• 한국지반공학회논문집
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• 제20권5호
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• pp.79-86
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• 2004

지반과 숏크리트 사이의 인터페이스 특성은 지반하중이 숏크리트 라이닝에 전달되는 과정에서 중요한 역할을 한다. 또한 인터페이스 특성은 지반 및 숏크리트 라이닝의 거동에 상당한 영향을 미친다. 그러나 대부분의 수치 해석적 연구에서는 이러한 인터페이스 특성을 단순히 가정하여 적용해 왔으며 이를 규명하기 위한 시도도 거의 이루어지지 않았다. 따라서 본 연구에서는 터널 측벽에서 회수된 숏크리트/암석 코어에 대해 직접전단시험과 인터페이스 수직압축시험을 실시하여 점착력, 인장강도, 마찰각, 전단강성 및 수직강성과 같은 인터페이스 특성을 규명하고자 하였다. 인터페이스 특성의 시간 의존적인 변화양상과 비교하기 위하여 압축강도와 탄성계수와 같은 숏크리트의 역학적 물성도 측정하였다. 실험결과로부터, 지반과 숏크리트 라이닝 사이의 인터페이스 특성은 역학적 물성과 유사하게 상당한 시간 의존적 거동을 보인다는 것을 확인하였다. 또한 인터페이스 특성의 시간의존적인 거동을 지수함수와 로그함수 형태로 잘 근사 시킬 수 있었다.

• Restorative Dentistry and Endodontics
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• 제29권3호
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• pp.249-266
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• 2004

The purpose of this study was to determine whether pH and time has any influence on the degradation behavior of composite restoration by analyzing the leached monomers of dental composites qualitatively and quantitatively after storage in acetate buffer solution as a function of time using high performance liquid chromatography (HPLC) / mass spectrometer. Materials and Methods：Three commercial composite restorative resin materials (Z-250, Heliomolar and Aeliteflo) with different matrix structure and filler composition were studied. Thirty specimens (7mm $diameter{\times}2mm$ thick) of each material were prepared. The cured materials were stored in acetate buffer solution at different pH (4, 7) for 1, 7 and 45days. As a reference, samples of unpolymerized composite materials of each product were treated with methanol (10mg/ml). Identification of the various compounds was achieved by comparison of their mass spectra with those of reference compound, with literature data. and by their fragmentation patterns. Data were analysed statistically using ANOVA and Duncan's test. Results：1. Amounts of leached TEGDMA in Aeliteflo were significantly larger than those of UDMA in Z-250 and Heliomolar at experimental conditions of different storage time and pH variation (p<0.001). 2. As to comparison of the amounts of leached monomers per sorage time, amounts of leached TEGDMA in Aeliteflo and UDMA in Z-250 and Heliomolar were increased in the pH 4 solution more significantly than in the pH 7 solution after 1day, 7days and 45days, respectively (p<0.001). 3. In total amounts of all the leached monomers with storage times, the overall amounts of pH 4 extracts were larger than those of pH 7 extracts for all resin groups, but there was no significant difference (p>0.05).

• Journal of Astronomy and Space Sciences
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• 제23권2호
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• pp.105-116
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• 2006

근접촉쌍성 EG Cep의 8개의 새로운 극심 시각을 제시하였다. 우리의 관측치를 포함한 EG Cep의 관측된 모든 극심시각을 수집하여 이 별의 공전 주기변화를 연구하였다. 그 결과 EG Cep의 공전주기는 위로 향한 포물선 모양의 영년 변화 위에 주기적인 항이 겹쳐 변화한다는 것을 발견하였다. 관측된 영년 주기 증가량은 약 $3.22{\times}10^{-8}d/y$이며, 보존적인 질량이동을 가정하면, 이는 매년 약 $3.18{\times}10^{-8}M_{\odot}$의 항성 가스가 질량이 작은 반성으로부터 주성으로 이동하고 있음을 의미한다. 공전주기의 주기적인 변화의 원인을 제3천체에 의한 광시간 효과로 해석하였다. 광시간 궤도의 주기, 반진폭과 이심율은, 각각 38.4년, 0.0034일, 그리고 0.29이다. EG Cep계에 제안한 제3천체의 질량 범위는 $i_3{\geq}30^{\circ}$일 때 $0.10M_{\odot}{\leq}M_3{\leq}0.21M_{\odot}$으로 상당히 작다.

