• 제목/요약/키워드: low temperature composition

검색결과 974건 처리시간 0.028초

PNN-PZT 세라믹스의 저온 소결 및 전기적 특성 평가 (Low Temperature Sintering of PNN-PZT Ceramics and Its Electrical Properties)

  • 이명우;김성진;윤만순;류성림;권순용
    • 한국전기전자재료학회논문지
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    • 제21권12호
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    • pp.1077-1082
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    • 2008
  • To fabricate a multi-layered piezoelectrics/electrodes structure, the piezoelectrics should be sintered at the temperature lower than $950^{\circ}C$ to use the silver electrode, which is cheaper than the electrodes containing noble metals such as Pd and Pt. Therefore, in this study, we modified the composition of $Pb(Zr,Ti)O_3$-based material as $(Pb_{0.98}Cd_{0.02})(Ni_{1/3}Nb_{2/3})_{0.25}Zr_{0.35}Ti_{0.4}O_3$ to lower the sintering temperature and to improve the piezoelectric properties. Small amount of $MnCO_3$, $SiO_2$, and $Pb_3O_4$ were also added to lower the sintering temperature of the ceramic. The prepared raw powders were mixed by using a ball mill for 24 hours. And then the mixed powders were calcinated for 2 hours at $800^{\circ}C$. The calcinated powders were again crushed with the ball mill for 72 hours. The final powders were pressed for making the shape of ${\emptyset}15\;mm$ disk. The disk-type samples were sintered at temperature range of $850{\sim}950^{\circ}C$. The crystal phases of the sintered specimens were perovskite structure without secondary phases. All of the measured electrical properties such as electromechanical coupling coefficients ($k_p$), mechanical quality factors ($Q_m$), and piezoelectric charge constants ($d_{33}$) were decreased with decreasing the sintering temperatures. The electrical properties measured at the sample sintered at $950^{\circ}C$ were 54% of $k_p$, 503 of $Q_m$, and 390 pC/N of $d_{33}$, respectively. These properties were considered to be fairly good for the application of multi-layered piezoelectric generators or actuators.

거제도 능포 정치망 어장의 어획물과 어획량 변동요인 (Catch variation of a set net fishing ground in the coastal waters off Neungpo, Goeje Island)

  • 차병열
    • 수산해양기술연구
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    • 제45권4호
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    • pp.211-222
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    • 2009
  • The fisheries resources by a set net in the coastal waters off Neungpo, Goeje Island from 2003 to 2004 were studied to determine species composition and catch variation. The main fishing period by a set net were from April to December in 2003 and from May to December in 2004. A total weight of 48 species caught through the survey period was 540,688.0kg. Most of them were 44 species of fishes and a few were 4 species of cephalopods. Dominant species was Trachurus japonicus accounting to 57.5% in total catch. Sub-dominant species were Trichiurus lepturus(12.9%), Engraulis japonicus(10.6%), Scomber japonicus(6.9%), Clupea pallasii(4.5%), Todarodes pacificus(2.8%) and Parapristipoma trilineaturm(1.3%). The remnant species showed a low catch, indicating the catch had less than 1% in total, respectively. T. japonicus and T. lepturus were caught throughout the survey period, but C. pallasii, Gadus macrocephalus, Oncorhynchus keta in low temperature season and Thunnus obesus in high temperature season. The fishing ground temperature was 11.7-24.0${^{\circ}C}$ in range and the catch by a set net was higher in autumn than in spring and in summer with the variation of fishing ground temperature. The annual catch by a set net was much higher in 2004 than in 2003 due to high temperature(>17${^{\circ}C}$) and the recruitment of T. japonicus from offshore seas. Therefore we concluded that the catch of Neungpo fishing ground by a set net was highly related to the variation of T. japonicus catch with fishing ground temperature.

Low Temperature Sintering and Microwave Dielectric Properties of 0.85CaWO4-0.15LnNbO4 (Ln = La, Sm) Ceramics

  • Kim, Su-Jung;Kim, Eung-Soo
    • 한국재료학회지
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    • 제17권8호
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    • pp.442-446
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    • 2007
  • Microwave dielectric properties of $0.85CaWO_4-0.15LnNbO_4$ (Ln = La, Sm) ceramics were investigated as a function of the sintering temperature and $Li_2WO_4$ content from 0.8 wt.% to 1.5 wt.%. A single phase with tetragonal scheelite structure was obtained at a given composition ranges. For the specimens with $Li_2WO_4$, the sintering temperature could be effectively reduced from $1150^{\circ}C$ to $900^{\circ}C$ due to the enhancement of sinterability. Dielectric constant (K) of the specimens with $LaNbO_4$ and $SmNbO_4$ was increased with the increase of sintering temperature and/or $Li_2WO_4$ content. However, K of the specimens with $LaNbO_4$ was higher than that of $SmNbO_4$ due to the larger dielectric polarizability $(\alpha)$ of $LaNbO_4$ ($18.08{\AA}$) than that of $SmNbO_4$ ($16.75{\AA}$). With an increase of $Li_2WO_4$ content, Qf value of the specimens with $SmNbO_4$ was decreased, while that of the specimens with $LaNbO_4$ was increased. Temperature coefficient of resonant frequency (TCF) was increased with the increase of $Li_2WO_4$ content.

