• Title/Summary/Keyword: magnetic silica

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Polyamine Group Assembled Silica Coated Ferrite Nanoparticle for Lambda DNA Detection

  • Park, Moo-Eon;Chang, Jeong-Ho
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1193-1194
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    • 2006
  • The magnetic ferrite nanoparticles were synthesized and coated by silica precursor in controlling the coating thicknesses and sizeses. The surface modification was performed with amino-functionalized organic silanes on silica coated magnetic nanoparticles. The use of functionalized self-assembled magnetic ferrite nanoparticles for nucleic acid separation process give a lot of advantages rather than the conventional silica based process.

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Fabrication of Double-Doped Magnetic Silica Nanospheres and Deposition of Thin Gold Layer

  • Park, Sang-Eun;Lee, Jea-Won;Haam, Seung-Joo;Lee, Sang-Wha
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.869-872
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    • 2009
  • Double-doped magnetic particles that incorporated magnetites into both the surface and inside the silica cores were fabricated via the sol-gel reaction of citrate-stabilized magnetites with silicon alkoxide. Double-doped magnetic particles were easily fabricated and exhibited an higher magnetism in comparison to the singledoped magnetic particles that were prepared by the erosion of surface-deposited magneties from double-doped magentic particles. Thin gold layer was formed over magnetic silica nanospheres via nanoseed-mediated growth of gold clusters. The plasmon-derived absorption bands of double-doped magnetic silica-gold nanoshells were more broadened and shifted down by ca. 20 nm as compared to those of single-doped magnetic silicagold nanoshells, which were attributed to not only the surface scattering of incident light due to relatively rough surafce morphology, but also heterogeneous permittivity of dielectric cores due to surface-deposited magnetites.

Fluorescent Magnetic Silica Nanotubes with High Photostability Prepared by the Conventional Reverse Micro-Emulsion Method

  • Zhang, Yuhai;Son, Sang Jun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4165-4168
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    • 2012
  • Magnetic fluorescent silica nanotubes were fabricated using reverse micro-emulsions coupled with conventional sol-gel methods. Anodic aluminum oxide templates were used to separate spatially the magnetic and the fluorescent moieties on individual nanotubes and so prevent quenching of the fluorescence. C18 and fluorescent layers were deposited sequentially on silica. Magnetism was then obtained by the introduction of pre-made magnetic nanoparticles inside the nanotubes. The photo- and chemical stabilities of nanotubes were demonstrated through dye release and photobleaching tests. The produced nanotubes did not show fluorescence quenching upon the addition of the nanoparticles, an advantage over conventional spherical fluorescent magnetic nanoparticles. High photostability of nanotubes, magnetism and biocompatiblily make them potentially useful in bioanalysis.

Interaction of magnetic water, silica fume and superplasticizer on fresh and hardened properties of concrete

  • Mazloom, Moosa;Miri, Sayed Mojtaba
    • Advances in concrete construction
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    • v.5 no.2
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    • pp.87-99
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    • 2017
  • After passing through a magnetic field, the physical quality of water improves, and magnetic water (MW) is produced. There are many investigations on the effects of magnetic field on water that shows MW properties like saturation and memory effect. This study investigates the fresh and hardened properties of concrete mixed with MW, which contains silica fume (SF) and superplasticizer (SP). The test variables included the magnetic field intensity for producing MW (three kinds of water), SF content replaced cement (0 and 10 percent), water-to-cementitious materials ratio (W/CM=0.25, 0.35 and 0.45) and curing time (7, 28 and 90 days). The results of this study show that MW had a positive impact on the workability and compressive strength of concrete. By rising the intensity of the magnetic field which was used for producing MW, its positive influence on both workability and compressive strength improved. MW had greater positive impacts on samples containing SP that did not have SF. Moreover, the best compressive strength improvements of concrete achieved as W/CM ratio decreased.

Effect of Silica Coating on Particle Shape and Magnetic Properties of Iron Powder(I) (실리카 피착이 철립말의 입자형태 및 자기특성에 미치는 영향 (제1보))

  • 오재희;김종식;류병환
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.21-28
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    • 1985
  • The properties of magnetic recording materials largely depend on their shape magnetic anisotropy. The control of their shape and size distribution is very important for improving magnetic properties. The silica-coated goethite$(SiO_2$/$\alpha$-FeOOH=1.5wt%) having acicular shape was prepared. The sillica-coated goethite was heat-treated at 40$0^{\circ}C$~1,00$0^{\circ}C$ 1hr and then reduced at 50$0^{\circ}C$ 2hr. When the silica-coated goethite was heat-treated at 80$0^{\circ}C$ its acicular shape was maintained and its magnetic properties were improved(Hc: 1,325 Oe $\sigma$m:138.8 emu/g, Rs:0.56) However the acicular shape of the paricles was broken for non-coated hematite obtained by dehydration at 80$0^{\circ}C$ They were sintered and showed poor magnetic properties.

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Design simulation of magnetic separator for purification of silica sand (자력선별방식을 이용한 고순도 실리카 정제 최적화를 위한 전산모사)

  • Choi, Hyun-Jin;Jo, Young Min;Lee, Jun Yub;Kim, Sang Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.181-187
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    • 2016
  • Silica is an essential material in the electronics industries of LCDs and OLEDs, which particularly require high purity. This study attempted to find the optimal design of a magnetic separator for silica sand containing iron compounds using CFD simulation. Three designs of magnetic separation were prepared and their efficiency was examined. As a result of the evaluation, the sufficient contact of particulate silica with the surface of magnetic emitters improved the magnetic separation effects. In addition, the loss of $SiO_2$ and the removal rate of $Fe_2O_3$ depended strongly on the particle size, flow rate and magnetic flux density. In addition, magnetic separation is quite effective for a particle size of $10{\mu}m$ with a 0.2 m/s flow rate.

