• Title/Summary/Keyword: low-VOC

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Effect of Solvent Extraction on the Low Molecular Weight and Volatile Organic Compounds of Polycarbonate (폴리카보네이트의 저분자량 화합물 및 휘발성 유기물에 대한 접촉추출 영향)

  • Choi, Su-Jung;Yoon, Kyung-Hwa;Hwang, In-Hye;Lee, Chang-Young;Kim, Hee-Seung;Yoo, Seung-Yoon;Kim, Youn-Cheol
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.532-536
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    • 2010
  • A study on the volatile organic compounds (VOCs) and low molecular weight (LMW) amount which is contained within bisphenol A polycarbonate (PC) was performed by the solvent extraction with ketone type solvents (acetone, butanone, pentanone). The LMW amount of untreated PC was 2.6 wt%, but the values of treated samples with acetone and pentanone were 0.96 and 1.53 wt%, respectively. Acetone is a more effective solvent than pentanone on the LMW extraction. Methylene chloride (MC) and toluene were certified and quantified by GC-Mass experiments, and the quantitative results indicated the fact that the pentanone was the effective solvent on VOC extraction. Focused on the change of VOCs and LMW amount, the use of co-solvent might be more useful, and the experimental results of co-solvent extraction showed that the optimum condition was 50 : 50 volume percent.

Preparation of nanoparticles CuInSe2 absorber layer by a non-vacuum process of low cost cryogenic milling (저가의 cryogenic milling 비진공법을 이용한 나노입자 CuInSe2 광흡수층 제조)

  • Kim, Ki-Hyun;Park, Byung-Ok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.108-113
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    • 2013
  • Chalcopyrite material $CuInSe_2$ (CIS) is known to be a very prominent absorber layer for high efficiency thin film solar cells. Current interest in the photovoltaic industry is to identify and develop more suitable materials and processes for the fabrication of efficient and cost-effective solar cells. Various processes have been being tried for making a low cost CIS absorber layer, this study obtained the CIS nanoparticles using commercial powder of 6 mm pieces for low cost CIS absorber layer by high frequency ball milling and cryogenic milling. And the CIS absorber layer was prepared by paste coating using milled-CIS nanoparticles in glove box under inert atmosphere. The chalcopyrite $CuInSe_2$ thin films were successfully made after selenization at the substrate temperature of $550^{\circ}C$ in 30 min, CIS solar cell of Al/ZnO/CdS/CIS/Mo structure prepared under various deposition process such as evaporation, sputtering and chemical vapor deposition respectively. Finally, we achieved CIS nanoparticles solar cell of electric efficient 1.74 % of Voc 29 mV, Jsc 35 $mA/cm^2$ FF 17.2 %. The CIS nanoparticles-based absorber layers were characterized by using EDS, XRD and HRSEM.

Tightness of specimen sealing box in 20 L test chamber to evaluate building materials emitting pollutants (건축자재에서 방출되는 오염물질 평가 시 사용되는 20 L 시험챔버 시편홀더의 기밀성 개선)

  • Shin, Woo Jin;Lee, Chul Won;Kim, Man Goo
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.261-267
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    • 2007
  • The 20 L small chamber test method is to evaluate pollutants such as TVOC, formaldehyde emitted from building materials. This method was only designed to evaluate the surface emission of sample exposed in the chamber. In this method, building materials cut with a fixed standard size are fixed in a sample sealing box. The sample sealing box is put into the 20 L test chamber. This chamber is ventilated at a standard air change rate with purified air for 7 days then the sample from the chamber is collected and analyzed to measure the emission rate of TVOC and formaldehyde. In this method, however, if the sealing box does not guarantee airtightness, accurate evaluation for the building materials can not be achieved due to the pollutants emitted from edge of the sample so called, edge effect. This edge effect can be much greater when evaluating panels such as plywood, flooring due to their surface treatment. In this study, flooring was tested to check airtightness of the sample sealing box with analytic results between 1L and 20 L test chamber. Furniture materials like LPM coated one side surface treatment and MDF coated both sides surface treatment with LPM were tested to identify whether the improvement of the sample sealing box airtightness is possible with the comparison between existing and improved test method that low VOC emission tape was used to seal the sample edge. After 7 days, MDF TVOC emission rate was different according to the existence and nonexistence of tape. The emission rate of the existing test method was $0.009mg/m^2h$ and that of improved test method was $0.003mg/m^2h$. Relative standard deviation for the existing test method was $0.004mg/m^2h$ and relative standard deviation for the improved test method was $0.002mg/m^2h$ when the same sample was analyzed three times. The improved test method in this study using low VOC emission tape was effective and able to reduce the heterogeneous effect of the edge from the sample sealing box.

Investigated properties of Low temperature curing Ag Paste for Silicon Hetero-junction Solar Cell

  • Oh, Donghyun;Jeon, Minhan;Kang, Jiwoon;Shim, Gyeongbae;Park, Cheolmin;Lee, Youngseok;Kim, Hyunhoo;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.160-160
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    • 2016
  • In this study, we applied the low temperature curing Ag paste to replace PVD System. The electrode formation of low temperature curing Ag paste for silicon Hetero-junction solar cells is important for improving device characteristics such as adhesion, contact resistance, fill factor and conversion efficiency. The low temperature curing Ag paste is composed various additives such as solvent, various organic materials, polymer, and binder. it depends on the curing temperature conditions. The adhesion of the low temperature curing Ag paste was decided by scratch test. The specific contact resistance was measured using the transmission line method. All of the Ag electrodes were experimented at various curing temperatures within the temperature range of $160^{\circ}C-240^{\circ}C$, at $20^{\circ}C$ intervals. The curing time was also changed by varying the conditions of 10-50min. In the optimum curing temperature $200^{\circ}C$ and for 20 min, the measured contact resistance is $19.61m{\Omega}cm^2$. Over temperature $240^{\circ}C$, confirmed bad contact characteristic. We obtained photovoltaic parameter of the industrial size such as Fill Factor (FF), current density (Jsc), open-circuit voltage (Voc) and convert efficiency of up to 76.2%, 38.1 mA/cm2, 646 mV and 18.3%, respectively.