316L 오스테나이트계 스테인리스강의 저온 플라즈마질화처리시 공정변수가 표면경화층 특성에 미치는 영향 (The Effects of Processing Parameters on Surface Hardening Layer Characteristics of Low Temperature Plasma Nitriding of 316L Austenitic Stainless Steel)

  • 이인섭
    • 한국표면공학회지
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    • 제52권4호
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    • pp.194-202
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    • 2019
  • A systematic investigation was made on the influence of processing parameters such as gas composition and treatment temperature on the surface characteristics of hardened layers of low temperature plasma nitrided 316L Austenitic Stainless Steel. Various nitriding processes were conducted by changing temperature ($370^{\circ}C$ to $430^{\circ}C$) and changing $N_2$ percentage (10% to 25%) for 15 hours in the glow discharge environment of a gas mixture of $N_2$ and $H_2$ in a plasma nitriding system. In this process a constant pressure of 4 Torr was maintained. Increasing nitriding temperature from $370^{\circ}C$ to $430^{\circ}C$, increases the thickness of S phase layer and the surface hardness, and also makes an improvement in corrosion resistance, irrespective of nitrogen percent. On the other hand, increasing nitrogen percent from 10% to 25% at $430^{\circ}C$ decreases corrosion resistance although it increases the surface hardness and the thickness of S phase layer. Therefore, optimized condition was selected as nitriding temperature of $430^{\circ}C$ with 10% nitrogen, as at this condition, the treated sample showed better corrosion resistance. Moreover to further increase the thickness of S phase layer and surface hardness without compromising the corrosion behavior, further research was conducted by fixing the $N_2$ content at 10% with introducing various amount of $CH_4$ content from 0% to 5% in the nitriding atmosphere. The best treatment condition was determined as 10% $N_2$ and 5% $CH_4$ content at $430^{\circ}C$, where the thickness of S phase layer of about $17{\mu}m$ and a surface hardness of $980HV_{0.1}$ were obtained (before treatment $250HV_{0.1}$ hardness). This specimen also showed much higher pitting potential, i.e. better corrosion resistance, than specimens treated at different process conditions and the untreated one.

사천 연안 새우조망에서 부수 어획된 어류의 군집구조 (Species composition of bycatch in the shrimp beam trawl fishery of coastal Sacheon, Korea)

  • 송세현;정재묵;유준택;김희용
    • 수산해양기술연구
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    • 제54권3호
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    • pp.204-216
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    • 2018
  • A study for species composition and abundance of the fish assemblages in the coastal Sacheon Bay, Korea were conducted using monthly collection by a shrimp beam trawl from March 2015 to February 2016. The number of individuals, biomass and species diversity indices fluctuated with the station and month. Of all 73 species collected, the dominant species in terms of numbers were Liparis tanakae, Zoarces gillii, Amblychaeturichthys hexanema, Ricuzenius pinetorum and Pleuronichys cornutus. The peak number of fishes occurred in March and April, whereas the biomass of fishes was highest in April. The numbers and biomass of fishes were lower in February corresponding with the low temperature, and diversity indices were highest in June. Due to those seasonal difference in abundance of the dominant species, fish community were divided into three main groups. In addition, seasonal difference by station of fish community were devided into four main groups. Juvenile fishes of coastal Sacheon were presented during the study period. It presented that the study area served as an important role in spawning and nursery ground for fisheries resource.

Biosynthesis of polyhydroxybutyrate and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by bacillus thuringiensis R-510

  • Park, Sang-Kyu;Lee, Kang-Tae;Kim, Young-Baek;Rhee, Young-Ha
    • Journal of Microbiology
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    • 제35권2호
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    • pp.127-133
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    • 1997
  • Biosynthesis of polyhydroxybutyrate and copolymer consisting of 3-hydroxybutyrate and 3-hydroxyvalerate [poly(3HB-co-3HV)] by Bacillus thuringiensis R-510 grown with glucose or with mixtures of glucose and propionate was investigated. n-Alkanoic acids other than propionate were not precursors of 3HV units. The fraction of 3HV unit in the copolymer increased from 0 to 84 mol% of 3HV. Polymer yield decreased as the fraction of propionate was increased but the molecular weight distribution was not affected by the composition of carbon substrate. The minimum melting temperature (around 65.deg.C) of poly (3HB-co-3HV) copolymers was observed for the polymer bearing approximately 35 mol% of 3HV. Polyhydroxyalkanoates production by this organism was not dependent on nutritional limitation, but remarkably influenced by dissolved oxygen concentration in the culture medium. Low level of dissolved oxygen concentration prevented spore formation in the cells and stimulated the synthesis of polyhydroxyalkanoate. The composition of poly (3HB-co-3HV) produced by B. thuringiensis R-510 lyhydroxyalkanoate. The composition of poly(3HB-co-3HV) propduced by B. thuringiensis R-510 varied according to the growth time. However, there was no evidence that polymers isolated from cells were mixtures of immiscible polymers.

