• 제목/요약/키워드: mass balance method

검색결과 237건 처리시간 0.024초

발효당 생산을 위한 목질계 바이오매스의 2단 산당화 (Two-step Acid Hydrolysis Method for Producing Fermentable Sugar from Lignocellulosic Biomass)

  • 박장한;김준석
    • Korean Chemical Engineering Research
    • /
    • 제54권1호
    • /
    • pp.1-5
    • /
    • 2016
  • 목질계 바이오매스를 이용하여 효소를 사용하지 않고 발효당을 얻기 위해 황산을 이용한 당화를 수행하였다. 바이오매스로는 pinus rigida와 palm농업 부산물인 EFB를 사용하였다. 산을 이용한 당화에서는 당의 과분해 생성물을 줄이기 위한 당화조건을 생각해 보아야 한다. 따라서 본 연구에서는 목질계 바이오매스를 이용한 2단 산당화를 수행하였다. 산을 이용한 1차 가수분해에서는 72 wt%의 황산을 이용하여 $80^{\circ}C$에서 반응시켰을 경우 가장 높은 당화율을 보였고 pinus rigida와 EFB 각각 11.49 wt%, 32 wt%의 당화율을 보였다. 이후 1차 가수분해에서 얻은 액상을 9~15 wt%의 산농도가 되도록 묽혀 $50{\sim}120^{\circ}C$의 온도로 2차 가수분해를 진행했다. 2차 가수분해시 9%의 황산농도와 $120^{\circ}C$의 온도조건에서 80분간 반응시켰을 때 최종 글루코오스 당화율은 pinus rigida의 경우 86.8 wt.% (39 g/L), EFB의 경우 95.3 wt%(32.4 g/L)를 얻을 수 있었다. 각 단계에서 분석된 결과는 물질수지를 통해 확인하고 당화 효율을 비교해 보았다.

빌딩 내의 공기유동량 예측을 위한 누입 및 환기모델의 개발 (Development of an Infiltration and Ventilation Model for Predicting Airflow Rates within Buildings)

  • 조석호
    • 한국환경과학회지
    • /
    • 제23권2호
    • /
    • pp.207-218
    • /
    • 2014
  • A ventilation model was developed for predicting the air change per hour(ACH) in buildings and the airflow rates between zones of a multi-room building. In this model, the important parameters used in the calculation of airflow are wind velocity, wind direction, terrain effect, shielding effect by surrounding buildings, the effect of the window type and insect screening, etc. Also, the resulting set of mass balance equations required for the process of calculation of airflow rates are solved using a Conte-De Boor method. When this model was applied to the building which had been tested by Chandra et al.(1983), the comparison of predicted results by this study with measured results by Chandra et al. indicated that their variations were within -10%~+12%. Also, this model was applied to a building with five zones. As a result, when the wind velocity and direction did not change, terrain characteristics influenced the largest and window types influenced the least on building ventilation among terrain characteristics, local shieldings, and window types. Except for easterly and westerly winds, the ACH increased depending on wind velocity. The wind direction had influence on the airflow rates and directions through openings in building. Thus, this model can be available for predicting the airflow rates within buildings, and the results of this study can be useful for the quantification of airflow that is essential to the research of indoor air quality(temperature, humidity, or contaminant concentration) as well as to the design of building with high energy efficiency.

노인의 흡연상태에 따른 식이섭취 패턴 (Dietary Patterns of Elderly People by Smoking Status)

