface modification, heteroatom doping, and hybridization based on the interaction mechanism. Finally, we summarize and discuss the prospects of LIG and its functionalization.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.99-102
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• 2002

The BSCCO superconductor materials of using Self-propagating High-temperature Synthesis (SHS) were studied. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product. In this paper as an effort for fabricating the SHSed BSCCO superconductor powder SHS method was considered to application in the synthesis of superconducting materials.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.481-483
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• 1998

The problem of production of new materials based on polyheteroarylenes and other polymers combining good mechanical and dielectric properties. radiation and chemical stability with heat- and thermal stability is related with the development of efficient synthesis technique of starting low-molecular compounds. Alicyclic dianhydrides are believed to be the promising monomers to synthesize various polymers.