• Title/Summary/Keyword: major elements

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The study on Comparison Evaluation of Shear Bond Strength of Co-Cr Based Alloy using for Porcelain Fused Metal (도재용착주조관용 Co-Cr계 비귀금속 합금의 전단결합강도 비교평가에 관한 연구)

  • Kim, Hee-Jin;Kim, Bu-Sob
    • Journal of Technologic Dentistry
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    • v.32 no.3
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    • pp.195-207
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    • 2010
  • Purpose: The purpose of this study was to observe the microstructural changes of surface in the specimens, performing the shear bond strength testing. The currently most used non-precious alloys are nickel-chromium based alloys with or without beryllium. However, their biocompatibility has been questioned concerning possible damages to the health of the patient and professionals involved in the fabrication of prosthesis caused by long exposure to Ni and Be. An option to nickel-chromium alloys is the cobalt-chromium alloy, an alternative that does not sacrifice the physical properties of the metal porcelain systems. Studies in the animals substantially show that the cobalt-chromium alloys are relatively well tolerated, being therefore more biocompatible than the nickel-chromium alloys. Methods: Non-addition Be to nickel-chromium based alloy(Bellabond plus) and cobalt-chromium alloy which has been widely used(Wirobond C) fused with ZEO light porcelain classified control group and cobalt-chromium alloy which is developing alloy of Alphadent company in Korea(Alphadent alloy) fused with ZEO light porcelain classified experimental group. The specimens of $4mm{\times}4mm{\times}0.5mm$ were prepared as-cast and as-opaque to cast body to analyze the mechanical characteristic change, the microstructure of alloy surface. The phase change was used to observe through XRD analysis and OM/SEM was used to observe the surface of specimens as-cast and as-opaque to cast body. Chemical formation of their elements was measured with EDS. Then hardness was measured with Micro Vicker's hardness tester. Shear bond strength test thirty specimens of $10mm{\times}10mm{\times}2mm$ was prepared, veneered, 3mm high and 3mm in diameter, over the alloy specimens. The shear bond strength test was performed in a universal testing machine(UTM) with a cross head speed of 0.5mm/min. Ultimate shear bond strength data were analyzed with one-way ANOVA and the Scheffe's test (P<0.05). Within the limits of this study, the following conclusions were drawn: The X-ray diffraction analysis results for the as-cast and as-opaque specimens showed that the major relative intensity of Bellabond plus alloy were changed smaller than Wirobond C and Alphadent Co-Cr based alloys. Results: Microstructural analysis results for the opaque specimens showed all the alloys increased carbides and precipitation(PPT). Alphadent Co-Cr based alloy showed the carbides of lamellar type. The Vickers hardness results for the opaque specimens showed Wirobond C and Alphadent Co-Cr based alloys were increaser than before ascast, but Bellabond plus alloy relatively decreased. The mean shear bond strengths (MPa) were: 33.11 for Wirobond C/ZEO light; 25.00 for Alphadent Co-Cr alloy/ZEO light; 18.02 for Bellabond plus/ZEO light. Conclusion: The mean shear bond strengths for Co-Cr and Ni-Cr based alloy were significantly different. But the all groups showed metal-metal oxide modes in shear bond strengths test at the interface.

A Design Of Cross-Shpaed CMOS Hall Plate And Offset, 1/f Noise Cancelation Technique Based Hall Sensor Signal Process System (십자형 CMOS 홀 플레이트 및 오프셋, 1/f 잡음 제거 기술 기반 자기센서 신호처리시스템 설계)

  • Hur, Yong-Ki;Jung, Won-Jae;Lee, Ji-Hun;Nam, Kyu-Hyun;Yoo, Dong-Gyun;Yoon, Sang-Gu;Min, Chang-Gi;Park, Jun-Seok
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.5
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    • pp.152-159
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    • 2016
  • This paper describes an offset and 1/f noise cancellation technique based hall sensor signal processor. The hall sensor outputs a hall voltage from the input magnetic field, which direction is orthogonal to hall plate. The two major elements to complete the hall sensor operation are: the one is a hall sensor to generate hall voltage from input magentic field, and the other one is a hall signal process system to cancel the offset and 1/f noise of hall signal. The proposed hall sensor splits the hall signal and unwanted signals(i.e. offset and 1/f noise) using a spinning current biasing technique and chopper stabilizer. The hall signal converted to 100 kHz and unwanted signals stay around DC frequency pass through chopper stabilizer. The unwanted signals are bloked by highpass filter which, 60 kHz cut off freqyency. Therefore only pure hall signal is enter the ADC(analog to dogital converter) for digitalize. The hall signal and unwanted signal at the output of an amplifer and highpass filter, which increase the power level of hall signal and cancel the unwanted signals are -53.9 dBm @ 100 kHz and -101.3 dBm @ 10 kHz. The ADC output of hall sensor signal process system has -5.0 dBm hall signal at 100 kHz frequency and -55.0 dBm unwanted signals at 10 kHz frequency.