  • 강명희;박정아
    • 한국식품영양과학회지
    • /
    • 제24권5호
    • /
    • pp.663-675
    • /
    • 1995
  • It has been proposed that differences in diet between smokers and nonsmokers may partially explain the positive association between cigarette smoking and chronic diseases such as cancer and coronary heart disease. To investigate the potential for this confounding, the authors studied the relation between cigarette smoking and dietary pattern including nutrient intake in 152 Korean elderly people aged 59∼84years. Dietary intake was determined by a 24-hour recall method and a food frequency questionnaire. Male smokers were lighter than nonsmokers and had a lower body mass index(BMI)(p<0.05). But there were no differences in body weight and BMI between female smokers and nonsmokers. Female smokers had lower intakes of energy and carbohydrates than nonsmokers(p<0.05), but in male, smokers and nonsmokers did not show the difference in energy intake. The mean intake of fiber, protein, fat, minerals, and vitamins did not vary significantly by smoking status. However, both male and female smokers consumed fewer fruits than nonsmokers and ate fresh fruits less often than nonsmokers. The total food frequency score which reflect dietary quality of smokers was lower than those of nonsmokers(p<0.05). Male exsmokers' diet were similar to those of smokers, but in female, dietary patterns of exsmokers were similar to those of nonsmokers. These results confirm that elderly smokers have partially different nutrient and food intake patterns from nonsmokers. The decreased ingestion of fruits and less balanced diet by cigarette smokers could contribute to their increased risks of chronic disease compared with those by nonsmokers. The increased ingestion of nutrients and improved nutritional balance in the diet of exsmokers may help to reduce their risks as well.

  • PDF

시분해 레이저 유도 백열법을 이용한 매연 입자 크기에 관한 수치적 연구 (Numerical Investigation on Soot Primary Particle Size Using Time Resolved Laser Induced Incandescence (TIRE-LII))

  • 이종호;김정용;정동수;장영준;전충환
    • 대한기계학회논문집B
    • /
    • 제29권9호
    • /
    • pp.1022-1031
    • /
    • 2005
  • Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to obtain an appropriate calibration curve for determining primary particle size by comparing the gated signal ratio and double-exponential curve fitting methods. Not only the effects of laser fluence and gas temperature on the cooling behavior but also heat transfer mechanisms of heated soot particle have been investigated. The second-order exponential curve fitting showed better agreements with the LII signals than the gated signal ratio method which was based on the lust-order exponential curve fit. And the temporal decay rate of the LII signal and primary particle size showed nearly linear relationship, which was little dependent on the laser fluence. And it also could be reconfirmed that vaporization was dominant process of heat loss during first loons after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.

자동차용 연료전지 시스템의 가습모델과 열/물균형 유지방법 (Humidification model and heat/water balancing method of PEMFC system for automotive applications)

  • 정승훈;윤석호;김민수
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2005년도 춘계학술대회
    • /
    • pp.339-344
    • /
    • 2005
  • A PEMFC system model for FCEV was constructed and simulated numerically to examine the heat/water flow of the system and air/fuel humidification process for various operation conditions (ambient pressure /temperature/humidity, operating temperature, power load). We modeled PEMFC stack which can generate maximum electricity of about 80 kW. This stack consists of 400 unit cells and each unit cell has $250cm^2$ reacting area. Uniform current density and uniform operating voltage per each cell was assumed. The results show the flow characteristics of heat and water at each component of PEMFC system in macro-scale. The capacity shortage of the radiator occurred when the ambient was hot $(over\;40^{\circ}C)$ and power level was high (over 50 kW). In spite of some heat release by evaporation of water in stack, heat unbalance reached to 20kW approximately in such a severe operating condition. This heat unbalance could be recovered by auxiliary radiators or high speed cooling fan with additional cost. In cold environment, the capacity of radiator exceeded the net heat generation to be released, which may cause a problem to drop the operating temperature of stack. We dealt with this problem by regulating mass flow rate of coolant and radiator fan speed. Finally, water balance was not easily broken when we retrieved condensed and/or unused water.

  • PDF

치과용 아말감의 파절에 관한 연구 (A STUDY ON THE FRACTURE OF DENTAL AMALGAM)

