• Title/Summary/Keyword: low-temperature-active

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Control of electrical types in the P-doped ZnO thin film by Ar/$O_2$ gas flow ratio

  • Kim, Young-Yi;Han, Won-Suk;Kong, Bo-Hyun;Cho, Hyung-Koun;Kim, Jun-Ho;Lee, Ho-Seoung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.11-11
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    • 2008
  • ZnO has a very large exciton binding energy (60 meV) as well as thermal and chemical stability, which are expected to allow efficient excitonic emission, even at room temperature. ZnO based electronic devices have attracted increasing interest as the backplanes for applications in the next-generation displays, such as active-matrix liquid crystal displays (AMLCDs) and active-matrix organic light emitting diodes (AMOLEDs), and in solid state lighting systems as a substitution for GaN based light emitting diodes (LEDs). Most of these electronic devices employ the electrical behavior of n-type semiconducting active oxides due to the difficulty in obtaining a p-type film with long-term stability and high performance. p-type ZnO films can be produced by substituting group V elements (N, P, and As) for the O sites or group I elements (Li, Na, and K) for Zn sites. However, the achievement of p-type ZnO is a difficult task due to self-compensation induced from intrinsic donor defects, such as O vacancies (Vo) and Zn interstitials ($Zn_i$), or an unintentional extrinsic donor such as H. Phosphorus (P) doped ZnO thin films were grown on c-sapphire substrates by radio frequency magnetron sputtering with various Ar/ $O_2$ gas ratios. Control of the electrical types in the P-doped ZnO films was achieved by varying the gas ratio with out post-annealing. The P-doped ZnO films grown at a Ar/ $O_2$ ratio of 3/1 showed p-type conductivity with a hole concentration and hole mobility of $10^{-17}cm^{-3}$ and $2.5cm^2/V{\cdot}s$, respectively. X-ray diffraction showed that the ZnO (0002) peak shifted to lower angle due to the positioning of $p^{3-}$ ions with a smaller ionic radius in the $O^{2-}$ sites. This indicates that a p-type mechanism was due to the substitutional Po. The low-temperature photoluminescence of the p-type ZnO films showed p-type related neutral acceptor-bound exciton emission. The p-ZnO/n-Si heterojunction LEO showed typical rectification behavior, which confirmed the p-type characteristics of the ZnO films in the as-deposited status, despite the deep-level related electroluminescence emission.

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A optimization study on the preparation and coating conditions on honeycomb type of Pd/TiO2 catalysts to secure hydrogen utilization process safety (수소 활용공정 안전성 확보를 위한 Pd/TiO2 수소 상온산화 촉매의 제조 및 허니컴 구조의 코팅 조건 최적화 연구)

  • Jang, Young hee;Lee, Sang Moon;Kim, Sung Su
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.47-54
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    • 2021
  • In this study, the performance of a honeycomb-type hydrogen oxidation catalyst to remove hydrogen in a hydrogen economy society to secure leaking hydrogen. The Pd/TiO2 catalyst was prepared based on a liquid phase reduction method that is not exposed to a heat source, and it was showed through H2-chemisorption analysis that it existed as very small active particles of 2~4 nm. In addition, it was found that the metal dispersion decreased and the active particle size increased as the reduction reaction temperature increased. It was meant that the active metal particle size and the hydrogen oxidation performance were in a proportional correlation, so that it was consistent with the hydrogen oxidation performance reduction result. The prepared catalyst was coated on a support in the form of a honeycomb so that it could be applied to the hydrogen industrial process. When 20 wt% or more of the AS-40 binder was coated, oxidation performance of 90% or more was observed under low-concentration hydrogen conditions. It was showed through SEM analysis that long-term catalytic activity can be expected by enhancing the adhesion strength of the catalyst and preventing catalyst desorption. It is a basic research that can secure safety in a hydrogen society such as gasification, organic resource, and it can be utilized as a system that can respond to unexpected safety accidents in the future.

