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Thermal and Mechanical Properties of OG POSS Filled DGEBA/DDM (OG POSS의 첨가가 DGEBA/DDM의 열적, 기계적 물성에 미치는 영향)

  • Choi, Chunghyeon;Kim, YunHo;Kumar, Sarath Kumar Sathish;Kim, Chun-Gon
    • Composites Research
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    • v.30 no.6
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    • pp.379-383
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    • 2017
  • A study on the low Earth orbit (LEO) space environment have been conducted as a use of composites have increased. Among the LEO environmental factors, atomic oxygen is one of the most critical factors because atomic oxygen can react and erode a surface of polymer-based composite materials. POSS (Polyhedral Oligomeric Silsesquioxane) materials have been widely studied as an atomic oxygen-resistant nanomaterial. In this study, nanocomposites, which are composed of OG (Octaglycidyldimethylsilyl) POSS nanomaterials and DGEBA/DDM epoxy, were fabricated to find out its thermal and mechanical properties. FT-IR results showed that the nanocomposites were fully cured and contained OG POSS enough. Thermogravimetric analysis and differential scanning calorimetry were performed to measure the thermal properties of the nanocomposites. The initial mass loss temperature and char yield were increased through the filling of OG POSS. As the content of OG POSS increased, glass transition temperature tended to increase to 5 wt.% of OG POSS, but the temperature decreased significantly at 10 wt.% of OG POSS. The tensile test results showed that the content of OG POSS did not affect tensile strength and tensile stiffness.

Distribution of Organic Matters and Metallic Elements in the Surface Sediments of Masan Harbor, Korea (마산항 표층 퇴적물의 유기물 및 금속원소의 분포)

  • Hwang Dong-Woon;Jin Hyun-Gook;Kim Seong-Soo;Kim Jung-Dae;Park Jong-Soo;Kim Seong-Gil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.2
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    • pp.106-117
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    • 2006
  • We measured the concentrations of organic matter and metallic elements (Al, Fe, Cr, Mn, Ni, Cu, Zn, As, Cd, Pb and Hg) in the surface sediments of Masan Harbor (in the southern sea, Korea) to evaluate the geochemical characters of sediment and the pollutions by organic matter and metallic elements. The mean grain size of the surface sediments in the study area ranged from $5.6{\phi}$ to $7.8{\phi}$, indicating silt sediment. The water content of the surface sediments exceeded 60% except at some stations. The contents of ignition loss (IL), total organic carbon (TOC) and total nitrogen (TN) ranged from 7.2-14.3%, 1.2-3.2%, and 0.10-0.28%, respectively. Based on the C/N ratios, the organic matter in the surface sediments of Masan Harbor may originate from terrigenous sources including fluvial inputs (mainly sewage in urban areas). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) ranged from $11.3-29.9\;mgO_2/g\;dry$ and 0.20-4.47 mgS/g dry, respectively, and low concentrations were observed near a shipping route. In addition, the concentrations of metallic elements showed large spatial variations in Masan Harbor and the distributions of metallic elements were also comparable to those of organic matter. This implies that the distributions of organic matter and metallic elements in the surface sediments of Masan Harbor are mainly controlled by biogenic matter and artificial action (mainly dredging). In addition, we calculated the enrichment facto. (EF) and geoaccumulation index (Igeo) in order to evaluate pollution by metallic elements. The enrichment of metallic elements relative to Al was three to eighteen times higher at the study sites, compared to levels in the Earth's crust except for Fe, Ni and Mn. In addition, the Igeo class indicated that the surface sediments in the study area were moderately to strongly polluted in terms of metallic elements.

Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea (한국 서해남부 조간대 표층 퇴적물의 지화학적 특성)

  • Hwang, Dong-Woon;Ryu, Sang-Ok;Kim, Seong-Gil;Choi, Ok-In;Kim, Seong-Soo;Koh, Byoung-Seol
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.2
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    • pp.146-158
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    • 2010
  • In order to evaluate the characteristics of sediments and pollution by organic matter and metallic elements in intertidal sediments along the southwestern coast of Korea, we measured various geochemical parameters, including the mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and metallic elements (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, As), in intertidal surface sediments. The Mz of the surface sediments ranged from 2.1 to 8.3$\phi$, indicating that the surface sediments consist of various sedimentary facies, such as sand, slightly gravelly mud, sandy mud, and silt. The IL and COD in surface sediment ranged from 0.8 to 5.5% (mean $2.9\pm1.2%$) and from 3.9 to $13.8\;mgO_2/g{\cdot}dry$ (mean $8.5\pm2.6\;mgO_2/g{\cdot}dry$), respectively, which were lower than the values for surface sediment in areas near fish and shellfish farms or industrial complexes. No AVS was detected at any sampling station, despite various sedimentary facies. Most of metallic elements in surface sediments showed relatively good positive correlations with Mz and IL, which imply that the concentrations of metallic elements are mainly controlled by grain size and the organic matter content. The concentrations of metallic elements, except As, at some stations were considerably lower than those in the Sediment Quality Guideline (Effect Range Low, ERL) proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Similarly, the geoaccumulation index (Igeo) class indicated that pollution by metallic elements in intertidal surface sediment, except As, was moderate or non-existent. Our results imply that the intertidal surface sediments along the southwestern coast of Korea are not polluted by organic matter and metallic elements and are healthy for benthic organisms.

