• Journal of Magnetics
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• 제18권1호
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• pp.30-33
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• 2013

The magnetocaloric effect and magnetization behavior have been analyzed in the double-perovskite $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound with the sintering temperature at 1273 K. Samples were fabricated by the conventional solid-state reaction method. X-ray diffraction measurement revealed that all the samples had a single phase in orthorhombic. Detailed investigations of the magnetic entropy behavior of the samples were discussed with the variation of $T_C$. The magnetic entropy changes, ${\Delta}S_M$ of approximately 0.36-1.14 J/kg K were obtained in the temperature range of 145-350 K for the $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound. The enhancement of the magnetic entropy change is believed to be due to changes in the microstructure, which changes the magnetic part of the entropy of a solid around the magnetic ordering temperature.

• 한국재료학회지
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• 제26권11호
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• pp.623-627
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• 2016

$La_{1-x}Ba_xMnO_3$ (x = 0.30, 0.35 and 0.40) samples have been prepared by solid-state reaction method. The X-ray diffraction (XRD) study showed that all the samples crystallized in a rhombohedral structure with an R-3c space group. Variation of the magnetization as a function of the temperature and applied magnetic field was carried out. All the samples revealed ferromagnetic to paramagnetic (FM-PM) phase transition at the Curie temperature $T_C{\sim}342K$. The magnetic entropy change was also studied through examination of the measured magnetic isotherms M(H, T) near $T_C$. The magnetocaloric effect was calculated in terms of the isothermal magnetic entropy change. The maximum entropy change reaches a value of 1.192 J/kgK under a magnetic field change of 2.5T for the $La_{0.6}Ba_{0.4}MnO_3$ composition. The relative cooling power (RCP) is 79.31 J/kg for the same applied magnetic field.

• 한국자기학회지
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• 제10권4호
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• pp.149-153
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• 2000

변하는 자기장을 단결정 및 다결정 망간 산화물 La$_{0.7}$Ca$_{0.3}$MnO$_3$에 인가하였을 때 자기 엔트로피가 크게 변하는(거대 자기 엔트로피 변화)현상이 관측되었다. 이 거대 자기 엔트로피 변화는 Curie온도에서 유사 1차상전이에 의한 자화값의 급격한 변화에 의한 것으로 추측된다. 이 거대 자기 엔트로피 변화와 망간 산화물 Curie 온도의 100 K＜T＜400 K 내의 조절 용이성은 상온을 포함한 넓은 온도에서 망간 산화물을 이용한 자기 냉각 기관의 개발 가능성을 제시하고 있다. 있다.

• 한국자기학회지
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• 제18권2호
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• pp.63-66
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• 2008

초상자성 코발트 페라이트 나노입자를 제조하여 자화 및 자기엔트로피 변화를 조사하였다. 제조된 시료는 전형적인 입방 스피넬 구조를 띠고 있었다. 5K와 300K에서의 최대 자화는 덩어리 상태에서의 최대 자화보다 작은 값을 가졌다. 시료의 초상자성적 거동은 M vs. H/T 곡선의 겹침에 의해 확인되었다. 열역학적 이론을 바탕으로 자기엔트로피의 변화에 대한 온도 의존성을 도출한 결과, 온도가 높을수록 자기엔트로피의 변화는 더 크게 감소하는 것으로 나타났다.

• Journal of Magnetics
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• 제18권4호
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• pp.405-411
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• 2013

The structural, magnetic and magnetocaloric properties of $CoMn_{1-x}Cr_xGe$ (x=0.05-0.125) have been investigated by using electron microscopy, x-ray diffraction, calorimetric and magnetic measurements. In this study, our aim is to justify the magnetocaloric effect by tuning the structural and magnetic transition temperature with Cr doping on CoMnGe pure system. The substitution of Cr for Mn leads to a decrease of both structural and magnetic transition temperatures. However, structural and magnetic transition temperatures do not close to each other. From magnetization measurement, we calculate that isothermal entropy change associated with magnetic transition can be as high as 3.82 J $kg^{-1}K^{-1}$ at 302 K in a field of 7 T. Meanwhile, structural phase transition contribution to isothermal entropy change is calculated as 5.85 J $kg^{-1}K^{-1}$ at 322 K for 7 T.

