• 제목/요약/키워드: lubricants

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폴리올 에스테르 유도체에 대한 합성 윤활유의 제조 및 그의 특성 (Synthesis and Characteristics of Synthetic Lubricants for the Polyol ester derivatives)

  • 이재덕;정노희
    • 한국응용과학기술학회지
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    • 제26권2호
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    • pp.213-223
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    • 2009
  • Conventional additives were added to a newly synthesized base oil to create synthetic lubricants. Commercial polyol ester prepared in this laboratory were obtained as esterification of 1,1,1-trimethylol propane and respectively. This newly synthesized base oil had a variable chemical structure that could achieved the following properties; oxidation or thermal stability, low temperature fluidity, and higher flash points. When compared with commercial mineral lubricants, the synthetic lubricants show superior thermal and oxidation stability, and anti-wear properties.

효소정제의 붕해에 미치는 첨가제의 영향 (Effect of Additives on Disintegration of Enzyme Tablets)

  • 김승환;최문상;차봉진;권종원;민신홍
    • Journal of Pharmaceutical Investigation
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    • 제20권1호
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    • pp.7-12
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    • 1990
  • In case of the slowly disintegrating tablets such as enzyme preparations, disintegration time (DT) may be the important factor in formulating those preparations. The effects of tablet hardness, lubricants and disintegrants on DT were investigated in this approach. Disintegration time was significantly affected by disintegrants, moderately by lubricants, but not by tablet hardness. The effect was in the order of magnesium stearate >talc, PEG, sodium benzoate in case of lubricants, and of Ac-Di-Sol>LHPC>Primogel >Kollidon in case of disintegrants. Because lubricants and disintegrants influenced the tablet hardness and DT profile showed complicated pattern, it should be remembered that all factors mentioned above should be simultaneously considered in the formulation of enzyme tablets.

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자동차용 마찰재에 사용되는 고체 윤활제에 따른 제동특성에 관한 연구 (Effect of Different Solid Lubricants in the Automotive Friction Material on Friction Characteristics)

  • 이정주;장호
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1998년도 제27회 춘계학술대회
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    • pp.328-334
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    • 1998
  • In this work, friction materials with three different formulations containing different amounts of the solid lubricants were investigated to study the role of lubricants on the friction performance. The three friction materials contained graphite 10 vol. %, graphite 7 vol. % + MoS$_2$ 3 vol.%, and graphite 7 vol. % + $Sb_2S_3$ 3 vol. %, respectively, with the same amount of other ingredients. Results of this work showed that each formulation with different lubricants had unique advantages and disadvantages. The friction materials containing graphite 7 vol. % + MoS$_2$ 3 vol. % and graphite 7 % + $Sb_2S_3$ 3 vol. % showed better resistance to fading and improved friction stability compare to the friction materials containing graphite only as a lubricant. However, the friction materials with two lubricants (graphite + MoS$_2$ or $Sb_2S_3$) showed disadvantages on stick-slip phenomena, amplitude of torque, and rotor wear.

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적외선 스펙트럼 측정방식을 이용한 윤활유의 변화연구 (Infrared Spectroscopic Investigation of Lubricants under Shear)

  • 안영재
    • Tribology and Lubricants
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    • 제3권2호
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    • pp.44-49
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    • 1987
  • Molecular alignment has been postulated as influencing non-Newtonian behavior of liquid lubricants containing various additives. Four blended lubricants, two synthetic and two mineral were analyzed by FTIR spectroscopy. All of the lubricants exhibited polarization changes in their infrared emission spectra at 60$\circ$C under shear. For this work a special mockup journal bearing was constructed to seperate load and shear effects. At a temperature of 100$\circ$C polarization by shear was always reduced, presumably by Browninn motion. This work should be useful in pointing to the shear-sensitive factors. The presence of of a VI improving additive is manifested by the independence of the infrared emissivity with temperature at several wavelengths; a lubricant without a VI improver generally shows a decrease of emissivity at higher temperature.

재료 및 윤활제에 따른 전단 마찰 상수값과 평가 (The evaluation of friction factor according to materials and lubricants)

  • 김동진
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1999년도 춘계학술대회논문집
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    • pp.119-124
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    • 1999
  • Quantitative evaluation of the tribological conditions at the tool-workpiece interface in metal forming is usually accomplished by the ring-compressinon. test This paper describes an experimental investigation into shear friction factor under cold and hot forming conditions according to materials and lubricants using the ring compression test. Six different materials and five different lubricants were applied in the experiments. calibration curves with the friction coefficient were obtained using FEM analysis and verified by the verified by the experimental results. The influence of materials and lubricants level on friction are discussed. In the ring compression test the shear friction factor has a different from steels and aluminum water base graphite lubricants on cold working conditions and hot working conditions.

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Advanced Lubricants for Heat Engines

  • Hsu, S.M.;Li, H.;Perez, J.M.;Ku, C.S.;Wang, J.
    • Tribology and Lubricants
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    • 제11권5호
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    • pp.47-54
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    • 1995
  • An advanced liquid lubricants for heat engines has been developed and tested successfully in a prototype engine. The lubricant possesses superior oxidation stability and high temperature stability and is capable of surviving for a minimum of three minutes at 425$^{\circ}$C (800$^{\circ}$C) at the ring zone and maintains stability at an oil sump temperature of 171$^{\circ}$C. The lubricant has been evaluated by the Cummins Engine Co. Out of a field of several dozens of lubricant, six lubricant was selected for a prototype 200 hours endurance testing. The NIST lubricant was one of the two lubricants that successfully finished the endurance testing. This paper describes the key lubricant considerations including oxidation and thermal stability, volatility, deposit control. The engine test conditions and the results will be presented.

