• Journal of Korean Society of Environmental Engineers
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• v.37 no.8
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• pp.450-457
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• 2015

In this research a adsorbent, PVA-Zeolite bead, was prepared by immobilizing zeolite with PVA. The results of XRD and SEM analysis showed that the prepared PVA-Zeolite beads had porous structure and the zeolite particles were in mobilized within the internal matrix of the beads. The adsorption properties of Sr ion and Cs ion with the adsorbent were studied by different parameters such as effect of pH, adsorption rate, and adsorption isotherm. The adsorption of Sr ion and Cs ion reached equilibrium after 540 minutes. The adsorption kinetics of both ions by the PVA-Zeolite beads were fitted well by the pseudo-second-order model more than pseudo-first-order model. The equilibrium data fitted well with Langmuir isotherm model. The maximum adsorption capacities of Sr ion and Cs ion calculated from Langmuir isotherm model were 52.08 mg/g and 58.14 mg/g, respectively. The external mass transfer step was very fast compared to the intra-particle diffusion step in the adsorption process of Cs ion and Sr ion by the PVA-Zeolite beads. This result implied that the rate controlling step was the intra-particle diffusion step.

• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.44-54
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• 2003

A kinetic model for evaluating effects of surfactant on the biodegradation of HOC(hazardous organic chemicals) in soil-slurry systems was developed. The model includes the partition of HOC and surfactant, the dissolved-, micellar-, and sorbed-phase biodegradation, the enhanced solubilization of HOC by surfactant addition, and the mass transfer of HOC. Phenanthrene as HOC and Trition X-100, Tergitol NP-10, Igepal CA-720, and Brij 30 were used in the model simulations. The biodegradation rate was increased even with a small micellera-phase bioavailability. The biodegradation was not greatly enhanced due to decreased aqueous HOC concentration by increasing surfactant dose in both cases with and without micellar-phase bioavailability. The effect of sorbed-phase biodegradation on total biodegradation rate was not highly important compared to aqueous- and micellar-phase biodegradation. The model can be applied for surfactant screening and optimal design of surfactant-based soil bioremediation process.

• Journal of Soil and Groundwater Environment
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• v.16 no.6
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• pp.79-94
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• 2011

Black carbon (BC), a kind of high surface area carbonaceous material (HSACM), was isolated from Andong lake sediment. Sorption and desorption kinetics of naphthalene (Naph) and phenanthrene (Phen) in organic carbon (OC) and BC in the Andong lake sediment were investigated. Several kinetic models such as one-site mass transfer model (OSMTM), two-compartment first-order kinetic model (TCFOKM), and a newly proposed modified two-compartment first-order kinetic model (MTCFOKM) were used to describe the sorption and desorption kinetics. The MTCFOKM was the best fitting model. The MTCFOKM for sorption kinetics showed that i) the sorbed amounts of PAHs onto BC were higher than those onto OC, consistent with BET surface area; ii) the equilibration time for sorption onto BC was longer than those onto OC due to smaller size of micropore ($11.67{\AA}$) of BC than OC ($38.18{\AA}$); iii) initial sorption velocity of BC was higher than OC; and iv) the slow sorption velocity in BC caused the later equilibrium time than OC even though the fast sorption velocity was early completed in both BC and OC. The MTCFOKM also described the desorption of PAHs from the OC and BC well. After desorption, the remaining fractions of PAHs in BC were higher than those in OC due to stronger PAHs-BC binding. The remaining fractions increased with aging for both BC and OC.