Relationships between Health, Depression, Memory Self-Efficacy and Metamemory in Adults (성인의 건강, 우울, 기억, 자기효능과 메타기억과의 상관관계 연구)

  • Kim, Jeong-Hwa;Kang, Hyun-Sook
    • The Korean Journal of Rehabilitation Nursing
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    • v.1 no.1
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    • pp.61-71
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    • 1998
  • Defining prediction variables related to metamemory for the adults in aging process has worthwhile meaning from the perspective that the produced results can be helpful to reducing the difficulty of memorizing efforts and it can also enhance quality of life of aged. This study attempted to analysis relationship between perceived health status, depression, memory self-efficacy and meta memory for the subjects of middle age and old age adults. This study was designed by adopting descriptive correlational analysis method for the 468 middle and old age adults who are living in Seoul. Samples were selected by convenience sampling. Data collection was done over 1 month period in june 1998. The instruments used in this study were health status measuring scale including depression measuring scale, memory self efficacy measuring scale and metamemory measuring scale which were verified for reliability. Data collected were analized by using SPSS for frequency, Peason correlation, t-test and ANOVA according to the variables character and the study purposes. Results of the study were as follows. 1. Relationship between perceived health status, depression, memory self-efficacy and metamemory. Relational analyses between perceived health status, depression, memory self-efficacy and metamemory supported the hypotheses of 1st, 2nd and 3rd(p < .01). These results suggested that the aged perceived great health status then their memory self-efficacy, and metamemory showed the high scores. In the case of depression when its level became decreased metamemory was inclined to increased. Thus, it is identified that strong relationship exists between these variables. 2. Perceived health status, depression, memory self-efficacy by subject's general characteristics. Scores of perceived health status were high in the group of man compared to the group of women, and also highly educated group showed great perceived health status. Group of persons having occupation showed high score of perceived health status and low depression score. The score of memory self-efficacy and metamemory showed higher in the middle aged than the old aged. The high scores of memory self-efficacy and metamemory were found in the group of highly educated people and who have continuing education. The high scores of memory self-efficacy were found in the group of persons having their job and high metamemory scores found in the group of persons having religion. In summary, the greater perceived health status and memory self-efficacy, the more metamemory scores were likely increased and the more depression level was decreased, the more metamemory was likely increased. Also it was found that general characteristics like educational level, continuing education and religion influenced the metamemory of the aged. Therefore, prevention the aged from getting depression and activation of health promotion are needed to delay time of memory loss.

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Comparative Analysis of pre and Post Digital X-ray Equipment Construction and Web-Based Wireless Network Environment Construction for Medical Screening Vehicles (Digital X-ray장비 구축 검진차량의 웹 기반 무선 네트워크 환경 구축 전과 후의 비교분석)

  • Ryu, Young-Hwan;Kweon, Dae-Cheol;Goo, Eun-Hoe;Dong, Kyung-Rae;Choi, Sung-Hyun;Jang, Young-Ill
    • Korean Journal of Digital Imaging in Medicine
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    • v.12 no.2
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    • pp.103-111
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    • 2010
  • A total of 200 hospital employees participated in this study from January 2009 to June 2010. For the survey, each participant was given necessary items for external health exams. Cronbach's alpha was calculated for the survey regarding wireless networks. There was a need for educating data processing workers in the medical field regarding fundamental information prior to wireless network construction. The reason is high scores would be collected, which would reflect knowledge regarding data processing used at hospitals and the differences between paper charts and electronic charts. However, low scores were obtained which reflected knowledge regarding the differences between wired and wireless networks and Mini-PACS. Time for each patient was shortened to a maximum of three minutes and minimum of one minute for treatment and transmitting medical images when comparing pre and post wireless network construction(p < 0.01). Scores from the pre and post construction survey increase 1.98, 1.65, and 1.43 points for activity in the health screening area, usage of space in the health screening vehicle, and patient information storage respectively(p < 0.05). The number of patients receiving external health screenings twelve times was 3,655 prior to construction of a wireless network system. However, the number increased to 4,265 after construction. The increasing percentage was 17% in total. Prior to construction, X-ray images were taken 527 times, but after construction of a wireless network, this number growed to 1,194 and it was 116% increase. The loss of patient's medical treatment charts was reduced from 19.8% to 18.7% after construction. We believe that educating medical workers on Mini-PACS and Mini-OCS Systems will not only increase their efficiency but also make patients receiving better treatment.

