• Korean Journal of Medicinal Crop Science
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• v.16 no.6
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• pp.439-445
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• 2008

This study was performed to investigate a methodology of improving immune activities of Berberis koreana Palibin by ultra high pressure on low temperature extraction process. Extraction yield was enhanced up to more than 35% by above process, compare to the control and extraction average. The cytotoxicity on human kidney cell (HEK293) was showed below 20.4%, 21.6% in adding 1.0 mg/ml of the highest concentration. Generally, the extracts by ultra high pressure extraction process showed less toxicity about 5% than the other processes. It could tell that toxic materials that existing in the plant could be reduced or broken by ultra high pressure process due to can be broken bond such the hydrogen bond, the electrostatic bond, the van der Waals bond, and the hydrophobic bond, can be broken by high pressure. The result could be employed to develop a new type of functional food from B. koreana Palibin by low temperature high pressure process.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.3
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• pp.307-313
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• 2020

The 3.9 liter diesel engine with a mechanical fuel injection system was converted to di-methyl ether (DME) engine and performance optimized. In order to switch to the DME engine, the plunger of the high pressure fuel pump was replaced and the diameter of the injector nozzle was increased. Through this, the disadvantage of DME having low calorific value per volume can be compensated. To optimize the performance, the number of injector nozzle holes, injector opening pressure, and fuel injection timing were changed. As a result, the optimum number of injector nozzle holes was 5, the injector opening pressure was from 15 MPa to 18 MPa, and the injection timing was 15 crank angle degree before top dead center (CAD BTDC). The power was at the same level as the base diesel engine and nitrogen oxides (NOx) emissions could be reduced.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.255-260
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• 2005

To achieve efficient combustion within a manageable length, a successful fuel injection scheme must provide rapid mixing between the fuel and airstreams. The aim of the present numerical research is to investigate the flame holding and combustion enhancement. Additional fuel into the cavity prevents shear flow impingement on the trailing edge of the cavity. The high temperature freestream flow mixes with the cold hydrogen fuel that is injected into the cavity and raises the fuel temperature remarkably and become to start combustion. The high pressure in the cavity due to the cavity structure and combustion leads the hydrogen fuel to upstream. The shock in the cavity to be generated by the fuel injection joins together and reflects off the ceiling wall. This makes high pressure and low mach number region and makes a small recirculation in this region. This high stagnation temperature is nearly recovered in the shear layer in front of the cavity and leads to start combustion. In the downstream of the cavity, the wall pressure drops significantly. This means that the combustion phenomenon is diminished. Because fuel lumps at the trailing edge of the cavity then it spreads after the cavity so, in this region there is a strong expansion.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.5
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• pp.570-576
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• 2017

Gas turbine system with steam injection has shown outstanding advantages such as high specific power and NOx reduction. In the present work, a comparative exergetic analysis was carried out for Steam Injected Gas Turbine (STIG), Regenerative Steam Injected Gas Turbine (RSTIG), and Regenerative After Fogging Gas Turbine (RAF). Effects of pressure ratio, steam injection ratio and steam injection method on the system performance was theoretically investigated. The results showed that the order of the highest exergy efficiency is RSTIG, RAF, and STIG for low pressure ratios but STIG, RSTIG, and RAF for high pressure ratios. In each arrangement, the combustion chamber has the highest exergy destruction and the compressor has the second one.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.6
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• pp.526-533
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• 2009

In this paper, cycle performance analysis of $CO_2-C_3H_8$ (R744-R290) cascade refrigeration system with internal heat exchanger is presented to offer the basic design data for the operating parameters of the system. The operating parameters considered in this study include subcooling and superheating degree and gas cooling pressure and evaporating temperature in the propane (R290) low temperature cycle and the carbon dioxide (R744) high temperature cycle. The main results were summarized as follows : The COP of cascade refrigeration system of $CO_2-C_3H_8$ (R744-R290) increases with the increasing subcooling degree, but decreases with the increasing superheating degree. The COP of cascade refrigeration system increases with the increasing evaporating temperature, but decreases with the increasing gas cooling pressure. Therefore, superheating and subcooling degree, compressor efficiency, evaporating temperature and gas cooling pressure of $CO_2-C_3H_8$ (R744-R290) cascade refrigeration system have an effect on the COP of this system.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.727-736
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• 2016

