• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.413-420
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• 2000

Cheju Island has nature of typical trass through volcanic activities in many times. The soil in Cheju Island has principally sprung from basalt and partially made up of trachyte, trachyte's nature and site. Also ancient relics, plain coarse pottery's kilns and pantiles kilns are homogeneously distributed all over the Cheju Island. In this study, as a result of X-ray fluorescence spectrometer and Mossbauer spectroscopy of a sample are from plain coarse pottery and pantiles in 5 regions of Cheju Island. It is thought that these samples are partially formed from neutral volcanic rock like trachyte and Atomicity state of iron is almost Fe$\^$3+/. Also the magnetic hyperfine field length of goethite, contained these samples is less than synthetic goethite magnetic hyperfine field length and this result shows that disintegration of inner magnetic order, created by partial substitution of diamagnetic positive ion containing Fe$\^$3+/ and Al$\^$3+/ in goethite lattice.

• Proceedings of the Korean Magnestics Society Conference
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• 2004.12a
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• pp.166-167
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• 2004

• Korean Journal of Materials Research
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• v.2 no.4
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• pp.293-297
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• 1992

The magnetic properties of the amorphous Fe/sub 32/Ni/sub 36/Cr/sub 14/P/sub 12/B/sub 6/ has been studied by Mossbauer spectroscopy in the temperature range of 88-400K. The analysis of the spectrum of B8K, the magnetic hyperfine field and quadrupole splitting are found to be 140.5kOe and almost zero, which means that the magnetic hyperfine field is randomly oriented with respect to the principal axes of the electric field gradient, respectively. The values of quadrupole splitting in paramagnetic phase with Tc=280K are independent on the changes of temperature. Debye temperature is found to be about 288k from the analysis of recoilless fraction.

• Journal of the Korean Magnetic Resonance Society
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• v.19 no.1
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• pp.11-17
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• 2015

The Kubo formalism and utilizing the projection operator technique (POT) introduced by Kawabata, the electron spin resonance (ESR) line-shape formula for carbon nanotubes through the hyperfine interaction introduced earlier in terms of POT. We can see that the line-width decreases exponentially as the temperature increases. The spin relaxation time show gradual decrease as magnetic field becomes larger. The analysis reveals the peculiarities in spin relaxation inherent to one dimensional system at low temperature and weak magnetic fields. Thus, the present technique is considered to be more convenient to explain the carbon nanotubes as in the case of other optical transitions.

• Journal of Magnetics
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• v.12 no.3
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• pp.108-112
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• 2007

Nature of phase transition in $LaVO_3$ has been studied using X-ray diffraction, SQUID magnetometer, and $M\"{o}ssbauer$ spectroscopy with 1% of $^{57}Fe$ doped sample. The crystal structure was orthorhombic with space group Pnma. Antiferromagnetic phase transition temperature $T_N$ was 140K, below which a weak ferromagnetic trace has been found. $M\"{o}ssbauer$ spectra below $T_N$ were single set of hyperfine sextet, which enabled us to discard the possibility of two inequivalent magnetic sites or uncompensated antiferromagnetism. Hyperfine magnetic field abruptly disappeared as low as about 90K, much below $T_N$.

• Journal of Magnetics
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• v.14 no.2
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• pp.86-89
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• 2009

Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

• Journal of the Korean Magnetics Society
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• v.7 no.5
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• pp.225-231
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• 1997

Sulphur Spinel $Co_{0.95}Fe_{0.05}Cr_2S_4$ has been studied with Mossbauer Spectroscopy between 4.2 K and room temperature. The $Fe^{2+}$ ion in a tetrahedral site is the Jahn-Teller active and the dynamic Jahn-Teller distortion starts below the magnetic ordering temperature. The distortion cause a quadrupole shift to appear which increases with decreasing temperature. The magnetic hyperfine field has a maximum at 100 k and then decreases with decreasing temperature. The magnitude of the interaction ratio R between the electric quadrupole and magnetic dipole interaction increases from 0 near the magnetic ordering temperature to 5.4 at 4.2 K. The optimum values of 0, the polar angle of the magnetic hyperfine field with respect to the principle axis of the electric field gradient (EFG) remains zero and the asymmetry of the EFG n is about 0.25. The simulations of Mossbauer spectra coincidence with the experimental results.

• Journal of the Korean Magnetics Society
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• v.8 no.1
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• pp.1-5
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• 1998

Acicular Fe-Co alloy particles are one of the candidates for high-density magnetic recording media. We examined the effects of Co additions on the magnetic properties of Fe-Co alloy particles by using M$\'{o}$ssbauer spectroscopy, TEM, and X-ray diffraction. Acicular $Fe_n$Co (n=5, 4, 3, 2) alloy particles coated with silica, were prepared by a chemical coprecipitation method and subsequent H $_2$ reduction. The crystal structure was found to be cubic in all n ranges. The lattice constant $a_0$ decreases with increasing Co contents. Analysis of $^{57}Fe$ M\'{o}$ssbauer effect data in terms of the local configurations of Co atoms has permitted the influence of magnetic hyperfine interactions to be monitored.

• Journal of the Korean Magnetics Society
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• v.18 no.1
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• pp.19-23
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• 2008

The mixed ferrite $V_xFe_{3-x}O_4$(x=0.0, 0.15, 0.5, 1.0) thin films were prepared by sol-gel method. Their crystallographic and magnetic hyperfine properties have been studied using X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS) and conversion electron $M\"{o}ssbauer$ spectroscopy(CEMS). The crystal structure is found to be cubic spinel throughout the series($x{\leq}1.0$), and the lattice parameter $a_0$ increases linearly with increasing V content. XRD, XSP and CEMS indicate that $V^{3+}$ substitution for $Fe^{3+}$ in B-site is superior to $V^{2+}$ substitution for $Fe^{2+}$ in B-site. It is noticeable that both quadrupole shift and hyperfine field decreases with increasing V composition, suggesting the change of local symmetry and accompanying line-broadening. The line-broadening on CEMS spectra can be explained by the distribution of magnetic hyperfine fields.

• Journal of the Korean Magnetics Society
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• v.7 no.4
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• pp.196-204
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• 1997

In order to study the effect of substituted $Al^{3+}$ of goethite, which was collected from Shinpyeongli in Cheju Island, we used X-ray diffractometer and Mossbauer spectrometer. In X-ray diffraction analysis, the X-ray diffraction peaks of goethite are not detected due to the high substituted Al contents of goethite. Isomer shifts indicated that the valence of Fe ions is almost oxidized trivalent of high spin state. It is believed that the contents of substituted diamagnetic $Al^{3+}$ for $Fe^{3+}$ is about 15.5 mol%. It seems that Neel temperature and saturated magnetic hyperfine field of the clay goethite are about 250 K and 498 kOe, respectively. For the temperature lower than Neel temperature, quadrupole splittings of the clay goethite are greatly influenced by $Al^{3+}$ substitution. It is believed that the high decrease of Neel temperature and magnetic hyperfine field of the clay goethite results from the magnetic dilution produced by substituting the diamagnetic $Al^{3+}$/TEX> for $Fe^{3+}$.