• Structural Engineering and Mechanics
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• v.35 no.1
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• pp.53-65
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• 2010

The rigid body inertia properties of a structure including the mass, the center of gravity location, the mass moments and principal axes of inertia are required for structural dynamic analysis, modeling of mechanical systems, design of mechanisms and optimization. The analytical approaches such as solid or finite element modeling can not be used efficiently for estimating the rigid body inertia properties of complex structures. Several experimental approaches have been developed to determine the rigid body inertia properties of a structure via Frequency Response Functions (FRFs). In the present work two experimental methods are used to estimate the rigid body inertia properties of a frame. The first approach consists of using the amount of mass as input to estimate the other inertia properties of frame. In the second approach, the property of orthogonality of modes is used to derive the inertia properties of a frame. The accuracy of the estimated parameters is evaluated through the comparison of the experimental results with those of the theoretical Solid Work model of frame. Moreover, a thorough discussion about the effect of accuracy of measured FRFs on the estimation of inertia properties is presented.

• Journal of Hydrogen and New Energy
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• v.18 no.4
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• pp.422-431
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• 2007

Polymer electrolyte membrane fuel cell(PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance and effect of temperature. These problems can be approached to be solved by using mathematical models which are useful tools for analysis and optimization of fuel cell performance and for heat and water management. In this paper, the present work is to develop an electrochemical model to examine the electrochemical process inside PEM fuel cell. A complete set of considerations of mass, momentum, species and charge is developed and solved numerically with proper account of electrochemical kinetics. When depth of gas channel becomes thinner, diffusion of reactant makes well into gas diffusion layer(GDL) and the performance increases. Although at low current region there is little voltage difference between experimental data of PEM fuel cell and numerical data. When the porosity size of gas diffusion layer for PEM fuel cell is bigger, oxygen diffusion occurs well and oxygen mass fraction appears high in catalyst layer.

• Environmental Analysis Health and Toxicology
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• v.17 no.1
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• pp.37-51
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• 2002

Eleven phenols including two chlorophenols, eight alkylphenols and bisphenol A were derivatized with isobutylchloroformate to form their isobutoxycarbonyl derivatives. Standard phenol mixture was concentrated for the isobutoxycarbonyl (isoBOC) derivatization and analysed by gas chromatography/mass spectrometry (GC/MS). The recoveries of the derivatization method of alkylphenols, chlorophenols, and bisphenol A were calculated by gas chromatography/mass spectrometry-selected ion monitoring mode using two work-up methods for comparison; shaking and heating method. The linear detector responses were obtained in the concentration range of 5∼400 ng, with correlation coefficients varying from 0.9755∼0.9981. Recoveries of the alkylphenols, chlorophenols, and bisphenol A were determined by gas chromatography/mass spectrometry-selected ion monitoring mode using two work-up methods for comparison ; the US-EPA method and the isoBOC derivatization method, Eleven phenols in water samples were extracted with dichloromethane and then concentrated. Also, solid-phase extraction (SPE) with XAD-4 and subsequent conversion to isobutoxycarbonyl derivatives for sensitive analysis with the selected ion-monitoring (SIM) mode. The recoveries were 85.1∼109.9％ and 90.3∼126.6％ for the US-EPA method and the isoBOC.

• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.92-99
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• 2010

Photoexcitation of a precursor ion inside a cell floated at high voltage installed in a tandem time-of-flight (TOF) mass spectrometer provides triple tandem mass spectrometric information and allows kinetic and mechanistic studies. In this work, the factors affecting, or downgrading, the performance of the technique were identified. Ion-optical and computational analyses showed that an optimum instrument could be designed by utilizing a reflectron with linear-plus-quadratic potential inside. Theoretical predictions were confirmed by tests with instruments built with different ion-optical layout. With optimized instruments, masses of intermediate ions in the consecutive dissociation of a precursor ion could be determined with the maximum error of $\pm5$ Da. We also observed excellent agreement in dynamical parameters (critical energy and entropy) for the dissociation of a model peptide ion determined by instruments with different ion-optical layout operated under optimum conditions. This suggests that these parameters can be determined reliably by the kinetic method developed previously when properly designed and operated tandem TOF instruments are used.

• Tunnel and Underground Space
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• v.15 no.2 s.55
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• pp.129-136
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• 2005

This paper describes the implementation of rock mass rating evaluation based on genetic algorithm(GA) and conditional simulation technique to estimate RMR in the area without sufficient borehole data RMR were estimated by GA and conditional simulation technique with reflecting distribution feature and spatial correlation. And RMR determined by GA were compared with the results from kriging. Through the analysis of the results from 30 simulations, the uncertainty of estimation could be quantified.

• Smart Structures and Systems
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• v.23 no.2
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• pp.155-171
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• 2019

In this study, Semi-active Tuned Mass Dampers (STMDs) are employed in order to cover the prevailing uncertainties and promote the efficiency of the Tuned Mass Dampers (TMDs) to mitigate undesirable structural vibrations. The damping ratio is determined using type-1 and type-2 Fuzzy Logic Controllers (T1 and T2 FLC) based on the response of the structure. In order to increase the efficiency of the FLC, the output membership functions are optimized using genetic algorithm. The results show that the proposed FLC can reduce the sensitivity of STMD to excitation records. The obtained results indicate the best operation for T1 FLC among the other control systems when the uncertainties are neglected. According to the irrefutable uncertainties, three supplies for these uncertainties such as time delay, sensors measurement noises and the differences between real and software model, are investigated. Considering these uncertainties, the efficiencies of T1 FLC, ground-hook velocity-based, displacement-based and TMD reduce significantly. The reduction rates for these algorithms are 12.66%, 26.43%, 20.98% and 21.77%, respectively. However, due to nonlinear behavior and considering a range of uncertainties in membership functions, T2 FLC with 7.2% reduction has robust performance against uncertainties compared to other controlling systems. Therefore, it can be used in actual applications more confidently.

