• Title/Summary/Keyword: magnetic composites

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Electrical and Magnetic Properties in [La0.7(Ca1-xSrx)0.3MnO3)]0.99/(BaTiO3)0.01 Composites

  • Kim, Geun-Woo;Bian, Jin-Long;Seo, Yong-Jun;Koo, Bon-Heun
    • Korean Journal of Materials Research
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    • v.21 no.4
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    • pp.216-219
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    • 2011
  • Perovskite manganites such as $RE_{1-x}A_xMnO_3$ (RE = rare earth, A = Ca, Sr, Ba) have been the subject of intense research in the last few years, ever since the discovery that these systems demonstrate colossal magnetoresistance (CMR). The CMR is usually explained with the double-exchange (DE) mechanism, and CMR materials have potential applications for magnetic switching, recording devices, and more. However, the intrinsic CMR effect is usually found under the conditions of a magnetic field of several Teslas and a narrow temperature range near the Curie temperature ($T_c$). This magnetic field and temperature range make practical applications impossible. Recently, another type of MR, called the low-field magnetoresistance(LFMR), has also been a research focus. This MR is typically found in polycrystalline half-metallic ferromagnets, and is associated with the spin-dependent charge transport across grain boundaries. Composites with compositions $La_{0.7}(Ca_{1-x}Sr_x)_{0.3}MnO_3)]_{0.99}/(BaTiO_3)_{0.01}$ $[(LCSMO)_{0.99}/(BTO)_{0.01}]$were prepared with different Sr doping levels x by a standard ceramic technique, and their electrical transport and magnetoresistance (MR) properties were investigated. The structure and morphology of the composites were studied by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). BTO peaks could not be found in the XRD pattern because the amount of BTO in the composites was too small. As the content of x decreased, the crystal structure changed from orthorhombic to rhombohedral. This change can be explained by the fact that the crystal structure of pure LCMO is orthorhombic and the crystal structure of pure LSMO is rhombohedral. The SEM results indicate that LCSMO and BTO coexist in the composites and BTO mostly segregates at the grain boundaries of LCSMO, which are in accordance with the results of the magnetic measurements. The resistivity of all the composites was measured in the range of 90-400K at 0T, 0.5T magnetic field. The result indicates that the MR of the composites increases systematically as the Ca concentration increases, although the transition temperature $T_c$ shifts to a lower range.

Effect of Magnetic Force on the Compressive and Dynamic Properties of Magnetorheological Elastomers (자기력이 자기유동 탄성체의 압축 및 동적 특성에 미치는 영향)

  • Ryu, Sang-Ryeoul;Lee, Dong-Joo;Lee, Jong-Hang
    • Composites Research
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    • v.23 no.1
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    • pp.17-22
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    • 2010
  • The compressive and dynamic properties of magnetorheological elastomers were investigated as functions of magnetizable particle volume fraction, alignment of the embedded particle and magnetic force. The specimens consisted of pure and filled silicons with randomly dispersed, longitudinal and transverse aligned magnetizable particle chains. To align the embedded particles in the elastomer, the cross-linking of the elastomer composites took place in a magnetic field. The compression and dynamic tests in the absence and the presence of different magnetic forces were carried out. The modulus and loss factor of the elastomer composites increase with increasing volume fraction at the same magnetic force. The case of longitudinal alignment shows a high modulus and loss factor when compared to the case of transverse alignment or random dispersion.

Influence of Machining on Magnetic Properties of Soft Magnetic Composites

  • Igarashi, Kazunori;Miyahara, Masahisa;Morimoto, Koichiro
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1175-1176
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    • 2006
  • Influences of machining on magnetic properties of soft magnetic composites (SMC's) with addition of two kinds of binder, i.e., organic binder and inorganic one, were investigated. Machining does not affect DC magnetic properties of the SMC compacts. This can be ascribed to their particular structure in which the ironpowder particles are highly isolated by the binder. On the other hand, decrease in resistivity and resultant increase in eddy current loss was confirmed in the machined compacts containing inorganic binder. It is supposed that the brittleadditive binder existing between the iron particles is partly broken, and iron-to-iron contact is formed on the machined surface.

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Microwave Absorbing Properties of Rubber Composites Containing Soft Magnetic Fe-Alloy Particles (철계 연자성 합금 분말을 함유한 고무 복합재의 전파흡수특성)

  • Cho, Han-Shin;Kim, Sung-Soo
    • Journal of Powder Materials
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    • v.20 no.2
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    • pp.125-128
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    • 2013
  • Magnetic and dielectric properties of rubber composites are controlled by using two kinds of high-permeability metal particles with different electrical conductivity (Sendust, Permalloy), and their effect on microwave absorbance has been investigated, focusing on the quasi-microwave frequency band (0.8-2 GHz). Noise absorbing sheets are composite materials of magnetic flake particles of high aspect ratio dispersed in polymer matrix with various filler amount of 80-90 wt.%. The frequency dispersion and magnitude of complex permeability is almost the same for Sendust and Permalloy composite specimens. However, the complex permittivity of the Permalloy composite (${{\varepsilon}_r}^{\prime}{\simeq}250$, ${{\varepsilon}_r}^{{\prime}{\prime}}{\simeq}50$) is much greater than that of Sendust composite (${{\varepsilon}_r}^{\prime}{\simeq}70$, ${{\varepsilon}_r}^{{\prime}{\prime}}{\simeq}0$). Due to the large dielectric permittivity of Permalloy composite, the absorbing band is shifted to lower frequency region. However, the investigation of impedance matching reveals that the magnetic permeability is still small to satisfy the zero-reflected condition at the quasi-microwave frequency band, resulting in a small microwave absorbance lower than 10 dB.

