• Title/Summary/Keyword: magnesia

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Solidification of Heavy Metal Ions Using Magnesia-phosphate Cement (인산염 마그네시아 시멘트에 의한 중금속 이온 고정화)

  • Choi, Hun;Kang, Hyun-Ju;Song, Myung-Shin;Jung, Eui-Dam;Kim, Ju-Seng
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.20-25
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    • 2011
  • Since 1980's, many mines have been closed and abandoned due to the exhaustion of deposits and declining prices of international mineral resources. Because of the lack of post management for these abandoned mines, Farm land and rivers were contaminated with heavy metal ions and sludge. We studied on the solidification/stabilization of heavy metal ions, chromium ions and lead ions, using magnesia-phosphate cement. Magnesia binders were used calcined-magnesia and dead-burned magnesia. Test specimens were prepared by mixing magnesia binder with chromium ions and lead ions and activators. We analyzed the hydrates by reaction between magnesiaphosphate cement and each heavy metal ions by XRD and SEM-EDAX, and analyzed the content of heavy metal ions in the eruption water from the specimens for the solidification and stabilization of heavy metal ions by ICP. The results was shown that calcined magnesia binder is effective in stabilization for chromium ions and dead-burned magnesia binder is effective in stabilization for lead ions.

characteristics of Magnesia Dam Block for Tundish Vessel in Steel Making Process (턴디쉬용 마그네시아질 댐블록의 제조와 그특성)

  • 정두화;김상모;이석근
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.876-885
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    • 1999
  • In order to develop high performance basic dam block for tundish vessel in steel-making binders and additives on hydration and thermal characteristics of magnesiz castable refractories were studied. Crack initiation and propagation in cement bonded magnesia castables due to slaking of magnesia clinker at drying process were suppressed by using spinel clinker instead of magnesia powder. In case of Na2O$.$2CaO$.$P2O5(NC2P) bonded castable crack initiation due to slaking of magnesia clinker did not occur but bending strength at high temperature was low. Mechanical properties of NC2P bonded castable refractories at high temperature were improved by using magnesia clinker that contains low SiO2 contents.

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$Fe_2O_3$ 함유 MgO C1'를 적용한 시멘트 Kiln용 염기성 벽돌의 고온 특성

  • 김동한;엄창중;이승제;김상재
    • Cement Symposium
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    • no.30
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    • pp.132-138
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    • 2003
  • 시멘트 kiln용 염기성 벽돌의 시멘트 coating 부착성과 고온 강도 특성 향상을 위하여 $Fe_2O_3$함유 magnesia clinker을 적용하였다. $Fe_2O_3$ 함유 magnesia clinker가 사용된 Magnesia-Chromite질 벽돌은 통기율이 크게 저하되었고 상온 및 고온 꺽임강도가 증가되었다. 특히, $Fe_2O_3$ 함유 magnesia clinker를 적용하여 약 1$\%$$Fe_2O_3$ 함량을 가지는 Magnesia-Spinel질 벽돌은 고온에서 높은 꺽임 강도, 열충격 저항성, 향상된 시멘트 coating 부착성을 나타내었다.

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Influences of Milk of Magnesia and Chewing Gum on Oral Conditions of Patients

  • Lee, Eun-Ok
    • Journal of Korean Academy of Nursing
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    • v.1 no.1
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    • pp.44-48
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    • 1970
  • 무의식환자와 수술후환자의 구강청결방법으로 Milk of Magnesia를 사용하였을 때의 효과여부와 수술 환자에게 Milk of Magnesia와 함께 Chewing Gum을 사용했을 때의 효과여부를 측정하기 위하여 인디아나대학 Medical Center에 입원한 무의식환자 2명과 수술 후 마취에서 깨어난 환자 4명을 대상으로 하여 7-8시간 간격으로 2일간 구강청결을 실시했다. 본 연구는 1969년 가을학기에 시행했으며 분석방법으로는 표본 크기가 적은 경우에도 사용할 수 있는 방법의 T-test를 사용했으며 그 결과는 다음과 같다. 1. 무의식환자에서 Milk of Magnesia로 구강청결을 시행했을 때의 구강상태는 시행전보다 유의적으로 호전되지 못했다(p>0.1). 2. 수술 후 환자에서 Milk of Magnesia로 구강청결을 시행했을 때의 구강상태는 시행전보다 유의적으로 호전되었다(p>0.05). 3. 수술 후 환자에서 Milk of Magnesia와 Chewing Gum을 동반하여 사용했을 때의 구강상태는 유의적으로 호전되었다(p<0.05).

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Study on Phosphate Investment for High Temperature Precision Castings(II);The Effect of MgO on the characteristics of the Investment (고온정밀주조용 인산염계 매몰재에 관한연구(II);매몰재의 특성에 미치는 Mgo의 영향)

  • SunWoo, Jung-Ho;Lee, Jong-Nam
    • Journal of Korea Foundry Society
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    • v.5 no.2
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    • pp.97-108
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    • 1985
  • In order to investigate the effect of magnesia clinker on the characteristics of the investments, temperature change during setting, setting time, compressive strength and thermal expansion of the investments were measured, and x-ray analyses were also performed. The investments were prepared in accordance with variation of the content and the particle size of magnesia clinker respectively. From this experiment, the results were summarized as follows; 1. Temperature of the investments during setting rapidly increased with increase of MgO contents and decrease of the particle size of magnesia clinker. 2. Setting time decreased with increase of MgO contents and decrease of the particle size of magnesia clinker. 3. Compressive strength increased with increase of MgO contents and decrease of the particle size of magnesia clinker. 4. Thermal expansion decreased with increase of MgO contents and decrease of the particle size of magnesia clinker. From the above results, the investment which contains 8% of MgO (270-325mesh) could be recommended for phosphate investment castings.

