• Title/Summary/Keyword: mass transfer model

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Load Variation Removal and Stack Durability Experiments to Improve Lifetime of Fuel Cell Stack for Hydrogen Electric Vehicles (수소전기차 연료전지 수명 향상을 위한 부하 변동 제거 및 스택 내구성 실험)

  • DONGWON LEE;BEOMJUN KIM;SEOUNGRO LEE
    • Journal of Hydrogen and New Energy
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    • v.35 no.4
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    • pp.370-376
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    • 2024
  • Load variations reduce the lifespan of polymer electrolyte fuel cells (PEFCs). To analyze the impact of load variations on durability of PEFCs, two stacks were built and operated continuously for 400 hours, one under load variations and the other under constant current condition with the same energy output. Using the example model provided by Mathworks, we obtained load variation data for the experiments. The performance curves were measured every 100 hours and analyzed by current interruption method and electrochemical impedance spectroscopy. The degradation comparison shows a much larger decrease in performance under the load variation. The activation resistance, electrical resistance, and mass transfer resistance are all found to increase more.

The Removal of Toluene by a Granular Activated Carbon Bioreactor using Yeast (Yeast와 입상활성탄을 이용한 미생물반응기의 휘발성유기화합물 분해 특성)

  • NamGung, Hyeong-Kyu;Shin, Seung-Kyu;Ahmed, Zubair;Song, Ji-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1218-1224
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    • 2008
  • A liquid culture of yeast "Candida tropicalis" was used in a fluidized bioreactor to achieve high removal efficiencies of volatile organic compounds (VOCs). In this study, granular activated carbon (GAC) was used as a fluidized material to improve adsorptive capacity as well as mass transfer of gaseous toluene, the model VOC. The GAC fluidized bioreactor demonstrated toluene removal efficiencies ranging from 50 to 80%, when inlet toluene loading varied in a range between 13.1 and 37.4 g/m$^3$-hr. The maximum elimination capacity determined in the GAC fluidized bioreactor was 172 g/m$^3$-hr at a toluene loading of 291 g/m$^3$-hr. Transient loading experiments revealed that the removal efficiency was remained unchanged during an increased loading period, and toluene introduced to the bioreactor was first absorbed to GAC and then slowly desorbed and became available to the yeast culture. Hence the fluidized GAC helped to achieve an improved mass transfer between the gas and liquid phases, resulting in high toluene removal capacity. Consequently, the GAC fluidized bioreactor using C. tropicalis can be successfully applied for the removal of VOCs, and is a feasible alternative over conventional processes such as packed-bed biofilters.

Estimation of Fire Dynamics Properties for Charring Material Using a Genetic Algorithm (유전 알고리즘을 이용한 탄화 재료의 화재 물성치 추정)

  • Chang, Hee-Chul;Park, Won-Hee;Lee, Duck-Hee;Jung, Woo-Sung;Son, Bong-Sei;Kim, Tae-Kuk
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.106-113
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    • 2010
  • Fire characteristics can be analyzed more realistically by using more accurate material properties related to the fire dynamics and one way to acquire these fire properties is to use one of the inverse property analyses. In this study the genetic algorithm which is frequently applied for the inverse heat transfer problems is selected to demonstrate the procedure of obtaining fire properties of the solid charring material with relatively simple chemical structure. The thermal decomposition on the surface of the test plate is occurred by receiving the radiative energy from external heat sources, and in this process the heat transfer through the test plate can be simplified by an unsteady 1-D problem. The inverse property analysis based on the genetic algorithm is then applied for the estimation of the properties related to the reaction pyrolysis. The input parameters for the analysis are the surface temperature and mass loss rate of the char plate which are determined from the unsteady 1-D analysis with a givenset of 8 properties. The estimated properties using the inverse analysis based on the genetic algorithm show acceptable agreements with the input properties used to obtain the surface temperature and mass loss rate with errors between 1.8% for the specific heat of the virgin material and 151% for the specific heat of the charred material.

Sound transmission of multi-layered micro-perforated plates in a cylindrical impedance tube (원통형 임피던스 튜브 내 다중 미세천공 판의 음향투과)

  • Kim, Hyun-Sil;Ma, Pyung-Sik;Kim, Bong-Ki;Lee, Seong-Hyun;Seo, Yun-Ho
    • The Journal of the Acoustical Society of Korea
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    • v.39 no.4
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    • pp.270-278
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    • 2020
  • In this paper, sound transmission of Micro-Perforated Plates (MPPs) installed in an impedance tube with a circular cross-section is described using an analytic method. Vibration of the plates is expressed in terms of an infinite series of modal functions, where modal function in the radial direction is given by the Bessel function. Under the plane wave assumption, a low frequency approximation is derived, and a formula for the sound transmission coefficient of multi-layered MPPs is presented using the transfer matrix method. The Sound Transmission Losses (STLs) of single and double MPPs are computed using the proposed method and compared with those done by the Finite Element Method (FEM), which shows an excellent agreement. As the perforation increases, the STL is degraded, since the STL becomes dominated by the perforation ratio rather than by vibration of the plate. The STL shows dips at natural frequencies as well as at the mass-spring-mass resonance frequency. The proposed model for the STL prediction in this study can be applied to an arbitrary number of MPPs, where each MPP may or may not have a perforation.