A Study on the Content Variation of Metals in Welding Fumes (용접흄 충 금속함량 변화에 관한 연구)

  • 윤충식;박동욱;박두용
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.117-129
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    • 2002
  • Concentration of welding fumes and their components is known to be hazardous to welder and adjacent worker. To determine the generation rates of metals in fumes, $CO_2$ flux cored arc welding on stainless steel was performed in well designed fume collection chamber. Variables were different products of flux cored wire(2 domestic products and 4 foreign products) and input energy(low-, optimal- , high input energy). Mass of welding fumes was determined by gravimetric method(NIOSH 0500 method), and 17 metals were analysed by inductively coupled plasm-atomic emission spectroscopy(NIOSH 7300 method). Flux cored wire tube and flux were analysed by scanning electron microscopy to determine their metal composition. 17 metals were classified by their generation rates. Generation rates of iron, manganese, potassium and sodium were all above 50mg/min at optimal input energy level. Generation rates of chromium and amorphous silica were 25~50mg/min. At 1~25mg/min level, nickel, titanium, molybdenum, and aluminum were included. Copper, zinc, calcium, lead, magnesium, lithium, and cobalt were generated below 1 mg/min. Generation rates of metal components in fumes were influenced by input energy, types of flux cored wire. Flux cored wire was consisted of outer shell tube and inner flux. Iron, chromium, and nickel were the major components of outer tube. Flux contained iron, chromium, nickel, potassium, sodium, silica, and manganese. The use of flux cored wire can increase the hazards by increasing the amounts of fumes formed relative to that of solid wire. The reason might be the direct transfer of elements from the flux, since the flux is fine power. Ratio of metals to the fume of flux cored wire was lower than that of solid wire because non-metal components of flux were transferred. Total metal content of fumes in flux cored arc welding was 47.4(24.3~57.2) percent that is much lower than that of solid wire, 75.9 percent. We found that generation rates of iron, manganese, chromium and nickel, all well known to cause work related disease to welder, increased more rapidly with increasing input energy than those of fumes. To reduce worker exposure to fumes and hazardous component at source, further research is needed to develop new welding filler materials that decrease both the amount of fumes and hazardous components.

The Metallic Composition of PM2.5 and PM10 in a Northeast Region of Seoul During the Spring 2001 (2001년 봄철 서울시 북동부지점에서 관측한 중금속성분의 농도분포)

  • Choi, Gyoo-Hoon;Kang, Chang-Hee;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.23 no.6
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    • pp.514-525
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    • 2002
  • The analysis of heavy metals associated with both PM2.5 and PM10 fraction of aerosols was made from a northeast region of Seoul during the spring period of 2001. The mean concentrations of fine (PM2.5), coarse (PM10-PM2.5), and PM10 fraction were observed as 49.3${\pm}$29.2, 50.5${\pm}$35.0, and 95.5${\pm}$46.1 ${\mu}g$/m$^3$, respectively during this study period. According to the results of enrichment factor (EF) analysis between different particle fractions, major elements (including Fe, Ca, Na, and K) were found to exhibit EF values of less than 10. However, heavy metal components (like Zn and Pb) showed very high EF values. Comparison of fine/coarse (F/C) concentration ratio showed that Zn, Cr, Pb, and Ni have higher ratio values than others. The metallic composition of particles was also compared on both absolute and relative terms. The results of our analysis showed an evidence that the increase in the total metallic contents is prominent during the spring period due mostly to the Asian Dust event.

Petrochemistry and Sr ${\cdot}$ Nd Isotopic Composition of foliated Granite in the Jeoniu Area, Korea (전주지역 엽리상화강암의 암석화학 및 Sr ${\cdot}$ Nd 동위원소 조성)

  • Shin, In-Hyun;Park, Cheon-Young;Jeong, Youn-Joong
    • Journal of the Korean earth science society
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    • v.22 no.1
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    • pp.1-9
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    • 2001
  • Composition of the major and trace elements, Rb-Sr isochron age Sr-Nd isotope composition were determined for foliated in the Jeonju area, in the middle part of the Ogcheon Fold Bet, Korea. The geochemical characteristics of the Jeonju foliated granite indicate that the granite had been crystallized from a calc-alkaline series, and formed in a volcanic are environment. The isotopic compositions of the Jeonju foliated granite give Rb-Sr whole rock errorchron age of 168.2${\pm}$8 Ma(2${\sigma}$), corresponding to the middle Jurassic period, with the Sr initial ratio of 0.71354${\pm}$0.00031. $^{143}$Nd/$^{144}$Nd ratios, ${\varepsilon}$Nd and ${\varepsilon}$Sr values range from 0.511477 to 0.511744, -15.4${\sim}$-21.2, and +108.8${\sim}$+l42.6, respectively. Model ages were caculated to be 1.82${\sim}$2.89Ga. The isotopic data of Jeonju foliated granite indicate that the source material may have been derived from partial melting of continental crust materials.