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Effect of Fluxes on the Wear of MgO Coating Materials for Tundish (턴디쉬용 MgO Coating 재의 손상에 미치는 Flux의 영향)

  • 홍기곤;박재원;김효준
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.677-684
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    • 1997
  • The effects of fluxes on MgO coating materials for tundish were investigated. As the number of charge in continuous casting was increased, the basicity of tundish slag was decreased due to the increase of silica formed by dissolution from rice hull. As a result, the wear of magnesia lining was increased. In aggregates of MgO coating materials, magnesioferrite was formed by the reaction between magnesia and ferric oxide formed by the oxidation of molten steel, while matrix parts of MgO coating materials were worn by CaO-Al2O3-SiO2 compounds. Silica in rice hull extracted to the molten slag reduced basicity of slag and formed forsterite in the result of its reaction with magnesia lining. Also, fayalite was formed from the reaction between silica and ferric oxide and it caused the increment of magnesia lining's wear. The wear of magnesia lining by flux of CaO-SiO2 was larger than that of Cao-Al2O3 and calcia in the flux increased the wear of magnesia lining through the formation of rankinite.

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Solidification of Heavy Metal Ions using Magnesia-Phosphate (인산염 마그네시아에 의한 중금속 이온 고정화)

  • Song, Myong-Shin;Kang, Hyun-Ju;Choi, Hun;Kim, Ju-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.317-318
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    • 2010
  • At the latest industry develops, heavy metals or sludge contaminated surrounding farm land and rivers. In this study, wished to solve problem by saying contaminated sludge and tailing and heavy metals to do solidification using Magnesia phosphate cement. Confirmed through above experiment that magnesia is effect in solidification and stabilization of chromium and lead.

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The Quality Properties According to the Ratio of Magnesia and Potassium Phosphate of Magnesia Composites for Living Concrete Panel (리빙 콘크리트 패널용 마그네시아 복합체의 마그네시아 및 인산칼륨 비율에 따른 기초 품질 특성)

  • Choi, Yun-Wang;Nam, Eun-Joon;Kim, Cheol-Gyu;Yang, Neung-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.617-624
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    • 2021
  • In this study, the quality properties according to the ratio of magnesia and potassium phosphate of the magnesia composite were evaluated to control the quality of the parent material in terms of materials when designing living concrete panels. The quality properties are 7 levels (30, 35, 40, 45, 50, 55 and 60%) for W/B, 4 levels for P:M (1:0.5, 1:1.0, 1:2.0 and 1:3.0 vol. %) was prepared and evaluated. As a result of evaluating the flow of the magnesia complex, as W/B increased, the flow showed a tendency to increase, and the flow showed a tendency to decrease as the P:M increased. As a result of the evaluation of the compressive strength of the magnesia composite, the strength showed a tendency to decrease as P:M increased. In addition, it was confirmed that an optimal P:M ratio exists.

Study on Solidification and Strength of Soft Soils by Using Waste Magnesia-Carbon Powder (폐 Magnesia-Carbon Powder를 이용한 연약지반 고형화 및 강도 증진에 대한연구)

  • Choi, Hun;Song, Myong Shin;Kang, Hyung Ju;Jung, Eui Dam;Kim, Ju Seng
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.1
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    • pp.35-40
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    • 2011
  • Magnesia-carbon brick is used to refractory material in Converter and/or Ladle furnace for molten steel manufacturing. The rapid growth of steel making industry, molten steel industry is increased. Therefore, growth of molten steel industry lead to make waste magnesia-carbon brick by repair of Converter and/or Ladle furnace. These waste magnesia-carbon brick is abandoned all. Besides, as it is loosely composed of silt and clay including sand falling according to the type of gangue, rainwater inflows and outflows relatively easily, but silt or clay particles absorb water for a long period, weakening ground. This study tried to show that when colluvial soil is solidified using waste magnesia-carbon brick powder as a way to solidify strengthen the rigidity of colluvial soil.

Experimental Study on Fundamental Quality Characteristics of Non-cement Repair Mortar Using High-volume Fly Ash Based on Potassium Magnesia Phosphate (마그네시아-인산칼륨 기반 하이볼륨 플라이애시 활용 무시멘트 보수 모르타르의 기초 품질 특성에 대한 실험적 연구)

  • Doo-Won Lee;Il-Young Jang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.2
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    • pp.152-161
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    • 2024
  • This paper investigates the manufacturing and fundamental quality characteristics of potassium magnesia phosphate-based non-cement high-volume fly ash repair mortar. To derive the optimal mix for non-cement mortar, the manufacturing characteristics were evaluated based on the magnesia ratio, and the mortar manufacturing characteristics were assessed with the fly ash mixture. Additionally, the non-cement magnesia repair mortar was produced considering the effects of fly ash mixture and basalt fiber. The evaluation results determined the optimal mix of non-cement magnesia repair mortar, and the feasibility was examined through workability and fundamental quality assessments. The optimal magnesia ratio was found to be P:M 1:0.5, with W/B at 30 %. It was also confirmed that mixing FA and basalt fiber improves fiber dispersion and workability. Even with over 50 % FA mixture, the target strength was achieved within six hours, with a flow increase of up to 18 % and a flexural strength decrease of about 1-2 MPa.