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LTCC 슬러리 및 그린시트의 물성 변화에 미치는 혼합용매 조성의 영향 (Effect of Solvent Mixture on the Properties of LTCC Slurry and Green Sheets)

  • 조범준;박은태
    • 한국재료학회지
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    • 제16권9호
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    • pp.533-537
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    • 2006
  • The effects of binary solvent mixtures with various ratios of toluene and ethanol on the properties of slurries and green sheets were investigated. Viscosity of slurry was changed by varying the ratio of solvent mixture which affected the solubility of binder. The relative solvency behavior of a solvent mixture could be predicted with the Hildebrand solubility parameter(${\delta}$) and hydrogen bonding index( ${\gamma}$). The minimum viscosity, the best dispersion of binder, was reached at the composition of toluene:ethanol=4:6, which corresponded to our forecast. The mechanical properties of green sheets related to evaporation of solvents were influenced by the composition of the solvent mixture. At the azeotrope the skin was formed on a drying cast during the drying process because of fast evaporation. At a range of concentrations over 50wt% toluene, green sheets could not be fully dried at low temperature due to excessive toluene. The mechanical properties of green sheets were excellent at the azeotrope-like composition of toluene:ethanol=4:6 which has a little excess of toluene over the azeotrope.

2007-2009년 매물도에서 새우조망에 의한 어류 종조성의 연변동 (Yearly Fluctuation in the Fish Species Composition of Shrimp Beam Trawls off Maemuldo, Korea, during 2007-2009)

  • 박중연;강현숙;강정하;김진구;유정화;김동선
    • 한국수산과학회지
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    • 제46권5호
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    • pp.619-625
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    • 2013
  • We investigated yearly fluctuation of the fish species composition of beam trawls off Maemuldo in the east southern sea of Korea, from March 2007 to November 2009. A total of 75 fish species were collected during the period. The number of fish species accumulated amounted to 54, 64 and 75 species in 2007, 2008 and 2009, respectively. The number of newly occurring species increased with time. The number of expected resident species in Maemuldo was estimated as 9 species including Conger myrister, Okamejei kenojei and Pholis nebulosa, each of which appeared more than 14 out of a total 27 times. Cluster analysis showed that the years 2007 and 2008 were closely clustered, while the year 2009 was distantly clustered with 2007 and 2008. This may be due to the high catch ratio of Clidoderma asperrimum in 2009 alone, when a low water temperature phenomenon was observed unlike the situation in 2007 and 2008.

Cu2ZnSnSe4 Thin Films Preparation by Pulsed Laser Deposition Using Powder Compacted Target

  • Kim, Kyoo-Ho;Wibowo, Rachmat Adhi;Alfaruqi, M.Hilmy;Ahn, Jong-Heon
    • 한국표면공학회지
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    • 제44권5호
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    • pp.185-189
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    • 2011
  • $Cu_2ZnSnSe_4$ thin films for solar absorber application were prepared by pulsed laser deposition of a synthesized $Cu_2ZnSnSe_4$ compound target. The film's composition revealed that the deposited films possess an identical composition with the target material. Further film compositional control toward a stoichiometric composition was performed by optimizing substrate temperature, deposition time and target rotational speed. At the optimum condition, X-ray diffraction patterns of films showed that the films demonstrated polycrystalline stannite single phase with a high degree of (112) preferred orientation. The absorption coefficient of $Cu_2ZnSnSe_4$ thin films were above 104 cm.1 with a band gap of 1.45 eV. At an optimum condition, films were identified as a p type semiconductor characteristic with a resistivity as low as $10^{-1}{\Omega}cm$ and a carrier concentration in the order of $10^{17}cm^{-3}$.

유채의 지방산조성개량육종에 관한 연구 -제V보 유채재배시기이동에 따른 종실유의 지방산조성변화- (Breeding for Improvement of Fatty Acid Composition in Rapeseed Brassica napus L, -V. Changes of the Fatty Acid Composition of the Rapeseed Oil by the Different Seasonal Planting-)

  • 이정일;지하민부;고류겸치
    • 한국작물학회지
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    • 제19권
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    • pp.78-82
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    • 1975
  • 1. 재배시기이동에 따른 유채종자유에 따른 지방산조성은 지방산의 종류에 따라 함량이 높은 Erucic acid가 가장 큰 차이를 나타냈으며 함량이 적은 지방산의 변동은 적었다. 2. 추파재배한 유채종자가 춘파재배한 것보다 Erucic acid함량이 높은데 대해서 Oleic acid와 Linoleic acid함량은 반대로 낮었다. 이들 차이는 1%수준에서 유의차가 있었다. 3. 추파재배된 유채종자가 Erucic acid함량이 높았으며 이는 등숙기간의 적산온도가 낮고 강수량이 많은데 있다. 이들 기상조건과 Erucic acid간에는 높은 상관관계가 있었다. 4. 단쇄지방산인 Oleic acid와 Linoleic aci의 증감경향은 항상 정상관관계가 있으며 장쇄지방산인 Erucic acid와는 부의 상관관계에 있었다.

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