• Title/Summary/Keyword: material balance method

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Purity Assessment of Organic Reference Materials with a Mass Balance Method: A Case Study of Endosulfan-II

  • Kim, Seung-Hyun;Lee, Joonhee;Ahn, Seonghee;Song, Young-Sin;Kim, Dong-Kyum;Kim, Byungjoo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.531-538
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    • 2013
  • A mass balance method established in this laboratory was applied to determine the purity of an endosulfan-II pure substance. Gas chromatography-flame ionization detector (GC-FID) was used to measure organic impurities. Total of 10 structurally related organic impurities were detected by GC-FID in the material. Water content was determined to be 0.187% by Karl-Fischer (K-F) coulometry with an oven-drying method. Non-volatile residual impurities was not detected by Thermal gravimetric analysis (TGA) within the detection limit of 0.04% (0.7 ${\mu}g$ in absolute amount). Residual solvents within the substance were determined to be 0.007% in the Endosulfan-II pure substance by running GC-FID after dissolving it with two solvents. The purity of the endosulfan-II was finally assigned to be ($99.17{\pm}0.14$)%. Details of the mass balance method including interpretation and evaluating uncertainties of results from each individual methods and the finally assayed purity were also described.

Evaluation of energy response of space steel frames subjected to seismic loads

  • Ozakgul, Kadir
    • Structural Engineering and Mechanics
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    • v.54 no.4
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    • pp.809-827
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    • 2015
  • In this paper, seismic energy response of inelastic steel structures under earthquake excitations is investigated. For this purpose, a numerical procedure based on nonlinear dynamic analysis is developed by considering material, geometric and connection nonlinearities. Material nonlinearity is modeled by the inversion of Ramberg-Osgood equation. Nonlinearity caused by the interaction between the axial force and bending moment is also defined considering stability functions, while the geometric nonlinearity caused by axial forces is described using geometric stiffness matrix. Cyclic behaviour of steel connections is taken into account by employing independent hardening model. Dynamic equation of motion is solved by Newmark's constant acceleration method in the time history domain. Energy response analysis of space frames is performed by using this proposed numerical method. Finally, for the first time, the distribution of the different energy types versus time at the duration of the earthquake ground motion is obtained where in addition error analysis for the numerical solutions is carried out and plotted depending on the relative error calculated as a function of energy balance versus time.

Electro-optical Simulation of Twist Nematic Liquid Crystal Displays considering Anchoring Energy (Weak Anchoring 에너지를 고려한 TN-LCD의 Simulation)

  • Jung, Jin-Taek;Park, Woo-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.969-976
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    • 2007
  • In this thesis, an anchoring energy in the upper and lower substrates of TFT-LCD cell has been modeled and applied in the numerical calculation of the molecular orientation of the TN-LCD. The molecular orientation of liquid crystals defined as tilt and twist angles was simulated using the Newton-Raphson method and the Gaussian integration method. From the results, the tilt and twist angles for the strong anchoring energy were proven to be coincide with those of the conventional results. on the other hand, for the weak anchoring energy, azimuth angles of the molecules were changed abruptly from $0^{\circ}\;to\;90^{\circ}$ near the middle area of the cell due to the balance of the anchoring energy and the elastic energy of the liquid crystals.

Vibration Control of Reinforced Concrete Slabs (철근콘크리트 슬래브의 진동제어)

  • 변근주;노병철;유동우;이호범
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.04a
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    • pp.201-206
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    • 1993
  • As the vibration loads are variable and the design criteria are more strict, in this study, the dynamic characteristics of the slab is analyzed and the and the vibration is controlled for the special peculiarity of structures. First, the procedure of dynamic analysis is developed by the finite element method and then examined by using the slab model tests. Second, in order to improve the dynamic characteristics, the effects of the number of supports, material properties, position of exciting force, added mass and dynamic balance on the dynamic behavior of reinforced concrete slabs are analysed. It is concluded that the vibration can be controlled by the change in the natural frequency of system and the use of the high-strength concrete or polymer impregnated concrete (PIC), and the dynamic characteristics can be considerably affected by the arrangement of equipments, added mass, and dynamic balance, etc.

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A Study on the Heat Balance of Cooling System for Armored Vehicles (밀폐형 차량 냉각시스템에 대한 열평형 연구)

  • Kim, S.K.;Ahn, S.H.;Nam, K.W.
    • Journal of Power System Engineering
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    • v.11 no.1
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    • pp.70-75
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    • 2007
  • Heat transfer coefficient and fin efficiency of a heat exchanger dispersed in the microelement of control volume were predicted with various flow patterns, conditions and material properties. A computational program was developed by using the method of efficiency-NTU(Number of transfer unit). The modelling was applied to heat exchangers, also was integrated in power pack cooling system in an armored vehicle. The compatibility and the generality were proved by comparing the prediction values with the test results. The developed program may be useful for the design of the cooling system in an armored vehicle.

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Nonlinear dynamic characteristic of sandwich graphene platelet reinforced plates with square honeycomb core

  • Mamoon A.A. Al-Jaafari;Ridha A. Ahmed;Raad M. Fenjan;Nadhim M. Faleh
    • Steel and Composite Structures
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    • v.46 no.5
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    • pp.659-667
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    • 2023
  • Nonlinear forced vibration behaviors of sandwich plates having graphene platelets (GPL) based face sheets have been researched in this article. Possessing low weight together with low stiffness, square honeycomb cores are mostly constructed by aluminum. Herein, the square shaped core has been fortified by two skins of GPL-based type in such a way that the skins have uniform and linearly graded GPL dispersions. The square shaped core has the effective material specification according to the relative density concept. The whole formulation has been represented based upon classical plate theory (CPT) while harmonic balance approach is applied for solving the problem and plotting the amplitude-frequency curves. The forced vibration behaviors of such plates are influenced by square-shaped core and the relative density, skin's height and GPL fortification.

