• Title/Summary/Keyword: mass transfer model

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Modeling of Ammonia Mass Transfer Using a Hollow Fiber Membrane Contactor (중공사막 접촉기를 이용한 암모니아 물질전달 모델링)

  • Oh, Dae-Yang;Jeong, Joo-Young;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.503-510
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    • 2011
  • Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling (Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도)

  • Sohn, Ho-Sang;Jung, Kwang-Hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

DUST SHELL MODELS FOR LOW MASS-LOSS RATE OXYGEN-RICH AGB STARS

  • SUH KYUNG-WON
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.267-270
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    • 2005
  • We investigate the spectral energy distributions (SEDs) of low mass-loss rate O-rich asymptotic giant branch (AGB) stars using the infrared observational data including the Infrared Space Observatory (ISO) data. Comparing the results of detailed radiative transfer model calculations with observations, we find that the dust formation temperature is much lower than 1000 K for standard dust shell models. We find that the superwind model with a density-enhanced region can be a possible alternative dust shell model for LMOA stars.

A Prediction of Pollutant Emission Rate using Numerical Analysis and CFD in Double-Layered Building Materials (수치해석 및 CFD를 이용한 소형챔버내 복합건축자재의 오염물질 방출량 예측)

  • Kim, Chang-Nam;Leigh, Seung-Bok;Kim, Tae-Yeon
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.277-282
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    • 2006
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in double-layered building materials through the CFD(Computational of Fluid Dynamics) and Numerical analysis based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient($h_m'$) which indicates the existing convective mass transfer coefficient($h_m$) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

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Data Reduction on the Air-side Heat Transfer Coefficients of Heat Exchangers under Dehumidifying Conditions (제습이 수반된 공조용 증발기 습표면의 열전달계수 데이터 리덕션)

  • Kim, Nae-Hyun;Oh, Wang-Kyu;Cho, Jin-Pyo;Park, Hwan-Young;Yoon, Baek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.1
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    • pp.73-85
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    • 2003
  • Four different methods of reducing the heat transfer coefficients from experimental data under dehumidifying conditions are compared. The four methods consist of two different heat and mass transfer models and two different fin efficiency models. Data are obtained from two heat exchanger samples having plain fins or wave fins. Comparison of the data with the reduction methods revealed that the single potential heat and mass transfer model yielded the humidity independent heat transfer coefficients. Two different fin efficiency models - enthalpy model and humidity model - yielded approximately the same fin efficiencies and accordingly approximately the same heat transfer coefficients. The heat transfer coefficients under wet conditions were approximately the same as those of the dry conditions for the plain fin configuration. For the wave fin configuration, however, wet surface heat transfer coefficients were approximately 12% higher. The pressure drops of the wet surface were 10% to 45% larger than those of the dry surface.

Ionic Mass Transport Correlation of Double-Diffusive Convection in Horizontal Fluid Layers

  • Kim, Min-Chan;Hyun, Myng-Taek;Yoon, Do-Young
    • Journal of Mechanical Science and Technology
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    • v.14 no.12
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    • pp.1396-1402
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    • 2000
  • Here is investigated the characteristics of double-diffusive convection in thermally-stable stratified horizontal fluid layer. By employing an electrochemical technique, and adopting aqueous CuSO$_4$-H$_2$SO$_4$solution as electrolyte, experiments on ionic mass transfer have been conducted systematically. And, also a new mass transfer correlation in double-diffusive situations has been derived by extending the model of micro-scales of turbulence, which was proposed by Arpaci. The resulting correlation of the Sherwood number as a function of the thermal Rayleigh number was in good agreement with the present experimental results. The present study provides plausible understanding in controlling both mass and heat transfer rates for practical situations including double-diffusive convection.