Magnetic Pulsed Compaction and Sintering Characteristics of Al Composite Powders Reinforced with Waste Stainless Steel Short Fibers (폐 스테인레스강 단섬유로 강화한 알루미늄 복합분말의 자기펄스압 성형 및 소결 특성)

  • Hyun, Chang-Yong;Won, Chul-Hyun;Park, Jae-Soon
    • Journal of Powder Materials
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    • v.14 no.6
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    • pp.380-385
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    • 2007
  • Characteristics of Al-based composites with waste stainless steel short fiber, fabricated by magnetic pulsed compaction and sintering were investigated. The compacts prepared by magnetic pulsed compaction showed high relative density and homogeneous microstructure compared with that by conventional press compaction. The relative density of sintered composites at $430^{\circ}C$ for 1 h exhibited the same value with compacts and decreased with increase in STS short fiber content. The reaction between Al and STS phase was confirmed by the microstructural analysis using EDS. The sintered composites, prepared by magnetic pulsed compaction, showed increased hardness value with increasing STS fiber content. Maximum yield strength of 100 MPa and tensile strength of 232 MPa were registered in the AI-based composite with 30 vol% STS short fiber.

The influence of magnetic field on the alignment of steel fiber in fresh cementitious composites

  • Li, Hui;Li, Lu;Li, Lin;Zhou, Jian;Mu, Ru;Xu, Mingfeng
    • Computers and Concrete
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    • v.30 no.5
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    • pp.323-337
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    • 2022
  • This paper proposes a numerical model to simulate the rotational behavior of steel fiber in fresh cement-based materials in the presence of a magnetic field. The results indicate that as the aspect ratio of fiber increases, the required minimum magnetic field intensity to make fiber rotate in viscous fluid increases. The optimal magnetic field intensity is 0.03 T for aligning steel fiber in fresh cement-based materials to ensure that the applying time of the magnetic field can be conducted concurrently with the vibrating process to increase the aligning efficiency. The orientation factor of steel fiber in cement mortar can exceed 0.85 after aligning by 0.03 T of the uniform magnetic field. When the initial angle of the fiber to the magnetic field direction is less than 10°, the magnetic field less than 0.03 T cannot make the fiber overcome the yield stress of fluid to rotate. The coarse aggregate in steel fiber-reinforced concrete is detrimental to the rotation and alignment of the steel fiber. But the orientation factor of ASFRC under the 0.03T of the magnetic field can also exceed 0.8, while the orientation factor of SFRC without magnetic field application is around 0.6.

Characterization of FeCo Magnetic Metal Hollow Fiber/EPDM Composites for Electromagnetic Interference Shielding (FeCo 자성 금속 중공형 섬유 고분자 복합재의 전자파 차폐 특성 연구)

  • Choi, Jae Ryung;Jung, Byung Mun;Choi, U Hyeok;Cho, Seung Chan;Park, Ka Hyun;Kim, Won-jung;Lee, Sang-Kwan;Lee, Sang Bok
    • Composites Research
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    • v.28 no.6
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    • pp.333-339
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    • 2015
  • Electromagnetic interference shielding composite with low density ($1.18g/cm^3$) was fabricated using electroless plated FeCo magnetic metal hollow fibers and ethylene propylene diene monomer (EPDM) polymer. Aspect ratio of the fibers were controlled and their hollow structure was obtained by heat treatment process. The FeCo hollow fibers were then mixed with EPDM to manufacture the composite. The higher aspect ratio of the magnetic metal hollow fibers resulted in high electromagnetic interference shielding effectiveness (30 dB) of the composite due to its low sheet resistance (30 ohm/sq). The enhanced electromagnetic interference shielding effectiveness was mainly attributed to the formation of conducting network over the percolation threshold by high aspect ratio of fibers as well as an increase of the reflection loss by impedance mismatch owing to low sheet resistance, absorption loss, and multiple internal reflections loss.

Characterization of PMMA/MWNT Composites Fabricated by a Twin Screw Extruder (이축 압출기를 이용하여 제조된 PMMA/MWNT 복합체의 특성 분석)

  • Woo, Jong-Seok;Lee, Geon-Woong;Kye, Hyoung-San;Shin, Kyung-Chul;Bang, Dae-Suk
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.151-158
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    • 2007
  • MWNTs have been widely investigated due to unique properties of such as good electrical conductivity and thermal stability in polymer composites industries. This paper established the procedure to fabricate PMMA/MWNT composites by a modular intermeshing co-rotating twin screw extruder with L/D ratio of 42. The electrical properties of PMMA/MWNT composites with different content of MWNT have been investigated. A sheet resistance percolation was observed at 4 wt% of MWNT for the melt processed composites. Sheet resistance of PMMA/MWNT composite film containing 4 wt% of MWNT was nearby $10^4{\Omega}/sq$ and this shows the possibility of potential application to EMI (Electronic Magnetic Interference) shielding materials. The characteristics of composites were analyzed by TGA, DSC, and SEM. In addition, MFI (Melt Flow Index) has been measured to analyze the rheological property.