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Studies on the Selenium Type and Metabolism of Selenium Accumulation in the Selenium-Enriched Mushroom, Flammulina Velutipes, and Its Spent Mushroom Composts (셀레늄 강화 팽이버섯과 폐배지의 셀레늄 형태 및 팽이버섯내 셀레늄 축적대사에 관한 연구)

  • Lee, S.H.;Kwak, W.S.;Kim, W.Y.
    • Journal of Animal Science and Technology
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    • v.47 no.2
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    • pp.305-316
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    • 2005
  • This study was conducted to determine the total amount and type of seleniwn (Se) in the Se-enriched mushroom and its spent mushroom composts (SMC), and to investigate the metabolism in relation to Se accwnulation in the mushroom. Mushrooms, Flammulina velutipes, used in this study were grown for 60 days by adding 2 rng of inorganic Se (Na2Se03) per kg of mushroom composts (MC) on as-fed basis and were compared with normal mushrooms grown on the non Se-supplemented Me. Total Se contents for Se-treated mushrooms were significantly increased (P < 0.0001) by 20-fold (4.51 $\mu$/ g of dry) compared to Se-untreated (0.23 $\mu$/ g of dry). On the contrary, organic Se ratio was significantly lower (P < 0.0001) in the Se-treated mushroom (72.3 %) than the Se-untreated one (100 %, not analytically detected of inorganic Se). Se distribution upon a length in the Se-treated mushrooms was the highest in the bottom part (6.86 $\mu$/ g of dry) near to MC, and top and middle parts were significantly lower (3.71 and 3.01 $\mu$/ g of dry, respectively; P < 0.001) than the bottom. In the SMC from Se-treated mushrooms, the significant amount of Se (5.04l1g/g of dry) was remained, but that from the Se-untreated mushrooms was significantly low (P$\mu$ / g of dry. Se-treated SMC showed a high ratio of organic Se (65.67 %), suggesting that the significant amount of inorganic Se in the SMC was converted to organic Se by mushroom mycelia. Prior to mycelia inoculation in the mushroom culture, the sterilization of MC brought approximately 18% of Se loss in the MC. Apparent and net accumulation rates (%) for Se into mushrooms were 14.81 and 10.14 %, respectively, resulting from the Se volatilization into the air via metabolic process of mushroom itself. The result of this study shows that inorganic Se addition to MC for mushroom improved the organic Se contents in the mushroom and SMC. This study showed the possibility that Se in Se-enriched mushroom and SMC could be utilized as Se sources of food for human as well as feed for livestock.

Optimization of the Unducted Auxiliary Ventilation for Large-Opening Underground Limestone Mines (대단면 지하 석회석 광산내 무풍관 국부통기 최적화 연구)

  • Nguyen, Van Duc;Lee, Chang Woo
    • Tunnel and Underground Space
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    • v.29 no.6
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    • pp.480-507
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    • 2019
  • This paper aims at optimizing the auxiliary ventilation system in large-opening limestone mines with unducted fans. An extensive CFD and also site study were carried out for optimization at the blind entries. The fan location, operating mode, and layout are the parameters for optimization. Since the jet stream discharged from the auxiliary fan is flowing faster than 15 m/s in most of the cases, the stream collides with floor, sides or roof and even with the jet stream generated from the other fan placed upstream. Then, it is likely to lose a large portion of its inertial force and then its ventilation efficiency drops considerably. Therefore, the optimal fan installation interval is defined in this study as an interval that maximizes the uninterrupted flowing distance of the jet stream, while the cross-sectional installation location can be optimized to minimize the energy loss due to possible collision with the entry sides. Consequently, the optimization of the fan location will improve ventilation efficiency and subsequently the energy cost. A number of different three-dimensional computational domains representing a full-scale underground space were developed for the CFD study. The velocity profiles and the CO concentrations were studied to design and optimize the auxiliary ventilation system without duct and at the same time mine site experiments were carried out for comparison purposes. The ultimate goal is to optimize the auxiliary ventilation system without tubing to provide a reliable, low-cost and efficient solution to maintain the clean and safe work environment in local large-opening underground limestone mines.

