• Title/Summary/Keyword: major oxides

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Petrology and Petrochemistry of the Yangpyeong Igneous Complex (양평화성(楊平火成) 복합체(複合體)에 대(對)한 암석학적(岩石學的) 연구(硏究))

  • Lee, Dai Sung;Kim, Yong Jun
    • Economic and Environmental Geology
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    • v.7 no.3
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    • pp.123-152
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    • 1974
  • The study focused to the so called "Yangpyeong Igneous Complex" which intruded into the Gyeong Gi gneiss complex of Pre-cambrian basement of Yangpyeong area. The geologic sequence of the mapped area was shown in table 1. In laboratory work, 31 modal analyses and 7 chemical analyses on the rock samples taken from the igneous complex have been made to discuss the nomenclature of the rocks and the petrological relationship between rock types. The petrographical and petrochemical features based on the analyses are as follow; 1) The classification of this rocks based on the systematics of igneous rocks of IUGS showed that Yangpyeong Igneous complex consist of hornblende gabbro, diorite and porphyritic monzonite. The major rock forming minerals in hornblende gabbro are hornblende and plagiodase ($An_{46{\sim}55}$), in diorite, hornblende, biotite and plagioclase ($An_{23{\sim}33}$) and in porphyritic monzonite, K-feldspar, plagioclase ($An_{21{\sim}35}$), hornblende and biotite. Hornblende gabbro and diorite show coarse to medium grained hypidiomorphic granular texture and porphyritic monzonite was named by the characteristically porphyritic texture of K-feldspar phenocrysts. 2) Silica-oxides variation diagram (Fig.4) illustrate that the igneous complex is similar ttl that of Daly's average basalt-andesite-dacite-rhyolite and equivalent to the calc-alkalic rock series of Peacock's rock series. In AMF diagram (Fig. 5), the trend of the igneous complex is nearly pararell to that of the Skaergaard intrusion which shows the trend of the fractional crystalization of magma. 3) In normative Or-Ab-An diagram (Fig. 6) the general trend of the data points from gabbro to porphyritic monzonite of the igneous complex directs to a point of Or/Ab=1:1 on the side of Or-Ab. The field and laboratory evidences suggested that the Yangpyeong igneous complex was thought to be a series of comagmatic differential products.

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Distribution Characteristics of Gold in the Volcanic Rocks, Korea (국내에 분포하는 화산암류중 금의 분포특징에 관한 연구)

  • Yoon, Chung-Han;Oh, Keun-Chang
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.257-267
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    • 1996
  • One hundred of thirty volcanic rocks col1ected from the Jeju island, Jeongog, Guryongpo and other areas were analyzed for major elements and trace elements with Au by inductively coupled argon plasma and graphite furnace atomic absorptiom spectrometry. The Au content is the highest values (0.2~43.4 ppb, average; 10.34 ppb) from the Jeju island volcanic rocks and the lowest (0.5~11.0 ppb, average; 1.23 ppb) from the Guryongpo volcanic area. The content of Au tends to be higher in the Quarternary volcanic rocks than Tertiary or Cretaceous volcanic rocks. The Au content of the calc alkali volcanic rocks tends to increase from mafic to felsic volcanic rocks, but that of the alkalic volcanic rocks tends to increase from felsic to mafic volcanic rocks. The Au content of the volcanic rocks collected from the Jeju island shows the highest values in the feldspar olivine basalts. Elements or oxides which have positive or negative correlations with Au are Ag, Mo, Rb, V, Y, $K_2O$, MgO and $SiO_2$, but other elements analyzed are not shown correlations with Au. It has a tendency to show that samples from the Jeju with 5 ppb gold and more are plotted in the non-Dupal area and those with less than 5 ppb gold in the Dupal area, while those from the Jeongog with 5 ppb gold and more are plotted in the Dupal area and those with less than 5 ppb gold in the non-Dupal area, in the Ba/Nb-La/Nb, Zr/Nb-Ba/Nb diagrams. It shows that samples from the Jeju and Guryongpo with high gold content are plotted in the within-plate, while those with low gold content are plotted in the arc-related area, and those from the Jeongog are scattered in the $TiO_2-Al_2O_3$, $Zr/A1_2O_3-TiO_2/Al_2O_3$ diagrams.

