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Thermotropic Liquid Crystalline Properties of α,ω-Bis(4-cyanoazobenzene-4'-oxy)alkanes (α,ω-비스(4-사이아노아조벤젠-4'-옥시)알케인들의 열방성 액정 특성)

  • Jeong, Seung Yong;Kim, Hyo Gap;Ma, Yung Dae
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.358-366
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    • 2011
  • A homologous series of linear liquid crystal dimers, the ${\alpha},{\omega}$-bis(4-cyano-azobenzene-4'-oxy)alkanes (CATWETn, where n, the number of methylene units in the spacer, is 2~10) were synthesized, and their thermotropic liquid crystalline phase behavior were investigated. The CATWETn with n of 3 and 6 exhibited monotropic nematic phases, whereas other derivatives showed enantiotropic nematic phases. The nematic-isotropic transition temperatures of the dimers and their entropy variation at the phase transition showed a large odd-even effect as a function of n. This phase transition behavior was rationalized in terms of the change in the average shape of the spacer on varying the parity of the spacer. The thermal stability and degree of order in the nematic phase and the magnitude of the odd-even effect of CATWETn were similar to those for the methoxy-, nitro-, and pentyl-substituted dimers, while they were significantly different from those for the monomesogenic compounds, 1-{4-(4'-cyanophenylazo)phenoxy}alkylbromides and the side-chain liquid-crystalline polymers, the poly[1-{4-(4'-cyanophenylazo)phenoxyalkyloxy}ethylene]s. The results were discussed in terms of 'virtual trimer model' by Imrie.

Study on Health Predictors of Early Retirement of Middle-aged and Elderly Workers in Korea: Proportional Hazard Model Analysis by Employment Type (중·고령자의 건강 악화가 조기은퇴에 미치는 영향 연구-근로형태 별 비례위험모형 분석)

  • Chung, Jongwoo
    • 한국노년학
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    • v.37 no.4
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    • pp.871-891
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    • 2017
  • The purpose of this paper is to reduce the reverse-causality and overestimate bias of analysis on how health affected middle-aged and elderly worker's early retirement. From the Korean Longitudinal Study of Ageing(KLoSA) panel data, I researched 1,049 people who were 45-52 years old in 2006. To eliminate the reverse-causality problem, I used the health data which is surveyed before retirement. To reduce bias, I controlled the health status when retirees worked. The main results are as follows. First, the worsened health still affects the hazard of early retirement, with reducing the endogeneity problem. Second, chronic illness is one of the strong predictors of early retirement to self-employed, and self-reported bad health is the main health predictor of wage workers. These results give two implications; first, the impact magnitude of the health indicator depends on employment type. Each employment type has different flexibility of working hours. It seems that the flexibility can reduce early retirement hazard with health problems. Self-employed, who has more flexibility of working hours can work until they have to stop working due to the serious health problem or doctor's advice. Second, to promote middle-aged and elderly workers to keep working, the long-term health policy which decreases chronic illness is needed.

Video Watermarking Scheme with Adaptive Embedding in 3D-DCT domain (3D-DCT 계수를 적응적으로 이용한 비디오 워터마킹)

  • Park Hyun;Han Ji-Seok;Moon Young-Shik
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.15 no.3
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    • pp.3-12
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    • 2005
  • This paper introduces a 3D perceptual model based on JND(Just Noticeable Difference) and proposes a video watermarking scheme which is perceptual approach of adaptive embedding in 3D-DCT domain. Videos are composed of consecutive frames with many similar adjacent frames. If a watermark is embedded in the period of similar frames with little motion, it can be easily noticed by human eyes. Therefore, for the transparency the watermark should be embedded into some places where motions exist and for the robustness its magnitude needs to be adjusted properly. For the transparency and the robustness, watermark based on 3D perceptual model is utilized. That is. the sensitivities from the 3D-DCT quantization are derived based on 3D perceptual model, and the sensitivities of the regions having more local motion than global motion are adjusted. Then the watermark is embedded into visually significant coefficients in proportion to the strength of motion in 3D-DCT domain. Experimental results show that the proposed scheme improves the robustness to MPEG compression and temporal attacks by about $3{\sim}9\%$, compared to the existing 3D-DCT based method. In terms of PSNR, the proposed method is similar to the existing method, but JND guarantees the transparency of watermark.

