• Title/Summary/Keyword: low-temperature-active

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Bench-scale Experiment on Catalytic Decomposition of 1,2 Dichlorobenzene by Vanadia-Titania Catalyst

  • Jeong, Ju-Young;Chin, Sung-Min;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.709-714
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    • 2009
  • Catalytic activities of $V_2O_5/TiO_2$ catalyst were investigated under reaction conditions such as reaction temperature, catalyst size, inlet concentration and space velocity. A 1,2-dichlorobenzene(1,2-DCB) concentrations were measured in front and after of the heated $V_2O_5/TiO_2$ catalyst bed, and conversion efficiency of 1,2-DCB was determined from it's concentration difference. The conversion of 1,2-DCB using a pellet type catalyst in the bench-scale reactor was lower than that with the powder type used in the micro flow-scale reactor. However, when the pellet size was halved, the conversion was similar to that with the powder type catalyst. The highest conversion was shown with an inlet concentration of 100 ppmv, but when the concentration was higher or lower than 100 ppmv, the conversion was found to decrease. Complete conversion was obtained when the GHSV was maintained at below 10,000 $h^{-1}$, even at the relatively low temperature of $250^{\circ}C$. Water vapor inhibited the conversion of 1,2-DCB, which was suspected to be due to the competitive adsorption between the reactant and water for active sites.

A Basic Study on Accelerated Life Test Method and Device of DSA (Dimensionally Stable Anode) Electrode (촉매성 산화물 전극 (DSA, Dimensionally Stable Anode)의 가속수명 테스트 방법과 장치에 관한 기초 연구)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.27 no.6
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    • pp.467-475
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    • 2018
  • The lifetime of the electrode is one of the most important factors on the stability of the electrode. Since the lifetime of the DSA (Dimensionally stable anode) electrode is long, an accelerated lifetime test is required to reduce the test time. Beacuse there is no basis or standard method for accelerated lifetime testing, many researchers use different methods. Therefore, there is a need for basis and methods for accelerated lifetime testing that other researchers can follow. We designed a reactor system for accelerated lifetime testing and planned specific methods. Reactor system was circulating batch reactor. Reactor volume and cooling water tank were 12.5 L and 100 L, respectively. Electrode size was $2cm{\times}3cm$ (real electrolysis area, $5cm^2$). In order to maintain the harsh conditions, accelerated lifetime test was carried out in a high current density ($0.6A/cm^2$) and low electrolyte concentration (NaCl, 0.068 mol/L). Maintaining a constant temperature was an important operation parameter for exact accelerated lifetime test. As the accelerated lifetime test progressed, the active component of electrode surface was consumed and desorption occurred. At the point of 5 V rise, corrosion of the surface of the base material(titanium) also started.

Toluene Catalytic Oxidation by Manganese Oxide : (I) Activity and Characterization (망간 산화물에 의한 톨루엔 촉매 산화 반응 : (I) 촉매 반응 및 특성 평가)

  • Cheon Tae-Jin;Kim Hye Jin;Choi Sung-Woo
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.2
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    • pp.161-168
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    • 2005
  • The catalytic oxidation of toluene in low concentration was investigated over manganese oxide/$\gamma$-A1$_{2}$O$_{3}$ catalysts. As increased manganese loading, the conversion of toluene increased at a lower temperature. The 18.2wt$\%$ Mn/$\gamma$-Al$_{2}$O$_{3}$ appeared to be the most active catalyst. XRD results indicated that most of the catalysts exist as MnO$_{2}$ and Mn$_{2}$O$_{3}$ crystalline phase. After the reaction, the used and the fresh catalysts were characterized by XPS. For the used catalyst, a prominent feature has increased. TPR profiles of 18.2 wt$\%$ Mn/$\gamma$-Al$_{2}$O$_{3}$ changed significantly as the manganese loading increased at a lower temperature.