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A Study on the Characteristic and Droplet Uniformity of Spray Injection to Exhaust Gas Flow from Urea Solution Injector (Urea 수용액의 배기가스 유동장내 분무 특성과 분무 균일도에 관한 연구)

  • Oh, Jung-Mo;Cha, Won-Sim;Kim, Ki-Bum;Lee, Jin-Ha;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.83-89
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    • 2011
  • Diesel engines can produce higher fuel efficiency and lower $CO_2$ emission, they are subject to ever more stringent emission regulation. However, there are two major emission concerns fo diesel engines like such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, it is not easy to satisfy the regulations on the emission of NOx and PM, which are getting more strengthened. One of the solutions is to apply the new combustion concept using multistage injection such as HCCI and PCCI. The other solution is to apply after-treatment systems. For example, lean NOx trap catalyst, Urea-SCR and others have various advantages and disadvantages Especially, Urea-SCR system have advantages such as a high conversion efficiency and a wide operation conditions. Hence the key factor to implementation of Urea-SCR technology, good mixing of urea(Ammonia) and gas, reducing Ammonia slip. Urea mixer components are required to facilitate evaporation and mixing because the liquid state of urea poses significant barriers for evaporation, and the distance to mixer is the most critical that affect mixer performance. In this study, to find out the distance from injector to mixer and simulation factor, a laser diagnostics and high speed camera are used to analyze urea injector spray characteristics and to present a distribution of urea solution in transparent manifold In addition, Droplet Uniformity Index is calculated from the acquired images by using image processing method to clarify the distribution of spray.

A Study on the Effect of Automotive Engine Performance by Using Carbon Nano Colloid Cooling Water (탄소나노콜로이드 냉각수를 사용하여 자동차 엔진성능의 향상에 관한 연구)

  • Yi, Chung-Seob;Lee, Byung-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.134-142
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    • 2011
  • Although combustion is essential in most energy generation processes, it is one of the major causes of air pollution. Exhaust pipes with circular fin were designed to study the effect of cooling the recirculated exhaust gases (EGR) of Diesel engines on the chemical composition of the exhaust gases and the reduction in the percentages of pollutant emissions. The gases examined in this study were oxides of nitrogen (NOx), carbon dioxide ($CO_2$) and carbon monoxide (CO). In addition, $O_2$ concentration in the exhaust was measured. The designs adopted in this study were about exhaust pipes with solid and hollow fins around them direct surface force measurement in water using a nano size colloidal probe technique. The direct force measurement between colloidal surfaces has been an essential topic in both theories and applications of surface chemistry. As particle size is decreased from micron size down to true Carbon nano Colloid size (<10 nm), surface forces are increasingly important. Nano particles at close proximity or high solids loading are expected to show a different behavior than what can be estimated from continuum and mean field theories. The current tools for directly measuring interaction forces such as a surface force apparatus or atomic force microscopy (AFM) are limited to particles much larger than nano size. This paper use Water and CNC fluid at normal cooling system of EGR. Experimental result showed all good agreement at Re=$2.54{\times}10^4$ by free convection and Re=$3.36{\times}10^4$ by forced air furnace.

Impact of Cooking, Storage, and Reheating Conditions on the Formation of Cholesterol Oxidation Products in Pork Loin

  • Min, Joong-Seok;Khan, Muhammad I.;Lee, Sang-Ok;Yim, Dong Gyun;Seol, Kuk Hwan;Lee, Mooha;Jo, Cheorun
    • Food Science of Animal Resources
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    • v.36 no.1
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    • pp.23-28
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    • 2016
  • This study investigates the effect of cooking, storage, and reheating conditions on the formation of cholesterol oxidation products (COPs) in pork loin. Samples of pork loin procured 24 h postmortem were initially processed and assessed for total fat and cholesterol content. The cooking methods evaluated were pan roasting, steaming, oven grilling, and microwaving. Cooked pork loin samples were stored at 4℃ and reheated after 3 and 6 d of storage using the original method of preparation or alternately, microwaving. Fat content increased significantly with cooking as a result of the loss in moisture but cholesterol content remained unchanged. Pan roasting and microwave cooking caused a significantly higher production of COPs, as with the process of reheating using microwave, pan roasting, and oven grilling methods. The major COPs found in pork loin were cholestanetriol, 20-hydroxycholesterol, and 25-hydroxycholesterol, whose concentrations varied according to the different cooking and reheating methods used. Moreover, the aerobic storage of cooked pork loin under a refrigerated condition also increased the formation of cholesterol oxides on reheating.