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Analysis of Nutritional Compositions and Antioxidative Activities of Korean Commercial Blueberry and Raspberry (국내 시판 블루베리와 라즈베리의 영양성분 분석 및 항산화 활성)

  • Jeong, Chang-Ho;Choi, Sung-Gil;Heo, Ho-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1375-1381
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    • 2008
  • The nutritional compositions and antioxidative activities of Korean commercial blueberry and raspberry were investigated. The proximate compositions were 10.47% and 22.67% in moisture, 2.66% and 2.64% in crude protein, 2.04% and 1.67% in crude fat, 81.36% and 70.19% in nitrogen free extracts, 1.48% and 0.85% in crude fiber, and 1.99% and 1.98% in ash of blueberry and raspberry, respectively. Total phenolics content were higher in blueberry (9.028 mg/g) than in raspberry (5.340 mg/g). Major elements of blueberry and raspberry were Ca (451.34 and 97.48 mg/100 g), K (355.40 and 215.20 mg/100 g), P (321.10 and 294.04 mg/100 g), and Na (137.58 and 137.67 mg/100 g). The total amino acid contents of blueberry and raspberry were 2,011.44 mg /100 g and 2,098.82 mg/100 g, respectively. Amino acid were mainly composed of glutamic acid, aspartic acid and leucine. The DPPH and ABTS radical scavenging activities of the 80% methanol extract from blueberry and raspberry were 88.67% and 62.77%, 76.34% and 30.53% at a concentration of 5 mg/mL. The 80% methanol extract from blueberry and raspberry showed considerable antioxidative activity against reducing power in dose-dependent manner. Antioxidative activities using $\beta$-carotene-linoleate and FTC method were twice higher in blueberry than raspberry.

A Study on the European Symbolist Costume -Focusing on Gustav klimt's Art World- (유럽 상징주의 복식에 관한 연구 -구스타브 클림트(Gustav Klimt)의 회화 세계를 중심으로-)

  • 양숙희
    • Journal of the Korean Society of Costume
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    • v.22
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    • pp.277-296
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    • 1994
  • The progressive artists in Austria including Gustav Klimt organized the Viennes Se-cessionist in 1897 and they took an active part in the reformation of the reformation of the applied art by accepting the Jugendstil standing for the true art. The vocabularies which characterize this group are decoration literature and the power of symbol. Klimt especially expressed these characteristics and his strong person-ality. For he created his works with the sym-bolic and friendly splendor through his highly decorative talents by accepting the enwly changed artistic situation in those days and by getting out of the naturalistic trends he was regarded as an avant-garde artist as a major figure among the Symbolist artists who revived European culture which was destroyed through the World War I. The characteristics of klimt's works was to express the various human thoughts and minds through the decorativeness and the femininity and to use the decorative elements of old Greek and Egyptian culture and Japanese art as the motives of his works, His art is to be found between the naturalistic characteristics and formalization as well as between the in-dustrial arts and the fine arts. In his many portraits he preferred women by trying to express eroticism hidden behind the human inner world. For this he demonstrated the attractiveness and the characteristics of the models by designing the illusionary and unique clothes. In general his genius was to be seen through the costume which was decorated with metals and jewels and through the characteristics of the modern costume in which the previous solid silhouette was removed and the gentle and elegant me-dium color was used. by accepting the new artistic trends in the turn of the century by fully expressing those characteristics in his creative world and by taking his theme from the eroticism through the decorativeness and the expression of women Gustav Klimt's uniquely decorative ex-pression completely realized the aesthetics of Jugendstil symbol decoration and expression which displayed not only the external appear-ance but also the inner world. Especially he created a new appearance emphasizing the costume of the characters in his works. Also through the costume he expressed his artistic consciousness and psy-chology. He showed the characteristics of the reformed costume through the medium color the simple forms and gentle silhouette. Also he tried to symbolize the passionate inner pow-er by designing the small mosaics such as the geometrical patterns whirlpool patterns and the indecent meanings all over the costume. Klmt's this kinds of attemps shows a Stil Kostume as the external outcome of the inner spiritual activities like art and it establishes a basis for the theory of costume are which deals with the concepts of costume from the artistics points of view. This tradition playing an important role in the contemporary history of costume even has been still inherited up to today.