Analysis of Operation Characteristics of DC Circuit Breaker with Superconducting Current Limiting Element (초전도 전류제한소자를 적용한 DC 차단기의 동작 특성 분석)

  • Jung, Byung-Ik
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.6
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    • pp.1069-1074
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    • 2020
  • Since DC has no zero point, an arc occurs when the DC circuit breaker performs a shutdown operation. In this case, a fatal accident may occur in the circuit breaker or in the grid, depending on the magnitude of the arc. Therefore, the shutdown performance and the reliability of the circuit breaker are important in the commercialization of HVDC. In this study, a superconducting LC circuit breaker was proposed to improve the performance and the reliability of the DC circuit breaker. The superconducting LC circuit breaker applied a superconducting coil to the inductor of the existing LC circuit breaker. Other than limiting the initial fault current, it also creates a stable zero point in the event of a fault current. To verify this, simulation was performed through EMTDC/PSCAD. Furthermore, the superconducting LC circuit breaker was compared with the LC circuit breaker with a normal coil. As a result, it was found that the LC circuit breaker with the superconducting coil limited the initial fault current further by approximately 12 kA compared to the LC circuit breaker with a normal coil. This reduced the arc extinguish time by approximately 0.16 sec, thereby decreasing the elctrical power burden on the circuit breaker.

The 33-mode Dielectric and Piezoelectric Properties of PIN-PMN-PT Single Crystal under Stress and Electric Field (압축하중 및 전계 인가에 따른 PIN-PMN-PT 단결정의 33-모드 유전 및 압전특성)

  • Lim, Jae Gwang;Park, Jae Hwan;Lee, Jeongho;Lee, Sang Goo
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.91-96
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    • 2020
  • The 33-mode dielectric and piezoelectric properties of Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 piezoelectric single crystals were measured under large electric field and compressive stress. The phase transition from the low temperature rhombohedral to the high temperature tetragonal structure was observed in the range of 110~140℃, and the Curie temperature changing to the cubic structure was about 165℃. The polarization change according to the compressive stress and electric field was measured. Relative dielectric constant was calculated from the slope of the polarization curve applied to the electric field, and the calculated relative dielectric constant increased as the applied stress increased, and the relative dielectric constant decreased as the applied electric field increased. The strain according to the compressive stress and electric field change was measured, the piezoelectric constant was calculated from the slope of the curve, and the phase transition according to the application of pressure was confirmed. In the case of practical application as an underwater or medical ultrasonic actuator, it is necessary to properly design the magnitude of the compressive stress applied to the device and the DC bias in order to maintain linear driving.

A Study on Improving the Efficiency of Facility Safety Inspection Work Using Images (영상을 활용한 시설물 안전점검 작업 효율성 향상 방안 연구)

  • Jeon, Kyungsik;Kim, Jintae;Lee, Byoungkil
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.39 no.3
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    • pp.179-186
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    • 2021
  • In general, the daily safety inspection activities, which investigate damages in structures and measures the size of the damage, have been relied heavily on the visual inspection so far. Since the probe of the condition and performance of facilities by such personnel is often dependent on the subjective judgment of the investigator, the consistency and repeatability of the probing results may reduce. Particularly, damage located in a difficult-to-reach place depends mainly on experience with the naked eye, and an unsafe method using a ladder has mainly applied when necessary. Therefore, in this study, we tried to propose a way of using images that can reduce the deviation between safety inspection investigators, enhance objectivity, and improve the safety of workers. In this study, we have applied homographic transformation as a method of correcting the image. As a result of analyzing the size of the damage in the corrected image of the test subject, it confirms that the accuracy of measuring the magnitude of the damage can satisfy the target levels of 5.0mm and 0.005m2, the target accuracy levels. As a result of the field verification test to which the proposed image correction technique applied, the coefficient of variation of the crack length in the structure decreased from 5.4~7.0% to 0.072~0.12%, and that of the damaged area from 10.9% to 1.6%. It confirms that the measurement accuracy is improved. Therefore, it is expected that this study on the image utilization technique in safety inspection activities can increase the accuracy of damage measurement and improve the reliability of the safety inspection reports and exterior survey drawings.

Analysis of Behavior Characteristics According to The Foundations Fixing Conditions of Storage Racks (적재설비 기초 고정조건에 따른 거동특성 분석)

  • Park, Chae-Rin;Heo, Gwang-Hee;Kim, Chung-Gil;Park, Jin-Yong;Ko, Byeong-Chan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.3
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    • pp.68-76
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    • 2021
  • Storage racks have suffered huge losses due to earthquakes, but related research and regulations are relatively insufficient non-structural elements compared to the structural elements. In this study, we tried to experimentally analyze the behavioral characteristics of storage racks due to external force according to the fixing conditions of the column-foundations connection of storage racks. In general, the column-foundations connection of storage racks is installed according to the user's convenience without installation standards and regulations. For this reason, this study conducted a behavior analysis test on four full-scale storage racks with the condition of column-foundations connection of four typical storage racks. The behavior characteristics analysis test was performed by two-direction of the shake table with El-Centro seismic wave. To confirm the behavior characteristics according to the magnitude of the seismic load, 50% ~ 150% of the seismic waves were increased by 50% for each test. In addition, a resonance search test was conducted to confirm the natural frequency of each storage racks foundations fixing condition. Among the data obtained through the test, the displacement of the top layer and the permanent displacement after the test were compared for each condition to analyze the behavior characteristics of the column-foundations fixed conditions of the storage racks. As a result, the change of natural frequency was small in storage racks due to the change of the conditions of the foundations, and the behavior characteristics were changed due to the difference of the restoring force due to the change of the storage racks foundations condition rather than the influence of the natural frequency of the input load.

