• Title/Summary/Keyword: luminescence properties

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Luminescence Properties of $Dy^{3+}-(or Tm^{3+}-)$ Doped $Ga_2O_3$ and $ZnGa_2O_4$ Phosphors

  • Ryu, Ho-Jin;Park, Hee-Dong
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.134-138
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    • 1997
  • $Dy^{3+}-(or Tm^{3+}-)$ doped $Ga_2O_3 \;and\; ZnGa_2O_4$ phosphors were prepared using the solid state reaction method to investigate their photoluminescent characteristics. Under 254 nm excitation, $Dy^{3+}-doped Ga2_O_3$ exhibited two emission bands of 460~505nm and 570~600nm. On the other hand, $Dy^{3+}-(or Tm^{3+}-)$ doped $ZnGa_2O_4 $phosphors exhibited a broad-band emission extending from 330 nm to 610 nm, peaking at about 430 nm(or 370 nm). In this study, an emission peak shift of nealy 50 nm towards longer wavelength region was observed with $Dy^{3+}$ doping in the $ZnGa_2O_4 $.

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Effect of additives on luminescence properties of long-persistence phosphor $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$

  • Han, Sang-Do;Singh, Krishan.C.;Gwak, Ji-Hye;Cho, Tai-Yeon;Kim, Jung-Duk;Han, Chi-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1512-1514
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    • 2007
  • Long afterglow $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$ is synthesized by a solid state reaction. The effect of flux $B_2O_3$ on the sintering dynamic process, the optimum concentrations of $Eu^{2+}$ and $Dy^{3+}$ for long lasting bright luminescence property and the effect of charge compensators like $Mg^{2+}$, $Zn^{2+}$, $Na^+$, $K^+$ on long persistence have been investigated.

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Development of Yb(HFA-D)$_3$Complexes for Liquid Laser Material (액체 레이저 매질로서의 신물질 Yb(HFA-D)$_3$착물의 개발)

  • 김정호;박용필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.12
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    • pp.1045-1050
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    • 2000
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(HFA-D)$_3$]complexes were synthesized by the keto-enol tautomerism reaction of Yb(HFA-H$_3$) in methanol-d$_4$in rder to reduct the radiationless transition to the ligands. The luminescence properties of Yb(HFA-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescnce in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(HFA-D)$_3$complex.complex.

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Electro-luminescence Characteristics of Nano-Structural Thin Film (나노구조 박막의 EL 특성)

  • Choi, Yong-Sung;Cho, Jang-Hoon;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.274-275
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    • 2006
  • A new thin film materials can be built up at the molecular level, and the relationship between these artificial structures and the properties of materials can be explored. In this paper, in order to confirm the application possibility to the molecular electronic device of the organic materials, we have investigated electro-luminescent (EL) characteristics of organic EL device using $Alq_3$, PBD as emitting material. Current and luminance can be seen that express a similar relativity in voltage and could know that luminance is expressing current relativity.

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Synthesis and luminescence of silver doped zinc sulfide phosphor

  • Jeong, Young-Ho;Khatkar, S.P.;Park, Jin-Won;Hua, Yang;Han, Sang-Do
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1013-1016
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    • 2003
  • A new route for the synthesis of silver doped of zinc sulfide phosphor by combustion method has been investigated. Silver nitrate was decomposed with urea or carbohydrazide to give small size particles in presence of alkali metal halides at low temperature compared to the conventional method. The high temperature inherent to the highly exothermic nature of redox reaction leads to well-crystallized powder in short time. The phosphors thus obtained were further heated at $1050^{\circ}C$ in an inert atmosphere for 3hrs to get better luminescence properties.