A Study of Thermal and Chemical Quenching of Premixed Flame by Flame-Surface Interaction (화염-표면 상호작용에 의한 예혼합 화염의 열소염 및 화학소염에 관한 연구)

  • Kim, Kyu-Tae;Lee, Dae-Hoon;Kwon, Se-Jin
    • Journal of the Korean Society of Combustion
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    • v.10 no.2
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    • pp.1-8
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    • 2005
  • Incomplete combustion due to quenching in a narrow confinement has been a major problem for realization of a reliable micro combustion device. In most micro combustors, effects of flows are absent in the quenching because the flow is laminar and no severe stretch is present. In such circumstance, quenching is caused either by heat loss or by removal of active radicals to the wall surface of the confinement. An experimental investigation was carried out to investigate the relative significance of these two causes of quenching of a premixed flame. A premixed jet burner with a rectangular cross section at the exit was built. At the burner exit, the flame stands between two walls with adjustable distance. The gap between the two walls at which quenching occurs was measured at different wall surface conditions. The results were analyzed to estimate the relative significance of heat loss to the wall and the removal of radicals at the surface. The measurements indicated that the quenching distance was independent of the wall surface characteristics such as oxygen vacancy, grain boundary, or impurities at low temperature. At high temperature, however, the surface characteristics strongly affect the quenching distance, implying that radical removal at the wall plays a significant role in the quenching process.

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A multisource image fusion method for multimodal pig-body feature detection

  • Zhong, Zhen;Wang, Minjuan;Gao, Wanlin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.11
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    • pp.4395-4412
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    • 2020
  • The multisource image fusion has become an active topic in the last few years owing to its higher segmentation rate. To enhance the accuracy of multimodal pig-body feature segmentation, a multisource image fusion method was employed. Nevertheless, the conventional multisource image fusion methods can not extract superior contrast and abundant details of fused image. To superior segment shape feature and detect temperature feature, a new multisource image fusion method was presented and entitled as NSST-GF-IPCNN. Firstly, the multisource images were resolved into a range of multiscale and multidirectional subbands by Nonsubsampled Shearlet Transform (NSST). Then, to superior describe fine-scale texture and edge information, even-symmetrical Gabor filter and Improved Pulse Coupled Neural Network (IPCNN) were used to fuse low and high-frequency subbands, respectively. Next, the fused coefficients were reconstructed into a fusion image using inverse NSST. Finally, the shape feature was extracted using automatic threshold algorithm and optimized using morphological operation. Nevertheless, the highest temperature of pig-body was gained in view of segmentation results. Experiments revealed that the presented fusion algorithm was able to realize 2.102-4.066% higher average accuracy rate than the traditional algorithms and also enhanced efficiency.

Cryogenic Tensile Behavior of Ferrous Medium-entropy Alloy Additively Manufactured by Laser Powder Bed Fusion

  • Seungyeon Lee;Kyung Tae Kim;Ji-Hun Yu;Hyoung Seop Kim;Jae Wung Bae;Jeong Min Park
    • Journal of Powder Materials
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    • v.31 no.1
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    • pp.8-15
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    • 2024
  • The emergence of ferrous-medium entropy alloys (FeMEAs) with excellent tensile properties represents a potential direction for designing alloys based on metastable engineering. In this study, an FeMEA is successfully fabricated using laser powder bed fusion (LPBF), a metal additive manufacturing technology. Tensile tests are conducted on the LPBF-processed FeMEA at room temperature and cryogenic temperatures (77 K). At 77 K, the LPBF-processed FeMEA exhibits high yield strength and excellent ultimate tensile strength through active deformation-induced martensitic transformation. Furthermore, due to the low stability of the face-centered cubic (FCC) phase of the LPBF-processed FeMEA based on nano-scale solute heterogeneity, stress-induced martensitic transformation occurs, accompanied by the appearance of a yield point phenomenon during cryogenic tensile deformation. This study elucidates the origin of the yield point phenomenon and deformation behavior of the FeMEA at 77 K.

Crystal Structure and Functional Characterization of a Xylose Isomerase (PbXI) from the Psychrophilic Soil Microorganism, Paenibacillus sp.

