• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.9
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• pp.1232-1238
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• 2018

This paper proposes methods for improving mass spectral resolution for a gas chromatograph mass spectrometer. The slope signs of the 1st and 2nd fitting functions for the ion signal block of each mass index are obtained, and the unnecessary element signals in the ion signal block are removed. The spectrum can be obtained by obtaining the second-order fitting function of the reconstructed ion signal block using only the effective ion signals. In addition, the resolution of the mass spectrum can be improved by correcting the error caused by the shift of the spectral peak position. To verify the performance of the proposed methods, computer simulations were performed using the actual ion signals obtained from the GC-MS system under development. Simulation results show that the proposed method is valid.

• Journal of KSNVE
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• v.6 no.1
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• pp.83-88
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• 1996

The significance of spectral element method is that it can treat the mass and stiffness distribution exactly in contrast to the conventional finite element method, and therefore the dynamic behaviors within each spectral element can be obtained exactly. The present study provides the derivation of the spectral element of a curved beam, while the previous ones presented that of a straight structure. Further, in order to verify the derived spectral element, the natural frequencies of a ring by the spectral element method are compared with those by the analytical method and those by the FEM. From the verification, derived spectral element is admissible. And the dynamic behaviors of curved beam are simulated by using the derived spectral element of a curved beam.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.68 no.1
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• pp.102-107
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• 2019

This paper proposes a method to improve the mass spectral detection performance of the residual gas analyzer. By improving the mode estimation method for setting the threshold value and improving the additive noise elimination method, it is possible to detect mass spectrums having low peak values of the threshold level difficult to distinguish from noise. Ion signal blocks for each mass index with noise removed by the improved method are effective for eliminating invalid ion signals based on the linear and quadratic fittings. The mass spectrum can be obtained from the quadratic fitted curves for the reconstructed ion signal block using only the valid ion signals. In addition, the resolution of the mass spectrum can be improved by correcting the error caused by the shift of the spectral peak position. To verify the performance of the proposed method, computer simulations were performed using real ion signals obtained from the residual gas analysis system under development. The simulation results show that the proposed method is valid.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.23 no.6
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• pp.666-674
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• 2019

In the mass spectrum of the mass spectrometer, the spectrum of the low peak adjacent to the spectrum having the high peak value is connected to each other and thus the separation is difficult. This inter-spectral overlap causes degradation of the mass spectral detection performance and resolution. In this paper, we propose a method to improve the mass spectrum detection performance and peak accuracy of residual gas analyzer. The type discrimination according to the characteristics of the ion signal block and the pre-correction for the peak position error can separate and detect the spectrum of the low peak connected to the adjacent spectra. To verify the performance of the proposed method, we compared the proposed method with the conventional method in simulations using actual ion signals obtained from the mass spectrometer under development.

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2143-2147
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• 2013

Matrix assisted laser desorption/ionization (MALDI) mass spectrometry (MS) is a very effective method for lipid mass fingerprinting. However, MALDI MS suffered from spectral complexities, differential ionization efficiencies, and poor reproducibility when analyzing complex lipid mixtures without prior separation steps. Here, we aimed to find optimal MALDI sample preparation methods which enable selective or class-wide mass fingerprinting of two totally different lipid classes. In order to achieve this, various matrices with additives were tested against the mixture of phosphatidylcholine (PC) and cerebrosides (Cers) which are abundant in animal brain tissues and also of great interests in disease biology. Our results showed that, from complex lipid mixtures, 2,4,6-trihydroxyacetophenone (THAP) with $NaNO_3$ was a useful MALDI matrix for the class-wide fingerprinting of PC and Cers. In contrast, THAP efficiently generated PC-focused profiles and graphene oxide (GO) with $NaNO_3$ provided Cer-only profiles with reduced spectral complexity.

• Structural Engineering and Mechanics
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• v.68 no.1
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• pp.39-51
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• 2018

In this study, a frequency domain model updating method is presented using power spectral density (PSD) data. It uses the sensitivity of PSD function with respect to the unknown structural parameters through a decomposed form of transfer function. The stiffness parameters are captured with high accuracy through solving the sensitivity equations utilizing the least square approach. Using numerically noise polluted data, the model updating results of a truss model prove robustness of the method against measurement and mass modelling errors. Results prove the capabilities of the method for parameter estimation using highly noise polluted data of low ranges of excitation frequency.

