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Characteristics of Gasification for a Refused Plastic Fuel (플라스틱 고형 연료의 가스화 특성)

  • Chun, Young Nam;Lim, Mun Sup;Jo, Dae Young
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.636-641
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    • 2015
  • Waste energy conversion to SRF (Solid Refuse Fuel) has the effects not alternative fossil fuel usage but also the reduction of greenhouse gas. But the direct burning of the SRF including a plastic waste generates air pollution problem like soot, dioxin, etc. so that an application of pyrolysis and gasification treatment should be needed. The purpose of this study is to supply a basic thermal data of the pyrolysis gasification characteristics in the plastic-rich SRF which are needed for developing the novel pyrolyser or gasifier. To do so, a bench-scale test rig was newly engineered, and then experiments were achieved for the production characteristics of gas, tar, and char. While SRF sample, gasification air ratio, holding time changed as 2 g, 0.691, 32 min respectively, the $H_2$ 1.36%, $CH_4$ 2.18%, CO 1.88%, $Cl_2$ 15.9 ppm, HCl 6.4 ppm were composed. Also light tar benzene $4.03g/m^3$, naphthalene $0.39g/m^3$, anthracene $0.11g/m^3$, pyrene $0.06g/m^3$, gravimetric tar $18g/m^3$, and char 0.29 g was formed.

A Study of Working Environments and Workers Exposed to Chromium (크롬 취급 사업장의 작업환경 및 근로자 폭로 실태에 관한 연구)

  • Yu, Byung-Chul;Son, Byung-Chul;Jun, Jin-Ho;Han, Yong-Soo;Son, Hye-Sook;Lee, Chae-Eun;Jeong, Woon
    • Journal of Preventive Medicine and Public Health
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    • v.27 no.3 s.47
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    • pp.517-530
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    • 1994
  • For the purpose of providing the basic data for health management of workers who are exposed to chromium and for improving the quality of working environment, the authors evaluated blood and urinary level of chromium, the occupational history. AST, ALT, Hb, Hct, nasal specular examinaton on 287 workers who have been dealed chromium compounds in 56 manufacturing Industries of five types, that is, 38 metal plating services(plating),4 manufacture of other fabricated metal products (fabricated metal product), 5 manufacturing of dyestuff(dyestuff), 6 dressing and dyeing of leather(leather), 3 others(manufacture of pottery and ceramic househod wares, motor vehicles, electronic valves and tubes and other electronic components) and also measured the level of chromium in air from February to October 1993. The results were as follows ; 1. The utilized type of chromium compounds was the hexavalent state in plating fabricated metal product dyestuff, leather and the trivalent state in .other, and atmosperic chromium concentration as geometric mean was $0.0138mg/m^3(0.001{\sim}0.068mg/m^3)$ in plating, $0.0115mg/m^3(0.006{\sim}0.015mg/m^3)$ in fabricated matal product, $0.068mg/m^3(0.002{\sim}0.019mg/m^3)$ in dyestuff, $0.0083mg/m^3(0.002{\sim}0.028mg/m^3)$ in leather $0.0039mg/m^3(0.003{\sim}0.005mg/m^3)$ in other by the type of industry and it exceeded TLV-TWA ($0.05mg/m^3$) in five (13.6%) of plating services. 2. The geometric mean of chromium in blood was $1.54{\mu}g/dl(0.10{\sim}3.62{\mu}g/dl)$ in Plantng, $0.94{\mu}g/dl(0.27{\sim}2.82{\mu}g/dl)$ in fabricated metal product, $0.51{\mu}g/dl(0.10{\sim}3.25{\mu}g/dl)$ in dyestuff, $0.87{\mu}g/dl(0.15{\sim}8.00{\mu}g/dl)$ in leather, $0.55{\mu}g/dl(0.20{\sim}2.28{\mu}g/dl)$ in other by the type of industry(p<0.001). 3. The geometric mean of chromium in urine was $14.47{\mu}g/l(6.90{\sim}28.00{\mu}g/l)$ in planting, $4.63{\mu}g/l(0.24{\sim}43.00{\mu}g/l)$ in fabricated metal product, $5.93{\mu}g/l(1.00{\sim}33.00{\mu}g/l)$ in dyestuff, $11.09{\mu}g/l(0.80{\sim}48.00{\mu}g/l)$ in leather, $12.41{\mu}g/l(10.10{\sim}41.00{\mu}g/l)$ in other by the type of industry(p<0.001). 4. As the result of nasal specular examination, twenty four cases (8.4%) of nasal septal perforation among 287 total subjects was observed, and there were 17 (9.7%) cases in plating, 4 csaes (14.3%) in dressing and dyeing of leather. In the comparison of chromium concentration in blood and urine between the perforated group and non-perforated group, the perforated group showed a significantly higher value as $1.883{\pm}3.055{\mu}g/dl\;and\;0.793{\pm}0.815{\mu}g/dl$(P<0.001), $21.31{\pm}34.610{\mu}g/L\;and\;9.304{\pm}11.079{\mu}g/L$ (P<0.001). 5. The mean concentration of chromium in blood, urine and the mean level of AST, ALT, Hb and Hct in exposure group were higher than those of control group(p<0.001).