Magnetic Nanochain-Based Smart Drug Delivery System with Remote Tunable Drug Release by a Magnetic Field

  • Byunghoon Kang;Moo-Kwang Shin;Seungmin Han;Ilyoung Oh;Eunjung Kim;Joseph Park;Hye Young Son;Taejoon Kang;Juyeon Jung;Yong-Min Huh;Seungjoo Haam;Eun-Kyung Lim
    • BioChip Journal
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    • v.16
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    • pp.280-290
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    • 2020
  • Considerable attention is given to drug delivery technology that efficiently delivers appropriate levels of drug molecules to diseased sites with significant therapeutic efficacy. Nanotechnology has been used to develop various strategies for targeted drug delivery, while controlling the release of drugs because of its many benefits. Here, a delivery system was designed to control drug release by external magnetic fields using porous silica and magnetic nanoparticles. Magnetic nanochains (MNs) of various lengths (MN-1: 1.4 ± 0.8 ㎛, MN-2: 2.2 ± 1.1 ㎛, and MN-3: 5.3 ± 2.0 ㎛) were synthesized by controlling the exposure time of the external magnetic force in magnetic nanoaggregates (MNCs). Mesoporous silica-coated magnetic nanochains (MSMNs) (MSMN-1, MSMN-2, and MSMN-3) were prepared by forming a porous silica layer through sol-gel polymerization. These MSMNs could load the drug doxorubicin (DOX) into the silica layer (DOX-MSMNs) and control the release behavior of the DOX through an external rotating magnetic field. Simulations and experiments were used to verify the motion and drug release behavior of the MSMNs. Furthermore, a bio-receptor (aptamer, Ap) was introduced onto the surface of the DOX-MSMNs (Ap-DOX-MSMNs) that could recognize specific cancer cells. The Ap-DOX-MSMNs demonstrated a strong therapeutic effect on cancer cells that was superior to that of the free DOX. The potent ability of these MSMNs as an external stimulus-responsive drug delivery system was proven.

Characteristics of Silica Coated ${\gamma}-Fe_{2}O_{3}$ with Heat-treatment (열처리에 따른 실리카 피착 ${\gamma}-Fe_{2}O_{3}$의 특성)

  • Lee, J.Y.;Byeon, T.B.;Kim, D.Y.;Lee, H.;Han, K.H.;Sohn, J.G.
    • Journal of the Korean Magnetics Society
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    • v.3 no.2
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    • pp.108-114
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    • 1993
  • This paper presents a study on the effects of silica coating in the production of ${\gamma}-Fe_{2}O_{3}$ powders suitable for magnetic recording media. Emphasis has been put on investigating the relationship between the powder characteristics and the effects of silica coating in the heat-treatment stage of ${\gamma}-Fe_{2}O_{3}$ production. After we prepared non-coated ${\gamma}-Fe_{2}O_{3}$ and silica coated ${\gamma}-Fe_{2}O_{3}$ with coating water glass on the surface of goethite and heattreatment process, we compared and investigated powder characteristics. As silica coated layer played a role of preventing the powders from overreduction to metal iron and rapid oxidation, silica coated ${\gamma}-Fe_{2}O_{3}$ showed superior magnetization value due to inhibiting t!1e adulteration of ${\alpha}-Fe_{2}O_{3}$ into the final product. When silica coated layer acted as a sintering restrainer, silica coated ${\gamma}-Fe_{2}O_{3}$ showed high coercivity and specific sur-face area due to good acicularity.

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Fabrication and Characterization of Silica Coated Fe3O4 Nanoparticles in Reverse Micro Emulsion (마이크로에멀젼법을 이용하여 실리카 코팅된 나노 Fe3O4 분말의 합성과 분석연구)

  • Yu, Ri;Kim, Yoo-Jin;Pee, Jae-Hwan;Hwang, Kwang-Taek;Yang, Hee-Seung;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.113-116
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    • 2010
  • The silica coated $Fe_3O_4$ nanoparticles have been synthesized using a micro-emulsion method. The $Fe_3O_4$ nanoparticles with the sizes 6 nm in diameter were synthesized by thermal decomposition method. Hydrophobic $Fe_3O_4$ nanoparticles were coated silica using surfactant and tetraethyl orthosilicated (TEOS) as a $SiO_2$ precursor. Shell thickness of silica coated $Fe_3O_4$ can be controlled (11~20 nm) through our synthetic conditions. The $Fe_3O_4$ and silica coated $Fe_3O_4$ nano powders were characterized by transmission electron microscopy (TEM), x-ray diffraction (XRD) and vortex magnetic separation (VMS).

Effect of Silica Coating on Particle Shape and Magnetic Properties of Iron Powder (II) (실리카 피착이 철분말의 입자형태 및 자기특성에 미치는 영향(제2보))

  • 오재희;김종식;류병환
    • Journal of the Korean Ceramic Society
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    • v.23 no.2
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    • pp.31-37
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    • 1986
  • The effect of dehydration temperature on the reduction process of silica-coated hematite was invest-igated The particle shape and magnetic properties of the products reduced from hematite at various conditions and the oxidation resistance of silica-coated iron powder were examined. It was revealed that single phase iron powder obtained over 45$0^{\circ}C$ had good magnetic properties. The iron powder manufactured between 45$0^{\circ}C$ and 50$0^{\circ}C$ displayed the maximum coercive force as a result of maintaining its acicular shaped. However the coercive force of iron powder reduced over 50$0^{\circ}C$ was decreased. The oxidation resistance of silica-coated iron powder in air was very good up to 11$0^{\circ}C$ and for 12 days.

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