• Title/Summary/Keyword: martensitic steel

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Corrosion Behavior and Oxide Film Formation of T91 Steel under Different Water Chemistry Operation Conditions

  • Zhang, D.Q.;Shi, C.;Li, J.;Gao, L.X.;Lee, K.Y.
    • Corrosion Science and Technology
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    • v.16 no.1
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    • pp.8-14
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    • 2017
  • The corrosion behavior of a ferritic/martensitic steel T91 exposed to an aqueous solution containing chloride and sulfate ions is investigated depending on the stimulated all-volatile treatment (AVT) and under oxygenated treatment (OT) conditions. The corrosion of T91 steel under OT condition is severe, while the corrosion under AVT condition is not. The co-existence of chloride and sulfate ions has antagonistic effect on the corrosion of T91 steel in both AVT and OT conditions. Unlike to corrosion resistance in the aqueous solution, OT pretreatment provides T91 steel lower oxidation-resistance than VAT pretreatment. From scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) and X-ray diffraction (XRD) analysis, the lower corrosion resistance in the aqueous solution by VAT conditions possibly is due to the formation of pits. In addition, the lower oxidation resistance of T91 steel pretreated by OT conditions is explained as follows: the cracks formed during the immersion under OT conditions accelerated peeling-off rate of the oxide film.

Corrosion behavior and mechanism of CLAM and 316L steels in flowing Pb-17Li alloy under magnetic field

  • Xiao, Zunqi;Liu, Jing;Jiang, Zhizhong;Luo, Lin;Huang, Qunying
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1962-1971
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    • 2022
  • The liquid lead-lithium (Pb-17Li) blanket has many applications in fusion reactors due to its good tritium breeding performance, high heat transfer efficiency and safety. The compatibility of liquid Pb-17Li alloy with the structural material of blanket under magnetic field is one of the concerns. In this study, corrosion experiments China low activation martensitic (CLAM) steel and 316L steel were carried out in a forced convection Pb-17Li loop under 1.0 T magnetic field at 480 ℃ for 1000 h. The corrosion results on 316L steel showed the characteristic with a superficial porous layer resulted from selective leaching of high-soluble alloy elements and subsequent phase transformation from austenitic matrix to ferritic phase. Then the porous layers were eroded by high-velocity jet fluid. The main corrosion mechanism of CLAM steel was selective dissolution-base corrosion attack on the microstructure boundary regions and exclusively on high residual stress areas. CLAM steel performed a better corrosion resistance than that of 316L steel. The high Ni dissolution rate and the erosion of corroded layers are the main causes for the severe corrosion of 316L steel.

A Study on the Machining Characteristics by the Internal Quality of Heat Resisting Steel (내열강의 내부품질에 따른 절삭가공 특성에 관한 연구)

  • 채왕석
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.1
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    • pp.24-29
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    • 2000
  • This paper is experimental study of machining characteristics about martensitic heat resisting steel STR11. Machining characteristics are different according to internal quality(chemical compositions, microscopic structure and nonmetallic inclusion) mechanical properties(tensile strength value impact value and hardness) and dynamic cutting force. Following are the results : 1. In analyzing internal quality test materials have typical martensite structure and a minute needle-shaped structure. 2. Tensile strength and reduction of area and hardness are larger. But values of elongation and impact values are smaller. Fracture surface of tensile specimen is ductile. 3, Cutting force is decreasing with cutting speed increasing 4. Cutting force is increasing with feed speed increasing.

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Fatigue Damage Behavior in TIG Welded Joint of F82H Steel under Low Cycle Fatigue Loading (저주기 피로부하에서 F82H 강 TIG 용접 접합부의 피로손상거동)

  • Kim, Dong-Hyun;Park, Ki-Won
    • Journal of Welding and Joining
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    • v.33 no.6
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    • pp.42-48
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    • 2015
  • Reduced activation ferritic/martensitic steels are recognized as the primary candidate structural materials for fusion blanket systems. Welding is an inevitable for breeding blanket for pressure tightness and radioisotope confinement. Especially, TIG welding was chosen for sealing because it has the largest gap allowance compared to the other welding methods, and its properties are controllable by feed wire and welding conditions. In this study, the low cycle fatigue test using two-type gage such as extensometer and strain gage was applied to the TIG welded joint of F82H steel, for evaluating fatigue damage accumulation behavior of the HAZs. As the result, the over-tempered HAZ have shown a higher fatigue damage accumulation compared with other materials at all the testing conditions.

Corrosion Prevention of Cr steels in $SO_2$ Atmosphere for Electrial Power Plants (화력발전소의 장수명화를 위한 Cr 강(鋼)의 고온 $SO_2$가스 부식저감 대책 기술)

  • Lee, Dong-Bok;Choe, Jeong-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.114-115
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    • 2007
  • The corrosion characteristics of Cr steels were investigated to protect Cr steels from the SO2-gas corrosion in the coal-fired power plant. The samples tested were low alloy ferritic steel (ASTM T22, 23), martensitic steel (ASTM T91, 92, 122), and austenitic stainless steel (ASTM 347HFG). The corrosion tests were performed between 600oC and 1000oC in Ar + (0.2, 1)%SO2 gas for 100 hr. Chromium was quite beneficial to corrosion resistance, while iron was not. The corrosion resistance increased in the order of T22, T23, T91, T92, T122, and 347HFG.