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Power Supply for USN by Using SMD Type Solar Cell Array (SMD 타입 태양전지 어레이를 이용한 USN용 전원 공급 장치)

  • Kim, Seong-Il
    • New & Renewable Energy
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    • v.5 no.3
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    • pp.22-25
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    • 2009
  • For increasing the output voltage, six SMD(surface mount device) type AlGaAs/GaAs solar cells were connected in series. The electrical properties of the array were measured and compared with one sun (100 mW/$cm^2$) and indoor light (480 lux) conditions. Under one sun condition, output power was 21.57 mW and it was $14.67\;{\mu}W$ under indoor light condition. Under the indoor light condition, the intensity of the light is very low compared to one sun condition. Thus the Voc(open circuit voltage) and Isc (short circuit current) of the sample under indoor light condition decreased very much compared to that of under the one sun condition. This kind of solar cell power supply can be used as a power source for ubiquitous sensor network (USN).

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Correlation between surface functionalities of nano-structured photo electrode and electrochemical response of dye sensitized solar cells

  • Dhayal, Marshal;Park, Gye-Choon;Park, Kyung-Hee;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.57.1-57.1
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    • 2010
  • Development of low cost hybrid functional nano-structured materials has great interest to enhance sensitivity of dye-sensitized solar cells and reduction of the production cost. In this talk we will discuss about using different processes to modify functional characteristics of photoelectrode and investigate effects of chemical modification without significant structural variation on to enhance performance of DSSCs. Efficient electron transportation between dye molecules and photoelectrode has been obtained by appropriate chemical modification and efficiency of DSSC has been significantly improved. A comparative analysis on effects of surface functional and electron states of photoelectrode on VOC and JSC has been also carried out to discuss effects of composite materials on physical structure and electronic properties to correlate enhanced performance of these devices.

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Development of a flexible solar cell fiber by using an organic-inorganic hybrid materials (${\codt}$ 무기 하이브리드 재료를 이용한 플렉서블 태양전지 섬유의 개발)

  • Song, Jun-Hyung;Kim, Joo-Yong;Park, Jung-Hyun;Kim, Gu-Young;Kim, Young-Kwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.299-301
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    • 2007
  • An organic-inorganic hybrid solar cell fibers with characteristics such as formability, low-cost and tailorability was developed by deposition of C60 and CuPc on fiber surface. In spite of some variation according to the temperature of ITO deposition, the maximum open circuit voltage of 0.39V was attained at $150^{\circ}C$(1000end). The resulting solar cell showed the performances Isc=0.482, Voc=0.320, FF=0.285 ${\eta}_{e}=0.044$% which are comparable to one of other types of solar cells in literature.

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Down-Conversion Effect Applied to GaAs p-i-n Single Junction Solar Cell

  • Park, Jun-Seo;Kim, Ji-Hun;Go, Hyeong-Deok;Lee, Gi-Yong;Kim, Jeong-Hyeok;Han, Il-Gi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.694-694
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    • 2013
  • With the growing need of more effective energy harvesting, solar energy has been sought as one of the prominent candidates among the eco-friendly methods. Although many types of solar cells have been developed, the electronic conversion efficiency is limited by the material's physical properties: solar cells can only harvest solar energy from limited range in solar energy spectrum. To overcome this physical limit, we approached by using the down conversion effect, transforming the high energy photons to low energy photons, to the range the designated solar cell can convert to electronic energy. In our study, we have fabricated GaAs single junction solar cells and applied CdSe quantum dots for down-conversion. We examine the effects of such application on the solar cell efficiancy, fill-factor, JSC, VOC, etc.

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Simultaneous Control of Dust and Gases Using a Double Centrifugal Device (이중 원심력 집진장치를 이용한 분진-가스 동시 처리)

  • Jang, Jung-Hee;Lee, Ju-Heon;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.3
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    • pp.336-345
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    • 2008
  • A large volume of work has been attempted to improve the separation efficiency of cyclone by establishing new design and optimum operation. An auxiliary device called Post Cyclone (PoC) has been introduced and tested in an earlier work (In order to reduce the emission of fine dust from the reverse flow cyclones). This work applies the PoC to remove the dust and gaseous elements using a centrifugal effect remained in the discharging flow over the cyclone. As a result of the experiment, the efficiency was found best at the high gas concentration and low inlet velocity.

Development of a novel VI Tracer using Visual C++ (Visual C++을 이용한 VI Tracer 개발)

  • Lee, Jae-Deuk;Kim, Bong-Tae;Park, Min-Won;Sung, Ki-Chul;Yu, In-Keun
    • Proceedings of the KIEE Conference
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    • 2001.07b
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    • pp.1306-1308
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    • 2001
  • Hardware and software studies strongly indicate the feasibility of commercially producing a low cost, user-friendly photovoltaic cell curve tracer. The instrument will be used in conjuntion with an IBM compatible PC. The system will show not only the parameters; Voc, Isc, FF, Iop, Vop, that the conventional VI tracer shows but also the internal parasitic resistance and the detail parameters.

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