• Title/Summary/Keyword: low temperature composition

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Structural and Magnetic Properties of NixZnyFe3-x-yO4 Films Prepared by Spin-Spray Ferrite Plating Method (스핀 스프레이 페라이트 플레이팅법으로 제작한 NixZnyFe3-x-yO4 박막의 결정학적 및 자기적 특성)

  • Kim, Myung-Ho;Jang, Kyung-Uk
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.51 no.2
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    • pp.82-86
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    • 2002
  • A series of $Ni_xZn_yFe_{3-x-y}O_4$ films were prepared by spin-spray ferrite plating on glass substrates from aqueous solution at $90[^{\circ}C]$. The magnetic properties in terms of contents of Ni and Zn in the plated films are presented. All the films are polycrystalline with spinel structure. At x+y=0.58, the film presents preferential orientation. As composition of y in the films increases grain size and void in the films increases, while saturation magnetization and coercive force of the films decrease.

Effect of Impurities in Grain Boundary Phases on Wear Behavior of $Si_3N_4$ (질화규소의 입계상에 존재하는 불순물이 마모에 미치는 영향)

  • 오윤석;임대순;이경호
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.277-284
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    • 1996
  • The water test results indicated that the impurities had detrimetal effect on the wear resistance of silicon nitride and the effects were getting severe as the temperature increased. Especially when Ca existed as an impurity the detrimental effects was the most severe. These results were resulted from the fact that impurities lowered the mechanical properties of the grain boundary phase of silicon nitride. The wear test results of glass/glass-ceramic specimens having a similar composition to the grain boundary phase of silicon nitride revea-led that the specimen containing CaO showed the lowest wear resistance. The existence of Fe and Ca at the grain boundary phase assisted forming a grain boundary phase with relatively low refractoriness. Therefore at a given wear condition the removal of deformed layer would be easier. The results showed that the glass phases could be modified by heat-treatment and this modification improved tribological characteristics of the silicon nitride.

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Crystal Growth and Phase Transition of Piezoelectric $KAlSiO_4$ (압전성 $KAlSiO_4$ 단결정 육성 및 상변화)

  • 오광석;박봉모;정수진;이태근;박병규;김호성
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.362-370
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    • 1996
  • Kalsilite (KAlSiO4) system undergoes a displacive phase transition from hexagonal phase with p63 space group to the phase with P63mc at 886$^{\circ}C$. The flux composition having kalsilite :K2O:B2O3=1:2:2 has enabled the growth of hexagonal kalsilite with the size of 0.5~1 mm at a slow cooling rate (0.3$^{\circ}C$/hr). On decreasing the cooling rate the size has increased and pyramidal (1011) faces are newly developed with the shape of (0001) and (1010) faces. Upon stirring (1011) faces are degraded. The space group of O1 and O2 are P21221 and C2221 respectively. Their orthorombic modification O1 and O2 are synthesized at relatively low and high temperature respectively.

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Effects of Intermediate Layer in DLC Thin Film on Al2O3 for Improvement of High Temperature Strength

  • Ok, Chul-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.125-130
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    • 2007
  • DLC coating on ceramics is very useful for manufacturing the materials with hardness and low friction. Adhesion of DLC thin film on ceramics, on the other hand, is usually very weak. Adhesion of DLC film depends on many parameters such as contamination and chemical bonding between thin film and substrate. In this study, adhesion of DLC film on ceramics was improved by the intermediate layer when the plasma immersion ion deposition (PIID) technique was applied. It is found that the chemical composition and the thickness of intermediate layer have significantly an effect on the adhesion of DLC thin film on $Al_2O_3$.

PC/ASA blends having enhanced interfacial and mechanical properties

  • Kang, M.S.;Kim, C.K.;Lee, J.W.
    • Korea-Australia Rheology Journal
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    • v.18 no.1
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    • pp.1-8
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    • 2006
  • Blend of bisphenol-A polycarbonate (PC) and (acrylonitrile-styrene-acrylic rubber) terpolymer (ASA) having excellent balance in the interfacial properties and mechanical strength was developed for the automobile applications. Since interfacial adhesion between PC and styrne-acrylonitrile copolymer (SAN) matrix of ASA is not strong enough, two different types of compatibilizers, i.e, diblock copolymer composed of tetramethyl polycarbonate (TMPC) and SAN (TMPC-b-SAN) and poly(methyl methacrylate) (PMMA) were examined to improve interfacial adhesion between PC and SAN. TMPC-b-SAN was more effective than PMMA in increasing interfacial adhesion between PC and SAN matrix of ASA (or weld-line strength of PC/ASA blend). When blend composition was fixed, PC/ASA blends exhibited similar mechanical properties except impact strength and weld-line strength. Impact strength of PCI ASA blend at low temperature was influenced by rubber particle size and its morphology. PC/ASA blends containing commercially available PMMA as compatibilizer also exhibited excellent balance in mechanical properties and interfacial adhesion.

