• Title/Summary/Keyword: manganese-aluminium

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Analysis of Cracking Phenomenon Occurring During Hot Rolling of Fe-23Mn High-manganese Steels with Different Aluminium and Carbon Contents (알루미늄과 탄소 함량에 따른 Fe-23Mn계 고망간강의 열간 압연 시 발생하는 균열 현상 분석)

  • Lim, Hyeon-Seok;Lee, Seung-Wan;Hwang, Byoungchul
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.4
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    • pp.176-180
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    • 2016
  • In this study, a microstructural investigation was conducted on the cracking phenonmenon occurring during hot rolling of Fe-23Mn high-manganese steels with different aluminium and carbon contents. Particular emphasis was placed on the phase stability of austenite and ferrite dependent on the chemical composition. An increase in the aluminum content promoted the formation of ferrite band structures which were easily deformed or cracked. In the steels containing high carbon contents of 0.4 wt.% or higher, on the other hand, the volume fraction and thickness of ferrite bands decreased and thus the cracking frequency was significantly reduced. Based on these findings, it is said that the microstructural evolution occurring during hot rolling of high-manganese steels with different aluminium and carbon contents plays an important role in the cracking phenomenon. To prevent the cracking, therefore, the formation of second phases such as ferrite should be minimized during the hot rolling by the appropriate control of the chemical composition and process parameters

The Properties of Aluminium Alloy Powder for Aluminothermy Process with $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진의 Al 테르밋 반응용 Al 합금분말의 특성)

  • Kim, Youn-Che;Song, Youn-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.71-77
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    • 2013
  • Aluminium powder as reductant in aluminothermy process needs a fine particle size under 200 mesh, but it is not easy economically to make that because of its high ductility and powder production cost. In order to reduce the production cost of fine aluminum powder as reductant of $Mn_3O_4$ waste dust, therefore, the properties of aluminium alloy powder were investigated. Aluminium alloy ingot containing large amount of manganese can be crushed easily because of its intermetallic compounds having brittle properties. The manganese is also main element in ferro-manganese. We can obtain economically Al-15%Mn alloy powder by mechanical comminution process. And the result of thermite reaction using Al-15% Mn alloy powder instead of pure Al powder showed the fact that can be obtained the ferro-manganese which have a high purity in case of using pure aluminium powder as reductant. The recovery of manganese from $Mn_3O_4$ waste dust with Al-15%Mn alloy powder was higher level of about 70% than about 65% in case of using aluminium powder, that is due to lower spatter loss.

Recent developments of manganese-aluminium as rare-earth-free magnets

  • Sirisathitkul, Chitnarong
    • Advances in materials Research
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    • v.9 no.4
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    • pp.323-335
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    • 2020
  • This article reviews findings and progresses in the past decade on manganese-aluminium (MnAl) based magnets as the interest has been revived to fulfill their potential as commercial magnets. The challenges in developments of these rare-earth-free magnets are to acquire a high remanence and coercivity from the ferromagnetic τ-phase in MnAl alloys. To this end, the phase transformation to this τ-MnAl with L10 body centered tetragonal structure has been promoted by a variety of methods and a few percents of carbon (C) is often added to prevent the phase decomposition. Magnetization and coercivity are not only influenced by the phase composition but also the microstructure. The fabrication processes and factors affecting the phase and microstructure are therefore covered. Finally, the productions of bulk MnAl magnets are addressed.

A Study on Metalliding of Al on Steel from Molten Fluorides (불화물계 용융염중에서 Steel 기지 소재의 Al 전해피복에 관한 연구)

  • 이민구;서길원;백영현
    • Journal of the Korean institute of surface engineering
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    • v.26 no.4
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    • pp.183-191
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    • 1993
  • Diffusion coating(metalliding) of aluminium on steel from molten fluorides(29.2wt.% LiF-11.7wt.% NaF-59.1wt.% KF, FLINAK) was studied. The electrolytic cell consists of a steel cathode and a consumable aluminium anode. Effects of manganese on the aluminium deposition were also investigated. The quality of the deposit was analyzed by SEM, OM, EPMA, EDXA, and also examined by means of Micro-Vickers hardness and corrosion tests. Deposit layer was identified as an aluminium-rich iron alloy caused by diffusion process. The optimum condition for the metalliding was found to be the current density, 50 to $150mA/\textrm{cm}^2$, the bath tem-perature, $57.5^{\circ}C$, and the amount of AlF3, 10wt.%. Addition of manganese fluoride (up to 5wt.%) as a co-de-posit element improved significantly the quality of the deposit layer.

