• 제목/요약/키워드: m-term

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Amperometric Detection of Hydroquinone and Homogentisic Acid with Laccase Immobilized Platinum Electrode

  • Quan, De;Shin, Woon-Sup
    • Bulletin of the Korean Chemical Society
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    • 제25권6호
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    • pp.833-837
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    • 2004
  • DeniLite$^{TM}$ laccase immobilized platinum electrode was used for amperometric detection of hydroquinone (HQ) and homogentisic acid (HGA) by means of substrate recycling. In case of HQ, the obtained sensitivity is 280 nA/ ${\mu}$M with linear range of 0.2-35 ${\mu}$M ($r^2$ = 0.998) and detection limit (S/N = 3) of 50 nM. This high sensitivity can be attributed to chemical amplification due to the cycling of the substrate caused by enzymatic oxidation and following electrochemical regeneration. In case of HGA, the obtained sensitivity is 53 nA/ ${\mu}$M with linear range of 1-50 $[\mu}M\;(r^2$ = 0.999) and detection limit of 0.3 ${\mu}$M. The response times ($t_{90%}$) are about 2 seconds for the two substrates and the long-term stability is 60 days for HQ and around 40-50 days for HGA with retaining 80% of initial activities. The very fast response and the durable long-term stability are the principal advantages of this sensor. pH studies show that optimal pH of the sensor for HQ is 6.0 and that for HGA is 4.5-5.0. This shift of optimal pH towards acidic range for HGA can be attributed to the balance between enzyme activity and accessibility of the substrate to the active site of the enzyme.

제천지역 전력부하변동에 따른 인체 전 판단 방법에 대한 연구 (A study for Decision Method of Human Body Safety according to Power Load Fluctuation of the Chechon Area)

  • 김상철;김두현
    • 한국안전학회지
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    • 제15권4호
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    • pp.69-77
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    • 2000
  • This paper presents a study for decision method of human body safety according to power load fluctuation of the Chechon area. To cope with substantial electromagnetics analysis, the safety assessments were analyzed the double 154 [kV] T/L, 345 [kV] T/L, Chechon-Ichon, Chechon-Youngju, respectively. As the results of case study, in case of 345 [kV] T/L, the electric field value was 11.4927 [kV/m], magnetic field value was 0.4622 [G] at the point about 7 [m] away from the line in severest case. The results showed that the membership of a proposition fuzzy '11.4937 [kV/m] is hazardous' is 0.7063 for the severest case in case of 345 [kV] T/L. As the analytic results using the fuzzy qualifier term, the membership in case of very false is 0.0862 and fairly false is 0.5419, respectively.

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Membrane distillation of power plant cooling tower blowdown water

  • Ince, Elif;Uslu, Yasin Abdullah
    • Membrane and Water Treatment
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    • 제10권5호
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    • pp.321-330
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    • 2019
  • The objective of this study was to examine the recovery of the power plant cooling tower blowdown water (CTBD) by membrane distillation. The experiments were carried out using a flat plate poly vinylidene fluoride (PVDF) membrane with a pore diameter of $0.22{\mu}m$ by a direct contact membrane distillation unit (DCMD). The effects of operating parameters such as transmembrane temperature difference (${\Delta}T$), circulation rate and operating time on permeate flux and membrane fouling have been investigated. The results indicated that permeate flux increased with increasing ${\Delta}T$ and circulation rate. Whereas maximum permeate flux was determined as $47.4L/m^2{\cdot}h$ at ${\Delta}T$ of $50^{\circ}C$ for all short term experiments, minimum permeate flux was determined as $7.7L/m^2{\cdot}h$ at ${\Delta}T$ of $20^{\circ}C$. While $40^{\circ}C$ was determined as the optimum ${\Delta}T$ in long term experiments. Inorganic and non-volatile substances caused fouling in the membranes.

Effects of Nonylphenol on the Secretion of Catecholamines and Adrenocortical Hormones from Short-Term Incubated Rat Adrenal Glands

  • Hee-Su Kim;Yong-Pil Cheon;Sung-Ho Lee
    • 한국발생생물학회지:발생과생식
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    • 제27권4호
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    • pp.213-220
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    • 2023
  • Previously, we showed that a chronic-low-dose nonylphenol (NP) exposure resulted in histological changes with sexually dimorphic pattern in rat adrenal glands. We hypothesized that such structural changes are closely related to the hormonal secretory patterns. To test this hypothesis, we developed the short-term adrenal incubation method, and measured the levels of catecholamines and cortical steroids using the high-performance liquid chromatography with electrochemical detection (HPLC-ECD) and specific enzyme-linked immunosorbent assay, respectively. The norepinephrine (NE) levels in media from NP-treated female adrenal, except 100 pM NP, were significantly increased [control (CTL) vs 1 nM NP, p<0.001; vs 10 nM NP, p<0.05; vs 100 nM NP, p<0.001; vs 1 µM NP, p<0.01]. The NE secretion from male adrenal was higher when treated with 100 nM and 1 µM NP (CTL vs 100 nM NP, p<0.05; vs 1 µM NP, p<0.05, respectively). The aldosterone level in the female adrenal media treated with 100 pM NP was significantly decreased, on the other hand, that of media treated with 10 nM NP was significantly increased (CTL vs 100 pM NP, p<0.05; vs 10 nM NP, p<0.01). In male adrenal media, the aldosterone levels of 10 nM, 100 nM and 1 µM NP-treated media were significantly declined (CTL vs 10 nM NP, p<0.001; vs 100 nM NP, p<0.001; vs 1 µM NP, p<0.001). These results showed the NP treatment altered secretory pattern of aldosterone from adrenals of both sexes, showing sexual dimorphism. It may be helpful for understanding possible adrenal pathophysiology, and endocrine disrupting chemicals-related sexually dimorphic phenomena in adrenals.