• International Journal of Naval Architecture and Ocean Engineering
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• 제8권2호
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• pp.127-136
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• 2016

Springing is the resonance phenomenon of a ship hull girder with incoming waves having the same natural frequency of the ship. In this study, a simple and reliable calculation method was developed based on quadratic strip theory using the Timoshenko beam approach as an elastic hull girder. Second-order hydrodynamic forces and Froude-Krylov forces were applied as the external force. To improve the accuracy of the strip method, the variation in the added mass along the ship hull longitudinal direction, so called tip-effect, was considered. The J-factor was also employed to compensate for the effect of three-dimensional fluid motion on the two-node vibration of the ship. Using the developed method, the first- and second-order vertical bending moments of the Flokstra ship were compared. A comparative study was also carried out for a uniform barge ship and a 10,000 TEU container ship with the respective methods including the J-factor and tip-effect.

• 한국산학기술학회논문지
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• 제13권4호
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• pp.1440-1446
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• 2012

본 논문은 수평 마이크로핀관내 초임계 $CO_2$와 PAG 혼합물의 열전달과 압력강하 특성에 대해서 실험적으로 연구한 것이다. $CO_2$와 PAG 혼합물의 열전달계수는 압력이 10 MPa이고, 질량유속은 520 kg/$m^2s$이며, PAG 오일 농도는 0.06~2.26%에서 측정하였다. PAG 오일농도가 0.3%인 경우, $CO_2$와 PAG 혼합물의 열전달계수와 압력강하는 순수 $CO_2$ 냉매의 열전달계수와 동일한 경향을 나타내었다. 그리고 PAG 질량농도가 2.26%인 경우, 초임계 온도근처에서 측정한 열전달계수는 순수 $CO_2$의 열전달계수 보다 약 50%정도 낮게 나타났다. 마찰압력강하는 $60^{\circ}C$의 $CO_2$ 평균온도에서 순수 $CO_2$의 압력강하보다 약 1.6배 더 높게 나타났다.

• 한국산업융합학회 논문집
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• 제4권3호
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• pp.243-251
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• 2001

The effects of various operating parameters(agitation speed, impeller type, antiform agents, impeller spacing etc.) on air-liquid mass transfer was characterized by volumetric mass transfer coefficient($k_La$). Also, the dual-impeller agitated systems are compared with single-impeller agitated systems with a special focus on its applications for bioreactors, $k_La$ was take over a range of 200~450 rpm of agitation speed, and 0.5~2.5 vvm of air flow rates, for four single impeller and impeller combinations consisting of four impeller types, namely rushton, pitched blade, scaba, intermig were tested. The rushton impeller showed the best $k_La$ as compared with other single impellers. The dual impeller system are found to be superior as compared to single impeller in all aspects, The best combination of the dual impeller was a intermig of axial flow type as an upper impeller and a rushton of radial flow type as a lower part. Also, the control of the DO level with the variation of agitation speed was more efficient than that with an increase in air flow rate. The addition of antiform dropped the $k_La$ very large up to 1g/L regardless the type. PPG was less effect on $k_La$ than other antiforms. The impeller spacing and presence of solute are found very effective on $k_La$. When the $NaNO_3$is presented as solute, the $k_La$ increased approximately 50% then control.