  • 허현도;엄정문
    • Restorative Dentistry and Endodontics
    • /
    • 제9권1호
    • /
    • pp.101-106
    • /
    • 1983
  • It was the purpose of this study to investigate the fracture mode of dental amalgam by observing the crack propagation, and to relate this to the microstructure of the amalgam. Caulk 20th Century Regular, Caulk Spherical, Dispersalloy, and Tytin amalgam alloys were used for this study. After each amalgam alloy and Hg measured exactly by the balance was triturated by the mechanical amalgamator (Capmaster, S.S. White), the triturated mass was inserted into the cylindrical metal mold which was 4 mm in diameter and 12 mm in height and was pressed by the Instron Universal Testing Machine at the speed of 1mm/min with 120Kg. The specimen removed from the mold was stored in the room temperature for a week. This specimen was polished with the emery papers from #100 to #200 and finally on the polishing cloth with 0.06${\mu}Al_2O_3$ powder suspended in water. The specimen was placed on the Instron testing machine in the method similar to the diametral tensile test and loaded at the crosshead speed of 0.05mm/min. The load was stopped short of fracture. The cracks on the polished surface of specimen was examined with scanning electron microscope (JSM-35) and analyzed by EPMA (Electron probe microanalyzer). The following results were obtained. 1. In low copper lathe-cut amalgam, the crack went through the voids and ${\gamma}_2$ phase, through the ${\gamma}_1$ phase around the ${\gamma}$ particles. 2. In low copper spherical amalgam, it was observed that the crack passed through the ${\gamma}_2$ and ${\gamma}_1$ phase, and through the boundary between the ${\gamma}_1$ and ${\gamma}$ phase. 3. In high copper dispersant (Dispersalloy) amalgam, the crack was found to propagate at the interface between the ${\gamma}_1$ matrix and reaction ring around the dispersant (Ag-Cu) particles, and to pass through the Ag-Sn particles. 4. In high copper single composition (Tytin) amalgam, the crack went through the ${\gamma}_1$ matrix between ${\eta}$ crystals, and through the unreacted alloy particle (core).

  • PDF

두개의 증발기가 장착된 소프트 아이스크림 제조기의 성능 해석 (Performance Analysis of the Soft Ice-cream Maker Having Two Evaporators Operating at Different Temperatures)

  • 김정식;김내현
    • 한국산학기술학회논문지
    • /
    • 제14권2호
    • /
    • pp.517-522
    • /
    • 2013
  • 아이스크림제조기는 원액통과 냉각통의 증발온도가 $4^{\circ}C$$-8^{\circ}C$로 각각 다르므로 다수의 모세관을 이용하는데 이 경우 서로 냉매 유량에 영향을 주므로 냉동사이클 설계가 복잡하다. 본 연구에서는 증발온도가 서로 다른 두개의 증발기(냉장 및 냉동)가 장착된 소프트 아이스크림 제조기의 성능을 해석하였다. 압축기 해석에는 효율모델을 적용하였고, 모세관은 1차원 유동으로 간주하여 해석하였으며, 응축기와 증발기는 UA-LMTD법을 적용하여 해석하였다. 요소부품에서의 엔탈피, 압력 및 질량의 평형을 적용하여 냉동사이클 시뮬레이션 프로그램을 개발하였고 R404A를 사용하는 아이스크림 제조기에 적용한 결과, 냉장과 냉동 증발기의 온도를 $3^{\circ}C$ 이내로 예측하여 측정치와 대체로 일치하였다.

지표 미량기체 방출에 대한 두 가지 다른 형태의 Enclosure 기반 측정 방법의 응용 및 Flow-through Dynamic System을 이용한 토양 NO 방출의 민감도 분석 (Two Different Enclosure-based Measurements Applications for Trace Gas Surface Emission and Sensitivity Analysis for Soil NO Emission by Using a Flow-through Dynamic System)

  • 김득수
    • 한국농림기상학회지
    • /
    • 제9권3호
    • /
    • pp.170-178
    • /
    • 2007
  • 지난 수 세기 동안 온실기체와 기타 화학적으로 중요한 미량기체들이 급격하게 증가하였다. 이러한 주요기체가 기후 변화에 미치는 영향을 이해하기 위해서는 각 기체들의 흡원과 발원을 규명하고, 생물권과 대기권 사이에서 발생하는 생물 기원 기체 플럭스들을 특성화하며, 주요 기체를 조절하는 프로세스들을 이해해야 한다. 본 논문에서는 야외 실험을 위한 실용적 방법인 enclosure 기반의 관측법을 소개한다. 특히, 토양표면에서 방출되는 일산화질소 플럭스에 대한 enclosure내에서의 질량수지 방정식과 flow-through dynamic 플럭스 챔버 기법의 민감도를 제시하고 flow-through dynamic 플럭스 챔버 방법의 물리적인 시스템과 이론을 소개한다. 또한 챔버 벽에서 발생하는 일산화질소의 손실을 고려하므로써 새로운 플럭스 계산식을 소개하였고 그 계산식의 불확실성을 논의하였다.

