• Title/Summary/Keyword: mass Transfer

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A Study on the Synthesis of Calcium Lactate Using Precipitated Calcium Carbonate (침강성 탄산칼슘을 이용한 젖산칼슘 합성에 관한 연구)

  • Park, Joo-Won;Cho, Kye-Hong;Park, Jin-Koo;Ahn, Ji-Whan;Han, Choon
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.173-178
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    • 2008
  • Calcium lactate was prepared by reacting lactic acid with precipitated calcium carbonate (PCC) which was prepared by carbonation process (calcite) and solution process (aragonite). Effects of PCC morphology (calcite and aragonite) on calcium lactate by the solution process were investigated experimentally. Despite the slow forming rate at the initial stage, the final yield of calcium lactate appeared higher when calcite was used. Therefore, the maximum yield of calcium lactate using aragonite was 85.0% and that using calcite was 88.7%, respectively. For both cases, the optimum temperature for the preparation appeared at around $60^{\circ}C$. Furthermore, the increase in lactic acid concentration over 2.0 mol% increased slurry viscosity and deteriorated mass transfer, which resulted in low yield of calcium lactate for both cases. SEM analyses showed that the prepared calcium lactate appeared as plate-like crystal form, irrespective of PCC morphologies, reaction temperatures, and concentrations of lactic acid.

Development of a Crash Cushion Using the Frictional and Inertial Energy by Computer Simulation (컴퓨터 시뮬레이션에 의한 관성과 마찰 에너지를 이용하는 충격흡수시설의 개발)

  • Kim, Dong-Seong;Kim, Kee-Dong;Ko, Man-Gi;Kim, Kwang-Ju
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.2
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    • pp.23-30
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    • 2009
  • Crash cushions are protective devices that prevent errant vehicles from impacting on fixed objects. This function is accomplished by gradually decelerating a vehicle to a safe stop in a relatively short distance. Commonly used crash cushions generally employ one of two concepts to accomplish this function. The first concept involves the absorption of the kinetic energy of a moving vehicle by crushable or plastically deformable materials and the other one involves the transfer of the momentum of a moving vehicle to an expendable mass of material located in the vehicle's path. Crash cushions using the first concept are generally referred to as compression crash cushions and crash cushions using the other concept are generally referred to as inertial crash cushion. The objective of this research is the development of a compression-type crash cushion by employing the two concepts simultaneously. To minimize the number of full-scale crash tests for the development of the crash cushion, preliminary design guide considering inertial and frictional energy absorption was constructed and computer simulation was performed. LS-DYNA program, which is most widely used to analyze roadside safety features, was used for the computer simulation. The developed crash cushion satisfied the safety evaluation criteria for various impact conditions of CC2 performance level in the Korean design guide.

Introduction to Chang'e-3 and Analysis of Estimated Mission Trajectory (창어 3호 개요 및 임무궤적 추정결과 분석)

  • Choi, Su-Jin;Lee, Donghun;Bae, Jonghee;Rew, Dong-Young;Ju, Gwanghyeok;Sim, Eun-Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.11
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    • pp.984-997
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    • 2015
  • Chang'e-3 consisting of a lunar lander and exploration rover was launched on December 1, 2013 aboard a Long March 3B rocket flying from Xichang space launch center. Chang'e-3 was inserted into the lunar orbit after about a 5-day transit to the Moon and landed on the targeted landing site after orbiting around the Moon for 8 days. The successful landing of the Chang'e-3 gives a lot of help to analyze the future needs of the subsystem technologies and to figure out the trajectory from launch to lunar landing as well as operation sequences in the development of Korean lunar exploration is scheduled. Therefore, the configuration and analysis of overall mission of Chang'e-3 is performed based on the public information from the press and website. As a result, overall mission trajectory is reconstructed by solving boundary condition and then estimating control variable. Visibility status and eclipse status also analyzes so communication and power charge condition is as good as to operate lunar lander. Mass budget of the lander is derived using ${\Delta}V$ according to specific impulse.