• 지질공학
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• 제6권1호
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• pp.23-31
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• 1996

NATM공법에 의한 지하 암반공동에서 숏크리트내의 불평형력이 지보 시스템에 전달되는 하중 전달 메커니즘을 고려하여 지보시스템내의 응력 재분배 과정을 모델링하였으며,그에 따른 지보시스템의 해석모델을 제안 하고 숏크리트의 탄성거동에 관하여 고찰하였다.응력 재분배 모델을 이용하여 설계변수가 변화함에 따라 지보시스템에 미치는 영향을 분석한 결과 숏크리트의 최대 압축응력은 현저히 감소되었다. 암반의 수평지압계수 및 탄성계수가 구조응답에 큰 영향을 미치나 지보시스템 자체의 특성 변화가 응답에 미치는 영향은 매우 적었다. 구조재의 안전율을 평가할 수 있는 상관식을 제시하였다. 본 연구결과를 이용하여 지하구조물의 안전성을 평가할 수 있을 것으로 기대된다.

• Journal of Mechanical Science and Technology
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• 제14권2호
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• pp.236-250
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• 2000

Compression ignition direct injection diesel engines employed a high pressure injection system have been developed as a measure to improve a fuel efficiency and reduce harmful emissions. In order to understand the effects of the pressure variation, many experimental works have been done, however there are many difficulties to get data in engine condition. This work gives numerical results for the high pressure effects on spray characteristics in wide or limited space with near walls. The gas phase is modelled by Eulerian continuum conservation equations of mass, momentum, energy and fuel vapour fraction. The liquid phase is modelled using the discrete droplet model approach in Lagrangian form and the drop behavior on a wall is calculated with a new droplet-wall interaction model based on the experiments observing individual drops. The droplet distributions, vapour fractions and gas flows are shown in various injection pressure cases. In free spray case which the injection spray has no wall impaction, the spray dispersion and vapour fraction increase and drop sizes decrease with increasing injection pressure. The same phenomena appears more clearly in wall impaction cases.

• 설비공학논문집
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• 제9권3호
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• pp.343-353
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• 1997

This paper presents a theoretical model for predicting transient behaviors during storage process of the cool storage system using the R141b clathrate. Introduction of the lumped capacitance method along with a brine reservoir having large thermal capacity yields a set of simplified energy equations. Based on the Arrhenius equation and the known experimental findings, the formation rate of clathrate for which the degree of subcooling is properly accounted is newly developed. An effective nondimensionalization of the model equations facilitates the closure of modeling as well as parametric study. Calculated results for a specific case not only simulate a typical pattern of temperautre variation in the tank successfully, but also agree reasonably well with available data. The effect of each characteristic parameter on the system performance is also investigated. It is revealed that the dominant among relevant parameters are the activation energy of reaction, the degree of subcoling and the initial mass fraction of refrigerant. Finally, the uncertainty associated with modeling of the shaft work variation appears to need further studies.

• Bulletin of the Korean Chemical Society
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• 제19권9호
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• pp.968-973
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• 1998

Solvolyses of para-substituted phenyl chloroformates in water, $D_2O,\;CH_3OD$, 50% $D_2O-CH_3OD$, and in aqueous binary mixtures of acetone, ethanol, methanol are investigated at 25.0 ℃. Product selectivities are reported for a wide range of ethanol-water and methanol-water solvent compositions. These data are interpreted using the Grunwald-Winstein relationship, Hammett equation, and quantum mechanical model. Grunwald-Winstein plots of the first-order rate constants for phenyl chloroformates with $Y_{Cl}$ (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. To account for these results, third-order rate constants, $k_{ww},\;k_{aw},\;k_{wa}$, and $k_{aa}$ were calculated from the observed $k_{ww}\;and\;k_{aa}$ values together with $k_{aw}\;and\;k_{wa}$ calculated from the computer fit. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination for para-substituted phenyl chloroformates solvolyses based on mass law and stoichiometric salvation effect studies. This study has shown that the quantum mechanical model predicts transition state variation correctly for $S_N2\;like\;S_AN$ reaction mechanism of para-substituted phenyl chloroformates.