• Earthquakes and Structures
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• v.3 no.3_4
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• pp.383-411
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• 2012

The objective of the present paper is to review and implement the most recent developments in the Spectral Element Method (SEM), as well as improve aspects of its implementation in the study of wave propagation by numerical simulation in elastic unbounded domains. The classical formulation of the method is reviewed, and the construction of the mass matrix, stiffness matrix and the external force vector is expressed in terms of matrix operations that are familiar to earthquake engineers. To account for the radiation condition at the external boundaries of the domain, a new absorbing boundary condition, based on the Perfectly Matched Layer (PML) is proposed and implemented. The new formulation, referred to as the Multi-Axial Perfectly Matched Layer (M-PML), results from generalizing the classical Perfectly Matched Layer to a medium in which damping profiles are specified in more than one direction.

• Journal of Physiology & Pathology in Korean Medicine
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• v.21 no.1
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• pp.231-234
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• 2007

Dichlororinated bibenzyl compound (4) has been isolated from the New Zealand liverwort. This compound was elucidated using 1D/2D-NMR and mass spectral method. The compound (3) inhibited the growth of the Gram positive bacterium Bacillus subtilis ATCC 19659, (2 mm inhibition zone and 2 mm inhibition zone at 30 ${\mu}$g/disc), Candida albicans ATCC 14053, (2 mm inhibition zone and 2 mm inhibition zone at 30 ${\mu}$g/disc), and the dermatophytic fungi Trichophyton mentagrophytes ATCC 28185, (12 mm inhibition zone at 30 ${\mu}$g/disc) and Cladosporium resinae ATCC 52833 (2 mm inhibition zone at 30 ${\mu}$g/disc). This bibenzyl compound (4) exhibited antimicrobial activity.

• Structural Engineering and Mechanics
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• v.68 no.2
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• pp.171-182
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• 2018

For the first time, nonlocal damped vibration and buckling analyses of arbitrary tapered bidirectional functionally graded solid circular nano-plate (BDFGSCNP) are presented by employing modified spectral Ritz method. The energy method based on Love-Kirchhoff plate theory assumptions is applied to derive neutral equilibrium equation. The Eringen's nonlocal continuum theory is taken into account to capture small-scale effects. The characteristic equations and corresponding first mode shapes are calculated by using a novel modified basis in spectral Ritz method. The modified basis is in terms of orthogonal shifted Chebyshev polynomials of the first kind to avoid employing adhesive functions in the spectral Ritz method. The fast convergence and compatibility with various conditions are advantages of the modified spectral Ritz method. A more accurate multivariable function is used to model two-directional variations of elasticity modulus and mass density. The effects of nanoscale, in-plane pre-load, distributed dashpot, arbitrary tapering, pinned and clamped boundary conditions on natural frequencies and buckling loads are investigated. Observing an excellent agreement between results of current work and outcomes of previously published works in literature, indicates the results' accuracy in current work.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.6
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• pp.1194-1202
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• 2002

A study on the topology optimization of a multi-spectral camera for space-use is presented. The optimization is carried out under self-weight and polishing pressure loading. A multi-spectral camera for space-use experiences degradation of optical image in the space, which can not be detected on the optical test bench on the earth. An optical surface deformation of a primary mirror, which is a principal component of the camera system, is an important factor affecting the optical performance of the whole camera system. In this study, topology optimization of the primary mirror of the camera is presented. As an objective function, a measure of Strehl ratio is used. Total mass of the primary mirror is given as a constraint to the optimization problem. The sensitivities of the objective function and constraint are calculated by direct differentiation method. Optimization procedure is carried out by an optimality criteria method. For the light-weight primary mirror design, a three dimensional model is treated. As a preliminary example, topology optimization considering a self-weight loading is treated. In the second example, the polishing pressure is also included as a loading in the topology optimization of the mirror. Results of the optimized design topology for the mirror with various mass constraints are presented.