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Studies on the Storage of Functional Red Soybean Curd (기능성 홍두부의 저장성)

  • 황태익;김순경;박영숙;변광의
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.6
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    • pp.1115-1119
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    • 2001
  • We prepared a functional red soybean curd (RS) from Ang-Khak according to various concentration (RS1 : red rice powder 0.1 g/10 mL, RS2: 0.2 g/10 mL, RS3: 0.3 g/10 mL, RS4: 0.4 g/10 mL, RS5: 0.5 g/10 mL, CS: control soybean curd). During the storage period of red soybean curd, pH, acidity, and microbial counts showed a minimum change in RS5. And in the case of color, all groups have slightly increased in yellowness except RS1. In the case of texture, hardness, gumminess, and springiness appeared to be increased for a few days and then fell down. As water drained out of soybean curd during storage at 1$0^{\circ}C$, it became so stiff and then rotten that the hardness of soybean curd increased in the early stage and then decreased after all. After a week, we could find a better preservative effect of RS than CS. Resultly, we need more efforts to prolong the shelf-life of soybean curd with applying the functionality of Ang-Khak.

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The effect of Indole acetic acid on the accumulation of Cd2+ and growth of Cd2+ - treated Commelina communis L. (닭의장풀에 Cd2+ 처리시 Cd2+ 흡수와 생장에 미치는 indole acetic acid의 영향)

  • Lee, Jun Sang
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.513-518
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    • 2004
  • 3-weeks old Commelina was transferred to and grown in Hoagland solution (Control, $100\muM$ $Cd^{2+}$, $100\muM$ $Cd^{2+}$+ $100\muM$ IAA, $100\muM$ $Cd^{2+}$+ $100\muM$ IAA + 2 mM sucrose) for 3 weeks and then the effects of indole acetic acid (IAA) on the accumulation of $Cd^{2+}$ and growth of $Cd^{2+}$-treated Commelina were investigated. In the treatment of $Cd^{2+}$, $Cd^{2+}$ was uptaked to 1.74, and 51.36 ${\mu}g/g$ frwt. at the first week, but for three weeks, 0.51 and 34,53 ${\mu}g/g$ frwt, in leaf and stem respectively. When IAA was treated along with $Cd^{2+}$, $Cd^{2+}$ was uptaked to 0.18 and 8.63 ${\mu}g/g$ fiwt, at the first week, and for the incubation of 3 weeks, 0,51 and 45.0 ${\mu}g/g$ fiwt. in leaf and stem. In case of $Cd^{2+}$+IAA+sucrose, $Cd^{2+}$ was uptaked to 1.45 and 18.33 ${\mu}g/g$ frwt. at the first week, but for 3 weeks, 0,51 and 25.45 ${\mu}g/g$ fiwt. in leaf and stem. Likewise $Cd^{2+}$ uptake, the growth was also affected by $Cd^{2+}$ and IAA. During the incubation of 3 weeks, $Cd^{2+}$ reduced the stem growth about 8% in all weeks, but the treatment of IAA recovered the inhibition of stem growth caused by $Cd^{2+}$ to the degree of the control Therefore, it could be concluded that IAA altered the pattern of $Cd^{2+}$ uptake and the growth which were supposed to change $Cd^{2+}$ toxicity.