Sectional analysis of stamping processes using Equilibrium approach (평형해법에 의한 스탬핑 공정의 단면 해석)

  • Yoon, J.W.;Yoo, D.J.;Song, I.S.;Yang, D.Y.;Lee, J.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.4
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    • pp.58-68
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    • 1994
  • An equilibrium approach is suggested as an effective tool for the analysis of sheet metal forming processes on the basis of force balance together with geometric relations and plasticity theroy. In computing a force balance equation, it is required to define a geometric curve approximating the shape of the sheet metal at any step of deformation from the geometric interaction between the die and the deforming sheet. Then the geometic informations for contacting and non-contacting sections of the sheet metal such as the number and length of both non-contact region, contact angle, and die radius of contact section are known from the geometric forming curve and utilized for optimization by force balance equation. In computation, the sheet material is assumed to be of normal amisotropy and rigid-phastic workhardening. It has been shown that there are good agreements between the equilibrium approach and FEM computation for the benchmark test example and auto-body panels whose sections can be assumed in plane-strain state. The proposed equilibrium approach can thus be used as a robust computational method in estimating the forming defects and forming severity rather quickly in the die design stage.

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Evaluation of Nitrogen and Phosphorus Balance in Green Manure-Rice Cropping Systems without Incorporation of Green Manure Crops (녹비작물 무 환원-벼 작부체계에서 질소와 인산수지 평가)

  • Kim, TaeYoung;Daquiado, Aileen Rose;Alam, Faridul;Lee, YongBok
    • Korean Journal of Environmental Agriculture
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    • v.31 no.4
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    • pp.308-312
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    • 2012
  • BACKGROUND: The nutrient balance in Korea during 1985-2006 had continually increased and maintained the highest levels among OECD countries. The use of green manure crops such as barley and hairy vetch is common practice for reducing chemical fertilizer application and maintaining soil fertility. However, green manure crops can also be used as a livestock feeding material which may reduce nutrient balance in the national scale. We calculated nitrogen and phosphate balance under green manure-rice cultivating system where all green manure was removed and used for feeding livestock. METHODS AND RESULTS: The barley and hairy vetch grown in pure stands or in mixtures with different sowing rates were tested for rice cultivation without chemical fertilization. The conventional fertilization (NPK) for rice cultivation was selected to compare nutrient balance with green manure-rice cultivation. Nitrogen and phosphate balance were calculated according to the surface balance method of the PARCOM guidelines. Total aboveground biomass of mixture (barley and hairy vetch) was higher compared to that of pure barley or hairy vetch. Among the mixture with barley and hairy vetch, the highest aboveground biomass was observed in B75H25 (barley 75%+hairy vetch 25%). The nitrogen and phosphate balance in the B75H25 mixture was-104 kg N/ha and-50.3 kg P/ha, respectively. CONCLUSION(S): The barley and hairy vetch mixture proved to be a very effective strategy for biomass production of green manure. The amount of nitrogen and phosphate fertilizer to be applied is estimated to be 104 kg N/ha and 50.3 kg P/ha in order to maintain soil fertility if all green manure and rice straw were removed from rice field for livestock feeding.

Pseudosteady-State Approach to Calculate Long-Time Performance of Closed Gas Reservoirs (유사정상상태 해법을 이용한 폐쇄 가스저류층의 장기거동 계산)

  • Lee Kun Sang
    • 한국가스학회:학술대회논문집
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    • 1998.09a
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    • pp.241-246
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    • 1998
  • This paper considers the applicability of a pseudosteady-state approach to the long-time behavior of real gas flow in a closed reservoir. The method involves a combination of a linearized gas diffusivity equation using a normalized pseudotime and a material balance equation. Comparison with a commercial reservoir simulator showed that highly accurate values of pseudopressure drawdown and well pressure are obtained by the pseudosteady-state approach with much less computational effort.

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Evaluation Method for Improvement of Indoor Air Quality Using Mass Balance (물질수지를 이용한 실내공기질 개선정도 평가)

  • Kim, Young-Hee;Kim, Moon-Hyeon;Yang, Won-Ho
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.913-918
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    • 2006
  • Despite the wide distribution of air pollutants, the concentrations of indoor air pollutants may be the dominant risk factor in personal exposure due to the fact that most people spend an average of 80% of their time in enclosed buildings. Researches for improvement of indoor air quality have been developed such as installation of air cleaning device, ventilation system, titanium dioxide$(TiO_2)$ coating and so on. However, it is difficult to evaluate the magnitude of improvement of indoor air quality in field study because indoor air quality can be affected by source generation, outdoor air level, ventilation, decay by reaction, temperature, humidity, mixing condition and so on. In this study, evaluation of reduction of formaldehyde and nitrogen dioxide emission rate in indoor environments by $TiO_2$ coating material was carried out using mass balance model in indoor environment. we proposed the evaluation method of magnitude of improvement in indoor air quality, considering outdoor level and ventilation. Since simple indoor concentration measurements could not properly evaluate the indoor air quality, outdoor level and ventilation should be considered when evaluate the indoor net quality.