• Title/Summary/Keyword: magneto-crystalline anisotropy

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Temperature Dependence of Magnetic Properties of YIG films Grown by Solid Phase Epitaxy (고상에피택시 YIG 박막의 온도에 따른 자기특성)

  • Jang, Pyug-Woo;Kim, Jong-Ryul
    • Journal of the Korean Magnetics Society
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    • v.15 no.1
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    • pp.25-29
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    • 2005
  • Magnetic properties of YIG films grown by solid phase epitaxy (SPE) was measured as a function of temperature with focus on magneto-crystalline and perpendicular magnetic anisotropy. Perpendicular magnetic anisotropy was not induced in the SPE YIG films annealed at low temperature by relaxing residual stress through formation of dislocation. On the contrary the films annealed at high temperature showed perpendicular magnetic anisotropy which shows very low density of dislocation. Perpendicular magnetic anisotropy field decreased linearly up to a high temperature of $230^{\circ}C$ above which magneto-crystalline anisotropy disappeared. Coercivity also decreased linearly with temperature up 세 $230^{\circ}C$. Magneto-crystalline anisotropy of perpendicular anisotropy induced epitaxial (111) YIG films can be measured using $H_k=4K_1/3M_s$. Temperature behavior of initial susceptibility can be successfully explained by Hopkinson effects. Curie temperature of YIG films grown on GGG substrate with high paramagnetic susceptibility can be easily measured using the results.

Novel Properties of Boron Added Amorphous Rare Earth-transition Metal Alloys for Giant Magnetostrictive and Magneto-optical Recording Materials

  • Jai-Young Kim
    • Journal of Magnetics
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    • v.3 no.3
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    • pp.78-81
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    • 1998
  • Large magneto crystalline anisotropy energy and demagnetization energy of rare earth-transition metal (RF-TM) alloys play roles of bottlenecks towards their commercial applications for giant magnetostrictive and blue wavelength magneto optical recording materials, respectively. To solve the above problems, boron is added into amorphous RE-TM alloys to produce its electron transferring. The boron added amorphous RE-TM alloys show novel magnetic and magneto-optical properties as follows; 1) an amorphous $(Sm_{33}Fe_{76})$97B3 alloy obtains the magnetostriction of$ -550{times}10^{-6}$ at 400 Oe compared with saturation magnetostriction of$ -60{\times}10^{-6}$ in conventional Ni based alloys, 2) an amorphous$ (Nd_{33}Fe_{67})_{95}B_5$ alloy increases effective magnetic anisotropy to$ -0.5{\times}10^{-6} ergs/cm^3 from -3.5{\times}10^6 ergs/cm^3$ without boron, which correspond to the polar Kerr rotation angles of 0.52$^{\circ}$and 0.33$^{\circ}$, respectively. These results attribute to selective 2p-3d electron orbits exchange coupling (SEC).

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Magnetic properties of micro-patterned array of anti-dots in Co/Ni bilayer

  • Deshpande, N.G.;Seo, M.S.;Zheng, H.Y.;Lee, S.J.;Rhee, J.Y.;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.276-276
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    • 2010
  • Large-area micropatterned array of Co/Ni bilayer anti-dots was fabricated using photolithography and wet etching process. The surface morphology as well as the surface topography was checked by scanning electron microscopy and atomic force microscopy, whereas the magnetic properties were studied by magneto-optical Kerr effect (MOKE) and magnetic force microscopy (MFM). Systematic studies of the magnetic-reversal mechanism, the in-plane anisotropy and the switching field properties were carried out. To get a comprehensive knowledge about the domain configuration, we also employed OOMMF simulations. It was found from the MOKE measurements that a combined effect of configurational and the magneto-crystalline anisotropy simultaneously works in such micropatterned bilayer structures. In addition, the inclusion of holes in the uniform magnetic film drastically affected the switching field. The MFM images show well-defined domain structures which are periodic in nature. The micromagnetic simulations indicate that the magnetization reversal of such a structure proceeds by formation and annihilation of domain walls, which were equally manifested by the field-dependent MFM images. The observed changes in the magnetic properties are strongly related to both the patterning that hinders the domain-wall motion and to the magneto-anisotropic bilayered structure.