• Nuclear Engineering and Technology
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• v.23 no.4
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• pp.387-400
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• 1991

An ocean compartment model simulating transport of nuclides by advection due to ocean circulation and intertaction with suspended sediments is developed, by which concentration breakthrough curves of nuclides can be calculated as a function of time. Dividing ocean into arbitrary number of characteristic compartments and performing a balance of mass of nuclides in each ocean compartment, the governing equation for the concentration in the ocean is obtained and a solution by the numerical integration is obtained. The integration method is specially useful for general stiff systems. For transfer coefficients describing advective transport between adjacent compartments by ocean circulation, the ocean turnover time is calculated by a two-dimensional numerical ocean model. To exemplify the compartment model, a reference case calculation for breakthrough curves of three nuclides in low-level radioactive wastes, Tc-99, Cs-137, and Pu-238 released from hypothetical repository under the seabed is carried out with five ocean compartments. Sensitivity analysis studies for some parameters to the concentration breakthrough curves are also made, which indicates that parameters such as ocean turnover time and ocean water volume of compartments have an important effect on the breakthrough curves.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.277-284
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• 2012

In this study, a heat-transfer performance analysis is carried out for a multi-channel volumetric air receiver for a solar power tower. On the basis of a series of reviews regarding the relevant literature, a calculation process is proposed for the prediction of the wall- and air- temperature distributions of a single channel at given geometric and input conditions. Furthermore, a unique mathematical model of the receiver effectiveness is presented through analysis of the temperature profile. The receiver is made of silicon carbide. A total of 225 square straight channels per module are molded to induce the air flow, and each channel has the dimensions of $2mm(W){\times}2mm(H){\times}0.2mm(t){\times}320mm(L)$. The heat-transfer rate, temperature distribution and effectiveness are presented according to the variation of the channel and module number under uniform irradiation and mass flow rate. The available air outlet temperature applied to the solar power tower should be over $700^{\circ}C$. This numerical model was actually used in the design of a 200 kW-level commercial solar air receiver, and the required number of modules satisfying the thermal performance could be obtained for the specified geometric and input conditions.

• Journal of Korean Society of Forest Science
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• v.85 no.2
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• pp.210-224
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• 1996

The SLODSVAT consists of interrelated submodels that simulate : the transfer of radiation, water vapour, sensible heat, carbon dioxide and momentum in two canopy layers determined by environmental conditions and ecophysiological properties of the vegetation ; uptake and storage of water in the "root-stem-leaf" system of plants ; interception of rainfall by the canopy layers and infiltration and storage of rain water in the four soil layers. A comparison of the results of modeling experiments and field micro-climatic observations in a spruce forest(Picea abies [L].Karst) in the Soiling hills(Germany) shows, that the SLODSVAT can describe and simulate the short-term(diurnal) as well as the long-term(seasonal) variability of water vapour and sensible heat fluxes adequately to natural processes under different environmental conditions. It proves that it is possible to estimate and predict the transpiration and evapotranspiration rates for spruce forest ecosystems on the patch and landscape scales for one vegetation period, if certain meteorological, botanical and hydrological information for the structure of the atmospheric boundary layer, the canopy and the soil are available.

• Journal of Energy Engineering
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• v.22 no.4
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• pp.399-405
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• 2013

The gas motion inside the engine cylinder plays a very important role in determining the thermal efficiency of an internal combustion engine. A precise information of in-cylinder three dimensional complex gas motion is crucial in optimizing engine design. Homogeneous charge compression ignition (HCCI) engine is a combustion concept, which is a hybrid between Otto and Diesel engine. The turbulent diffusion leads to increased rates of momentum, heat and mass transfer. The in-cylinder turbulence flow was found to affect the present HCCI combustion mainly through its influence on the wall heat transfer. This study investigates the effect of piston geometry shape on the turbulent flow characteristics of in-cylinder from the numerical analysis using the LES model and the results obtained can offer guidelines of the combustion geometries for better combustion process and engine performance.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.38.2-39
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• 2021