• Journal of ILASS-Korea
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• v.24 no.3
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• pp.105-113
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• 2019

In this paper, a study of Urea-SCR System for Dosing Injector for responding to enhanced environmental regulations has been conducted. There is a limit to the experimental approach due to the structural characteristics of the injector. In order to overcome this problem, The analysis was performed assuming unsteady turbulent flow through computational fluid analysis and the internal flow characteristics of the injector were analyzed. By changing the nozzle shape of the injector, the performance factors of the swirl injector by shape were selected and compared. The design parameters were modified by changing the diameter of the nozzle at a constant ratio compared to the base model. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. The Conv. model to which the taper was applied showed the dominance in mass flow rate, discharge coefficient and swirl because of the smooth fluid flow by shape. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. As a result of the comparison coefficient derivation with those performance parameters for comparing the performance of the model-specific injector, the Conv-140 model with the nozzle diameter expanded by 140% showed the best value of the comparison coefficient.

• Mass Spectrometry Letters
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• v.12 no.3
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• pp.85-92
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• 2021

The therapeutic antibody drug market has experienced explosive growth as mAbs become the main therapeutic modality for a variety of diseases. Characterization of glycosylation that directly affects the efficacy and safety of therapeutic monoclonal antibodies (mAbs) is critical for therapeutics development, bioprocess system optimization, lot release, and comparability evaluation. The LC/MS approach has been widely used to structurally characterize mAbs, and recently attempts have been made to obtain comprehensive information on the primary structure and post-translational modifications (PTMs) of mAbs through intact protein analysis. In this study, we performed state-of-the-art LC/MS based intact protein analysis to readily identify and characterize glycoforms of various mAbs. Different glycoforms of mAbs produced in different expression cell lines including CHO, SP2/0 and HEK cells were monitored and compared. In addition, the comparability of protein molecular weight, glycoform pattern, and relative abundances of glycoforms between the commercialized trastuzumab biosimilar and the original product was determined in detail using the given platform. Intact mAb analysis allowed us to gain insight into the overall mAb structure, including the complexity and diversity of glycosylation. Furthermore, our analytical platform with high reproducibility is expected to be widely used for biopharmaceutical characterization required at all stages of drug development and manufacturing.

• Smart Structures and Systems
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• v.26 no.3
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• pp.291-309
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• 2020

To study oceanic and meteorological problems related to climate change, Korea has been operating several ocean research stations (ORSs). In 2011, the Gageocho ORS was attacked by Typhoon Muifa, and its structural members and several observation devices were severely damaged. After this event, the Gageocho ORS was rehabilitated with 5 m height to account for 100-yr extreme wave height, and the vibration measurement system was equipped to monitor the structural vibrational characteristics including natural frequencies and modal damping ratios. In this study, a mass reallocation method is presented for structural model updating of the Gageocho ORS based on the experimentally identified natural frequencies. A preliminary finite element (FE) model was constructed based on design drawings, and several of the candidate baseline FE models were manually built, taking into account the different structural conditions such as corroded thickness. Among these candidate baseline FE models, the most reasonable baseline FE model was selected by comparing the differences between the identified and calculated natural frequencies; the most suitable baseline FE model was updated based on the identified modal properties, and by using the pattern search method, which is one of direct search optimization methods. The mass reallocation method is newly proposed as a means to determine the equivalent mass quantities along the height and in a floor. It was found that the natural frequencies calculated based on the updated FE model was very close to the identified natural frequencies. In conclusion, it is expected that these results, which were obtained by updating a baseline FE model, can be useful for establishing the reference database for jacket-type offshore structures, and assessing the structural integrity of the Gageocho ORS.

• Advances in aircraft and spacecraft science
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• v.10 no.3
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• pp.223-243
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• 2023

There is a burgeoning demand for minimizing the mass of satellites because of its direct impact on reducing launch-to-orbit cost. This must be done without compromising the structure's efficiency. The present paper introduces a relatively low-cost and easily implementable approach for optimizing structural mass to a maximum natural frequency. The natural frequencies of the satellite are of utmost pertinence to the application requirements, as the sensitive electronic instrumentation and onboard computers should not be affected by the vibrations of the satellite structure. This methodology is applied to a realistic model of Al-Azhar University micro-satellite in partnership with the Egyptian Space Agency. The procedure used in structural design can be summarized in two steps. The first step is to select the most favorable primary structural configuration among several different candidate variants. The nominated variant is selected as the one scoring maximum relative dynamic stiffness. The second step is to use perforation patterns reduce the overall mass of structural elements in the selected variant without changing the weight. The results of the presented procedure demonstrate that the mass reduction percentage was found to be 39% when compared to the unperforated configuration that had the same plate thickness. The findings of this study challenge the commonly accepted notion that isogrid perforations are the most effective means of achieving the goal of reducing mass while maintaining stiffness. Rather, the study highlights the potential benefits of exploring a wider range of perforation unit cells during the design process. The study revealed that rectangular perforation patterns had the lowest efficiency in terms of modal stiffness, while triangular patterns resulted in the highest efficiency. These results suggest that there may be significant gains to be made by considering a broader range of perforation shapes and configurations in the design of lightweight structures.