• Current Applied Physics
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• 제18권12호
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• pp.1605-1608
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• 2018

$Gd_{1-x}Ho_xNi$ melt-spun ribbons were fabricated by a single-roller melt spinning method. All the compounds crystallize in an orthorhombic CrB-type structure. The Curie temperature ($T_C$) was tuned between 46 and 99 K by varying the concentration of Gd and Ho. A spin reorientation (SRO) transition is observed around 13 K. Different from $T_C$, the SRO transition temperature is almost invariable for all compounds. Two peaks of magnetic entropy change (${\Delta}S_M$) were found. One at the higher temperature range was originated from the paramagnet-ferromagnet phase transition and the other at the lower temperature range was caused by the SRO transition. The maximum of ${\Delta}S_M$ around $T_C$ is almost same. The other maximum of ${\Delta}S_M$ around SRO transition, however, had significantly positive relationship with x. It reached a maximum about $8.2J\;kg^{-1}\;K^{-1}$ for x = 0.8. Thus double large ${\Delta}S_M$ peaks were obtained in $Gd_{1-x}Ho_xNi$ melt-spun ribbons with the high Ho concentration. And the refrigerant capacity power reached a maximum of $622J\;kg^{-1}$ for x = 0.6. $Gd_{1-x}Ho_xNi$ ribbons could be good candidate for magnetic refrigerant working in the low temperature especially near the liquid nitrogen temperature range.

• 한국재료학회지
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• 제28권8호
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• pp.445-451
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• 2018

We report the structural, magnetic and magnetocaloric properties of $Sr_{1.8}Pr_{0.2}FeMo_{1-x}W_xO_6$($0.0{\leq}x{\leq}0.4$) samples prepared by the conventional solid state reaction method. The X-ray diffraction analysis confirms the formation of the tetragonal double perovskite structure with a I4/mmm space group in all the synthesized samples. The temperature dependent magnetization measurements reveal that all the samples go through a ferromagnetic to paramagnetic phase transition with an increasing temperature. The Arrott plot obtained for each synthesized sample demonstrates the second order nature of the magnetic phase transition. A magnetic entropy change is obtained from the magnetic isotherms. The values of maximum magnetic entropy change and relative cooling power at an applied field of 2.5 T are found to be $0.40Jkg^{-1}K^{-1}$ and $69Jkg^{-1}$ respectively for the $Sr_{1.8}Pr_{0.2}FeMoO_6$ sample. The tunability of magnetization and excellent magnetocaloric features at low applied magnetic field make these materials attractive for use in magnetic refrigeration technology.

• Journal of Magnetics
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• 제16권4호
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• pp.337-341
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• 2011

The magnetic and magnetocaloric properties of $Gd_{1-x}Ce_xAl_2$ (x = 0, 0.25, 0.5, 0.75) intermetallic compounds alloys have been investigated in detail for the first time. XRD patterns indicated that all the samples were crystallized in a single phase with $MgCu_2$-type structure (Laves phase). Ce substitution for Gd increased the lattice parameters and decreased the Curie temperature from 163 K for x = 0 to 37 K for x = 0.75. A maximum entropy change of 3.82 J/kg K was observed when a 2 T magnetic field was applied to the x = 0 sample. This entropy change decreased with increasing Ce content to 2.04 J/kg K for the x = 0.75 sample.

• Journal of Magnetics
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• 제16권4호
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• pp.457-460
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• 2011

In this paper, magnetic property and magnetocaloric effect (MCE) in perovskite manganites of the type $La_{(0.75-X)}Ce_XCa_{0.25}MnO_3$ (x = 0.0, 0.2, 0.3 and 0.5) synthesized by using the standard solid state reaction method have been reported. From the magnetic measurements as a function of temperature and applied magnetic field, we have observed that the Curie temperature ($T_C$) of the prepared samples strongly dependent on Ce content and was found to be 255, 213 and 150 K for x = 0.0, 0.2 and 0.3, respectively. A large magnetocaloric effect in vicinity of $T_C$ has been observed with a maximum magnetic entropy change (${\mid}{\Delta}S_M{\mid}_{max}$) of 3.31 and 6.40 J/kgK at 1.5 and 4 T, respectively, for $La_{0.55}Ce_{0.2}Ca_{0.25}MnO_3$. In addition, relative cooling power (RCP) of the sample under the magnetic field variation of 1.5 T reaches 59 J/kg. These results suggest that $La_{0.55}Ce_{0.2}Ca_{0.25}MnO_3$ compound could be a suitable candidate as working substance in magnetic refrigeration at 213 K.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2002년도 동계연구발표회 논문개요집
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• pp.120-120
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• 2002

In past years, theoretical controversy involving a realistic and physical mechanism that leads to large magnetic entropy change as a large magneto-caloric effect in colossal magneto-resistance (CMR) materials had been left as an open question. Thus it is desirable to clarify this problem. (omitted)