A Study of the Development of Liquid-liquid Static Contactor Using Capillary Phenomena Induced by Highly Packed Fiber Bundle and its Characteristics (고밀집 섬유 집합체에 의해 유도된 모세관 현상을 이용한 정적 액-액 접촉장치의 개발과 그 특성 연구)

  • Kim, Kwang-Wook;Byeon, Kee-Hoh;Lee, Eil-Hee;Yoo, Jae-Hyung;Park, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.743-749
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    • 1996
  • A new static contractor using capillary phenomena induced by a highly packed fiber bundle was developed for the solvent extraction. When two immiscible phases being cocurrently and forcedly fed into the packed fiber bundle, the contactor brings about a very large liquid-liquid contact area for mass transfer within a small definite space without any turbulence and drop phenomena. In order to test the characteristics and stability of the static contractor system, continuous extraction experiments of TBP-uranyl ion-nitric acid system were done and compared with the batch extraction experiment of the same chemical system. The performance of the static contractor were the same as that of the ideal batch extractor with the same extraction condition. For the increase of the extraction yield by the contactor, the increase of organic flow rate was required at a fixed aqueous flow rate, and a certain residence time of the aqueous phase flow within the contactor system had to be maintained to meet the performance of the batch system of the same phase ratio. The residence time in the case of TBP-uranyl ion-nitric acid system was about 1.9 minutes. This system was confirmed to be effective and stable enough for purposes of the kinetic study of solvent extraction as well as the mutual separation and purification of ordinary materials because of good reproducibility and the stable and large static liquid-liquid contact area.

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Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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The Nonlinear Behavior Characteristics of the 3D Mixed Building Structures with Variations in the Lower Stories (입체 복합구조물의 하부골조 층수 변화에 따른 비선형 거동특성)

  • 강병두;전대한;김재웅
    • Journal of the Earthquake Engineering Society of Korea
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    • v.6 no.1
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    • pp.55-62
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    • 2002
  • The upper wall-lower frame structures(mixed building structures) are usually composed of shear wall structure in the upper part of structure which is used as residential space and frame structure in the lower part of structure which is used as commercial space centering around the transfer system in the lower part of structure. These structures are characteristics of stiffness irregularity, mass irregularity, and vertical geometric irregularity. The purpose of this study is to investigate the nonlinear response characteristics and the seismic capacity of mixed building structures when the number of stories in the lower frame is varied. The conclusions of this study are following. 1) As the result of push-over analysis of structure such as roof drift(i.e. roof displacement/structural height) and base shear coefficient, when the stories of lower frame system are increased, base shear coefficient is decreased, but roof drift is increased. 2) According to an increase in stories of the lower fame, story drift and ductility ratio of upper wall system are decreased and behavior of upper wall system is closed to elastic. 3) When the stories of lower frame system are increased, the excessive story drift is concentrated on the lower frame system.

Purification and Assay of Extracellular Autolysin from Moraxella sp. CK-l (Moraxella sp. CK-1의 세포외 Autolysin의 분리 정제 및 활성도 측정)

  • 오영상;이장현;한명수;윤문영
    • Korean Journal of Microbiology
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    • v.39 no.3
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    • pp.148-154
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    • 2003
  • Moraxella sp. CK-l is known to inhibits the growth of Anabaena cylindrica, a cyanobacterium. It has been documented that the ability of this growth inhibition of Anabaena cylindrica was attributed to extracellular autolysin from Moraxella sp. CK-l. However, it remains to be elucidated identification and characterization of autolysin have yet been elucidated. In this study, we tried to purify and identify autolysin secreted from Moraxella sp. CK-l. Cells were grown in a complex liquid medium (BGC-11) and culture supernatants were collected, followed by ammonium sulfate fractionation. Fractions were further separated with anion exchange column, Mono-Q, in FPLC system and analyzed by SDS/PAGE. The fraction containing high autolysin activity showed a single distinct protein peak in anion column and molecular mass of about 17 kDa in SDS/PAGE. Nterminal amino acid sequencing of the protein was analyzed, of which result showed the homology with some proteases, including extracellular serine protease, Dichelobacter nodosus.