Study on Surface Temperature Change of PV Module Installed on Green Roof System and Non-green Roof System (옥상녹화와 비 옥상녹화 평지붕에 설치 된 PV모듈의 표면온도 변화 고찰)

  • Yoo, Dong-Chul;Lee, Eung-Jik;Lee, Doo-Ho
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.214-219
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    • 2011
  • Today, various activities to save energy are being conducted around the world. Even in our country, carbon reduction policy is being conducted for low carbon green growth and with this movement, effort to replace energy sources by recognizing the problems on environment pollution and resource exhaustion due to the indiscrete usage of fossil fuel is being made. Therefore, active study on renewable energy is in progress as part of effort to replace the energy supply through fossil fuel and solar ray industry has rapidly developed receiving big strength of renewable energy policies. The conclusion of this study measuring the surface temperature change of single crystal and polycrystalline PV module in green roof system and non-green roof system aspect are as follows. There was approximately $4^{\circ}C$ difference in PV module temperature in green roof system and non-green roof system aspect and this has the characteristic to decrease 0.5% when the temperature rises by $1^{\circ}C$ when the front side of the module is $20^{\circ}C$ higher than the surrounding air temperature following the characteristic of solar cells. It can be concluded that PV efficiency will be come better when it is $4^{\circ}C$ lower. Also, in result of temperature measurement of the module back side, there was $5^{\circ}C$ difference of PV module installed on the PV module back side and green roof system side on the 5th, $3^{\circ}C$ on the 4th, $2^{\circ}C$ on the 5th to show decreasing temperature difference as the air temperature dropped, but is judged that there will be higher temperature difference due to the evapotranspiration latent heat effect of green roof system floor side as the temperature rises. Based on this data, it is intended to be used as basic reference to maximize efficiency by applying green roof system and PV system when building non-green roof system flat roof.

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Physio-chemical studies on the seed-browning in mature green peppers stored at low-temperature (Part 2) -Changes in enzymatic activity with the seed-browning effect- (녹숙(綠熟)고추의 저온저장(低溫貯藏)에 따른 종자갈변(種子褐變)에 관(關)한 생리화학적연구(生理化學的硏究) -제 2 보(第 2 報) 종자갈변(種子褐變)에 따른 효소활성(酵素活性)의 변화(變化)-)

  • Lee, Sung-Woo
    • Korean Journal of Food Science and Technology
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    • v.3 no.1
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    • pp.37-43
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    • 1971
  • (1) Relatively active polyphenol oxidase influence was seen at $0{\circ}C$, and the optimal pH level for the enzyme from the seeds of a small type sweet pepper Zairaisisi is 6.5. (2) The starting stage of the brown coloration with low-temperature injuries showed a strong activity of polyphenol oxidase, and the activity drops to 0 as the entire seed became brownish. (3) The browning effect with enzyme solution of polyphenol extracts suggested that the brown coloration continues in vitro even if polyphenol oxidase activity is nil. (4) Although cytochrome oxidase activity dropped when an abnormality occurrs in electron pathways of respiration at the starting stage of the browning with low temperature injuries, there was no marked influence of it on the total respiration, indicating the fact that polyphenol oxidase can take place of terminal oxidase in the compensatory respiration process.

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Induction of antioxygenic enzymes as defense systems in plant cells against low temperature stress : (II) $Mn^{+2}-induced$ SOD activation and enhancement of cold tolerance in rice seedlings (식물의 냉해에 대한 생체방어기구로서 항산소성 효소의 유도 : (II) $Mn^{+2}$이온에 의한 세포내 SOD의 활성화와 벼 유묘의 내냉성 향상)