Variations of NO Concentration Released from Fertilized Japanese Upland Soil Under Different Soil Moisture Conditions

  • Kim, Deug-Soo;Haruo Tsuruta;Kazuyuki Inubushi
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.E
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    • pp.9-17
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    • 1998
  • Oxides of nitrogen play important roles in atmospheric chemistry. Soil has been recognized as a major natural source of NO, and its emission depends on soil parameters such as soil nitrogen availability, soil moisture and temperature. It is necessary to understand effects of these controlling parameters on soil NO emission. In order to understand soil moisture effects on NO emission, variations of NO concentration and existence of its equilibrium concentration were observed from ammonium fertilized Japanese upland soil prepared for different soil moisture conditions. The closed chamber technique was employed for this study. The significant increases in NO with soil moisture were found. Maximum was occurred at sample ID4 (55% of water-filled pore space (WFPS)), but it decreased as soil moisture increased. No significant NO concentration was emitted from soil sample without fertilizer, but there was significant NO in fertilized soil samples. The magnitudes of NO from soil increased with time and reached at steady state within ten minutes approximately. These results suggest that nitrogen input from fertilizer takes charge in the first step of sharp increase in NO emission, and then soil moisture becomes important factor to control NO emission from the soils. NO concentrations from soil were compared to those one-day after the experiment. Results from the comparison analysis suggest that the soil NO flux might have been stimulated by soil disturbances like mixing, and this is much more effective in dry soils rather than in wet soils. It was found that much less NO came out from soils after a day; suggesting that most of NO was released from the soils within a day after fertilizer application during our experiment. The length of NO releasing time span may depend on the amounts of fertilizer applied, soil moisture condition, and other soil physical parameters.

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Melting of PCB scrap for the Extraction of Metallic Components (PCB스크랩으로부터 유가금속성분 회수를 위한 용융처리)

  • Kwon Eui-Hyuk;Jang Sung-Hwan;Han Jeong-Whan;Kim Byung-Su;Jeong Jin-Ki;Lee Jae-Chun
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.31-36
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    • 2005
  • It is well known that PCB (Printed Circuit Board) is a complex mixture of various metals mixed with various types of plastics and ceramics. In this study, high temperature pyre-metallurgical process was investigated to extract valuable metallic components from the PCB scrap. For this purpose, PCB scrap was shredded and oxidized to remove plastic materials, and then, quantitative analyses were made. After the oxidation of the PCB scrap, $30.6wt\%SiO_2,\;19.3wt\%Al_2O_3\;and\;14wt{\%}CaO$ were analyzed as major oxides, and thereafter, a typical composition of $32wt\%SiO_2-20wt\%Al_2O_3-38wt{\%}CaO-10wt\%MgO$ was chosen as a basic slag system for the separation of metallic components. Moreover a size effect of crushed PCB scrap was also investigated. During experiments a high frequency induction furnace was used to melt and separate metallic components. As a result, it was found that the size of oxidized PCB scrap was needed to be less 0.9 m to make a homogeneous liquid slag and to recycle metallic components over $95\%$.