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Magnetic Properties of FePt:C Nanocomposite Film

  • Ko, Hyun-Seok;A. Perumal;Shin, Sung-Chul
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.220-221
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    • 2003
  • Equiatomic FePt and CoPt alloy thin films have received considerable attention as possible magnetic and magneto-optic recording because of their high magnetic anisotropy energy and high coercivity. The high coercivity in these thin films is due to the presence of finely dispersed ordered FePt phase mixed with disordered FePt phase. However, a high temperature treatment, either substrate heating during deposition or post annealing, is needed to obtain the ordered L1$\_$0/ phase with high value of magneto crystalline anisotropy. Recent microstructural studies on these films suggest that the average grain size ranges from 10-50 nm and the grains are magnetically coupled between each other. On the other hand, the ultrahigh-density magnetic recording media with low media noise imposes the need of a material, which consists of magnetically isolated grains with size below 10 nm. The magnetic grain isolation can be controlled by the amount of additional non-magnetic element in the system which determines the interparticle separation and therefore the interparticle interactions. Recently, much research work has been done on various non-magnetic matrices. Preliminary studies showed that the samples prepared in B$_2$O$_3$ and Carbon matrices have shown strong perpendicular anisotropy and fine grain size down to 4nm, which suggest these nanocomposite films are very promising and may lead to the realization of a magnetic medium capable of recording densities beyond 1 Tb/in$^2$. So, in this work, the effect of Carbon doping on the magnetic properties of FePt nanoparticles were investigated.

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Effect of NiO spin switching on the Fe film magnetic anisotropy in epitaxially grown Fe/NiO/Ag(001) and Fe/NiO/MgO(001) systems

  • Kim, Won-Dong;Park, Ju-Sang;Hwang, Chan-Yong;Wu, J.;Qiu, Z.Q.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.366-366
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    • 2010
  • Single crystalline Fe/NiO bilayers were epitaxially grown on Ag(001) and on MgO(001), and investigated by Low Energy Electron Diffraction (LEED), Magneto-Optic Kerr Effect (MOKE), and X-ray Magnetic Linear Dichorism (XMLD). We find that while the Fe film has an in-plane magnetization in both Fe/NiO/Ag(001) and Fe/NiO/MgO(001) systems, the NiO spins switch from out-of-plane direction in Fe/NiO/MgO(001) to in-plane direction in Fe/NiO/Ag(001). These two different NiO spin orientations generate remarkable different effects that the NiO induced magnetic anisotropy in the Fe film is much greater in Fe/NiO/Ag(001) than in Fe/NiO/MgO(001). XMLD measurement shows that the much greater magnetic anisotropy in Fe/NiO/Ag(001) is due to a 90o-coupling between the in-plane NiO spins and the in-plane Fe spins which causes a switching of the NiO spins during the Fe magnetization reversal.

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Magnetic Properties and Cation Distribution of Phosphorous-Doped $Co-{\gamma}-{Fe_2} {O_3}$ Particles

  • Na, J.G.;Han, D.H.
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.51-54
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    • 1996
  • The effects of additional P-doping on the magnetic properties, thermal stability and cation distribution of Co-doped ${\gamma}-{Fe_2} {O_3}$have been investigated by means of magnetic annealing and measurements with vibration sample magnetometer and torque magnetometer. It is found that the P-doping promotes the coercivity and its magnetic-thermal stability, which may be attributed to increase of the cubic magneto-crystalline anisotropy constant, $K_1$ and the activation energy, E, for cation rearrangement, respectively. The cation distribution of P and Co-substituted iron oxide was calculated from the variation of the saturation magnetization with P-doping on the basis of the Neel model. It was found that the most of P ions in the iron oxides occupied the B-site of spinel lattice.

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Fabrication and Magnetic Properties of Ba Ferrite Powders by Sol-gel Process (졸겔법에 의한 Ba-ferrite분말의 제조 및 자기적 특성 연구)

  • An, Sung-Yong;Lee, Sang-Won;Choi, Dong-Hyeok;Shim, In-Bo;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.13 no.4
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    • pp.165-170
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    • 2003
  • M-type hexagonal BaFe$\sub$12/O$\sub$19/ ferrite powder was prepared by sol-gel process. The M-type hexagonal structure with ${\alpha}$ = 5.882 and c = 23.215 ${\AA}$ and its Curie temperature T$\sub$C/ was determined 780${\pm}$3 K. The isomer shifts of ,4f$_2$, 2a. 4f$_1$, 12k, and 2b were indicated 0.26, 0.24, 0.15, 0.25, and 0.24 mm/s, therefore, the valence states of the Fe ions were ferric (Fe$\^$3+/). By the law of approach to saturation (LAS), the effective anisotropy field H$\sub$A/ and crystalline anisotropy constant K$_1$ were estimated. The value of K$_1$ and H$\sub$A/ were K$_1$ = 2.5${\times}$10$\^6/erg/cm^3$ and H$\sub$A/ = 14 kOe, respectively.