대전공단지역의 대기중 독성금속에 대한 위해도 평가 (Risk Assessment of Airborne Toxic Metals in Thejon Industrial Complex)

  • 이진홍;윤미정;남병현;왕창근;강호
    • 환경영향평가
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    • 제8권2호
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    • pp.1-8
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    • 1999
  • The research centers on the concentration profile and risk assessment of toxic metals for ambient air in Taejon industrial complex. Airborne concentrations of each toxic metal for risk assessment were obtained from 2-year sampling by high volume air sampler and analysis by ICP-MS and ICP-AES in the complex. The long-term arithmetic mean of human carcinogen, arsenic, hexavalent chromium and nickel subsulfide was 5.53, 2.16 and $3.46ng/m^3$ while the mean of probable human carcinogen, beryllium, cadmium and lead was 0.08, 2.35, $293.29ng/m^3$, respectively. And the long-term arithmetic mean concentration of non-carcinogenic metal, manganese was $55.91ng/m^3$. The point risk estimate for the inhalation of carcinogenic metals was $3.6{\times}10^{-5}$, which was higher than a risk standard of $10^{-5}$. About 75% of the cancer risk was to the inhalation of human carcinogen, arsenic. Thus, it is necessary to properly manage arsenic risk in Taejon industrial complex. The point hazard index by the inhalation of manganese was 1.1. Therefore, an investigation into Taejon industrial complex is needed to obtain more fine long-term concentration data for airborne non-carcinogenic metals including manganese.

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농업기계 단기임대사업의 효율적 운영을 위한 실태조사 연구 (Status survey on short-term agricultural machinery rental system for efficient operation)

  • 홍순중;허윤근;정선옥;신승엽
    • 농업과학연구
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    • 제38권3호
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    • pp.583-591
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    • 2011
  • Status survey on short-term agricultural machinery rental business was conducted to provide basic data for effective and sustainable implementation of the rental system. Selected survey samples were 34 rental management institutions such as city and county level government offices and agricultural technology development centers, and Primary Agricultural Cooperatives. Survey was conducted through mailing of questionnaire papers and direct interviews with the officers in charge of the agricultural machinery short-term rental management. Number of agricultural machinery retained by the 34 management institutions for the machinery rental business was 3,699, and numbers of the machinery were 1630 for upland crops, 929 for rice, 542 for orchard farming, 274 for animal husbandry, and 324 for common use. Regarding size of warehouse for rental agricultural machinery, 50% of the institutes were less than 660 $m^2$, 26.5% were greater than 993 $m^2$, and 23.5% were between 663 and 990 $m^2$. Institutes maintaining machinery washing facilities were only 10 (29%) among the 34 rental management institutions. Agricultural machinery rental business was advertised to farmers by 91% of the institutes, and the methods were leaflet (35.2%), village broadcasting (26.5%), call-up education (23.6%), and TV and radio (14.7%). Major contents of the advertisement were rental procedure (52.9%), rental machinery (26.5%), and rental cost (20.6%).

Microstructural Evolution of X20CrMoV12.1 Steel upon Short-term Creep Rupture Test

  • Hino, Mariko;He, Yinsheng;Li, Kejian;Chang, Jungchel;Shin, Keesam
    • Applied Microscopy
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    • 제43권4호
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    • pp.164-172
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    • 2013
  • In this work, microstructural and hardness evolution of the X20 steel upon short-term creep test ($550^{\circ}C$ to $650^{\circ}C$, $180^{\circ}C$ to 60 MPa) was studied by using scanning electron microscope, electron backscattered diffraction, and transmission electron microscope, microhardness tester. After creep rupture, gauge and grip part of the specimens were microstructurally analyzed. Creep at the $650^{\circ}C$/60 MPa resulted in a rupture at 1,460 hours with growth of lath width from 1.31 to $2.87{\mu}m$ and a grain growth with a more equiaxed feature. There is a close relationship between Microhardness and lath width. The formation and coarsening of Laves phase, which was observed up to $600^{\circ}C$ of creep temperature, was accelerated by the applied stress. Slight coarsening of the $M_{23}C_6$ was observed in the $550^{\circ}C$ and $600^{\circ}C$ crept or aged specimens. The coarsening of $M_{23}C_6$ depended on the temperature, where specimens crept at $650^{\circ}C$ showed higher growth rate. The microstructural evolution of X20 after short-term creep test was extensively discussed in relation to the long-term creep/aging test reported in literatures.