Estimation of Ammonia Emission with Compost Application in Plastic House for Leafy Perilla Cultivation (시설잎들깨 재배의 퇴비 시용에 의한 암모니아 배출량)

  • Hong, Sung-Chang;Kim, Jin-Ho;Kim, Min-Wook
    • Korean Journal of Environmental Agriculture
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    • v.40 no.3
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    • pp.149-160
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    • 2021
  • BACKGROUND: Concerns have been raised about the impact of recent high concentrations of fine dust on human health. Ammonia(NH3) reacts with sulfur oxides and nitrogen compounds in the atmosphere to form ultrafine ammonium sulfate and ammonium nitrate (PM2.5). There is a growing need for accurate estimates of the amount of ammonia emitted during agricultural production. Therefore, in this study, ammonia emissions generated from the cultivation of leafy perilla in plastic houses were determined. METHODS AND RESULTS: Cow manure compost, swine manure compost, and poultry manure compost each at 34.6 ton ha-1, the amount commonly used by farmers in the field, was sprayed on the soil surface. Just after spraying cow manure compost, swine manure compost, and poultry manure compost, the ammonia was periodically measured and analyzed to be 22.5 kg ha-1, 22.8 kg ha-1, and 85.2 kg ha-1, respectively. The emission factors were estimated at 70.0 kg-NH3 ton-N, 62.8 kg-NH3 ton-N, and 234.1 kg-NH3 ton-N, respectively. Most ammonia was released in the two weeks after application of the compost and then the amount released gradually decreased. CONCLUSION: Therefore, it is necessary to improve the emission factor through a study on the estimation of ammonia emission by type of livestock manure and major farming types such as rice fields and uplands, and to update data on the production, distribution, and sales of livestock manure.

Life Cycle Assessment of Rural Community Buildings Using OpenLCATM DB (OpenLCATM DB를 이용한 농촌 공동체 건축물 전과정평가)

  • Kim, Yongmin;Lee, Byungjoon;Yoon, Seongsoo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.3
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    • pp.97-105
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    • 2021
  • Most of the rural development projects for the welfare of residents are mainly new construction and remodeling projects for community buildings such as village halls and senior citizens. However, in the case of the construction industry, it has been studied that 23% of the total carbon dioxide emissions generated in Korea are generated in the building-related sector. (GGIC, 2015) In order to reduce the emission of environmental pollutants resulting from construction of rural community buildings, there is a need to establish a system for rural buildings by predicting the environmental impact. As a result of this study, the emissions of air pollutants from buildings in rural communities were analyzed by dividing into seven stages: material production, construction, operation, maintenance, demolition, recycling, and transportation activities related to disposal. As a result, 12 kg of carbon dioxide (CO), 0.06 kg of carbon monoxide (CO), 0.02 kg of methane (CH), 0.04 kg of nitrogen oxides (NO), 0.02 kg of sulfurous acid gas (SO), and non-methane volatile organics per 1m of buildings in rural communities It was analyzed that 0.02 kg of compound (NMVOC) and 0.00011 kg of nitrous oxide (NO) were released. This study proved that environmentally friendly design is possible with a quantitative methodology for the comparison of operating energy and air pollutant emissions through the design specification change based on the statement of the rural community building. It is considered that it can function as basic data for further research by collecting major structural changes and materials of rural community buildings.

Experimental Verification of the Decomposition of Y2O3 in Fe-Based ODS Alloys During Mechanical Alloying Process

  • Byun, Jong Min;Park, Chun Woong;Kim, Young Do
    • Metals and materials international
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    • v.24 no.6
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    • pp.1309-1314
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    • 2018
  • In this study, we investigated the state of $Y_2O_3$, as a major additive element in Fe-based ODS alloys, during mechanical alloying (MA) processes by thermodynamic approaches and experimental verification. For this purpose, we introduced $Ti_2O_3$ that formed different reaction products depending on the state of $Y_2O_3$ into the Fe-based ODS alloys. In addition, the reaction products of $Ti_2O_3$, Y, and $Y_2O_3$ powders were predicted approximately based on their formation enthalpy. The experimental results relating to the formation of Y-based complex oxides revealed that $YTiO_3$ and $Y_2Ti_2O_7$ were formed when $Ti_2O_3$ reacted with Y; in contrast, only $Y_2Ti_2O_7$ was detected during the reaction between $Ti_2O_3$ and $Y_2O_3$. In the alloy of $Fe-Cr-Y_2O_3$ with $Ti_2O_3$, $YTiO_3$ (formed by the reaction of $Ti_2O_3$ with Y) was detected after the MA and heat treatment processes were complete, even though $Y_2O_3$ was present in the system. Using these results, it was proved that $Y_2O_3$ decomposed into monoatomic Y and O during the MA process.