A Path-Based Traffic Assignment Model for Integrated Mass Transit System (통합 대중교통망에서의 경로기반 통행배정 모형)

  • Shin, Seong-Il;Jung, Hee-Don;Lee, Chang-Ju
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.6 no.3
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    • pp.1-11
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    • 2007
  • Seoul's transportation system was changed drastically starting the first of June in two thousand. This policy includes integrated distance-based fare system and public transportation card system called smart card. Especially, as public transportation card data contains individual travel, transfer and using modes information it is possible to catch the characteristics of path-based individuals and mass transit. Thus, public transportation card data can contribute to evaluate the mass transit service in integrated public transportation networks. In addition, public transportation card data are able to help to convert previous researches and analyses with link-based trip assignment models to path-based mass transit service analysis. In this study, an algorithm being suitable for path-based trip assignment models is suggested and proposed algorithm can also contribute to make full use of public transportation card data. For this, column generation algorithm hewn to draw the stable solution is adopted. This paper uses the methodology that is to take local approximate equilibrium from partial network and expand local approximate equilibrium to global equilibrium.

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Experimental Study on Coefficient of Flow Convection (유수대류계수에 관한 실험적 연구)

  • Jeon, Sang-Eun;Kim, Kook-Han;Kim, Jin-Keun;Yang, Joo-Kyoung
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.314-322
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    • 2003
  • Pipe cooling method is widely used for reduction of hydration heat and control of cracking in mass concrete structures. However, in order to effectively apply pipe cooling systems to concrete structures, the coefficient of flow convection relating the thermal transfer between inner stream of pipe and concrete must be estimated. In this study, a device measuring the coefficient of flow convection was developed. Since a variation of thermal distribution caused by pipe cooling has a direct effect on internal forced flows, the developed testing device is based on the internal forced flow concept. Influencing factors on the coefficient of flow convection are mainly flow velocity, pipe diameter and thickness, and pipe material. Using experimental results from the developed device, the coefficient of flow convection was calculated. Finally, a general prediction model was proposed by theoretical procedures. The proposed prediction model is able to estimate the coefficient of flow convection with flow velocity and material properties of pipe. From comparison with experimental results, the coefficient of flow convection by this model was well agreed with those by experimental results.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2015 (설비공학회 분야의 최근 연구 동향 : 2015년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.6
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    • pp.256-268
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    • 2016
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2015. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering were carried out in the areas of flow, heat and mass transfer, cooling and heating, and air-conditioning, the renewable energy system and the flow inside building rooms. Research issues dealing with air-conditioning machines and fire and exhausting smoke were reduced. CFD seems to be spreading to more research areas. (2) Research works on heat transfer area were carried out in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the economic analysis of GHG emission, micro channel heat exchanger, effect of rib angle on thermal performance, the airside performance of fin-and-tube heat exchangers, theoretical analysis of a rotary heat exchanger, heat exchanger in a cryogenic environment, the performance of a cross-flow-type, indirect evaporative cooler made of paper/plastic film. In the area of pool boiling and condensing, the bubble jet loop heat pipe was studied. In the area of industrial heat exchangers, researches were performed on fin-tube heat exchanger, KSTAR PFC and vacuum vessel at baking phase, the performance of small-sized dehumidification rotor, design of gas-injection port of an asymmetric scroll compressor, effect of slot discharge-angle change on exhaust efficiency of range hood system with air curtain. (3) In the field of refrigeration, various studies were carried in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, a cold-climate heat pump system, $CO_2$ cascade systems, ejector cycles and a PCM-based continuous heating system were investigated. In the alternative refrigeration/energy system category, a polymer adsorption heat pump, an alcohol absorption heat pump and a desiccant-based hybrid refrigeration system were investigated. In the system control category, turbo-refrigerator capacity controls and an absorption chiller fault diagnostics were investigated. (4) In building mechanical system research fields, eighteen studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, and renewable energies, piping in the buildings. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the user and location awareness technology applied dimming lighting control system, the lighting performance evaluation for light-shelves, the improvement evaluation of air quality through analysis of ventilation efficiency and the evaluation of airtightness of sliding and LS window systems. The subjects of building energy were worked on the energy saving estimation of existing buildings, the developing model to predict heating energy usage in domestic city area and the performance evaluation of cooling applied with economizer control. The studies were also performed related to the experimental measurement of weight variation and thermal conductivity in polyurethane foam, the development of flame spread prevention system for sandwich panels, the utilization of heat from waste-incineration facility in large-scale horticultural facilities.