Development of a Self Balancing Electric Wheelbarrow (자기 균형 기능이 있는 외발 전동 손수레 개발)

  • Lee, Myung-Sub;Sung, Young-Whee
    • Journal of the Institute of Convergence Signal Processing
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    • v.21 no.1
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    • pp.21-28
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    • 2020
  • In this paper, a new type of electric wheelbarrow is proposed and developed. The developed electric wheelbarrow is equipped with an attitude reference system(ARS) sensor, which consists of 3-axis acceleration sensor and 2-axis Gyro sensor so that it can estimate pitch angle and roll angle. When an operator tilts the wheelbarrow up and down, the pitch angle is detected. The sign of the pitch angle is interpreted as the operator's intention for moving the wheelbarrow forward or backward and the controller drives the wheel of the wheelbarrow with the velocity according to the magnitude of the detected pitch angle. A cargo box of the wheelbarrow is designed to rotate and is controlled to maintain level always, so an operator can handle the electric wheelbarrow easily and safely. The wheelbarrow consists of an in-wheel motor, a DC motor, motor drives, an ARS sensor considering economical use in industrial field. Three experiments are performed to verify the feasibility and stability of the electric wheelbarrow.

Conservation for the Seismic Models of Intake Tower with Nonlinear Behaviors and Fluid Structure Interaction (비선형거동과 구조물유체상호작용을 고려한 취수탑 내진모델의 보수성평가)

  • Lee, Gye-Hee;Lee, Myoung-Kyu;Hong, Kwan-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.17-24
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    • 2020
  • In this study, series of nonlinear seismic analysis were performed on a reinforced concrete intake tower surrounded by water. To consider the fluid effect around the structure, analysis models were composed using an added mass and CEL approach. At this time, the implicit method was used for the added mass model, and the explicit method was used for the fluid structure interaction model. The input motions were scaled to correspond to 500, 1000, and 2400 years return period of the same artificial earthquake. To estimate the counteractivity of the fluid coupled model, models without fluid effect were constructed and used as a reference. The material models of concrete and reinforcement were selected to consider the nonlinear behavior after yielding, and analysis were performed by ABAQUS. As results, in the acceleration response spectrum of the structure, it was found that the influence of the surrounding fluid reducing the peak frequency and magnitude corresponding to the fundamental frequency of the structure. However, the added mass model did not affect the peak value corresponding to the higher mode. The sectional moments were increased significantly in the case of the added mass model than those of the reference model. Especially, this amplification occurred largely for a small-sized earthquake response in which linear behavior is dominant. In the fluid structure interaction model, the sectional moment with a low frequency component amplifies compared to that of the reference model, but the sectional moment with a high requency component was not amplified. Based in these results, it was evaluated that the counteractivity of the additive mass model was greater than that of the fluid structure interaction model.

A Study on Modeling of Leakage Current in ESS Using PSCAD/EMTDC (PSCAD/EMTDC를 이용한 ESS의 누설전류 모델링에 관한 연구)

  • Kim, Ji-Myung;Tae, Dong-Hyun;Lee, Il-Moo;Lim, Geon-Pyo;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.810-818
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    • 2021
  • A leakage current of ESS is classified mainly by the occurrence from a PCS(Power Conditioning System) section and an unbalanced grid current. The reason for the leakage current from the PCS section is a voltage change by IGBT (Insulated Gate Bipolar Transistor) switching and stray capacitance between the IGBT and heatsink. The leakage current caused by the grid unbalanced current flows to the ESS through the neutral line of grid-connected transformer for the ESS with a three limb iron type of Yg-wire connection. This paper proposes a mechanism for the occurrence of leakage current caused by stray capacitance, which is calculated using the heatsink formula, from the aspect of the PCS section and grid unbalance current. Based on the proposed mechanisms, this study presents the modeling of the leakage current occurrence using PSCAD/EMTDC S/W and evaluates the characteristics of leakage currents from the PCS section and grid unbalanced current. From the simulation result, the leakage current has a large influence on the battery side by confirming that the leakage current from the PCS is increased from 7[mA] to 34[mA], and the leakage current from an unbalanced load to battery housing is increased from 3.96[mA] to 10.76[mA] according to the resistance of the housings and the magnitude of the ground resistance.