  • Hahn, Chang-Kyun;Kim, Jong-Pyung;Jung, Jin
    • Applied Biological Chemistry
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    • v.34 no.2
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    • pp.168-173
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    • 1991
  • The uptake of $Mn^{+2}$, a metal cofactor Mn-SOD, by rice seedings resulted in not only a substantial increase in SOD activity in leaf tissues of the plants, but also a significant enhancement of their cold tolerance : the relative extent of the cold tolerance appeared to accord with relative level of the SOD activity. In contrast, $Fe^{+3},\;Cu^{+2}$ and $Zn^{+2}$, which are the cofactors of Fe-SOD and Cu/Zn-SOD, were found to be ineffective for increasing the SOD activity as well as for improving the chilling-resistant capacity of the plants. The results suggest that Mn-SOD, which is most likely induced by its substrate(superoxide) and activated by the presence of $Mn^{+2}$a at high level, is the enzyme acting as an active component of the defense system against low temperature stress in rice plants. In addition, the application of abscisic acid which has been know to protect to some extent certain plants from chilling injury brought about an increase in SOD activity in rice tissues, providing another affirmative information for the crucial role of SOD under the circumstance of cold stress in plants.

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The Comparison of Extraction Process for Enhancement of Immunomodulating Activities of Ulva pertusa kjellman (구멍갈파래의 면역활성 증진을 위한 추출방법 비교)

  • Han, Jae-Gun;Ha, Ji-Hye;Choi, Yeong-Beom;Go, Jeong-Lim;Kang, Do-Hyung;Lee, Hyeon-Yong
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.380-385
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    • 2009
  • The purpose of this study was to investigate the immunomodulatory effect of Ulva pertusa kjellman extract after undergoing a low temperature and high-pressure extraction process. First, the extracts obtained under the extraction conditions of 150 MPa and $80^{\circ}C$showed a relatively high antioxidant activity, with 90% super oxide radical activity compared to the extracts from conventional extraction process with water at $100^{\circ}C$. This extract also improved the growth of both human immune B and T cells up to $14.5{\times}10^4$ cells/mL and $14.2{\times}10^4$ cells/mL compared to $9.1{\times}10^4$ cells/mL in adding the extracts from conventional processes. It was found that the extracts obtained at 100 MPa and $60^{\circ}C$ showed better activities in NK cell growth and NO production from macrophage as $11.8{\times}10^2$ cells/mL and 30.0 ${\mu}M$. Overall, the extracts from high pressure and low temperature extraction process had relatively higher immune activation activity, possibly because the low temperature and high pressure extraction process may have higher yields of active compounds and have less damage to useful ingredients from relatively weak marine natural resources, such as Ulva pertusa kjellmann than that from the conventional extraction system.

A Design and Fabrication of the X-Band Transmit/Receive Module for Active Phased Array SAR Antennas (능동 위상 배열 SAR 안테나를 위한 X-대역 송수신 모듈의 설계 및 제작)

  • Chong, Min-Kil;Kim, Sang-Keun;Na, Hyung-Gi;Lee, Jong-Hwan;Yi, Dong-Woo;Baik, Seung-Hun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.10
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    • pp.1050-1060
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    • 2009
  • In this paper, a X-Band T/R-module for SAR(Synthetic Aperture Radar) systems based on active phased array antennas is designed and fabricated. The T/R modules have a and width of more than 800 MHz centered at X-Band and support dual, switched polarizations. The output power of the module is 7 watts over a wide bandwidth. The noise figure is as low as 3.9 dB. Phase and amplitude are controlled by a 6-bit phase shifter and a 6-bit digital attenuator, respectively. Further the fabricated T/R module has est and calibration port with directional coupler and power divider. Highly integrated T/R module is achieved by using LTCC(Low Temperature Co-fired Ceramic) multiple layer substrate. RMS gain error is less than 0.8 dB max. in Rx mode, and RMS phase error is less than $4^{\circ}$ max. in Rx/Tx phase under all operating frequency band, or the T/R module meet the required electrical performance m test. This structure an be applied to active phase array SAR Antennas.