I will presents the analysis of the gas properties of the protoplanetary disk surrounding the young low-mass (about 1.2M_sun) triple star, GG Tau A. This work makes use of ALMA observations of rotational lines of CO (¹²CO, ¹³CO and C¹⁸O) together NOEMA observations of a few dozens of other molecules. While the CO emission gives information on the molecular layer close to the disk atmosphere, its less abundant isotopologues ¹³CO and C¹⁸O bring information much deeper in the molecular layer. I will present the analysis of the morphology and kinematics of the gas disk using the CO isotopologues. A radiative transfer model of the ring in CO isotopologues will also be presented. The subtraction of this model from the original data reveals the weak emission of the molecular gas lying inside the cavity. Thus, I am able to evaluate the properties of the gas inside the cavity, such as the gas dynamics, excitation conditions, and the amount of mass in the cavity. High angular resolution observations of CO reveals sprials induced by embedded planet(s) located near the 3:2:1 mean-motion resonance that help to explain the special morphology of the circumbinary disk. I also discuss some chemical properties of the GG Tau A disk. I report the first detection of H2S and C₂S in a protoplanetary disk. The molecule abundance relative to ¹³CO of about twenties other molecules will also be given. In GG Tau A, the detections of rare molecules such as H₂S and C₂S have been probably possible because the disk is more massive (a factor about 3-5) than other disks where the molecules was searched. Such a large disk mass makes the system suitable to detect rare molecules and to study cold-chemistry in protoplanetary disks.

• Asian-Australasian Journal of Animal Sciences
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• v.33 no.12
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• pp.1948-1956
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• 2020

Objective: The purpose of this study was to reveal the metabolic shift in the fungus cocultured with the methanogen (Methanobrevibacter thaueri). Methods: Gas chromatography-mass spectrometry was used to investigate the metabolites in anaerobic fungal (Pecoramyces sp. F1) cells and the supernatant. Results: A total of 104 and 102 metabolites were detected in the fungal cells and the supernatant, respectively. The partial least squares-discriminant analysis showed that the metabolite profiles in both the fungal cell and the supernatant were distinctly shifted when co-cultured with methanogen. Statistically, 16 and 30 metabolites were significantly (p<0.05) affected in the fungal cell and the supernatant, respectively by the co-cultured methanogen. Metabolic pathway analysis showed that co-culturing with methanogen reduced the production of lactate from pyruvate in the cytosol and increased metabolism in the hydrogenosomes of the anaerobic fungus. Citrate was accumulated in the cytosol of the fungus co-cultured with the methanogen. Conclusion: The co-culture of the anaerobic fungus and the methanogen is a good model for studying the microbial interaction between H₂-producing and H₂-utilizing microorganisms. However, metabolism in hydrogenosome needs to be further studied to gain better insight in the hydrogen transfer among microorganisms.

• Bulletin of the Society of Naval Architects of Korea
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• v.13 no.1
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• pp.1-9
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• 1976

Using the computer programs for calculation of natural vibrations of ship's hull developed by the authors et al., an investigation into influences of various parameters on the accuracy of calculation was done through example calculations of a 30,000 DWT petroleum products carrier M/S Sweet Brier built by Korea Shipbuilding and Engineering Corporation. The methodical principles employed for the computer program development are as follows; (a) the ship system is reduced to an equivalent discrete elements system conforming to Myklestad-Prohl model, (b) the problem formulation is of transfer matrix method, and (c) to obtain solutions an extended $G\ddot{u}mbel's$ initial value method is introduced. The scope of the investigation is influences of number of discrete elements, choice of significant system parameters such as rotary inertia, bending stiffness and shear stiffness, and simplification of distributions of added mass and stiffness as trapezoidal ones referred to those of midship section on the calculation accuracy. From the investigation the followings are found out; (1) To obtain good results for the modes up to the seven-noded thirty or more divisions of the hull is desirable. For fundamental mode fifteen divisions may give fairly good results. (2) The influence of rotary inertia is negligibly small at least for the modes up to the 5- or 6- noded. (3) In the case of assuming either bending modes or shear modes the calculation results in considerably higher frequencies as compared with those based on Timoshenko beam theory. However, the calculation base on the slender beam theory surprisingly gives frequencies within 10% error for fundamental modes. (4) It is proved that to simplify distributions of added mass and stiffness as trapezoidal ones referred to those of midship section is a promising approach for the prediction of natural frequencies at preliminary design stage; provided good accumulation of data from similar type ships, we may expect to obtain natural frequencies within 5% error.