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Effects of Aluminium Alloy on the Oxidative Stability of Frying Oil

  • Jong-Youn Son;Soo
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.318-322
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    • 1994
  • Aluminium alloy, comprising water, silicone manganese and porous aluminium carrier added into soybean oil in order to investigated its effect on polar lipid content, polymer content, conjugated dienoic acid and free fatty acid value during deep-fat frying at 185$^{\circ}C$. Increase rates of polar lipid and polymer content of the frying ell were reduced about one thirds of the oil without aluminium alloy during deep-fat frying. The aluminium alloy, however, have no significantly effect to inhibit the increase of conjugated dienoic acid and free fatty acid value. Treatment of the frying oil with aluminium alloy was found to be able to inhibit polymer and polar lipid formation.

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Recovery of Aluminium Coagulants from Water Treatment Plant Sludges (정수 슬러지로부터 알루미늄 응집제의 회수에 관한 연구)

  • Lee, Jae-Bok;Hwang, Jeong-Wuk;Kim, Jin-Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.3
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    • pp.30-40
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    • 1998
  • Increasing water consumption produced sludge problems of the water treatment plants. The objective of this study is to investigate aluminium coagulants recovery n acidic and alkaline conditions. Water treatment plant sludge produced in Pusan Metropolitan City were tested for the aluminium extraction process. Experiment samples were obtained in summer from water treatment plants of Deoksan and Myongjang. Aluminium coagulants used in these plants during the test period were polyaluminium chloride(PAC), polyaluminium sulfate organic(PSO), polyaluminium sulfate silicate(PASS). Aluminium contents of water treatment sludge were in the range of 7.2~10.9% of the total solids. The recovery percentages for aluminium and iron by acidic extraction method was evaluated to 88% and 42% respectively. Extracted mass variation for other materials such as iron, manganese, total organic carbon was observed during the extraction operation. Alkaline extraction produced more than two times amount of total organic carbon than that in the acidic extraction process.

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The Effect of Manganese and Aluminium on the Germination of the Seeds of Pinus banksiana and Alnus tinctoria (방크스소나무 및 산오리나무의 발아와 묘목의 생장에 미치는 Mn과 Al의 영향)

  • 강상준
    • Journal of Plant Biology
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    • v.10 no.3_4
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    • pp.4-9
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    • 1967
  • The aim of present study is to elucidate the effects of manganese and aluminium ions on the germination and seedling growth of Pinus banksiana and Alnus tinctoria and to estimate the limiting level of those ions in the cultivated soils. The rate of germination of Pinus banksiana was increased under the relatively low concentration of Mn and Al (100 p.p.m), however, the germinating activity was not affected. High concentration over 110 p.p.m. of Mn and Al was related to the reduced percentage of germination and seedling growth of Pinus banksiana and Alnus tinctoria. Soils sampled from various parts of Korea contained Mn as much as high level that would be harmful for the seedling growth of Pinus banksiana and Alnus tinctoria.

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Study of a hybrid process combining ozonation and ceramic membrane for drinking water treatment (I) : manganese removal (정수처리를 위한 전오존-세라믹 막여과 조합공정에 관한 연구(I) : 망간 제거 중심)