WZ Cephei: A Dynamically Active W UMa-Type Binary Star

  • Jeong, Jang-Hae;Kim, Chun-Hwey
    • Journal of Astronomy and Space Sciences
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    • v.28 no.3
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    • pp.163-172
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    • 2011
  • An intensive analysis of 185 timings of WZ Cep, including our new three timings, was made to understand the dynamical picture of this active W UMa-type binary. It was found that the orbital period of the system has complexly varied in two cyclical components superposed on a secularly downward parabola over about 80y. The downward parabola, corresponding to a secular period decrease of $-9.{^d}97{\times}10^{-8}y^{-1}$, is most probably produced by the action of both angular momentum loss (AML) due to magnetic braking and mass-transfer from the massive primary component to the secondary. The period decrease rate of $-6.^{d}72{\times}10^{-8}y^{-1}$ due to AML contributes about 67% to the observed period decrease. The mass flow of about $5.16{\times}10^{-8}M_{\odot}y^{-1}$ from the primary to the secondary results the remaining 33% period decrease. Two cyclical components have an $11.^{y}8$ period with amplitude of $0.^{d}0054$ and a $41.^{y}3$ period with amplitude of $0.^{d}0178$. It is very interesting that there seems to be exactly in a commensurable 7:2 relation between their mean motions. As the possible causes, two rival interpretations (i.e., light-time effects (LTE) by additional bodies and the Applegate model) were considered. In the LTE interpretation, the minimum masses of $0.30M_{\odot}$ for the shorter period and $0.49M_{\odot}$ for the longer one were calculated. Their contributions to the total light were at most within 2%, if they were assumed to be main-sequence stars. If the LTE explanation is true for the WZ Cep system, the 7:2 relation found between their mean motions would be interpreted as a stable 7:2 orbit resonance produced by a long-term gravitational interaction between two tertiary bodies. In the Applegate model interpretation, the deduced model parameters indicate that the mechanism could work only in the primary star for both of the two period modulations, but could not in the secondary. However, we couldn't find any meaningful relation between the light variation and the period variability from the historical light curve data. At present, we prefer the interpretation of the mechanical perturbation from the third and fourth stars as the possible cause of two cycling period changes.

Analytical and Numerical Model Study to Predict the Temperature Distribution Around an Underground Food Cold Storage Pilot Cavern (냉동저장 공동 주변의 온도분포 예측을 위한 해석해 및 수치모델 적용에 관한 연구)

  • 이대혁;김호영
    • Tunnel and Underground Space
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    • v.12 no.3
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    • pp.142-151
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    • 2002
  • Claesson(2001)'s analytical solution, and two numerical models with Dirichlet and Neuman interior boundary condition respectively were investigated to estimate the transient temperature distribution with distances from the Taejon underground food cold storage pilot cavern. Claesson's solution, which is based on constant temperature boundary condition at the rock wall during a temperature decline step, showed relatively good agreement with temperature measurements in the rock mass in order of average error difference, 0.89$\^{C}$ without any adjustments on laboratory thermal properties to represent the rock mass. For the numerical model with heat flux through the rock wall, a boundary condition setting technique was newly proposed to overcome the difficulty of prescribing variable convective heat tranfer coefficient and far-field air temperature inside the cavern as they may be certainly changed according to the cooling-down time. The results showed also good agreement with measurements in order of average error difference, 1.58$\^{C}$, and were compared to those of the numerical model with fixed temperature at the rock wall. Finally, the most proper procedure to precisely predict the temperature profile around a cavern was proposed as a series of analysis steps including an analytical exact solution and numerical models.

Models of Wastewater Treatment by Rotating Discs (회전원판접촉법(回轉圓板接觸法)에 의한 폐수처리(廢水處理)의 모형(模型)에 관한 연구(研究))

  • Chung, Tai Hak;Park, Chung Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.2
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    • pp.39-46
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    • 1982
  • A model of substrate removal by rotating discs has been developed for a better understanding of the process, and the performance of the system has been evaluated under steady and unsteady state. The model was constructed based upon mass transfer of the substrate from the bulk solution to the biofilm and a simultaneous removal of the substrate by the biomass. The model is composed of a few sets of differential equations representing mass balance within the elements of a liquid film and a biofilm, and in the bulk solution. Substrate removal efficiency of the process is largely dependent on a diffusion coefficient of the substrate within the biofilm and a maximum rate of substrate removal of the biomass. The efficiency is affected to a greater extent when the substrate concentration is low and the maximum substrate removal rate is high. The efficiency increases proportionally with increasing film depth when the biofilm is shallow, however, the rate of increase gradually decreases with an increase of the film depth. As the film reaches a limiting depth, the efficiency remains constant. Unlike the steady state, the effluent quality is affected by the tank volume under dynamic state. Increasing tank volume decreases peak concentration of the effluent under peak loading. Additional tank volume provides a buffer capacitya.gainst a peak loading and the holding tank behaves like an equalization tank.

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