V700 Cygni: A Dynamically Active W UMa-type Binary Star II

  • Kim, Chun-Hwey;Jeong, Jang-Hae
    • Journal of Astronomy and Space Sciences
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    • v.29 no.2
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    • pp.151-161
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    • 2012
  • An intensive analysis of 148 timings of V700 Cyg was performed, including our new timings and 59 timings calculated from the super wide angle search for planets (SWASP) observations, and the dynamical evidence of the W UMa W subtype binary was examined. It was found that the orbital period of the system has varied over approximately $66^y$ in two complicated cyclical components superposed on a weak upward parabolic path. The orbital period secularly increased at a rate of $+8.7({\pm}3.4){\times}10^{-9}$ day/year, which is one order of magnitude lower than those obtained by previous investigators. The small secular period increase is interpreted as a combination of both angular momentum loss (due to magnetic braking) and mass-transfer from the less massive component to the more massive component. One cyclical component had a $20.^y3$ period with an amplitude of $0.^d0037$, and the other had a $62.^y8$ period with an amplitude of $0.^d0258$. The components had an approximate 1:3 relation between their periods and a 1:7 ratio between their amplitudes. Two plausible mechanisms (i.e., the light-time effects [LTEs] caused by the presence of additional bodies and the Applegate model) were considered as possible explanations for the cyclical components. Based on the LTE interpretation, the minimum masses of 0.29 $M_{\odot}$ for the shorter period and 0.50 $M_{\odot}$ for the longer one were calculated. The total light contributions were within 5%, which was in agreement with the 3% third-light obtained from the light curve synthesis performed by Yang & Dai (2009). The Applegate model parameters show that the root mean square luminosity variations (relative to the luminosities of the eclipsing components) are 3 times smaller than the nominal value (${\Delta}L/L_{p,s}{\approx}0.1$), indicating that the variations are hardly detectable from the light curves. Presently, the LTE interpretation (due to the third and fourth stars) is preferred as the possible cause of the two cycling period changes. A possible evolutionary implication for the V700 Cyg system is discussed.

Modeling of Liquid Hold-up in Fixed-bed Reactor for Fischer-Tropsch Synthesis (고정층 Fischer-Tropsch 반응기의 액상 왁스 정체 현상 모델링)

  • Park, Chansaem;Jung, Ikhwan;Park, Seongho;Na, Jonggeol;Kshetrimayum, Krishnadash;Han, Chonghun;Lee, Jong Yeol;Jung, Jongtae
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.63-67
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    • 2014
  • Fischer-Tropsch synthesis mainly produces a wax which is a viscous liquid for long carbon chain. When a catalytic fixed-bed reactor is used for Fischer-Tropsch synthesis, the wax generated on a catalyst surface can keep adsorbing on the catalyst surface. This liquid hold-up causes significant pressure drop and clogging problems through the reactor. Thus, the model for liquid hold-up is required to design the size of reactor and catalyst particles. In this study, the liquid hold-up model considering structural and operational conditions was proposed based on empirical equations for convective mass transfer between the syngas flow and the wax-adsorbed catalyst. The developed model was validated by comparing with the experimental data from Knochen's work (2010). The influence of reactor length and coross section on the wax hold-up in reactor were analyzed and the optimal reactor size were proposed.

Production of Bacterial Cellulose by Pilot Scale and Its Properties (Pilot Scale의 박테리아 셀룰로오스 생산 및 그의 물성)

  • Kim, Seong-Jun;Song, Hyo-Jeong;Chang, Mi-Hwa;Choi, Chang-Nam
    • KSBB Journal
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    • v.22 no.2
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    • pp.91-96
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    • 2007
  • The saccharogenic liquid (SFW) obtained by the enzymatic saccharification of food wastes was used as a medium for production of bacterial cellulose (BC). The enzymatic saccharification of food wastes was carried out by the cultivation supernatant of Tricoderma inhamatum KSJ1 culture. Acetobacter xylinum KJ1 was employed for the BC production culture. Under the scaled-up aeration condition of 1.0 vvm, 5.64 g/L of BC was produced in 3 days cultivation in 50 L air circulation bioreactor using SFW medium with addition of 0.4% agar. The productivity was similar to that of 10 L air circulation bioreactor (5.84 g/L). This cultivation method with 50 L air circulation bioreactor decreasing shear stress and increasing oxygen transfer coefficient ($k_La$) was very useful in BC mass production. The physical properties, such as morphology, molecular weight, crystallinity, and tensile strength of BC produced by the static culture (A), the air circulation culture using 10 L bioreactor (B) and 50 L bioreactor (C) were investigated. The number average molecular weight of BCs produced under the different culture conditions (A-C) showed 2,578,000, 1,975,000, and 1,809,000, respectively. Tensile strength was 1.72 $kg/mm^2$, 1.19 $kg/mm^2$, and 1.18 $kg/mm^2$, respectively. All of the BCs had a form of cellulose I representing pure cellulose. The relative degree of crystallinity showed the range of 86.2$\sim$87.8%. BC production by the air circulation culture mode brought more favorable results in terms of the physical properties and its ease of scale-up. Therefore, it is expected that the new BC production method, the air circulation culture using SFW, would contribute greatly to BC-related manufacturing.