Magnetic Properties and Workability of Fe-Si Alloy Powder Cores

  • Lee, Tae-Kyung;Kim, Gu-Hyun;Choi, Gwang-Bo;Jeong, In-Bum
    • Journal of Magnetics
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    • v.13 no.4
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    • pp.170-172
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    • 2008
  • Fe-6.5% Si alloys have good magnetic properties due to their high electrical resistivity, very low magneto-striction, and low crystalline anisotropy. Despite their strong potential, these alloys have seldom been used in magnetic applications because of the very poor ductility of Si-steel above 3.0 wt% Si [1-4]. It is difficult to achieve compressed Fe-6.5% Si powder cores with excellent properties because of the low density due to poor ductility. In compressed powder cores, high density is essential in order to obtain high magnetization and permeability. In this study, an attempt was made to produce Fe-3%Si powder cores because the Fe-3.0 wt% Si alloys have relatively good magnetic properties and room temperature ductility. Gas atomized Fe-3.0 wt% Si powder was compressed into toroid shape cores. By reducing the Si content to 3.0 wt%, the hysteresis loss could be greatly reduced and thus the total core loss could be minimized. The total core loss is 600 mW/$cm^3$ at 0.1 T and 50 kHz.

Crystallographic and Magnetic Properties of Nano-sized Nickel Substituted Cobalt Ferrites Synthesized by the Sol-gel Method

  • Choi, Won-Ok;Lee, Jae-Gwang;Kang, Byung-Sub;Chae, Kwang Pyo
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.59-63
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    • 2014
  • Nano-sized nickel substituted cobalt ferrite powders, $Ni_xCo_{1-x}Fe_2O_4$ ($0.0{\leq}x{\leq}1.0$), were fabricated by the sol-gel method, and their crystallographic and magnetic properties were studied. All the ferrite powders showed a single spinel structure, and behaved ferrimagnetically. When the nickel substitution was increased, the lattice constants and the sizes of particles of the ferrite powders decreased. The M$\ddot{o}$ssbauer absorption spectra of $Ni_xCo_{1-x}Fe_2O_4$ ferrite powders could be fitted with two six-line subspectra, which were assigned to a tetrahedral A-site and octahedral B-sites of a typical spinel crystal structure. The increase in values of the magnetic hyperfine fields indicated that the superexchange interaction was stronger, with the increased nickel concentration in $Ni_xCo_{1-x}Fe_2O_4$. This could be explained using the cation distribution, which can be written as, $(Co_{0.28-0.28x}Fe_{0.72+0.28x})[Ni_xCo_{0.72-0.72x}Fe_{1.28-0.28x}]O_4$. The two values of the saturation magnetization and the coercivity decreased, as the rate of nickel substitution was increased. These decreases could be explained using the cation distribution, the magnetic moment, and the magneto crystalline anisotropy constant of the substituted ions.

Coercivity Enhancement of Sintered Nd-Fe-B Magnets by Grain Boundary Diffusion with DyH3 Nanoparticles

  • Liu, W.Q.;Chang, C.;Yue, M.;Yang, J.S.;Zhang, D.T.;Liu, Y.Q.;Zhang, J.X.;Yi, X.F.;Chen, J.W.
    • Journal of Magnetics
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    • v.18 no.4
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    • pp.400-404
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    • 2013
  • Grain boundary diffusion technique with $DyH_3$ nanoparticles was applied to fabricate Dy-less sintered Nd-Fe-B permanent magnets with high coercivity. The magnetic properties and microstructure of magnets were systematically studied. The coercivity and remanence of grain boundary diffusion magnet were improved by 60% and reduced by 7% compared with those of the original magnet, respectively. Meanwhile, both the remanence temperature coefficient (${\alpha}$) and the coercivity temperature coefficient (${\beta}$) of the magnets were improved after diffusion treatment. Investigation shows that Dy is preferentially enriched as (Nd, Dy)$_2Fe_{14}B$ phase in the surface region of the $Nd_2Fe_{14}B$ matrix grains indicated by the remarkable enhancement of the magneto-crystalline anisotropy field of the magnet. As a result, the magnet diffused with a small amount of Dy nanoparticles possesses enhanced coercivity without remarkably sacrificing its magnetization.