• Title/Summary/Keyword: low pressure hydrogen

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The experimental study on the emission characteristics of the coal gas in the condition of high pressure combustion (석탄가스 고압연소시 배기가스 배출특성에 관한 실험적 연구)

  • Hong, Sung Joo;Lee, Min Chul;Kim, Ki Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.134-134
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    • 2010
  • Recently, the interest of the study about IGCC(Integrated Gasification Combined Cycle), one of New & Renewable Energy technologies, bas been increased due to the United Nations Framework Convention on Climate Change, the Low Carbon Green Growth policy, etc. Also, with this interest of IGCC, the study on the gas turbine utilizing the synthetic gas is performing actively. In the study of the gas turbine characteristic, the power performance and the combustion efficiency are mainly discussed and also the concern about the exhaust gas is being taken care of due to the increasing awareness of the environment. With this, we would like to go over the exhaust gas emission characteristic by the synthetic gas inflow in this test. In order to conduct such a test, we constructed a synthetic gas supplying system to supply the synthetic gases ($H_2$: hydrogen, $N_2$: nitrogen, CO: carbon monoxide, $CO_2$: carbon dioxide, and $H_2O$: steam) quantitatively and this combustion test was conducted by controlling the supplied synthetic gases artificially. The concentration of the exhaust gases appeared variously depending on the differences of the inflow nitrogen amount and the steam amount, whether or not the carbon dioxide flow in and so on. The results of the test can be able to be utilized for the IGCC study by understanding the exhaust gas emission characteristic of the coal gas turbine by synthetic gas composition.

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A Survey of Elementary School Students' Conceptions of Gas and an Analysis on the Type of Alternative Conceptions of Gas (기체에 대한 초등학생들의 개념 조사 및 대안 개념 유형 분석)

  • Jung, Dai-Kyun;Lee, Hea-Jung;Jeong, Sun-Hee;Oh, Chang-Ho;Park, Kuk-Tae
    • Journal of Korean Elementary Science Education
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    • v.26 no.4
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    • pp.359-371
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    • 2007
  • The purpose of this study was to investigate elementary school students' conceptions of gas and analyse the type of alternative conceptions of gas which students constructed. To appreciate the conceptions formed by elementary school students on this topic, 173 sixth grade students from an elementary school located in Suwon participated in this study. Additionally, their conceptions and their alternative conceptions of gas represented by the questionnaires were analyzed. The questionnaires consisted of 11 questions related to the conception of gas. To analyze the types of alternative conceptions which presented themselves, constructed prototypes were generated by interviewing the students themselves. From our results, we suggest that sixth grade elementary school students have various conceptions of gas and tend to think that gas is weighty, and that gaseous volume decreases by pressure. However, their conceptions of gas melting in water were very low, as only about 16% of students were aware of this scientific conception. Students who did not understand precisely the conception of the nature of oxygen, carbon dioxide and hydrogen were over 20%. The results of the interviews showed that the construction of alternative conceptions of gas was affected by various and complex causes.

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The Injection Characteristics and Environmental Effects for Grouting Materials (지반주입재 종류별 주입특성 및 환경적 유해성에 관한 연구)

  • Chun, Byung-Sik;Lee, Jae-Young;Ha, Kwang-Hyun
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.4
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    • pp.37-49
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    • 2002
  • In this study, it is performed that mix design of grouting materials which high strength, durability and environmentally safe materials for 2 types of suspension, solution grouting. The laboratory model tests such as permeation, solidification tests are performed to find injection effects by the injection pressure, soil condition. And environmental effects of the grouting materials is analyzed through the heavy-metal leaching tests. From the results, micro cement of suspension grouting superior permeation, solidification injection to Portland cement, and phosphoric acid and sodium hydrogen carbonate in solution grouting were similar to micro cement of suspension grouting. When compare to strength of grouted soils, micro cement of suspension grouting showed high compression strength to Portland cement. While, solution grouting showed very low compression strength comparing suspension grouting. Also, in the heavy-metal leaching tests results were satisfied with the environmental regulation standard for raw grouting materials and grouted soil by 7, 14, 28days curing.