Performance Analysis of Shell Coal Gasification Combined Cycle systems (Shell 석탄가스화 복합발전 시스템의 성능해석 연구)

  • Kim, Jong-Jin;Park, Moung-Ho;Song, Kyu-So;Cho, Sang-Ki;Seo, Seok-Bin;Kim, Chong-Young
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.104-113
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    • 1997
  • This study aims to develop an analysis model using a commercial process simulator-ASPEN PLUS for an IGCC (Integrated Gasification Combined Cycle) system consisting a dry coal feeding, oxygen-blown entrained gasification process by Shell, a low temperature gas clean up process, a General Electric MS7001FA gas turbine, a three pressure, natural recirculation heat recovery steam generator, a regenerative, condensing steam turbine and a cryogenic air separation unit. The comparison between those results of this study and reference one done by other engineer at design conditions shows consistency which means the soundness of this model. The greater moisture contents in Illinois#6 coal causes decreasing gasifier temperature and the greater ash and sulfur content hurt system efficiency due to increased heat loss. As the results of sensitivity analysis using developed model for the parameters of gasifier operating pressure, steam/coal ratio and oxygen/coal ratio, the gasifier temperature increases while combustible gases (CO+H2) decreases throughout the pressure going up. In the steam/coal ratio analysis, when the feeding steam increases the maximum combustible gas generation point moves to lower oxygen/coal ratio feeding condition. Finally, for the oxygen/coal ratio analysis, it shows oxygen/coal ratio 0.77 as a optimum operating condition at steam/coal feeding ratio 0.2.

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Chemoradiotherapy versus radiotherapy alone following induction chemotherapy for elderly patients with stage III lung cancer

  • Kim, Dong-Yun;Song, Changhoon;Kim, Se Hyun;Kim, Yu Jung;Lee, Jong Seok;Kim, Jae-Sung
    • Radiation Oncology Journal
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    • v.37 no.3
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    • pp.176-184
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    • 2019
  • Purpose: It is unclear whether adding concurrent chemotherapy (CT) to definitive radiotherapy (RT) following induction CT is a tolerable and cost effective treatment for non-small-cell lung cancer (NSCLC) patients aged 70 years or older with comorbidities. This study evaluated the actual clinical outcomes between concurrent chemoradiotherapy (CCRT) and RT alone following induction CT or not in patients (≥70 years) in a single institution's clinical practice. Materials and Methods: A total of 82 patients with unresectable stage III NSCLC between 2004 and 2016 were retrospectively analyzed. Their treatment tolerance and clinical outcomes such as overall survival (OS), locoregional recurrence (LRR), treatment toxicities and distant metastasis (DM) were evaluated. Early mortality rates were also evaluated as 4-month mortality after RT. Results: Fifty-four patients received CCRT and 28 patients received RT alone. Induction CT before RT was performed for 68.5% and 50.0% in CCRT and RT alone groups. Treatment tolerance was significantly worse in CCRT (p = 0.046). The median survival was 21.1 and 18.1 months for CCRT and RT alone, which was not statistically significant. LRR and DM were also not different. Most early deaths after CCRT were attributed to non-cancer-related mortality. Acute esophagitis of grade ≥2 occurred more following CCRT (p = 0.017). In multivariate analysis, a Charlson Comorbidity Index (CCI) of ≥5 and a weight loss of ≥5% after RT were associated with poor OS. The factors adversely affecting 4-month survival were a CCI of ≥5 and CCRT. Conclusion: There were no significant differences in OS, LRR, and DM between CCRT and RT alone treatment in elderly patients. However, there was a poorer tolerance and higher incidence of acute esophagitis in the CCRT group. Specifically, when the patients had a CCI of ≥5, RT alone seems to be reasonable with a low probability of early death.

Effects of Development Time and Severity of Rice Ear Blight on Rice Yield and Quality (벼 이삭마름병 발병시기와 정도가 수량 및 품질에 미치는 영향)

  • Shim Hong-Sik;Hong Sung-Jun;Hong Sung-Gi;Kim Yong-Ki;Ye Wan-Hae;Sung Jae-Mo
    • Research in Plant Disease
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    • v.12 no.1
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    • pp.5-9
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    • 2006
  • Grain discoloration, caused by several microorganisms, is a minor disease, but it is gaining importance in almost all rice growing areas of the world in recent years. Such grains are of low market value and consumption appeal in addition to their abnormal performance as seed of source of nutrient value. When the casual agents were inoculated on rice plant,'Ilmi-byeo'(at right before heading time and on heading time), the incidence of rice ear blight caused by Alternaria alternate and Nigrospora oryzae was higher in a plot inoculated at right before heading time than (in n plot inoculated) on heading time. Meanwhile, the incidence of rice ear blight caused by Bipolaris oryzae and Curvularia lunate was higher in a plot inoculated on heading time than in a plot inoculated at right before heading time. In rice quality, the ratio of imperfect grains was increased at right before heading time or on heading time by Nigrospora oryzae or Alternaria alternata, respectively. As discoloration rate of rice grains increased on 'Ilmi-byeo', the percentage of perfect grains decreased proportionally and the percentage of damaged rice grains increased remarkably.