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Effect of Cr on Mechanical Properties and Microstructure in 0.27% C-1.0% Si-1.5% Mn Steel (0.27% C-1.0% Si-1.5% Mn 강의 미세조직과 기계적성질에 미치는 Cr의 영향)

  • Jeong, Woo Chang
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.4
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    • pp.181-189
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    • 2016
  • The variation in microstructure and mechanical properties during heat treatment was examined in a series of 0.27% C-1.0% Si-1.5% Mn steels with chromium contents in the range of 0 to 1.0 wt%. It was found that chromium decreased the martensite packet size through the austenite grain refinement and increased tensile strength in the as-quenched steel, about 70 MPa per 1.0 wt%. The 0.27% C-1.0% Si-1.5% Mn-1.0% Cr steel showed tensile strength of 1700 MPa in the as-quenched steel. The 0.27% C-1.0% Si-1.5% Mn-1.0% Cr steel revealed a full martensitic structure after air cooling from $900^{\circ}C$ to room temperature, showing air hardening characteristics. Tempering at $150^{\circ}C$ slightly decreased the tensile strength and increased elongation, which is in a good agreement with impact toughness result.

Effect of Heat Treatments on Welding Residual Stresses of 18% Ni Maraging Steel (18% Ni 마레이징강의 용접 잔류 응력에 미치는 열처리의 영향)

  • 배강열;나석주;김원훈
    • Journal of Welding and Joining
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    • v.11 no.2
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    • pp.53-61
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    • 1993
  • One of the most interesting and promising steel groups considered for the rocket motor case, aircraft and aerospace component is the maraging(martensitic plus aging) nickel steel, developed by International Nickel Company in 1960. This material attains a very high strength with good fracture toughness by simple heat treatments which do not involve a quenching. Full strength can be obtained by "maraging" at 480.deg. for 3 hours for the 18% Ni maraging steel. The effect of heat treatments was considered on the residual stress field of 18% Ni maraging steel weldments. In experiments, various heat treatments such as stress relieve heat treatment, aging and solution heat treatment were carried out of the GTA weldments and the residual stresses were measured by using the hole drilling method. Whereas the conventional pattern of residual stress shows the stresses to be maximum along the weld centerline with tensile stress extending into the heat affected zone, the pattern in maraging steels shows the centerline stress to be compressive. After welding, a series of aging, solution heat treatment and solution heat treatment plus aging treatment were carried out and the residual stresses were measured to reveal that these heat treatments almost completely remove the welding residual stresses.

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Influence of Steel-making Process and Heat-treatment Temperature on the Fatigue and Fracture Properties of Pressure Vessel Steels (제강 및 열처리 조건이 압력용기강의 피로 및 파괴특성에 미치는 영향)

  • Koh, S.K.;Na, E.G.;Baek, T.H.;Park, S.J.;Won, S.Y.;Lee, S.W.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.87-92
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    • 2001
  • In this paper, high strength pressure vessel steels having the same chemical compositions were manufactured by the two different steel-making processes, such as vacuum degassing(VD) and electro-slag remelting(ESR) methods. After the steel-making process, they were normalized at $955^{\circ}C$, quenched at $843^{\circ}C$, and finally tempered at $550^{\circ}C$ or $450^{\circ}C$, resulting in tempered martensitic microstructures with different yielding strengths depending on the tempering conditions. Low-cycle fatigue(LCF) tests, fatigue crack growth rate(FCGR) tests, and fracture toughness tests were performed to investigate the fatigue and fracture behaviors of the pressure vessel steels. In contrast to very similar monotonic, LCF, and FCGR behaviors between VD and ESR steels, a quite difference was noticed in the fracture toughness. Fracture toughness of ESR steel was higher than that of VD steel, being attributed to the removal of impurities in steel-making process.

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The Study of Corrosion Behavior of Active Screen Plasma Nitrided Stainless Steels

  • Chiu, L.H.;Chang, C.A.;Yeh, S.H.;Chen, F.S.;Chang, Heng
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.251-256
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    • 2007
  • Plasma nitriding is a surface treatment process which is increasingly used to improve wear, fatigue and corrosion resistance of industrial parts. Active screen plasma nitriding (ASPN) has both the advantages of the classic cold wall and the hot wall conventional dc plasma nitriding (DCPN) method and the parts to be nitrided are no longer directly exposed to the plasma. In this study, AS plasma nitriding has been used to nitride the UNS S31803 duplex stainless steel, AISI 304 and AISI 316 austenitic stainless steel, and AISI 420 martensitic stainless steel. Treated specimenswere characterized by means of microstructural analysis, microhardness measurements and electrochemical tests in NaCl aerated solutions. Hardness of the nitride cases of AISI 420 stainless steel by Knoop test can get up to 1300 HK0.1. From polarization tests, the corrosion current densities of AISI 420 and UNS S31803specimens ASPN at $420^{\circ}C$ were generally lower than those of their untreated substrates. The corrosion resistance of UNS S31803 duplex stainless steel can be enhanced by plasma nitriding at $420^{\circ}C$ Cowing to the formation of the S-phase.

Brazing Process of Stainless Steel (스테인리스강의 브레이징 특성)

  • Hong, Sung-Chul;Park, Jun-Kyu;Oh, Joo-Hee;Lee, Jae-Hoon;Kim, Won-Joong;Jung, Jae-Pil
    • Journal of Welding and Joining
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    • v.29 no.6
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    • pp.40-44
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    • 2011
  • Brazing of a stainless steel was described in this article. Brazing is a joining technology without melting a substrate and joining temperature is higher than $450^{\circ}C$. Brazing can be broadly applicable across industries. In particular, brazing of stainless steel is widely used in aircraft parts, car engines, heat exchangers, etc. due to its excellent strength, corrosion resistance and other suitable characteristics. Characteristics of the stainless steel depend on their classification like austenitic, ferritic and martensitic stainless steels. In addition, there are many processes in brazing and various parameters such as brazing heat source, filler metals, joint design, etc. Therefore, it is necessary to know basic knowledge about brazing to achieve good brazing joint. Accordingly, properties of stainless steel and design of brazing joint and related process were described in this article.