A Study on Injection Characteristics of High Temperature Fuel through Orifice Injectors (고온 연료의 오리피스 인젝터 분사특성 연구)

  • Lee, Hyung Ju;Choi, Hojin;Kim, Ildoo;Hwang, Ki-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.2
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    • pp.119-126
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    • 2014
  • An experimental study was conducted to study fuel injection characteristics through plain orifice injectors when the fuel was heated to the temperature higher than its boiling point. Three injectors with different orifice diameters were used to measure the flow coefficient (${\alpha}$) for the injection pressure ranges of 3, 5, and 10 bar and the fuel temperature ranges between 50 and $270^{\circ}C$. The study showed that ${\alpha}$ decreases gradually with the fuel temperature below $180^{\circ}C$ while it drops abruptly when the temperature goes beyond $187^{\circ}C$, the boiling temperature of the fuel. The slope of ${\alpha}$ bifurcated at the boiling temperature for different injection pressures, and ${\alpha}$ decreased faster for the lower injection pressure due to the more active boiling in the injector. In addition, the larger orifice diameter had the higher ${\alpha}$ value, and ${\alpha}$ jumped at moderate temperature ranges when the injection pressure was low, implying the turbulent-laminar transition phenomena. The measured ${\alpha}$ was plotted against the cavitation number($K_c$), and the characteristics were independent of the applied pressure for small injectors when the fuel was evaporated before it was injected.

Changes in Growth Characteristics, Biological Activity and Active Compound Contents in Ginseng of Different Ages (재배년수에 따른 인삼의 생육특성, 생리활성, 성분의 변화)

  • Moon, Ji Won;Jang, In Bae;Yu, Jin;Jang, In Bok;Seo, Su Jeoung;Lee, Sung Woo
    • Korean Journal of Medicinal Crop Science
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    • v.27 no.6
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    • pp.383-389
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    • 2019
  • Background: Ginseng has been used as a medicine and functional food since ancient times. It is a perennial crop, and its whose commercial valuse increases with growing period and is affected by the atmosphere and soil environment. Methods and Results: In a selected field, we measured air temperature under a shade structure and soil physicochemical properties, and determied plant and root growth as well as ginsenoside and total polyphenol content of one- to five-year-old ginsengs plants. Although air temperature above 30℃ was recored for more than 37 days, no marked growth inhibition of ginseng was detected. Among all soil physicochemical properties, except for pH, were within the allowable range the shortage increases with ginseng years. In five-year-old ginseng, the quantity is about 9.7% higher than the average weight by standard, indicating that is not affected by temperature when grown under a shade structure. Three-year-old ginseng contained the highest total ginsenoside and total polyphenol levels and exhibited the greatest DPPH radical scavenging activity. Conclusions: The total ginsenoside and protopanaxadiol/protopanaxatriol ratio were both low at five-year-old ginseng plants, which was attributed to rapid growth of the root system in five-year-oid plants. There were no significant differences in total polyphenol content and antioxidant activity between.

Simulation Study on the Application of LNG Cold Energy for Hydrogen Liquefaction Process (수소액화공정에서 LNG 냉열 적용에 관한 시뮬레이션 연구)

  • HAN, DANBEE;BYUN, HYUNSEUNG;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.1
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    • pp.33-40
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    • 2020
  • As hydrogen utilization becomes more active recently, a large amount of hydrogen should be supplied safely. Among the three supply methods, liquefied hydrogen, which is an optimal method of storage and transportation convenience and high safety, has a low temperature of -253℃, which is complicated by the liquefaction process and consumes a lot of electricity, resulting in high operating costs. In order to reduce the electrical energy required for liquefaction and to raise the efficiency, hydrogen is cooled by using a mixed refrigerant in a precooling step. The electricity required for the precooling process of the mixed refrigerant can be reduced by using the cold energy of LNG. Actually, LNG cold energy is used in refrigeration warehouse and air liquefaction separation process, and a lot of power reduction is achieved. The purpose of this study is to replace the electric power by using LNG cold energy instead of the electric air-cooler to lower the temperature of the hydrogen and refrigerant that are increased due to the compression in the hydrogen liquefaction process. The required energy was obtained by simulating mixed refrigerant (MR) hydrogen liquefaction system with LNG cold heat and electric system. In addition, the power replacement rate of the electric process were obtained with the pressure, the temperature of LNG, the rate of latent heat utilization, and the hydrogen liquefaction capacity, Therefore, optimization of the hydrogen liquefaction system using LNG cold energy was carried out.