  • Park, Sun-Ha;Kwon, Sunghark;Lee, Chang Woo;Kim, Chang Min;Jeong, Chang Sook;Kim, Kyung-Jin;Hong, Jong Wook;Kim, Hak Jun;Park, Hyun Ho;Lee, Jun Hyuck
    • Journal of Microbiology and Biotechnology
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    • v.29 no.2
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    • pp.244-255
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    • 2019
  • Xylose isomerase (XI; E.C. 5.3.1.5) catalyzes the isomerization of xylose to xylulose, which can be used to produce bioethanol through fermentation. Therefore, XI has recently gained attention as a key catalyst in the bioenergy industry. Here, we identified, purified, and characterized a XI (PbXI) from the psychrophilic soil microorganism, Paenibacillus sp. R4. Surprisingly, activity assay results showed that PbXI is not a cold-active enzyme, but displays optimal activity at $60^{\circ}C$. We solved the crystal structure of PbXI at $1.94-{\AA}$ resolution to investigate the origin of its thermostability. The PbXI structure shows a $({\beta}/{\alpha})_8$-barrel fold with tight tetrameric interactions and it has three divalent metal ions (CaI, CaII, and CaIII). Two metal ions (CaI and CaII) located in the active site are known to be involved in the enzymatic reaction. The third metal ion (CaIII), located near the ${\beta}4-{\alpha}6$ loop region, was newly identified and is thought to be important for the stability of PbXI. Compared with previously determined thermostable and mesophilic XI structures, the ${\beta}1-{\alpha}2$ loop structures near the substrate binding pocket of PbXI were remarkably different. Site-directed mutagenesis studies suggested that the flexible ${\beta}1-{\alpha}2$ loop region is essential for PbXI activity. Our findings provide valuable insights that can be applied in protein engineering to generate low-temperature purpose-specific XI enzymes.

Poly-Si TFT Technology

  • Noguchi, Takashi;Kim, D.Y.;Kwon, J.Y.;Park, Y.S.
    • Information Display
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    • v.5 no.1
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    • pp.25-30
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    • 2004
  • Poly-Si TFT(Thin Film Transistor) technology are reviewed and discussed. Poly-Si TFTs fabricated on glass using low-temperature process were studied extensively for the application to LCD (Liquid Crystal Display) as well as to OLED(Organic Light Emitting Diode) Display. Currently, one of the application targets of the poly-Si TFT is emphasized on the highly functional SOG(System on Glass). Improvement of device characteristics such as an enhancement of carrier mobility has been studied intensively by enlarging the grain size. Reduction of the voltage and shrinkage of the device size are the trend of AM FPD(Active Matrix Flat Panel Display) as well as of Si LSI, which will arise a peculiar issue of uniformity for the device performance. Some approaches such as nucleation control of the grain seed or lateral grain growth have been tried, so far.

박막트랜지스터 효율 향상을 위한 ZnO 박막의 특성에 대한 연구

  • Park, Yong-Seop;Choe, Eun-Chang;Lee, Seong-Uk;Hong, Byeong-Yu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.63-63
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    • 2009
  • Many researchers have been studied as active and transparent electrode using ZnO (Zinc oxide) inorganic semiconductor material due to their good properties such as wide band-gap and high electrical properties compared with amorphous-Si. In this study, we fabricated ZnO films by the RF magnetron sputtering method at a low temperature for a channel layer in thin-film transistor (TFT) and investigated the characteristics of sputtered ZnO films. Also, the electrical properties of TFT using ZnO channel layer such as field effect mobility(${\mu}$), threshold voltage ($V_{th}$), and $I_{on/off}$ ratio are investigated for the application of the display and electronic devices.

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저온공정을 통한 Pt-silicide SB-MOSFET의 전기적 특성과 공정기술에 관한 연구

  • O, Jun-Seok;Jeong, Jong-Wan;Jo, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.36-36
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    • 2009
  • In this work, we describe a method to fabricate the Pt-silicided SB-MOSFETs with a n-type Silicon-On-Insulator (SOI) substrate as an active layer and demonstrate their electrical and structural properties. The fabricated SB-MOSFETs have novel structure and metal gate without sidewall. The gate oxide with a thickness of 7 nm was deposited by sputtering. Also, this fabrication processes were carried out below $500^{\circ}C$. As a result, Subthreshold swing value and on/off ratio of Fabricated SB MOSFETs was 70 [mV/dec] and $10^8$.

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