Characteristics of concentration distribution for indoor air pollutants (VOCs and Carbonyl compounds) in new apartments (신축 공동주택에서 실내공기오염물질(휘발성유기화합물 및 카보닐화합물) 농도분포 특성)

  • Jang, Seong-Ki;Chun, Jae-Young;Lee, Tae-Young;Lim, Soo-Gil;Lu, Jung-Min;Seo, Soo-Yun;Lim, Jeong-Yun
    • Analytical Science and Technology
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    • v.20 no.1
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    • pp.17-24
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    • 2007
  • This study was performed to investigate the distributions of volatile organic compounds and carbonyl compounds at the 120 households in new apartments before occupation. The concentration of toluene, m, p-xylene, formaldehyde, acetone and ethylbenzene dominated as $272.81{\mu}g/m^3$, $98.90{\mu}g/m^3$, $71.68{\mu}g/m^3$, $70.58{\mu}g/m^3$ and $49.76{\mu}g/m^3$, respectively. The identified compounds by standards occupied 42.5% of the TVOCs, also the concentration of toluene occupied the largest part of the identified compounds as 18.5%. The concentration of formaldehyde and acetone were 43.1% and 42.4% among carbonyl compounds. The indoor/outdoor ratio of the concentration of benzene, toluene, formaldehyde and o-xylene were investigated 1.29, 3.59, 10.76 and 28.74, respectively.

Change of Sea Sand Density by Washing (세척에 따른 바다모래 밀도 변화)

  • Kim, Hyun-Sik;Lim, Ji-Young;Kim, Jin-Han
    • Resources Recycling
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    • v.26 no.2
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    • pp.66-70
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    • 2017
  • The purpose of this research was to estimate density changes of sea sand by washing. To examine water content test, field density test, particle density test and measuring of dump regarding extracted sea sand and selling one. Measured result of mean particle density of barge and dump were $2.666g/cm^3$, $2.651g/cm^3$, respectively. Also, measured result of field density for each sea sand was $1.716g/cm^3$, $1.331g/cm^3$ on average. Converted to the volume of 1ton of each sea sand, $0.583m^3$, $0.751m^3$, respectively. Occurring to volume change approximately 28.8% on average. The mean field densities of measuring of sea sand that dump and barge were $1.398g/cm^3$ and $1.716g/cm^3$ respectively. This values indicated $0.715m^3$ and $0.583m^3$ each, when converted to the volume of sea sand 1ton. It was found that the average of 22.6% volume change occurred between the amount of sea sand and the sales volume.

A Study on the Rheological properties of Glucomannan (Glucomannan 의 유변학적 성질에 관한 연구)

  • 김경이
    • The Korean Journal of Rheology
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    • v.5 no.2
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    • pp.161-169
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    • 1993
  • Glucomannan(G.M.)은 Amorphophallus Konjac C. Koch의 tuber로부터 분리되었고. 이 G.M.은 다시 침전제로 메탄올을 사용하여 4단계로 분별되었다.(F.1, F.2, F.3, F.4,). 각분 별물에 비하여 직선으로부터 벗어남을 보였다. Low shear viscometer로 G.M. 용액의 viscosity를 측정하였고 농도와 zero shear specific viscosity의 logarithm을 도시한 결과 inflection point를 나타내었다. 이것은 G.M. 분자들의 coil overlap의 시작에서 기인한 것이 고 묽은 용액에서 진한 용액으로의 전이행동은 임계농도. C*=4/[η]에서 일어났고 이때의 zero shear specific viscosity는 10을 나타내었다. 또한 specific viscosity는 묽은 용액에대해 서는 C14로써 변화하였고 진한 요액에서는 C3.0으로변화하였다. G.M.의 고체상태에 대한 유 전성($\varepsilon$',$\varepsilon$")과 점탄성(C',C")계수들을 액체질소 온도에서부터 15$0^{\circ}C$ 온도범위에 걸쳐 4단계로 film을 건조시키면서 10Hz에서 측정하였다. G.M. film의 유전성과 점탄성의 허수부 분은 ($\varepsilon$", C"), -10$0^{\circ}C$에서 peak를 나타내었고 이 peak는 hydroxy methyl 기들의 회전 운동에서 생겨난 것이다. 건조시키지 않은 상태의 G.M. film의 유전성과 점탄성의 허수부분 의 값들은 -5$0^{\circ}C$에서 물 분자의 운동에 의하여 생긴 peak를 보였다.