Numerical simulations of n-heptane spray characteristics in a constant volume combustion chamber under diesel engine like conditions with increasing ambient gas density ($14.8-142kg/m^3$) and ambient temperature (800-1000 K) respectively were performed to understand the non-vaporizing and vaporizing spray behavior. The effect of fuel temperature (ranging 273-313 K) on spray characteristics was also simulated. In this simulation, spray modeling was implemented into ANSYS FORTE where the initial spray conditions at the nozzle exit and droplet breakups were determined through nozzle flow model and Kelvin-Helmholtz/Rayleigh-Taylor (KH-RT) model. Simulation results were compared with experimentally obtained spray tip penetration result to examine the accuracy. In case of non-vaporizing condition, simulation results show that with an increment of the magnitude of ambient gas density and pressure, the vapor penetration length, liquid penetration length and droplet mass decreases. On the other hand vapor penetration, liquid penetration and droplet mass increases with the increase of ambient temperature at the vaporizing condition. In case of lower injection pressure, vapor tip penetration and droplet mass are increased with a reduction in fuel temperature under the low ambient temperature and pressure.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.4
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• pp.425-435
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• 2014

Simulation studies on catalytic methanation reaction in externally cooled tubular reactor filled with monolithic catalysts were carried out using a general purpose modelling tool $gPROMS^{(R)}$. We investigated the effects of operating parameters such as gas space velocity, temperature and pressure of feeding gas on temperature distribution inside the reactor, overall CO conversion, and chemical composition of product gas. In general, performance of methanation reaction is favored under low temperature and high pressure for a wide range of their values. However, methane production becomes negligible at temperatures below 573K when the reactor temperature is not high enough to ignite methanation reaction. Capacity enhancement of the reactor by increasing gas space velocity and/or gas inlet pressure resulted no significant reduction in reactor performance and heat transfer property of catalyst.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.5
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• pp.355-363
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• 2010

High purity hydrogen, 97-99 vol.%, with CO at just ppm levels was obtained in a fixed bed of iron oxide employing the steam-iron cycle operation with reduction at 823K and oxidation in a steam-$N_2$ mixture at 773K TGA experiments indicated that temperature of the reduction step as well as its duration are important for preventing carbon build-up in iron and the intrusion of $CO_2$ into the hydrogen product. At a reduction temperature of 823K, oxide reduction by $H_2$ was considerably faster than reduction by CO. If the length of the reduction step exceeds optimal value, low levels of methane gas appeared in the off-gas. Furthermore, with longer durations of the reduction step and CO levels in the reducing gas greater than 10 vol.%, carbidization of the iron and/or carbon deposition in the bed exhibited the increasing pressure drop over the bed, eventually rendering the reactor inoperable. Reduction using a reducing gas containing 10 vol.% CO and a optimal reduction duration gave constant $H_2$ flow rates and off-gas composition over 10 redox reaction cycles.

• Korean Journal of Metals and Materials
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• v.56 no.11
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• pp.829-834
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• 2018

Although magnesium-based alloys are attractive materials for hydrogen storage applications, their activation properties, hydrogenation/dehydrogenation kinetics, thermodynamic equilibrium parameters, and degradation characteristics must be improved for practical applications. Further, magnesium poses several risks, including explosion hazard, environmental pollution, insufficient formability, and industrial damage. To overcome these problems, CaO-added Mg alloys, also called Eco-Mg (environment-conscious Mg) alloys, have been developed. In this study, $Eco-MgH_x$ composites were fabricated from Mg-CaO chips by hydrogen-induced mechanical alloying in a high-pressure atmosphere. The balls-to-chips mass ratio (BCR) was varied between a low and high value. The particles obtained were characterized by X-ray diffraction (XRD), and the absorbed hydrogen was quantified by thermogravimetric analysis. The XRD results revealed that the $MgH_2$ peaks broadened for the high BCR. Further, PSA results revealed particles size were decreased from $52{\mu}m$ to $15{\mu}m$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.4
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• pp.267-274
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• 2014

The first Low- and Intermediate-Level Waste (LILW) disposal facility with 6 silos has been constructed in granite host rock saturated with groundwater in Korea. A two-dimensional numerical modeling on gas migration was carried out using TOUGH2 with EOS5 module in the disposal facility. Laboratory-scale experiments were also performed to measure the important properties of silo concrete related with gas migration. The gas entry pressure and relative gas permeability of the concrete was determined to be $0.97{\pm}0.15bar$ and $2.44{\times}10^{-17}m^2$, respectively. The results of the numerical modeling showed that hydrogen gas generated from radioactive wastes was dissolved in groundwater and migrated to biosphere as an aqueous phase. Only a small portion of hydrogen appeared as a gas phase after 1,000 years of gas generation. The results strongly suggested that hydrogen gas does not accumulate inside the disposal facility as a gas phase. Therefore, it is expected that there would be no harmful effects on the integrity of the silo concrete due to gas generation.