차세대 고속철 주행속도를 대비한 교량받침의 장기마찰시험법 (A Long-Term Friction Test of Bridge Bearings Considering Running Speed of Next Generation Train)

  • 오순택;이동준;전성민;정신효
    • 한국구조물진단유지관리공학회 논문집
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    • 제20권2호
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    • pp.34-39
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    • 2016
  • 경부 고속철 40 m 단경간 PSC 교량을 대상으로 38 자유도 KTX 동력차를 주행속도 500 km/h까지 12 단계 불규칙 궤도형상과 상호 작용력을 고려하여 해석하였다. 차량의 윤축하중과 중심회전각을 평가하기 위하여 170 m 일반도상을 교량과 조합하여 횡압과 탈선계수 그리고 윤중감소율을 허용기준과 비교하였다. 단순교와 연속교의 교량받침 최대 변위와 누적이동거리를 주행속도별로 해석하였다. PTFE 마찰판과 DP-mate의 EN-1337-2 기준의 장기마찰시험을 수행하였다. 수행된 장기마찰시험은 차세대 고속철의 증가되는 주행속도를 고려하여 개선 방안을 제안하였다.

한반도 지상 풍속의 장기 추세 추정: 관측 자료의 물리적 및 통계적 보정 (Long-Term Trend of Surface Wind Speed in Korea: Physical and Statistical Homogenizations)

  • 최영주;박창현;손석우;김혜진
    • 대기
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    • 제31권5호
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    • pp.553-562
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    • 2021
  • The long-term trend of surface wind speed in Korea is estimated by correcting wind measurements at 29 KMA weather stations from 1985 to 2019 with physical and statistical homogenization. The anemometer height changes at each station are first adjusted by applying physical homogenization using the power-law wind profile. The statistical homogenization is then applied to the adjusted data. A standard normal homogeneity test (SNHT) is particularly utilized. Approximately 40% of inhomogeneities detected by the SNHT match with the sea-level-height change of each station, indicating that an SNHT is an effective technique for reconciling data inhomogeneity. The long-term trends are compared with homogenized data. Statistically significant negative trends are observed along the coast, while insignificant trends are dominant inland. The mean trend, averaged over all stations, is -0.03 ± 0.07 m s-1 decade-1. This insignificant trend is due to a trend change across 2001. A decreasing trend of -0.10 m s-1 decade-1 reverses to an increasing trend of 0.03 m s-1 decade-1 from 2001. This trend change is consistent with mid-latitude wind change in the Northern hemisphere, indicating that the long-term trend of surface wind speed in Korea is partly determined by large-scale atmospheric circulation.

The Dome Technique for Managing Massive Anterosuperior Medial Acetabular Bone Loss in Revision Total Hip Arthroplasty: Short-Term Outcomes

  • Tyler J. Humphrey;Colin M. Baker;Paul M. Courtney;Wayne G. Paprosky;Hany S. Bedair;Neil P. Sheth;Christopher M. Melnic
    • Hip & pelvis
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    • 제35권2호
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    • pp.122-132
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    • 2023
  • Purpose: The dome technique is a technique used in performance of revision total hip arthroplasty (THA) involving intraoperative joining of two porous metal acetabular augments to fill a massive anterosuperior medial acetabular bone defect. While excellent outcomes were achieved using this surgical technique in a series of three cases, short-term results have not been reported. We hypothesized that excellent short-term clinical and patient reported outcomes could be achieved with use of the dome technique. Materials and Methods: A multicenter case series was conducted for evaluation of patients who underwent revision THA using the dome technique for management of Paprosky 3B anterosuperior medial acetabular bone loss from 2013-2019 with a minimum clinical follow-up period of two years. Twelve cases in 12 patients were identified. Baseline demographics, intraoperative variables, surgical outcomes, and patient reported outcomes were acquired. Results: The implant survivorship was 91% with component failure requiring re-revision in only one patient at a mean follow-up period of 36.2 months (range, 24-72 months). Three patients (25.0%) experienced complications, including re-revision for component failure, inter-prosthetic dual-mobility dissociation, and periprosthetic joint infection. Of seven patients who completed the HOOS, JR (hip disability and osteoarthritis outcome score, joint replacement) survey, five patients showed improvement. Conclusion: Excellent outcomes can be achieved using the dome technique for management of massive anterosuperior medial acetabular defects in revision THA with survivorship of 91% at a mean follow-up period of three years. Conduct of future studies will be required in order to evaluate mid- to long-term outcomes for this technique.