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Induction of G2/M Cell Cycle Arrest by Glutamine Deprivation in Human Prostate Carcinoma PC3 Cells (글루타민 결핍에 의한 PC3 인체 전립선 암세포의 G2/M 세포주기 억제 유발)

  • Shin, Dong Yeok;Choi, Sung Hyun;Park, Dong Il;Choi, Yung Hyun
    • Journal of Life Science
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    • v.23 no.6
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    • pp.832-837
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    • 2013
  • In this study, it was investigated the possible mechanisms by which glutamine deprivation exerts its anti-proliferative action in cultured human prostate carcinoma PC3 cells. Glutamine deprivation resulted in inhibition of growth and G2/M arrest of the cell cycle in a time-dependent manner without apoptosis induction, as determined by MTT assay, DAPI staining and flow cytometry analyses. The induction of G2/M arrest by glutamine deprivation was associated with the inhibition of expression of Cdc2, cyclin A and cyclin B1, and up-regulation of the expression of cyclin-dependent kinase (Cdk) inhibitor p21(WAF1/CIP1) in both transcriptional and translational levels. Moreover, glutamine deprivation increased the phosphorylation of checkpoint kinase (Chk)1 and Chk2; however, the levels of Cdc25C phosphorylation were decreased in response to glutamine deprivation in a time-dependent manner. Our data provide a first biochemical evidence that glutamine deprivation suppresses cell viability through G2/M phase arrest without induction of apoptosis in PC3 cells.

Exposure Assessment of PM10 in Expressway Toll Booths (고속도로 톨게이트 부스 내 공기 중 PM10의 노출평가)

  • Nam, Mi Ran;Phee, Young Gyu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.2
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    • pp.151-157
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    • 2018
  • Objectives: This study was conducted in order to evaluate $PM_{10}$ concentrations at eight highway tollgate booths from July to September 2017. Methods: A total of 16 samples were collected from eight toll booths. Each $PM_{10}$ sample was collected using a 37 mm PTFE filter attached to a Personal Environment Monitor. Results: The geometric mean concentrations of $PM_{10}$ in the toll booths was $83.51{\mu}g/m^3$. The mean $PM_{10}$ concentrations measured on freight roadways were much higher than those of measured on general roadways($102.46{\mu}g/m^3$ and $68.05{\mu}g/m^3$, respectively). $PM_{10}$ was revealed to be higher in the morning($105.59{\mu}g/m^3$) than at dawn or in the afternoon($71.26{\mu}g/m^3$ and $61.22{\mu}g/m^3$, respectively). The mean $PM_{10}$ concentration in toll booths ventilated through an air conditioner was higher than that for those using a window or no ventilation. The rate of exceeding the Ministry of Environment Maintenance Limit($200{\mu}g/m^3$) was 6.25%, and the rate of exceeding the Ministry of Labor Recommended Limit($150{\mu}g/m^3$) was 12.5%. Conclusions: In order to protect the health of toll booth workers exposed to airborne dust, it is necessary to check the exposure level from indoor air quality on a regular basis and to manage it appropriately according to the results.

Anti-Adipogenic Effects of Ethanol Extracts Prepared from Selected Medicinal Herbs in 3T3-L1 Cells

  • Park, Min-Jun;Song, Ji-Hye;Shon, Myung-Soo;Kim, Hae Ok;Kwon, O Jun;Roh, Seong-Soo;Kim, Choon Young;Kim, Gyo-Nam
    • Preventive Nutrition and Food Science
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    • v.21 no.3
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    • pp.227-235
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    • 2016
  • Obesity is a major risk factor for various metabolic diseases such as cardiovascular disease, hypertension, and type 2 diabetes mellitus. In this study, we prepared ethanol extracts from Agastache rugosa (ARE), Chrysanthemum zawadskii (CZE), Mentha arvensis (MAE), Perilla frutescens (PFE), Leonurus sibiricus (LSE), Gardenia jasminoides (GJE), and Lycopus coreanus (LCE). The anti-oxidant and anti-adipogenic effects were evaluated. The $IC_{50}$ values for ascorbic acid and LCE against 2,2-diphenyl-1-picrylhydrazyl radicals were $246.2{\mu}g/mL$ and $166.2{\mu}g/mL$, respectively, followed by ARE ($186.6{\mu}g/mL$), CZE ($198.6{\mu}g/mL$), MAE ($337.1{\mu}g/mL$), PFE ($415.3{\mu}g/mL$), LSE ($548.2{\mu}g/mL$), and GJE ($626.3{\mu}g/mL$). In non-toxic concentration ranges, CZE had a strong inhibitory effect against 3T3-L1 adipogenes (84.5%) than those of the other extracts. Furthermore, the anti-adipogenic effect of CZE is largely limited in the early stage of adipogenesis, and we revealed that the inhibitory role of CZE in adipogenesis is required for the activation of Wnt signaling. Our results provide scientific evidence that the anti-adipogenic effect of CZE can be applied as an ingredient for the development of functional foods and nutri-cosmetics for obesity prevention.