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Synthesis and luminescence characterization of ZnS:Cu,Al phosphor by combustion method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Park, Jin-Won;Hua, Yang;Han, Sang-Do
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1009-1012
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    • 2003
  • A novel powder processing technique for the preparation of copper activated zinc sulfide (ZnS:Cu,Al) phosphor by combustion process has been proposed. Exothermic reaction between dissolved copper nitrate and carbohydrazide give small-sized particles in presence of alkali metal halides at lower temperature than the traditional method of preparation. This new route takes less than five minutes and requires much less energy. The optical and luminescence characteristics of ZnS:Cu,Al phosphor thus prepared were found to be enhanced significantly. Carbohydrazide acted as fuel at $500^{\circ}C$ with rapid heating and then the phosphors obtained were heated at $900^{\circ}C$ in an inert atmosphere for 3hrs to get better luminescent properties.

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Dependence of luminescence property of ZnMgS:Mn thin film phosphor on RTA temperature (ZnMgS:Mn 박막 형광체의 RTA 온도 변화에 따른 발광 특성 의존성)

  • Lee, Dong-Chin;Yun, Sun-Jin;Jeon, Duk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.102-105
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    • 2004
  • With varying rapid thermal annealing (RTA) temperature, luminescent properties of ZnMgS:Mn thin film sputter-deposited with one target were measured. Although all samples have the same composition, $Zn_{1-x}Mg_xS:Mn$ (x=0.25) can emit luminescence between 580 and 614 nm, which is controlled by only RTA temperature. It is understood that the energy band gap shift of ZnMgS:Mn thin film phosphor occurs with varying RTA temperature.

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One-Pot Synthesis of CdSe Quantum Dots Using Selenium Dioxide as a Selenium Source in Aqueous Solution

  • Wang, Yilin;Yang, Hong;Xia, Zhenyi;Tong, Zhangfa;Zhou, Liya
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2316-2318
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    • 2011
  • A novel technology has been developed for the synthesis of thioglycolic acid (TGA)-capped CdSe quantum dots (QDs) in aqueous medium. The reaction was carried out in air atmosphere with one-pot by using $SeO_2$ to replace Se or $Na_2Se$. The technological parameters including refluxing time, pH values and molar ratios of selenium to cadmium had significant influence on the luminescence properties of CdSe QDs. Furthermore, the obtained QDs were characterized by fluorescent spectroscopy, X-ray powder diffraction (XRD) and transmission electron microscopy (TEM), respectively. The results demonstrated that the CdSe QDs were of zinc-blended crystal structure in a sphere-like shape.

Fluorescent properties and synthesis of porphyrin square recognized methylene crown ether

  • Chang, Seung-Hyun;Kim, Jung-Sung
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.155-158
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    • 2003
  • New porphyrin square (1) was prepared by reaction of porphyrin containing pyridine and Re$(CO)_5Cl$ in THF/toluene solvent. 2-(Methylene15-crown-5)-nicotinoly ester(2) was synthesized by reaction of 2-(Hydroxymethyl-15-crown-5 and nicotinoly chloride in $CH_2Cl_2$. In fluorescence quenching studies luminescence was quenched by addition of the guest(2) into host(l). In the host-guest system we could obtain binding constant (K= $1.13{\times}10^{7}M^{-1}$) at decreasing concentration of (2). But the luminescence was dramatically increased after $Na^{+}$ was added into the host-guest system.

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SiO2/ZnS:Cu/ZnS Triplex Layer Coatings for Phosphorescence Enhancement

  • Zhang, Wen-Tao;Lee, Hong-Ro
    • Journal of the Korean institute of surface engineering
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    • v.41 no.4
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    • pp.169-173
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    • 2008
  • The objective of this study is to coat the $SiO_2$ layer uniformly on the ZnS:Cu phosphors by using Sol-Gel method. From results of SEM micrographs observation, XRD and XPS analysis, it could be confirmed that $SiO_2$ layer was relatively well coated on ZnS:Cu particles. $Ag_2S$ was used as a decoding chemical to analyze the dense and uniform coating performance of $SiO_2$ layer on phosphor particles. It could be concluded that phosphors synthesized from our two step replacement method showed strong blue peak comparing to other method and rather weak green peak also. Obtained particle size of phosphors were about 20m diameter. Luminescence properties of the phosphors were examined by photoluminescence spectra at the excitation wavelength of 270 nm.