  • Jin, Kwang Ho;Lim, Jae Lim;Lee, Kyung Hyuk;Wang, Chang Gun
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.6
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    • pp.633-640
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    • 2008
  • In this research, the $3.6m^3/day$ scale pilot plant consisting preozonation, coagulation, flocculation, and ceramic membrane processes was operated for long term period to evaluate the validity of ceramic membrane filtration process for treating lake water containing high concentration manganese. The higher concentration of dissolved manganese($Mn^{2+}$) was effectively oxidized to the bigger insoluble colloidal manganese ($MnO^2$) by 1~2 mg/L ozone. The colloidal manganese reacted with coagulant (poly aluminium chloride, PAC) and then formed the big floc. Ceramic membrane rejected effectively manganese floc during membrane filtration. Dissolved organic carbon(DOC) removal was dependent upon $Mn^{2+}$ concentration. While average $Mn^{2+}$ concentration was 0.43 and 0.85 mg/L in raw water, DOC removal rate in preozonation was 26.5 and 13.5%, respectively. The decrease rate of membrane permeability was faster without preozonation than with preozonation while membrane fouling decreased with NOM oxidation by ozone. In conclusion, raw water containing high concentration of manganese can be effectively treated in preozonation-coagulation-ceramic membrane filtration system.

Comparison of Heavy Metal Contents in Eyeliner Products -Focused on Domestic and Foreign Cosmetic Brands-

  • Lee, Kee-Young;Kim, Jeong-hee
    • Journal of Fashion Business
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    • v.19 no.3
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    • pp.113-120
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    • 2015
  • Heavy metal ingredients of eyeliner product could cause side effect ranging from simple irritation, keratitis, corneal epithelium inflammation, eyelid dermatitis and dry eye symptoms have been reported. This study was conducted in order to prepare fundamental data for acceptable quality level heavy metal ingredients in the domestic and foreign cosmetic brand eyeliner products and to assess theirs the heavy metal concentrations. We measured the concentration of 5 heavy metals in 10 eyeliner products using ICP/MS-LC. According to the results, the average metal concentrations were as follows.; In case of domestic eyeliner products, 289.4 ppm for aluminium(Al), 304 ppm for manganese(Mn), 44 ppm for nickel(Ni), 0.58 ppm for arsenic(As) and 0.35 ppm for lead(Pb). In case of Foreign eyeliner products, 11337.8 ppm for aluminium(Al), 1678.8 ppm for manganese(Mn), 74.2 ppm for nickel(Ni), 1 ppm for arsenic(As) and 0.8 ppm for lead(Pb). Foreign products contained higher amounts of the two elements(Pb, As) compared to domestic ones. Also, greater concentrations of arsenic(As) were detected from waterproof products than non-waterproof ones. In conclusion, for safety reasons we suggested the amounts of heavy metals from the domestic and foreign eyeliner products. This finding will be helpful to provide the fundamental data which is standard of toxicological heavy metals acceptable on eyeliner products.

Effect of Lime and Temperature on the Changes of Available Soil Nutrients in Acid Sulfate Soil under Submergence (특이산성토양(特異酸性土壤)에서 담수시(湛水時) 석회처리(石灰處理) 및 온도조절(溫度調節)이 토양(土壤)의 유효성분(有效成分) 변화(變化)에 미치는 영향(影響))

  • Kang, Ui-Gwm;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.282-288
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    • 1985
  • This experiment was conducted to investigate the changing patterns of the available elements by the control of lime addition amount and temperature in Acid Sulfate Soils under the submerged condition. The results obtained were summarized as follows: 1. pH and contents of available phosphate, soluble silicate, $NH_4-N$, and exchangeable iron in soils were decreased but exchangeable aluminium and manganese, and water soluble sulfur in soils increased after submergence. 2. Lime treatment increased pH, available phosphate, soluble silicate, $NH_4-N$, and water soluble sulfur, but that decreased exchangeable aluminium, iron, and manganese in soils. 3. Treatment with 12me/100gr of Ca as $CaCO_3$, showed the marked effect in increasing the exchangeable aluminium and iron, and increasing pH value to about 6.5 as well as available phosphate and $NH_4-N$. 4. Increases in available phosphate, $NH_4-N$, and exchangeable iron with aging of the soil flooded and lime treated were higher at $35^{\circ}C$ than those at $25^{\circ}C$. 5. Throughout submerged period a significant positive correlation was observed between pH and soluble silicate while the pH has negative correlation with exchangeable elements such as aluminium, iron, and manganese etc.

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