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A Simple Condensation Model on the Vapor Jets in Subcooled Water (과냉각수로 방출되는 증기제트의 응축모델)

  • Kim, Hwan-Yeol;Ha, Kwang-Soon;Bae, Yoon-Yeong;Park, Jong-Kyun;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.240-245
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    • 2001
  • Phenomena of direct contact condensation (DCC) heat transfer between steam and water are characterized by the transport of heat and mass through a moving steam/water interface. Application of the phenomena of DCC heat transfer to the engineering industries provides some advantageous features in the viewpoint of enhanced heat transfer. This study proposes a simple condensation model on the steam jets discharging into subcooled water from a single horizontal pipe for the prediction of the steam jet shapes. The analysis model was derived from the mass, momentum and energy equations as well as a thermal balance equation with condensing characteristics at the steam/water interface for the axi-symmetric coordinates. The extremely large heat transfer rate at the steam/water interface was reflected in the effective thermal conductivity estimated from the previous experimental results. The analysis results were compared with the experimental ones. The analysis model predicted that the steam jet shape (i. e. radius and length) was increasing as the steam mass flux and the pool temperature were increasing, which was similar in trend to that observed in the experiment.

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Heat and Mass Transfer between Hot Waste Gas and Cold Water in a Direct Contact Heat Exchanger (직접접촉식 열교환기내에서 물과 배기가스의 직접접촉에 의한 열 및 물질전달)

  • 이금배
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.6
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    • pp.1171-1178
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    • 1992
  • An experiment was performed to describe the heat and mass transfer occurring between hot waste gas and cold water through direct contact in a direct contact heat exchanger. This model was then used to obtain an equation of overall heat transfer coefficent based on heat exchanger volume. The diffusion heat transfer rate is 2-3 times larger than the convection heat transfer rate as results of condensation of the water vapor contained in the waste gas. The boiler efficiency increases over 10%.

Development of Analysis Model for Down Scaled Two Phase Catalytic Reactor (초소형 촉매 이상 분해 반응기 해석 모델 개발)

  • Lee, Dae-Hoon;Kwon, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.24-30
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    • 2004
  • Analysis model for the two-phase catalytic reactor is presented. With the progress in development of micro thermofluidic devices, needs fur understanding of the phenomena in two phase reaction in cm scale has been arisen. To investigate thermal and reactive performance of down scaled two phase reactor simple analysis model that is a kind of lumped flow model is proposed. Analysis model presented is based on the experiment on mm scale model reactor. Target experiment is catalytic decomposition of 70wt% hydrogen peroxide with existence of perovskite L $a_{0.8}$S $r_{0.2}$Co $O_3$ catalyst. It is composed of balance equations of mass and energy. Each phase is considered to be a species fur the simplicity. Axial diffusion and transversal distribution of properties are neglected. Two phase catalytic reaction is modeled as successive gasification of liquid lump around catalyst and reaction in gas phase. Heat transfer is modeled by model function ofNu number. Modeled Nu is expressed as Nu=N $u_{0}$ (1+ $a_1$( $a_2$ $T^{-}$ $a_3$)exp( $a_4$ $T^{-1}$)exp( $a_{5}$ z). Transfer coefficients are determined by the comparison of experimental results. With the model, heat transfer characteristics are investigated. Also by the mass transfer coefficient, characteristics in mass transfer is investigated. With the result basic understanding on design and analysis of mm scale two-phase reactive device is obtained. Also it can be further applied to micro scale reactive device fabricated by micromachining.ing..

Experimental investigations and development of mathematical model to estimate drop diameter and jet length

  • Roy, Amitava;Suneel, G.;Gayen, J.K.;Ravi, K.V.;Grover, R.B.
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3229-3235
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    • 2021
  • The key process used in nuclear industries for the management of radiotoxicity associated with spent fuel in a closed fuel cycle is solvent extraction. An understanding of hydrodynamics and mass transfer is of primary importance for the design of mass transfer equipment used in solvent extraction processes. Understanding the interfacial phenomenon and the associated hydrodynamics of the liquid drops is essential for model-based design of mass transfer devices. In this work, the phenomenon of drop formation at the tip of a nozzle submerged in quiescent immiscible liquid phase is revisited. Previously reported force balance based models and empirical correlations are analyzed. Experiments are carried out to capture the process of drop formation using high-speed imaging technique. The images are digitally processed to measure the average drop diameter. A correlation based on the force balance model is proposed to estimate drop diameter and jet length. The average drop diameter obtained from the proposed model is in good agreement with experimental data with an average error of 6.3%. The developed model is applicable in both the necking as well as jetting regime and is validated for liquid-liquid systems having low, moderate and high interfacial tension.