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Effects of Additives on Yield of Coal Liquefaction (석탄액화시 첨가제에 의한 수율 향상 효과)

  • 김종원;명광식;김연순;심규성;한상도
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.176-182
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    • 1996
  • The effects of some additives (black liquor, NaOH, water and wood) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around 375$^{\circ}C$. The addition of black liquor enhances the coal conversion yield about 38.6%, which is mainly due to NaOH in black liquor. Also, sulfur of the black liquor in coal liquefaction process evolved hydrogen sulfide, which causes the odor problem. Addition of water in coal liquefaction increased CO$_2$content in the gas phase, and low boiling range components in liquid products. Coprocessing of wood and coal at 400$^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above 400$^{\circ}C$ reduced liquid product due to increase of gas products.

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Modified parity space averaging approaches for online cross-calibration of redundant sensors in nuclear reactors

  • Kassim, Moath;Heo, Gyunyoung
    • Nuclear Engineering and Technology
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    • v.50 no.4
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    • pp.589-598
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    • 2018
  • To maintain safety and reliability of reactors, redundant sensors are usually used to measure critical variables and estimate their averaged time-dependency. Nonhealthy sensors can badly influence the estimation result of the process variable. Since online condition monitoring was introduced, the online cross-calibration method has been widely used to detect any anomaly of sensor readings among the redundant group. The cross-calibration method has four main averaging techniques: simple averaging, band averaging, weighted averaging, and parity space averaging (PSA). PSA is used to weigh redundant signals based on their error bounds and their band consistency. Using the consistency weighting factor (C), PSA assigns more weight to consistent signals that have shared bands, based on how many bands they share, and gives inconsistent signals of very low weight. In this article, three approaches are introduced for improving the PSA technique: the first is to add another consistency factor, so called trend consistency (TC), to include a consideration of the preserving of any characteristic edge that reflects the behavior of equipment/component measured by the process parameter; the second approach proposes replacing the error bound/accuracy based weighting factor ($W^a$) with a weighting factor based on the Euclidean distance ($W^d$), and the third approach proposes applying $W^d$, TC, and C, all together. Cold neutron source data sets of four redundant hydrogen pressure transmitters from a research reactor were used to perform the validation and verification. Results showed that the second and third modified approaches lead to reasonable improvement of the PSA technique. All approaches implemented in this study were similar in that they have the capability to (1) identify and isolate a drifted sensor that should undergo calibration, (2) identify a faulty sensor/s due to long and continuous missing data range, and (3) identify a healthy sensor.

A Study on Metal Hydride Electrode of Ni/MH Battery(I) (니켈/금속수소 축전지의 금속수소 전극에 관한 연구(I))

  • Kim, Jeong-Seon;Cho, Won-Il;Cho, Byung-Won;Yun, Kyung-Suk;Kim, Sang-Ju;Shin, Chee-Burm
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.81-89
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    • 1994
  • A study on Mm type electrode which is relatively high in electrode capacity and low in material cost was performed to develope high performance nickel-metal hydride battery. The electrode characteristics were investigated by P-C-T, charge-discharge and microencapsulation treatment experiments. The plateau pressure and hydrogen absorption capacity obtained from the P-C-T experiment were 0.4 atm and 310 mAh/g, respectively. The electrode capacity and stability of microencapsulated electrode were improved than those of conductor mixed electrode and the microencapsulation was possible without pretreatment. The electrode capacity of microencapsulated Mm type alloy was 240~250 mAh/g(0.2 C).

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The Effect of Different Particle Size from PAHs Contaminated Sediment by Ultrasonic Irradiation (PAHs로 오염된 침전물의 초음파 처리시 입자크기가 미치는 영향)

