• Title/Summary/Keyword: magnesium alloys

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Microstructure and Properties of Mg-RE-Zn Alloys for High Conductivity Parts (고전도성 부품용 Mg-RE-Zn계 합금의 미세조직 및 특성)

  • Kim, Jeong-Min;Kim, Nam-Hoon
    • Journal of Korea Foundry Society
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    • v.34 no.5
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    • pp.151-155
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    • 2014
  • The relatively low conductivity of conventional Mg-Al alloys often limits their areas of application. Therefore, several attempts to develop new high-conductivity magnesium alloys have been made recently. In this research, A Ce-rich rare-earth (RE)material and zinc were added to magnesium which contained no aluminum. As the RE and Zn content were increased, both the hardness and tensile strength were gradually increased, despite the fact that the electrical conductivity decreased slightly. The effects of an aging treatment on the conductivity and mechanical properties of Mg-RE-Zn alloys were also investigated. The electrical conductivity did not change according to the heat treatment conditions; however, the mechanical properties could be enhanced by proper aging heat treatments.

Effect of Extrusion Conditions on Microstructures and Mechanical Properties of AM80 Magnesium Alloys (AM80 마그네슘 합금의 미세조직 및 기계적 특성에 대한 압출조건의 영향)

  • Lee, S.K.;Kim, D.H.;Kim, D.H.;Lim, S.G.
    • Transactions of Materials Processing
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    • v.27 no.6
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    • pp.379-385
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    • 2018
  • This study investigated the effect of extrusion conditions on microstructures and mechanical properties of AM80 magnesium alloys. The billets of magnesium alloy used for hot extrusion were prepared by permanent mold casting method, and its extrusion was hot direct extrusion with different extrusion conditions. The results of microstructural analysis showed that the main phases in the as-casted alloys were ${\alpha}-Mg$, ${\beta}-Mg_{17}Al_{12}$, and lamella $Mg_{17}Al_{12}$. Hot extrusion results, The tensile strength of the most soundly manufactured extruded bars (extrusion temp: $350^{\circ}C$, extrusion ratio: 27:1, ram speed: 2mm/s) was approximately 327MPa at room temperature. The increase in the mechanical properties of hot-extruded alloys was as a result of grain refinement by dynamical recrystallization during hot extrusion.

A study on zinc phosphate conversion coatings on Mg alloys

  • Phuong, Nguyen Van;Lee, Kyuhwan;Chang, Doyon;Kim, Man;Lee, Sangyeoul;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.17-17
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    • 2012
  • Magnesium alloys exhibit many attractive properties such as low density, high strength/weight ratio, high thermal conductivity, very good electromagnetic features and good recyclability. However, most commercial magnesium alloys require protective coatings because of their poor corrosion resistance. Attempts have been made to improve the corrosion resistance of the Mg alloys by surface treatments, such as chemical conversion coatings, anodizing, plating and metal coatings, are commonly applied to magnesium alloys in order to increase the corrosion resistance. Among them, chemical conversion coatings are regarded as one of the most effective and cheapest ways to prevent corrosion resistance. In this study, zinc phosphate conversion coatings on various Mg alloys have been developed by selecting proper phosphating bath composition and concentration and by optimizing phosphating time, temperature. Morphology, coatings composition, corrosion resistance, adhesion and its formation and growth mechanism of the zinc phosphate conversion coatings were studied. Results have shown some attractive properties such as simplicity in operation, significantly increased corrosion protective property. However, adhesions between coatings and substrate and also between coatings and paint are still not satisfied. Resolving the problems and understanding the mechanism of phosphating process are targets of our study.

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Corrosion Monitoring of PEO-Pretreated Magnesium Alloys

  • Gnedenkov, A.S.;Sinebryukhov, S.L.;Mashtalyar, D.V.;Gnedenkov, S.V.;Sergienko, V.I.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.151-159
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    • 2017
  • The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

Design and Analysis of vehicle Hood using Magnesium Alloy Sheets (마그네슘 합금 판재를 이용한 차량용 후드의 설계 및 해석)

  • Shin H. W.;Yoo H. J.;Yeo D. H.;Shin K. Y.;Koh Y. S.;Choi S. W.;Lee S. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.220-226
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    • 2005
  • To achieve the weight reduction of a vehicle, Magnesium alloys are widely used in automobile parts because of its lightweight characteristics. Magnesium alloys also have advantages in recycling, stiffness, NVH , heat protection. But Magnesium alloy parts are mainly manufactured by diecasting processes, their productivity was not so high compared to by sheet metal working. We are developing vehicle hood using magnesium sheets. In this study we designed magnesium alloy hood which have equivalent mechanical characteristics to steel hood. Using finite element method we decided thickness of magnesium sheets under some design requirements and we changed the shape of hood inner panel and hinge reinforcements. Outer and inner panel thickness was 1.3mm, 1.5mm respectively. Panel dentibility analysis was performed to conform the new magnesium design by nonlinear FEM package. Formability and hemming of Magnesium sheets are the subjects for further study because they have poor stretchability compared to steel sheets.