A study for a Performance analysis of Hybrid heat pump Air conditioning system (복합열원형 히트펌프 냉난방 시스템의 성능분석에 관한 연구)

  • Lim, Hyun-Mook;Park, Hee-Moon;Cho, Soo;Sung, Uk-Joo;Park, Jin-Hoon;Park, Tae-Jin
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1373-1378
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    • 2009
  • This study is aiming comparison and analization between efficiency of hybride air conditioning system which uses low temperature water under dam and air and EHP(Electric Heat Pump). The experimental was carried out with air cooling tests for EHP system having 80HP and composition heat pump system. P-i diagram of both systems and COP was used to derive schemetic and calcuations. As results of the tests, hybride system has 1.4 time higher efficiency coefficient.

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Oxygen Isotope Data of Winter Water in the Western Weddell Sea: Preliminary Results

  • Khim, Boo-Keun;Park, Byong-Kwon;Kang, Sung-Ho
    • Journal of the korean society of oceanography
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    • v.33 no.1-2
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    • pp.1-7
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    • 1998
  • In the western Weddell Sea, winter mixed layer is characterized by near-freezing temperature and higher salinity due to brine injection through sea-ice formation. This layer becomes Winter Water being capped by warmer and less saline Antarctic Surface Water during the sea-ice melt-ing season. In this study, Winter Water was preliminarily identified by the oxygen isotopic com-positions. The ${\delta}^{18}$O values of Winter Water show the progressively increasing trend from south to north in the study area. It presumably reflects the enhanced mixing with Antarctic Surface Water due to the extent of influence by low S'"0 value of sea-ice/glacier meltwater. Correlations between salinity and 6'"0 values of seawater can be used to more generally characterize Winter Water with a view to identification. However, the prediction on the degree of mixing from these relationships needs more detailed isotope data, although this study allows the oxygen isotopic composition of seawater as a tracer to identify the water mass.

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Preparation and Piezoelectrical Properties of PMN-PZT Ceramics Prepared by High-Energy Ball Milling (고에너지볼밀법을 이용한 PMN-PZT 세라믹스의 제조와 압전특성)

  • Myoung, Seong-Jae;Koo, Bon-Keup
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.685-690
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    • 2005
  • Pb(Zr,Ti)$O_{3}$Pb($Mn_{1/3}$$Nb_{2/3}$)$O_{3}$ powder was successfully synthesised by high-energy milling method, and the behavior of low­temperature sintering and piezoelectrical properties of Pb(Zr,Ti)$O_{3}$-Pb($Mn_{1/3}$$Nb_{2/3}$)$O_{3}$ ceramics were investigated as a function of mechanical alloying time. In order to confirm whether the Perovskite phase in this composition was formed by mechanical activation technique or not, we performed X-Ray Diffraction pattern analysis (XRD). The microstructure for the sintered samples were characterized using a Scanning Electronic Microscope (SEM). And the piezoelectrical properties ($k_{p}$ and $Q_{m}$) of the sintered samples was measured using HP 4194A impedance analyzer.

Enhancement of Pulsed-Laser Ablation by Phase Explosion of Liquid (액체의 상폭발 과정에 의한 펄스 레이저 용발률의 증진)

  • Kim, Dong-Sik;Lee, Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.11
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    • pp.1483-1491
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    • 2001
  • Enhancement of pulsed-laser ablation by an artificially deposited liquid film is presented. Measurements of ablation rate, ablation threshold, and surface topography arc performed. Correlation between material ablation and photoacoustic effect is examined by the optical beam deflection method. The dependence of ablation rate on liquid-film thickness and chemical composition is also examined. The results indicate that photomechanical effect in the phase explosion of liquid is responsible for the enhanced ablation. The low critical temperature of liquid induces explosive vaporization with localized photoacoustic excitation in the superheat limit and increases the ablation efficiency. Experiments were carried out utilizing a Q-swiched Nd:YAG laser at near-threshold laser fluences with negligible plasma effect (up to ∼100 MW/cm$^2$).

The Development and Performance Test of a Small Wood Boiler (소형 화목보일러의 개발 및 성능시험)

  • Kim, Sa-Ryang;Lee, Jong-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.3
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    • pp.491-497
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    • 2002
  • In the present study, a new wood boiler was developed through the performance test. The efficiency of the boiler was obtained up to about 63.7%, which is 67% higher than that of conventional wood boiler, about 38.2%. The structure of the new boiler is more complicated than the conventional boiler. The passage of combustion gas is sufficiently long to exchange heat well with heating water. Therefore, the obtained efficiency is so high, and the temperature of exhaust gas was lower than 200$^{\circ}C$, which is as low as that of light oil boiler. The composition of exhaust gas was measured, and the CO gas concentration was obtained more than 3000 ppm. So, it seems that more study is needed to lower the concentration of CO gas.