흑연과 삼황화안티몬의 상대적인 함량에 따른 비석면 유기질 마찰재의 제동특성에 관한 연구 (Effects of the Relative Amounts of Graphite and Antimony Trisulfide (Sb$_2$S$_3$) on Brake Performance of Non-asbestos Organic (NAO) Type Brake Linings)

  • 김성진;장호
    • Tribology and Lubricants
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    • 제17권5호
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    • pp.351-357
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    • 2001
  • Tribological behavior of NAO type brake linings containing different volume ratios of graphite and Sb$_2$S$_3$ was investigated using a scale dynamometer. Three different test modes consisting of stop, drag, and fade tests were employed to elucidate the effect of the solid lubricants on brake performance. Results of this work showed that the two solid lubricants, graphite and Sb$_2$S$_3$, significantly affected friction characteristics at various braking situations. Compared with the brake linings containing a single lubricant, the brake linings containing both solid lubricants showed better friction stability due to the synergistic effect of the two disparate lubricants during the stop and the drag test. In particular, in the case of containing two solid lubricants, the brake lining with higher contents of graphite showed better fade resistance than others.

ZnDTP를 첨가한 혼합윤활유(광유/식물성 오일)의 마모, 산화 및 전단 특성 (Wear, Oxidation and Shear Characteristics of Mixed Lubricating Oil (Mineral/Vegetable oil) with ZnDTP)

  • 임태윤;김양회;나병기
    • Tribology and Lubricants
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    • 제34권4호
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    • pp.160-167
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    • 2018
  • Vegetable oils can contribute to the goal of energy independence and security owing to their naturally renewable resources. One of the representative vegetable oils is biodiesel, which is being used in domestic and European markets as a blended fuel with automotive diesel. Vegetable oils are promising candidates as base fluids to replace petroleum lubricants because of their excellent lubricity and biodegradability. We prepared biodiesel with a purity of 99.9% via the esterification of waste cooking oil. Blended biodiesel and Petro-lube base oil were mixed to produce five types of mixed lubricating oil. We analyzed the various characteristics of the blended biodiesel with Petro-lube base oil for different blending ratios. The lubricity of the vegetable lubricant improves as the content of biodiesel increases. In addition, since zinc dialkyldithiophosphates (ZnDTPs) are widely used as multifunctional additives in petroleum-based lubricants, we optimized the blending ratio for lubricity, oxidation stability, and shear stability by adding ZnDTP as a performance additive to improve the biodiesel properties, such as oxidation stability and hydrolysis. The optimized lubricants improve by approximately 25% in lubricity and by 20 times in oxidation stability and shear stability after the addition of ZnDTP.

고체윤활제 $Cu_2S$첨가 소결청동의 미끄럼 마찰마모특성 연구 (A Study of Sliding Friction and Wear Properties for Bronze added $Cu_2S$ as Solid Lubricants)

  • 이한영;지영명
    • Tribology and Lubricants
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    • 제23권2호
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    • pp.66-72
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    • 2007
  • [ $MoS_2$ ], is a well-known metal sulfide applied as solid lubricants and an additive to prolong the life of sintered bearings under severe conditions. However, the high price of $MoS_2$ limited its wide application. This study is aimed to investigate the possibility far application to solid lubricants for $Cu_2S$ as a substitute of $MoS_2$. Bronzes added $Cu_2S$ and $MoS_2$, are produced by powder metallurgy in this study, and then evaluated their friction and wear properties., as well as sintered bronze. The sliding wear test using pin-on-disc type machine, was conducted at several sliding speeds for three type test pieces sintered bronzes added $Cu_2S$ and $MoS_2$, and sintered bronze without lubricants. Addition of $Cu_2S$ to bronze leads to relatively good friction properties, although it is not so good as addition of $MoS_2$. However, the wear properies of sintered bronze added $Cu_2S$ are better than that of sintered bronze added $MoS_2$.

Applications of High-Quality Base Oil to Specialty Lubricants

  • Moon, Woo-Sik
    • KSTLE International Journal
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    • 제3권1호
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    • pp.30-37
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    • 2002
  • There have been significant improvements in base oil quality in order to satisfy recent market needs. In particular requirements of passenger car motor oils have been leading the trend. Now, high quality base oils such as VHVI base oils and PAOs are to be formulated in order to meet the tight volatility specifications. The severe hydrocracking, hydro-isomerized dewaxing and hydro-finishing process with noble-metal based catalysts (named UCO lube process) developed by SK corporation has been introduced as one of economic hydroprocessing routes to produce high quality VHVI base oils and food grade white mineral oils from fuels hydrocracker residue. Product quality of UCO lube process is similar to PAO in. general performances and therefore provides satisfactory performance far all straightforward applications in general lubricants. However, when applied to specialty lubricants like transformer oils, spray oils and coning oils, severely hydrocracked base oils are known to have various compatibility problems with gas or surfactants formulated in them. These problems are related to the difference in their composition; inherent high paraffin contents and lack of dissolving ability, Fortunately, it was found that excellent specialty lubricants could be made by carefully selecting and formulating adequate additives and/or aromatic compounds. Moreover, these specialties with high quality VHVI base oils ofter various advantages over conventional base oil based products.