Basic Study on the Heat Transfer During Rapid Freezing of Syobean Seed by Liquid Nitrogen

  • Kawano, Toshio;Nakano, Kohei;Murata, Satoshi
    • 한국농업기계학회:학술대회논문집
    • /
    • 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
    • /
    • pp.443-452
    • /
    • 1993
  • Direct freezing tests of soybean seed by liquid nitrogen were carried out at various moisture contents and the following important conclusions were drawn from the results of temperature measurements of soybean seed and photographs of bubbles generated on its surface : 1) Assuming that the temperature gradient in a soybean seed is negligible because of its small seed size and the freezing ratio is followed the Heiss's formula, and a differential equation based on the heat energy balance was introduced . The equation was easily solved by the Runge-Kutta-Gill method and the predicted values of the temperature were in good agreement with the observed data. 2) The photographs of bubble generation during freezing showed the boiling mode was nucleate, and then the most suitable formula on the nucleate boiling heat transfer was introduced from many formulate proposed up to now by fitting the calculated values based on the formula to the observed data. The formula used for the predict on of the seed temperature was as follows: $\frac{{\partial}T_s}{\partial\theta}\;=\;-\frac{{\alpha}(T_s\;-\;T_L)^{3.3}}{W(C_s\;-\;\frac{{\delta}m(CT_s\;+\;{\sigma})}{T_s^2})}$ where C = difference of the specific heat between pure ice and water m=moisture content of soybean seed $T_s$ = seed temperature $T_L$ = Temperature of liquid nitrogen W = mass of soybean seed $\alpha$ = proportional constant $\delta$ = constant depends on variety or the type of seed $\theta$ = time $\sigma$ = latent heat of melting of pure ice This study will give important information in the hydro-freezing technique by liquid nitrogen, available as a new technique of processing agricultural products in the near future.

  • PDF

영양교육과 운동중재 프로그램이 성인비만여성의 신체성분과 식이섭취, 혈중지질 및 기초체력에 미치는 효과 (The Effect of Nutrition Education and Excercise Program on Body Composition and Dietary Intakes, Blood Lipid and Physical Fitness in Obese Women)

  • 이희승;이지원;장남수;김지명
    • Journal of Nutrition and Health
    • /
    • 제42권8호
    • /
    • pp.759-769
    • /
    • 2009
  • This study investigated the effects of the nutrition education and exercise program on body composition, dietary intakes and physical fitness in obese women. The subjects were 44 obese women (BMI${\geq}$ 25 kg/$m^2$) who had been participating in nutrition education (1 time/week) and exercise program (3 time/week) for 12 weeks. Nutrition education was focused on low energy, high protein and low carbohydrate diet to reduce the body weight and improve the diet quality. To evaluate the effectiveness of the program, daily nutrient intakes were assessed by 24-hour recall method. Body composition, blood lipid profiles and physical fitness test were assessed before and after the intervention. After the intervention, body weight, BMI, percent body fat, soft lean mass and waist/hip ratio were significantly decreased (p < 0.001). Fasting blood sucrose, total cholesterol, LDL-cholesterol and atherogenic index (AI) were significantly decreased (p < 0.001), while HDLcholesterol was significantly increased (p < 0.001). Energy adjusted protein, fiber, vitamin A, vitamin $B_2$, vitamin $B_6$, vitamin C, vitamin E, niacin and folate were significantly increased. After the intervention, the muscle endurance, muscle strength, agility, balance were significantly increased. The changes in obesity indices (body weight, BMI, percent body fat, waist-hip ratio) were correlated with the changes of the nutrient intakes, serum lipid profiles, physical fitness. These results show that nutrition education and exercise program was effective not only for weight reduction but also for the improvement of physical strength and cardiovascular disease risk factors in obese women.