  • Na, Seung-Min;Khim, Jee-Hyeong;Cui, Ming-Can;Ahn, Yun-Gyong;Weavers, Linda K.
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.379-387
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    • 2010
  • Sediments of Little Scioto (LS) River in Ohio was contaminated by poor disposal of creosote from Baker Wood Creosoting Facility. Among the primary compounds of creosote, Polycyclic Aromatic Hydrocarbons (PAHs) are the most common ingredient PAHs are known for toxic, carcinogenic and mutagenic compounds. There are many difficulties to remove the PAHs in nature environment because their characteristics are having a less water-solubility, volatile and low mobility properties as increasing the molecular weight. The generation of hydroxyl radicals (${\cdot}OH$) and hydrogen peroxide ($H_2O_2$) forms as well as high temperature (5000 K) and pressure (1000 atm) by a physico-chemical effects of ultrasound during a cavitation collapse can promote the degradation and desorption of PAHs in sediment And it can also produces shock wave and microjets which are able to change the size and surface of particle in solid-liquid system as one of physical effects. Therefore, we explored to understand the role of particle size, the effect of elimination for PAHs concentration by ultrasound and optimize the conditions for ultrasonic treatment. The condition of various size of particles (> $150{\mu}m$, < $150{\mu}m$) and solid-liquid ratio (12.5g/L, 25g/L) for the treatment was considered and ultrasonic power (430 W/L) with liquid - hexane extraction and microwave extraction method were applied after ultrasound treatment.

Safety Assessment of By-product Gas Piping after Design Change (부생가스 연료배관의 설계변경에 따른 안전성 평가)

  • Yoon, Kee Bong;Nguyen, Van Giang;Nguyen, Tuan Son;Jeong, Seong Yong;Lee, Joo Young;Kim, Ji Yoon
    • Journal of the Korean Institute of Gas
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    • v.17 no.2
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    • pp.50-58
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    • 2013
  • Various process piping usually carries out high flammable and explosible gas under high pressure and high temperature. Due to frequent change of design and structure it becomes more complicated and compactly located. The safety management level is relatively low since it is considered as simply designed component. In this study a safety assessment procedure is proposed for complicated piping system around a mixing drum in which natural gas and by-product gases were mixed. According to ASME code, pipe stress analysis was conducted for determining design margin at some key locations of the piping. These high stress locations can be used as major inspection points for managing the pipe integrity. Sensitivity analysis with outside temperature of the pipe and support constraint condition. Possible effect of hydroen gas to the pipe steel during the previous use of the by-product gas was also discussed.

Performance Analysis of Methanol Fueled Marine Solid Oxide Fuel Cell and Gas Turbine Hybrid Power System (메탄올 연료형 SOFC/GT 하이브리드시스템의 성능 평가)

  • Oh, Sae-Gin;Lim, Tae-Woo;Kim, Jong-Su;Kil, Byung-Lea;Park, Sang-Kyun;Kim, Mann-Eung;Lee, Kyung-Jin;Oh, Jin-Suk;Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.8
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    • pp.1040-1049
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    • 2010
  • The strengthened regulations for atmospheric emissions from ships have caused a necessity of new, alternative power system in ships for the low pollutant emissions and the high energy efficiency. Recently, new kinds of propulsion power system such as fuel cell system, which use hydrogen as an energy source, have been sincerely considered. The purpose of this work is to predict the performance of methanol fueled SOFC/GT hybrid power system and to analyze the influence of operating temperature of stack, current density of stack, pressure ratio of turbine, temperature effectiveness of recuperator, turbine inlet temperature.

Growth of AlN Thin Film on Sapphire Substrates and ZnO Templates by RF-magnetron Sputtering (RF 마그네트론 스퍼터링법을 이용하여 사파이어 기판과 ZnO 박막 위에 증착한 AlN 박막의 특성분석)

  • Na, Hyun-Seok
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.58-65
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    • 2010
  • AlN thin films were deposited on sapphire substrates and ZnO templates by rf-magnetron sputtering. Powder-sintered AlN target was adopted for source material. Thickness of AlN layer was linearly dependent on plasma power from 50 to 110 W, and it decreased slightly when working pressure increased from 3 to 10 mTorr due to short mean free path of source material sputtered from AlN target by Ar working gas. When $N_2$ gas was mixed with Ar, the thickness of AlN layer decreased significantly because of low sputter yield of nitrogen. AlN layer was also deposited on ZnO template. However, it showed weak thermal stability that the interface between AlN and ZnO was deteriorated by rapid thermal annealing treatment above $700^{\circ}C$. In addition, ZnO layer was largely attacked by MOCVD ambient gas of hydrogen and ammonia around $700^{\circ}C$ through inferior AlN layer deposited by sputtering. And AlN layers were fully peeled off above $900^{\circ}C$.