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Characteristics of Mineralogy and Nanocrystals of Ingredient Materials of $Lumilite^{(R)}$ for Water Treatment (수질개선제 $Lumilite^{(R)}$ 원료광물의 광물학적 및 나노결정학적의 특징)

  • Lee, Jin-Kook;Park, Hi-Ho;Choo, Chang-Oh
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.27-35
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    • 2008
  • Characterization of mineralogy and nanocrystals of ingredient materials of $Lumilite^{(R)}$ used for water treatment was made using optical microscopy, XRD, SEM, FTIR, and XRF analyses. Constituent minerals identified by XRD and microscope are clinoptilolite, illite, quartz, and albite, characterized by dense and fine texture. The cross section of nanocrystals with the size $70{$\sim}100\;nm$ is generally round or subround. Numerous spheroids with few nanometers in diameter are extensively formed on the surface of nanocrystals. Bulk chemistry is $SiO_2$ $74.22{\sim}75.65\;wt.%$, $Al_2O_3$ $13.25{\sim}13.72\;wt.%$, CaO $4.23{\sim}5.15\;wt.%$, with other major elements being minimal. When heated to $700^{\circ}C$, the crystal structure was mostly destroyed, though it persisted to $500^{\circ}C$. It is likely that high capacity and applications of $Lumilite^{(R)}$ for water treatment are originated from its structural properties such as development of nanocrystals and various tiny pores.

Mineralogical Characteristic Changes of Noerok Occurred from Noeseong Mountain, a Raw Material for Pigment, Depending on its Firing Process (안료 원료인 뇌성산 산출 뇌록의 소성에 따른 광물학적 특성 변화)

  • Lee, Jang Jon;Kim, Jae Hwan;Han, Min Su
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.1
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    • pp.23-32
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    • 2018
  • Noerok ia a green pigment used in Joseon dynasty, and its main usage was for forming foundation layers of Dancheong, the ornamental paintings on the surface of traditional buildings in Korea, such as the Daeung-jeon(main hall) of Bulguk-sa temple. In this research, we investigated the mineralogical characteristic changes of Noerok, a traditional Korean pigment, depending on its firing temperature. The Noerok that we experimented on was mined from Noeseong Mountain, Pohang where it is locally reserved. The major composition mineral is Celadonite, and the main constituent elements are Fe, Si, K and Mg, that refers to the existence of Fe-rich mica. As a result of phased firing experiment from $105^{\circ}C$ to $1000^{\circ}C$, the color was changed from green to pale green, then to brown, and finally to red in order. In the thermal analysis, endothermic reaction induced by the dehydration of crystalline water was confirmed at around $616^{\circ}C$. In the mineralogical change, the crystal surface [($11{\bar{1}}$) and ($02{\bar{1}}$)] of the mineral collapsed at temperatures above $600^{\circ}C$, and iron oxide was formed at $1000^{\circ}C$ or higher. Therefore, it is estimated that the crystallization temperature of Noerok is below $600^{\circ}C$, and it is also considered that it has undergone the alteration phase up to stage I, based on the presence of only a celadonite.

Development of Integrated Model of Boiler and Its Supporting Steel Structure of Coal-Fired Power Plant for Finite Element Analysis (유한요소해석을 위한 석탄화력발전소의 보일러와 지지 철골의 통합모델 개발)

  • Lee, Boo-Youn
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.9-19
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    • 2020
  • An integrated finite element model composed of a boiler and its supporting steel structure for a 375-MW coal-fired power plant was developed. This study used the developed model for seismic analysis using SAP2000 software. For the complex superheaters, reheaters, economizers, and membrane walls of the boiler, which consisted of numerous tubes, a method of modeling them by the equivalent elements in the viewpoint of stiffness and/or inertia was proposed. In addition, a method of modeling for the connection between the boiler and steel structure was proposed. Many hangers that connect the boiler to the girders of a steel structure were transformed into equivalent hangers by decreasing the number. The displacements of the boiler stoppers on the buckstay and the posts of the steel structure were coupled by considering their interface condition. Static analysis under the self-loading condition for the developed integrated model was implemented, and the results of deformation indicated that the behavior of the steel members and the major components of the boiler were appropriate. In conclusion, the integrated model developed in this study can be used to evaluate the safety of the boiler and steel structure under seismic loads.