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Effect of Annealing Conditions on Microstructure and Damping Capacity in AZ61 Magnesium Alloy (열처리조건에 따른 AZ61 마그네슘 합금의 미세조직과 감쇠능에 미치는 영향)

  • Ahn, Jae-Hyeon;Kim, Kwon-Hoo
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.2
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    • pp.56-62
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    • 2018
  • Many researchers have studied on the precipitation control after solution treatment to improve the damping capacity without decreasing the strength. However, studies on the damping capacity and microstructure changes after deformation in the solid solution strengthening alloys were inadequate, such as the Al-Zn series magnesium alloys. Therefore, in order to investigate the effect of annealing condition on microstructure change and damping a capacity of AZ61 magnesium alloy. In this study, it was confirmed that the microstructure changes affect the damping capacity and hardness when annealed AZ61 alloy. AZ61 magnesium alloy was rolled at $400^{\circ}C$ with rolling reduction of 30%. These specimens were annealed at $350^{\circ}C$ to $450^{\circ}C$ for 30-180 minutes. After annealing, microstructure was observed by using optical microscopy, and damping capacity was measured by using internal friction measurement machine. Hardness was measured by Vickers hardness tester under a condition of 0.3 N. In this study, static recrystallization was observed regardless of the annealing conditions. In addition, uniform equiaxed grain structure was developed by annealing treatment. Hardness is decreased with increasing grain size. This is associated with Hall-Petch equation and static recrystallization. In case of damping capacity, bigger grain size show the larger damping capacity.

Effect of Hydrophobizing Method on Corrosion Resistance of Magnesium Alloy with Plasma Electrolytic Oxidation (소수성 처리 방법에 따른 플라즈마 전해 산화 처리된 마그네슘 합금의 내식성)

  • Joo, Jaehoon;Kim, Donghyun;Jeong, Chanyoung;Lee, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.96-102
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    • 2019
  • Magnesium and its alloys are prone to be corroded, thus surface treatments improving corrosion resistance are always required for practical applications. As a surface treatment of magnesium alloys, plasma electrolytic oxidation (PEO), creating porous stable oxide layer by a high voltage discharge in electrolyte, enhances the corrosion resistance. However, due to superhydrophilicity of the porous oxide layer, which easily allow the penetration of corrosive media toward magnesium alloys substrate, post-treatments inhibiting the transfer of corrosive media in porous oxide layer are required. In this work, we employed a hydrophobizing method to enhance the corrosion resistance of PEO treated Mg alloy. Three types of hydrophobizing techniques were used for PEO layer. Thin Teflon coating with solvent evaporation, self-assembled monolayer (SAM) coating of octadecyltrichlorosilane (OTS) based on solution method and SAM coating of perfluorodecyltrichlorosilane (FDTS) based on vacuum method significantly enhances corrosion resistance of PEO treated Mg alloy with reducing the contact of water on the surface. In particular, the vacuum based FDTS coating on PEO layer shows the most effective hydrophobicity with the highest corrosion resistance.

Effect of Aging Treatment on the Tensile Properties of Mg-Nd-Y-Zr-Zn Casting Alloys (Mg-Nd-Y-Zr-Zn 주조합금의 인장특성에 미치는 시효처리의 영향)

  • Kim, Hyun-Sik;Ye, Dea-Hee;Kang, Min-Cheol;Kim, In-Bea
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.266-271
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    • 2008
  • Magnesium alloys are alloyed with rare earth elements (Re, Ca, Sr) due to the limited use of magnesium in high-temperature conditions. In this study, the influences of Zr and Zn on the aging behavior of a Mg-Nd-Y alloy were investigated. magnesium alloys containing R.E elements require aging treatments Specifically, Nd, Y and Zr are commonly used for high-temperature magnesium alloys. Various aging treatments were conducted at temperatures of 200, 250 and $300^{\circ}C$ for 0.5, 1, 3, 6, and 10 hours in order to examine the microstructural changes and mechanical properties at a high temperature ($150^{\circ}C$). Hardness and high-temperature ($150^{\circ}C$) tensile tests were carried out under various aging conditions in order to investigate the effects of an aging treatment on the mechanical properties of a Mg-3.05Nd-2.06Y-1.13Zr-0.34Zn alloy. The maximum hardness was 67Hv; this was achieved after aging at $250^{\circ}C$ for 3 hours. The maximum tensile, yield strength and elongation at $150^{\circ}C$ were 237MPa, 145MPa and 13.6%, respectively, at $250^{\circ}C$ for 3 hours. The strengths of the Mg-3.05Nd-2.06Y-1.13Zr-0.34Zn alloy increased as the aging time increased to 3 hours at $250^{\circ}C$ This is attributed to the precipitation of a Nd-rich phase, a Zr-rich phase and $Mg_3Y_2Zn_3$.

Effect of CaO Addition on the High-temperature Oxidation of AZ31 Magnesium Alloys (AZ31 마그네슘 합금의 고온산화에 미치는 CaO 첨가 영향)

  • Won, Sung Bin;Lee, Dong Bok
    • Journal of the Korean institute of surface engineering
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    • v.46 no.2
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    • pp.80-86
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    • 2013
  • Magnesium alloys of AZ31 containing (0.5, 1, 1.5) wt.% of initially added CaO particles were cast in air, and their oxidation behavior was studied at $450-650^{\circ}C$ in air. The initially added CaO particles either decomposed to dissolve in the ${\alpha}$-Mg matrix or precipitated as $Al_2Ca$ along the grain boundaries of the matrix during casting. The ignition temperatures were $565.4^{\circ}C$ for AZ31, $608.6^{\circ}C$ for AZ31+0.5 wt.%CaO, and $689.7^{\circ}C$ for AZ31+1 wt.%CaO. No ignition occurred for AZ31+1.5 wt.%CaO up to $700^{\circ}C$, displaying good oxidation resistance. The CaO-rich oxide scales that formed on the surface of the AZ31+(0.5, 1, 1.5) wt.%CaO alloys improved the oxidation resistance of AZ31 alloys.